ABSTRACT Title of Document: UTILIZING HERBICIDE DEGRADATION PRODUCTS AND ARTIFICIAL SWEETENERS AS STABLE TRACERS TO EXAMINE AGRICULTURAL AND URBAN NUTRIENT SOURCES WITHIN TWO TRIBUTARIES OF THE CHESAPEAKE BAY Lucia Giorgina Geis Asteggiante, Master of Science, 2013 Directed By: Professor Alba Torrents, Department of Civil and Environmental Engineering Eutrophication of the Chesapeake Bay has contributed to a decline in ecosystem health within the watershed. In this study, MESA (a metabolite of metolachlor) and sucralose were proposed as stable that could be used to discriminate nutrient contributions from agricultural versus urban sources. Two estuaries of the Chesapeake Bay were chosen as model systems: the Choptank River (agricultural) and the Anacostia River (urban). Surface water samples were collected and analyzed for herbicides, metabolites, artificial sweeteners and nutrients. Results supported the hypothesis that sucralose is present in waterways influenced by wastewater plants, and MESA was correlated with changes in nitrate concentration in the Choptank indicating agricultural sources. This work provides proof of concept that tracers can be used in the Chesapeake Bay region to distinguish the influence of urban and agricultural nutrient loads and provides a path to better assess restoration efforts and improved allocation of total maximum daily loads. UTILIZING HERBICIDE DEGRADATION PRODUCTS AND ARTIFICIAL SWEETENERS AS STABLE TRACERS TO EXAMINE AGRICULTURAL AND URBAN NUTRIENT SOURCES WITHIN TWO TRIBUTARIES OF THE CHESAPEAKE BAY By Lucia Giorgina Geis Asteggiante Thesis submitted to the Faculty of the Graduate School of the University of Maryland, College Park, in partial fulfillment of the requirements for the degree of Master of Science 2013 Advisory Committee: Professor Alba Torrents, Chair Dr. Laura McConnell Professor Allen Davis ? Copyright by Lucia Giorgina Geis Asteggiante 2013 ii Dedication To my mother and siblings for their love and support iii Acknowledgements I would like to thank my advisors Dr. Alba Torrents and Dr. Laura McConnell for their patience and support. Also, I would like to acknowledge Dr. Gregory McCarty and Dr. Cathleen Hapeman, who together with my advisors have provided me of insightful conversations. I would like to express my sincere appreciation to Romina Heymann and Janie Dubois from the Joint Institute for Food Safety and Applied Nutrition, who kindly lend me their instrumentation for sample analysis. I am deeply grateful for the extraordinary help of Peter Downey and Alexander White, when doing sampling work, and for the endless encouragement, understanding and friendship of Anh Nguyen. I must also thank the amazing group of students with which I had the opportunity to share this process. Last but not least, I would like to thank my siblings and friends for their love and inspiration, my mother Sheila for giving me the strength and will needed to reach what I aspire in life, and Gian Marco for believing in me and making of this process a wonderful memory. iv Abbreviations 13C-2,4-D 13C-2,4-dichlorophenoxyacetic acid 13C-GLU 13C-Glucose 2,4-D 2,4-dichlorophenoxyacetic acid ACE acesulfame ACE-d4 acesulfame-d4 ACT acetochlor ACT-ESA acetochlor ethanesulfonic acid ACT-OXA acetochlor oxanilic acid ALA alachlor ALA-d13 alachlor-d13 ALA-ESA alachlor ethanesulfonic acid ALA-OXA alachlor oxanilic acid ATZ atrazine ATZ-d5 atrazine-d5 AWRP Anacostia Watershed Restoration Partnership BARC Beltsville Agricultural Research Center BMP best management practices CAAT desethyl-desisopropyl-atrazine CBI Chesapeake Bay Institute CE collision energy CEAT atrazine-desisopropyl CIAT atrazine-desethyl v CYL cyclamate DAD diode array detector DO dissolved oxygen ELISA Enzyme-linked inmmunosorbent assay ENR Enhanced Nutrient Removal GC Gas Chromatography HLB hydrophilic-lipophilic balanced HPLC High Performance Liquid Chromatography IS internal standard LC Liquid Chromatography LCL lowest calibration limit LOD limit of detection LOQ limit of quantification MAX mixed-mode anion exchange MCX mixed-mode cation exchange ME matrix effect MESA metolachlor ethanesulfonic acid MET metolachlor MET-d6 metolachlor-d6 MET-OH metolachlor-2-hydroxy MET-OXA metolachlor oxanilic acid MGD million gallons a day MM matrix-matched vi MS Mass Spectrometry MS/MS tandem Mass Spectrometry N nitrogen NPDES National Pollutant Elimination System OIET atrazine-2-hydroxy OP ortho-phosphorus P phosphorus PAH polycyclic aromatic hydrocarbons PCB polychlorinated biphenyl PDU poorly drained uplands QA quality assurance QC quality control RL reporting limit RSD relative standard deviation Rt retention time SAC saccharine SAT soil aquifer treatment SAV subaquatic vegetation SAX strong anion exchange SD standard deviation SDB styrol-divinylbenzene SPE Solid Phase Extraction SUC sucralose vii SUC-d6 sucralose-d6 TBZ terbuthylazine TKN total Kjeldahl nitrogen TMDL total maximum daily load TN total nitrogen TP total phosphorus TPP triphenylphosphate TSS total suspended solids UHPLC Ultra High Performance Liquid Chromatography US EPA United States Environmental Protection Agency US FDA United States Food and Drug Administration USDA United States Department of Agriculture USGS United States Geological Survey WAX weak anion exchange WDU well drained uplands WW wastewater WWTP wastewater treatment plant viii Table of Contents Dedication ........................................................................................................................... ii Acknowledgements ............................................................................................................ iii Abbreviations ..................................................................................................................... iv Table of Contents ............................................................................................................. viii List of Tables ...................................................................................................................... x Chapter 1: Introduction .................................................................................................... 1 Chapter 2: Literature Review ........................................................................................... 4 2.1 The Chesapeake Bay, eutrophication and agreements ........................................... 4 2.1.1 Nutrient enrichment and eutrophication ......................................................... 6 2.1.2 Nutrient dynamics ........................................................................................... 8 2.2 Choptank River ...................................................................................................... 9 2.3 Anacostia River .................................................................................................... 13 2.4 Organic tracers and their application for nutrient source determination ............. 16 2.4.1 MESA the nitrate tracer for agricultural sources .......................................... 17 2.4.2 Sucralose a tracer of contamination from urban sources .............................. 20 Chapter 3: Materials and Methods ................................................................................. 24 3.1 Materials .............................................................................................................. 24 3.2 Sites selection for Choptank River watersheds .................................................... 27 3.3 Sites selection for Anacostia River watersheds ................................................... 27 3.4 Sample collection ................................................................................................. 30 3.5 Nutrient analysis .................................................................................................. 30 3.6 Extraction of organic tracers ................................................................................ 31 3.7 LC-MS/MS conditions ......................................................................................... 33 Chapter 4: Results and Discussion ................................................................................. 36 4.1 MS and chromatographic optimization ................................................................ 36 4.2 Method validation ................................................................................................ 39 4.2.1 Sensitivity and linearity assessment .............................................................. 39 4.2.2 Identification and quantification criteria ....................................................... 40 4.2.3 Recoveries and precision .............................................................................. 42 4.2.4 Evaluation of matrix effects (MEs) ............................................................... 46 4.3 Choptank River analysis ...................................................................................... 48 4.3.1 Nutrients levels and fate ................................................................................ 50 4.3.2 Herbicides and artificial sweeteners fate ...................................................... 51 4.4 Anacostia River analysis ...................................................................................... 62 4.4.1 Nutrients levels and fate ............................................................................... 62 4.4.2 Herbicides and artificial sweeteners fate ...................................................... 66 4.5. Estimation of daily loads and comparison with TMDLs ....................................... 75 Chapter 5: Conclusions .................................................................................................. 77 Appendices ........................................................................................................................ 80 APPENDIX A ? Equations and calculations ................................................................ 80 APPENDIX B ? Recovery test raw data ....................................................................... 81 APPENDIX C ? Nutrient Analysis report .................................................................. 115 ix C.1 Data provided by ENVIRO-CHEM LABORATORIES, INC. for Choptank River samples .......................................................................................................... 115 C.2 Data provided by ENVIRO-CHEM LABORATORIES, INC. for Anacostia River samples .......................................................................................................... 117 APPENDIX D ? Organic compounds analysis ........................................................... 119 D.1 Raw data for Choptank River analysis - IS correction is not shown in this data sheet ........................................................................................................................ 119 D.2 Raw data for Anacostia River analysis - IS correction is not shown in this data sheet ........................................................................................................................ 193 References ....................................................................................................................... 254 x List of Tables Table 1. Location and flows of WWTP that discharge into the Choptank River ............. 13 Table 2. Anacostia watershed population and residential, industrial, forested and agricultural land percentages for some of the subwatersheds under study. .............. 14 Table 3. Physicochemical properties and acceptable daily intake information of selected artificial sweeteners .................................................................................................. 21 Table 4. Optimized MS/MS parameters, ionization modes used and retention times for the analytes under study. ........................................................................................... 35 Table 5. Average ion ratios and standard deviation (SD) obtained from calibration curve standards (n=22). ...................................................................................................... 42 Table 6. Percent recoveries (%Rec) and relative standard deviation (%RSD) for low, medium and high spiking levels (n=5 each). ............................................................ 45 Table 7. Matrix effects observed for the ?river matrix? sample consisting of a mix of all the samples collected. ............................................................................................... 47 Table 8. Water quality data, coordinates and discharge rate for Choptank River by location sampled. ...................................................................................................... 49 Table 9. Quantified nutrients, herbicides, herbicides metabolites and sucralose in Choptank River surface water by location sampled. ................................................ 54 Table 10. Water quality data, coordinates and discharge rates for Anacostia River by location sampled. ...................................................................................................... 65 Table 11. Quantified nutrients, herbicides, herbicides metabolites and sucralose in Anacostia River surface water by location sampled. ................................................ 73 Table 12. Daily loads estimated for the watersheds with discharge flow available (m3/s). ................................................................................................................................... 75 xi List of Figures Figure 1. Map of the Chesapeake Bay. Choptank River watershed is represented in pink and Anacostia River watershed in orange. .................................................................. 6 Figure 2. Chemical structures of the analytes under study ............................................... 25 Figure 3. Choptank River sampling and WWTPs locations ............................................. 28 Figure 4. Anacostia River sampling locations .................................................................. 29 Figure 5. Gradient used in UHPLC to achieve separation of the analytes. A ? Water 0.1 percent formic acid and B ? MeOH 0.1 percent formic acid. ................................... 34 Figure 6. Total ion chromatogram of a mix standard solution at a concentration of 100 ng/L in 50:50 (v/v) MeOH:H2O. ............................................................................... 38 Figure 7. Concentration of a) nitrate and OP; b) MET and MESA; c) ATZ; and d) SUC versus salinity. Linear trends and R2 are shown for each analyte. ............................ 56 Figure 8. Concentrations (?g/L) found for a) ATZ and its metabolites and b) for ATZ and MET by site sampled. ............................................................................................... 58 Figure 9. Concentration of MESA versus a) nitrate and b) OP. Linear trends and R2 are shown for each analyte. ............................................................................................. 59 Figure 10. Concentration of SUC versus OP. Linear trend and R2 are shown. ................. 61 Figure 11. Concentrations (?g/L) found for a) ATZ and its metabolites and b) for MET, MESA and SUC by site sampled. ............................................................................. 67 Figure 12. Concentration of MESA versus percentage of land used in agriculture. Linear trend and R2 are shown. ............................................................................................. 69 Figure 13. Relationship of: a) OP concentration versus SUC concentration normalized by population in each subwatershed; b) SUC concentration versus residential and industrial land use; c) SUC concentration versus forested land percentage. ............ 72 1 Chapter 1: Introduction Nutrient pollution in the Chesapeake Bay has been a serious concern for decades. Several restoration efforts were designed and implemented during the past 30 years in order to improve the water quality in the Bay. Many restoration efforts such as the increase of riparian forest buffers and wetland acreage are presumed to work on a large scale but were only tested to be effective in experiments at a field scale. Moreover, total maximum daily loads (TMDLs) have been established for many impaired segments of the Bay. These TMDLs allocate the daily amount of nutrients or other pollutants that can enter a waterway and are designed to achieve overall reductions for the entire Chesapeake Bay system. A main limitation when attempting to assess the effectiveness of these restoration efforts is our ability to determine what are the main contributors of nutrient pollution in the waterway under consideration. An approach to discriminate possible contributions is the use of tracers for nitrate and dissolved phosphorus (OP). A tracer is a chemical that is stable, has only one source and its fate and transport is similar to the pollutant of concern. Previous research done by several scientists at the US Department of Agriculture (USDA) in Beltsville, MD, US Geological Survey and National Oceanic and Atmospheric Administration have established that metolachlor ethanesulfonic acid (MESA), a metabolite of metolachlor, could be used as a tracer for nitrate that enters to the Choptank River only from agricultural sources. Likewise, in the recent years artificial sweeteners such as sucralose and acesulfame have been proposed as good tracers to assess wastewater contributions to groundwater and surface water. To the best of my knowledge, tracers that account for nutrient pollution from wastewater and other anthropogenic inputs in the Choptank River and Anacostia River have not yet been 2 assessed. Furthermore, even though sucralose has been associated to wastewater contamination before, the relationship between sucralose and nitrate and dissolved phosphorus has not been studied. The aim of this work is to assess the use of tracers as possible surrogate markers to discriminate the nutrient contributions from agricultural versus urban sources. In this study Choptank River and Anacostia River were sampled and analyzed simultaneously for nutrients, herbicides, their metabolites and artificial sweeteners. For Choptank River, 13 sites were selected to include tidal and non-tidal waters. The Choptank River watershed contains heavy agricultural activity in the uplands and more residential areas near the mouth including two large wastewater treatment plants. For the Anacostia River 11 non-tidal and tidal sites were sampled. The Beltsville Agricultural Research Center is located in the upper Anacostia watershed and may be a significant source of agricultural nitrate and phosphorus. The remaining areas of the watershed are both residential and urban, with some forested areas. This study was divided into two main objectives. The first objective was to develop an analytical multi-residue method that could effectively quantify MESA and sucralose with another 15 analytes of interest. Method development was constrained to a USDA previously developed extraction method for herbicide metabolites, as there was a significant interest to apply the method developed to a broad set of archive samples previously extracted and stored. Hence, the existent extraction method developed for 9 herbicide metabolites was extended for analysis of 17 analytes, including parent herbicides and artificial sweeteners. The second objective was to select adequate sampling locations in the Choptank River and Anacostia River watershed and analyze the 3 samples for the presence of nutrients, herbicides, herbicides metabolites and artificial sweeteners. The results obtained were used to evaluate possible relationships between the proposed tracers, MESA and sucralose, and the nutrients measured. When doing data interpretations other factors such as land use and hydrogeology characteristics will be considered. Ultimately, the method developed in this project will be utilized to initiate a long- term project examining the strength of agricultural and urban sources of nutrients in each of these watersheds. This information will allow for better assessment of TMDLs and evaluation of the effectiveness of the restoration efforts applied for the different type of sources. 4 Chapter 2: Literature Review 2.1 The Chesapeake Bay, eutrophication and agreements The Choptank and Anacostia River, focus of this work, are two of more than 50 tributaries of United States largest estuary, the Chesapeake Bay, which is located in the mid-Atlantic region (see Figure 1). Centuries ago, the Bay consisted of clear-waters, rich on vegetation such as meadows of grass, forest and wetlands with a variety of aquatic wildlife. The European migration caused a population expansion, which adversely affected the environment and natural resources provided by the Bay. The first hypoxic conditions were estimated to happen near 1760, due to increase on nutrient loading during this strong agricultural period (Curtin et al., 2001). Nutrients in excess cause eutrophication increasing the appearance of algal blooms, and hence reducing the amount of dissolved oxygen (DO). Nevertheless, dissolved oxygen measurements were not done systematically until 1949, after the Chesapeake Bay Institute (CBI) was founded in 1947 (Curtin et al., 2001). The increasing awareness about water quality and its effects on the environment lead to the creation of the Chesapeake Bay Program partnership in 1983, where the State of Maryland, Pennsylvania, Virginia, the District of Columbia, the Chesapeake Bay Commission and the U.S. Environmental Protection Agency (US EPA) sign an agreement to protect the Bay and establish restoration efforts. In 1987, a second agreement was signed, which objective was ?to equitably achieve by the year 2000 at least 40 percent reduction of the nitrogen and phosphorus entering the main stem of the Chesapeake Bay ? based on agreed-upon 1985 point source loads and on nonpoint loads in an average rainfall year? (Chesapeake Executive Council, 1987). In 2000, the Chesapeake Bay Program partners sign a new agreement, which continued with their goal 5 of a 40 percent reduction of nutrient inputs, but created new strategies which needed a ?tributary-specific? approach after the Clean Water Act deemed many parts of the Chesapeake Bay as ?impaired?. Other goals set were better harvest control, habitat restoration from a more ecological point of view, increase on mileage of riparian forest that act as buffer for contaminants, restoration of wetland and continue educating the society in best management practices to improve land use impacts (Chesapeake Bay Program (U.S.), 2000). In 2003, the US EPA published the Chesapeake Bay water quality criteria, which was the basis for later development of the Total Maximum Daily Loads (TMDLs). The establishment of TMDLs took several years of thorough study, water quality assessment and data analysis from many stakeholders. The TMDLs are a ?pollution diet? specified for the main contaminants of each Chesapeake Bay segment. They refer to the maximum pollutant load entering to the water body, which complies with water quality standards set in the Clean Water Act (US EPA, 2010a). TMDLs have been completed and compiled in the US EPA website (http://ofmpub.epa.gov/waters10/attains_index.control), for many sections of the Chesapeake Bay. Currently, the water quality in the Bay is poor. Even though pollutant trends showed a decrease on nutrients, their levels are still high. Only five percent of tidal waters have the needed clarity levels, 28 percent have no chemical contaminant impairment and 34 percent of total waters (open water, deep water and deep channel water) presented an adequate level of DO during the summer (Chesapeake Bay Program (U.S.), 2013). 6 Figure 1. Map of the Chesapeake Bay. Choptank River watershed is represented in pink and Anacostia River watershed in orange. 2.1.1 Nutrient enrichment and eutrophication The Chesapeake Bay is an estuary of approximately 300 Km long, 167.000 Km2 of watershed and with a mean depth of 6.5 m and maximum depth of 30 m. The estuary is formed by the combination of freshwater (oligohaline), coming from the upper-Bay, and seawater (polyhaline) coming from the ocean. The mid-Bay area has a medium salinity level (mesohaline), and it is the region with larger depths (Kemp et al., 2005). Density stratification is a natural process in the Bay; it is caused by temperature and salinity gradients, which are more noticeable during late spring and summer. Density stratification causes a reduction on the concentration of DO, which in healthy environments would be reversible (Hagy et al., 2004). However, it is well known that the 7 Bay suffers of eutrophication due to nutrient enrichment, which exacerbates the DO level reduction reaching hypoxic or even anoxic conditions in the bottom waters during the summer period since 1950 (Hagy et al., 2004). The problem of lower water quality due to eutrophication, its source, effects and restoration approaches have been thoroughly discussed elsewhere (Nixon, 1995; Hagy et al., 2004; Kemp et al., 2005; Boesch et al., 2001). This section will focus on briefly present the main findings on this topic, for the reader to achieve a better understanding of the scenario in which this work developed. Inhabited by a wide variety of animals and plants; the Bay is home of oysters, clams, blue crab and a variety of fish species. Two of the most noticeable living resources harvested every year are oysters and blue crab (Callinectes sapidus), but in the past years their production has decreased significantly due to overharvesting, lower water quality and disease. Overharvesting is the most important factor that affects oysters population, even if it has been under control since 1987 by the corresponding states following the Chesapeake Bay Program Agreements (Chesapeake Bay Program (U.S.), 1995). Kemp et al. (2005) reported that the oyster population in 2005 was one percent compared to two centuries ago. Moreover, it has been reported that the fish community in the Bay, affected by nutrient excess, increased on pelagic species and decreased in demersal species due to loss of benthic habitat (de Leiva Moreno et al., 2000). The Chesapeake Bay Agreement, as stated above, aims to improve the water quality and restore natural habitats. In order to achieve better water quality and therefore a healthier habitat, three important factors need to be controlled: (1) total suspended solids (TSS), (2) nutrient levels, and (3) DO levels. An elevated level of TSS impedes sunlight to reach the necessary depth for submerged aquatic vegetation (SAV) to grow, which is prominent as they produce O2 and provide 8 food and habitat for animals. The increase in nutrient input levels can originate from two main sources: (1) fertilizers used in agriculture and introduced into the Bay by runoff or via groundwater (Whitall et al., 2010); (2) wastewater treatment plants and septic tanks. Nutrient excess causes algae blooms, which would also block sunlight, affecting SAV. Also, the decomposition of organic matter after nutrient stimulation of the ecosystem, leads to subsequent habitat deterioration and living resources and algae decay, which causes DO reduction (even until complete depletion), also producing offensive odors (Boesch et al., 2001). Moreover, the algae may produce dangerous toxins causing fish kills. Ultimately, these processes may modify the ecosystem affecting animal and plant communities (Kemp et al., 2005; Breitburg, 2002; Whitall et al., 2007). 2.1.2 Nutrient dynamics Nutrient dynamics in the Bay has been a topic of interest for the past 35 years and there is a broad knowledge on how the nutrients are imported and exported from the Bay. Boynton et al. (1995) published a detailed work where inputs and losses of nutrients in the Bay were mass-balanced. The authors defined inputs by source type, classifying them into point, diffuse or non-point and atmospheric sources. Point sources are for example wastewater treatment plant outlets and poorly maintained septic tanks; non-point sources include groundwater inputs, precipitation and runoff from crop fields and urban areas. Annual inputs of total nitrogen (TN) and total phosphorus (TP) were estimated for the main stem Bay as 14 g N m-2 yr-1 and 1.1 g P m-2 yr-1, respectively. The main contributor to TN and TP inputs were the non-point sources (60 and 58 percent, respectively), followed by point sources (28 and 35 percent, respectively) and atmospheric wet depositions (12 and 7 percent, respectively). These values corresponded well to Magnien 9 et al. (1995) findings. Losses by denitrification were reported as 26 percent of TN inputs and losses by burial of particulate N were estimated as 35 percent. Burial is the main source of P loss. Losses due to fisheries were estimated and represented less than 10 percent (Boynton et al., 1995). Ultimately, Boynton et al. (1995) concluded that the main stem Bay exported up to 45 percent of TN inputs to the ocean and imported up to 37 percent of TP inputs from the ocean. Seasonal and spatial variations are very important; generally TN and TP concentrations decrease towards the mouth of the Bay, but N and P speciation changes by season. During summer periods N is found in particulate and dissolved organic forms and P is in dissolved inorganic forms in the mid-Bay region (Boynton et al., 1995). Considering that N and P can be recycled, the eutrophication process is significantly worsened, as the nutrients are reused, causing actual loads to be higher than presumed. Hypoxic conditions stimulate recycling due to higher inputs of phosphates from the sediments and inhibition of nitrification, a process that requires oxygen (Boesch et al., 2001). Therefore, summer conditions seriously affect the health of the Bay. 2.2 Choptank River The Choptank River is a tributary located on the eastern side Chesapeake Bay that drains approximately 1800 Km2 of the upper lands of the Delmarva Peninsula. It originates on Kent County in Delaware and crosses Queen Anne?s, Caroline, Talbot and Dorchester counties in Maryland. The river comprises a tidal region, from the mouth of the river to approximately the local US Geological Survey (USGS) monitoring station at Greensboro (USGS 014910000), and non-tidal watersheds above the station and the 10 Tuckahoe Creek sub-basin (McCarty et al., 2008). Some segments of the Choptank River were declared impaired in 1998 under the Federal Clean Water Act due to nutrient enrichment, sediments and fecal coliform. The last report from the US EPA considered all segments to be impaired. The mouth of the river presented excess of nutrients, high turbidity, polychlorinated biphenyls (PCB) and fecal coliforms. Other segments are polluted with nutrients and sediments (US EPA, 2010b). Currently, a report from the Maryland Department of Natural Resources (MD DNR, 2012) shows that the upper Choptank segment is considered impaired due to nutrient excess and sediments, which is expected, as it is an intense agricultural region. In this region no SAV is present and its biota is unhealthy. The water quality in middle Choptank is considered impaired due to high N concentrations, though P and sediments concentrations have improved. Outer Choptank water quality is good, with adequate levels of N, P and sediments. The DO concentrations are generally higher than 3 mg/L, and even though SAV growth is occurring, it is still lower than expected due to the degraded habitat. The slow improvement on the Choptank River water quality and habitat is due to the strong restoration efforts done, which include best management practices (BMP) (winter cover crops and conservation tillage), riparian grass, forest and wetland restoration (McCarty et al., 2008). The Choptank watershed land is mainly used for agriculture (60 percent), which centers on sustaining poultry farms in the area. The principal crops consist on corn (Zea mays L.) and soybean (Glycine max L.) (USDA, 2013). Forested areas cover 30 percent of the total land, but only half corresponds to riparian forest (Norton and Fisher, 2000), 11 wetlands correspond to four percent and urbanized land is approximately six percent (Whitall et al., 2010). The introduction of pollutants into the river is related to the land use. The primary cause of N and P enrichment in the Choptank River is the vast agriculture in the upper region (Whitall et al., 2010). The environmental fate is different depending on the hydrogeomorphic region as they are related to different transport and transformation processes. Phillips et al. (1993) reported an exhaustive description of the Delmarva Peninsula hydrogeomorphic regions and properties. Briefly, the land is categorized into seven hydrogeomorphic regions: well drained uplands (WDU), poorly drained uplands (PDU), surficial confined regions, inner coastal plain and three other coastal lowland regions, which are generally poorly drained and cover a minor area. WDU consists of permeable soils that associate to oxic groundwater, which generally present a higher concentration of nitrate due to denitrification inhibition. PDU presents hydric soils that associate to anoxic groundwater with lower nitrate concentrations (Hively et al., 2011). In 2011, Hively et al. reported that 68 percent of WDU and 55 percent of PDU are used for agriculture. This is an important fact as many PDU can only be used for agriculture after drainage by Public Drainage Association ditches. The drainage of PDU is considered the main cause for significant wetland losses. The amount of wetlands lost by 2002 accounted for 11 percent of the Choptank watershed (MD DNR, 2002). Moreover, drainage ditches should be carefully maintained in order to avoid overflow that causes runoff of pollutants and sediments into the river. Regarding WDU, their high permeable soils allow for a higher flow path of water, polluted with pesticides and nutrients, into the groundwater. 12 Restoration approaches proposed under the Chesapeake Bay Agreement have been applied to the Choptank River Basin. Between 1998 and 2005, agricultural land has been restored to riparian buffers by 11 percent, as part of the Conservation Reserve Enhancement Program (CREP), for a total of 44 percent average riparian buffers. As reported elsewhere (Peterjohn and Correll, 1984; Lowrence et al., 1997; Osborne and Kovacic, 1993; Gilliam, 1994), the use of riparian forest was expected to reduce N by denitrification and plant uptake, and P by sediment retention. However, when Sutton et al. (2010) evaluated the effect of riparian buffers in 15 Choptank River watersheds, no significant differences in N and P concentrations were observed. The authors justified the discrepancy by variation on land type, buffer age and dimensions, which agrees with previous observations (Lowrence et al., 1997; Norton and Fisher, 2000). Wetlands, as stated above, are important because they also promote nutrient removal by denitrification and plant uptake. The application of BMP in agriculture have demonstrated to improve water quality (McCarty et al., 2008) The Choptank watershed has several wastewater treatment plants (WWTP), permitted through the National Pollutant Discharge Elimination System (NPDES), which discharge into the river. They are classified as minor and major WWTP, depending on whether their discharge rate is lower or higher than 0.5 MGD, respectively. Table 1 shows a list of the principal WWTP in the area and their characteristics. Major WWTPs are located in the city of Cambridge and Easton and their average flow rate is at least 5- fold higher, compared to other WWTP present in the watershed. Moreover, from the seven WWTP listed only Easton, Denton and Cambridge have been upgraded to do 13 Enhanced Nutrient Removal (ENR). The Maryland Department of Environment have published a comparison for WWTP projected N and P loadings with and without ENR upgrade, demonstrating that when ENR upgrade is done nutrient loadings into the Chesapeake Bay decrease significantly and its use is necessary in order to achieve the targeted loadings (MDE, 2013). Table 1. Location and flows of WWTP that discharge into the Choptank River (Information provided by Mark Ramirez, Bio-solids Process Engineer at DC Water and Sewer Authority). WWTP Name Latitude Longitude Design Flow (MGD) Average Flow (MGD) Greensboro 38?58'40"N 75?48'8"W 0.25 0.18 Denton 38?52'21"N 75?49'3"W 0.80 0.38 North Caroline High School 38?54'30"N 75?50'28"W 0.02 0.002 Easton 38?44'55"N 76? 0'35"W 4.00 2.00 La Trappe 38?39'44"N 76? 3'57"W 0.20 0.14 Twin Cities 38?36'11"N 75?57'42"W 0.28 N/A Cambridge 38?33'54"N 76? 3'26"W 8.10 2.76 Note: N/A ? not available 2.3 Anacostia River Anacostia River is a tributary of the Potomac River and part of the Chesapeake Bay watershed. It is located on the Piedmont Plateau and Coastal Plain hydrogeomorphic regions, which forms a surficial aquifer that maintains the base flow of the river and other streams and recharges deeper aquifers that supply drinking water to the area (Koterba et al., 2010). Anacostia watershed consists of 14 subwatersheds located in Montgomery and Prince George?s Counties of the State of Maryland, and a tidal region, which is mostly located in Washington D.C. The tidal region is considered to start below the Northeast Branch subwatershed (Miller et al., 2013). The land use in Anacostia watershed is mainly urban or suburban (64 percent) with approximately 7 percent of agriculture, 27 percent of 14 forested or undeveloped areas and 2 percent of wetlands (Fry et al., 2011). Land use by subwatershed was summarized in Table 2 (AWRP, 2013). The US Department of Agriculture (USDA) has 2 municipal WWTPs in the Anacostia watershed, Beltsville Agricultural Research Center (BARC) East Side and BARC West Side, which average flow is estimated to 0.14 and 0.07 MGD, respectively. Table 2. Anacostia watershed population and residential, industrial, forested and agricultural land percentages for some of the subwatersheds under study (AWRP, 2013). Subwatershed Population Residential (%) Industry (%) Forest (%) Agriculture (%) Northwest Branch 172,039 52 - 22 9 Paint Branch 53,659 42 - 26 12 Little Paint Branch 36,900 37 - 31 11 Indian Creek 34,700 26 9 31 11 Upper Beaverdam 21,260 - - 61 17 Still Creek 12,000 32 - 55 - Sligo Creek 81,943 75 8 10 - Northeast Branch 67,911 51 10 26 - Hickey Run* 3,100 29 30 - - Note: * 34% are Park lands Compared to Choptank River, there are many more USGS monitoring stations located on the Anacostia watershed. Systematic water quality measurements started in 2003 and were collected in different years for the various USGS stations. Based on the information gathered, water quality reports have been published by USGS in 2007 and 2013 (Miller et al., 2007, 2013). The first priority on water quality assessment was to 15 evaluate contamination from toxic compounds, such as the pesticide heptachlor epoxide, polycyclic aromatic hydrocarbons (PAHs) and PCBs. A report from the University of the District of Columbia showed the presence of PCBs, PAHs and chlordane when biomonitoring Asian clams (Corbicula fluminea) were used (Phelps, 2005). An important consequence of urbanization and land use is the presence of sediments that rapidly accumulate, especially in storm events (Yorke and Herb, 1978). Hwang and Foster (2006) reported PAHs sediment enrichment during storm flows. USGS reported high yields of suspended solids compared to other watersheds on the Bay, but similar TN and TP yields. Langland et al. (2012) evaluated trends of TSS, TN and TP for a 24-year and 10-year period, in general TN is decreasing or remains unchanged, but TP and TSS increased. Groundwater analysis of wells in Washington DC area was done in 2005 and 2008 by USGS. It was reported that pesticides, including atrazine, simazine and metolachlor, were found mostly in well-drained sites constituted of coarse sediments located in northern areas of the Coastal Plain (Koterba et al., 2010). Anacostia River has completed TMDLs for PCBs (US EPA, 2013a), and local TMDLs were set by the State of Maryland and the District of Columbia for TSS, TN, TP, E. Coli and Enterococci (Miller et al., 2013). The Anacostia Watershed Restoration Committee set restoration efforts in the year 1991 and formed the Anacostia Watershed Restoration Partnership (AWRP) in 2006. Briefly, the restoration efforts involve the reduction of pollutants in order to meet water quality standards, enhancement of aquatic diversity and the creation and expansion of riparian-forested areas and wetlands. Many of these goals are being achieved after 16 intense work during the past 22 years, riparian forest and wetland coverage has increased and fish migration and habitat has improved after reopening almost 50 miles of the stream (AWRP, 2013). 2.4 Organic tracers and their application for nutrient source determination A tracer of water pollution is a compound that is not naturally present in the environment, is stable, hence it should not be chemically or biologically degraded and it should be highly soluble in water with very low adsorption to sediments and soils (low Koc) (Gasser et. al, 2010; McCarty et. al, 2013). Additionally, a good tracer should selectively correlate solely with a pollutant source. This last statement is critical when doing source differentiation and transport studies. Tracers have been previously used in environmental studies to determine the contribution of point source and non-point source contamination of pristine and surface waters and to determine pollutants fate. The selection of a tracer depends on the objective of the study; if the objective is to define a tracer for agricultural pollution, then it would have to comply with all the above- mentioned requirements, and at the same time be applied to the crops on a similar fashion as the pollutant of interest. Tracers have been used for over 3 decades with many different type of tracers used in different studies. Boron isotopes have been used to determine nitrate contamination sources in groundwater (Leenhouts et. al, 1998) and various tracers such as chloride and carbamazepine (Gasser et. al, 2010), human enteric viruses (Hunt et. al 2010), carbamazepine and atrazine (Segura et. al, 2011), caffeine (Buerge et. al, 2003), human steroidal hormones (Zgheib et. al, 2008), human pharmaceuticals (Glassmeyer et. al, 2005; Benotti et. al, 2009) and artificial sweeteners 17 (Mawhinney et. al, 2011; Van Stempvoort et. al, 2011a) were used to determine wastewater contamination of potable and surface water. Also, herbicide metabolites have been used in order to determine nitrate contamination from agricultural sources (McCarty et. al, 2013). Some limitations observed for the above-mentioned tracers are the high background of chloride due to its ubiquity; the need of specialized personal when working with human viruses; the losses of caffeine due to human metabolism and later degradation in WWTPs; and the variable population usage of pharmaceuticals depending on countries regulations. Artificial sweeteners, on the contrary, are highly consumed by individuals and the food industry worldwide, finding them at higher concentrations in wastewater. The analysis of tracers should be simple, selective and sensitive. When developing a method, good accuracy and precision, selectivity, low detection limits and broad dynamic ranges are desired. The extraction method should be tested for matrix effects in order to avoid bias in quantification when using external calibrations. 2.4.1 MESA the nitrate tracer for agricultural sources Non-point sources of nutrients are very difficult to determine and regulate. The use of a tracer that relates solely to agricultural production and correlates to nitrate is very useful for evaluation of non-point source nutrient contamination. The USDA Agriculture Research Service at Beltsville has worked in this area for many years and proposed a metolachlor metabolite, 2-[(2-ethyl-6-methylphenyl)(1-methoxy-2-propanyl)amino]-2- oxoethanesulfonic acid or metolachlor ethanesulfonic acid (MESA), as a nitrate tracer from agricultural sources (McCarty et. al, 2013). 18 Metolachlor is a pre-emergence herbicide mainly used on row crops such as corn and soybean (Phillips et. al 1999). The degradation or detoxification process of metolachlor into ethanesulfonic acid (MESA) and oxanilic acid (MET-OXA) metabolites has been carefully studied in aerobic soils (Aga et al., 1996; Field and Thurman, 1996). Metolachlor can be taken up by plants or by microorganisms and be detoxified by conjugation with glutathione, which substitutes the chlorine in the acetamide group. The transformation from the conjugated intermediary to MESA or MET-OXA requires aerobic conditions, as it follows an oxidation process (Feng, 1991; Field and Thurman, 1996; Van Eerd et al., 2003). Seybold et al. (2001) evaluated the formation of MESA and MET-OXA on anaerobic soils and, as expected, metolachlor degradation is not favorable. To the best of my knowledge, there is not many information about MESA?s physicochemical properties in the literature. Bayless et al. (2008) reported that MESA is very soluble in water (212.5 g/L), presents a low octanol-water partition coefficient (log Kow = -1.23), low soil organic carbon partition coefficient (log Koc = 1.13), low vapor pressure (Vp = 1.61?10 -4 mmHg) and its half life in soil under aerobic conditions was determined to be 70 days. In order for MESA to act as tracer for nitrate, their transport process should be similar. Domagalski et al. (2008a) demonstrated a similar transport for nitrate and MESA on Morgan Creek (MD) and other US watersheds. Moreover, vast data collection and work on Choptank watershed also showed that MESA and nitrate fate are related (Whitall et al., 2010; Hively et al., 2011; McCarty et al., 2013). It is important to notice that though MESA is very stable after entering to the groundwater and streamwater, nitrate is not as it could further undergo denitrification (Domagalski et. al, 19 2008a, 2008b). Therefore, MESA physicochemical properties, degradation and transportation pathways render it a very good tracer for nitrate contamination. The analysis of chloroacetanilide herbicides (metolachlor, alachlor and acetochlor) and its metabolites has considerably improved during the past 20 years due to the significant advances in analytical instrumentation. Initially only the parent herbicides were identified and quantified by gas chromatography coupled with mass spectrometry (GC-MS), but for large monitoring programs this analytical technique was very costly. Pome et al. (1998) developed an inmmunoassay in order to reduce the cost of analysis of triazine and chloroacetanilide herbicides. The enzyme-linked inmmunosorbent assay (ELISA) proved to be effective, with less than 12 percent false positives, but with a rate of false negatives as high as 23 percent. The main limitations of the ELISA is the cross reactivity among analytes with similar structure and, in this case, the high detection limit compared to GC-MS. In order to analyze OXA metabolites by GC-MS a derivatization step was necessary. Generally, derivatization steps are undesired because they are time consuming, have a limited reaction yield and the derivatization reagent could be hazardous. Heberle et al. (2000) used diazomethane, a carcinogenic and explosive, for derivatization of the OXA metabolites of acetochlor, alachlor and metolachlor. In the case of ESA metabolites, GC-MS is not suitable due to the analyte low vapor pressure. The first publications where ESA metabolites were analyzed involved the use of high performance liquid chromatography with diode array detector (HPLC-DAD) (Macomber et al., 1992). Compared to MS, DAD is less selective and it does not provide structural information; hence is more prone to false positive detections. Moreover, when HPLC- DAD is used rigorous confirmation is needed. Around the year 2000 more articles 20 appeared in the literature that used HPLC-MS and tandem MS (HPLC-MS/MS). The major difficulty associated with this technique is the structural similarities among the analytes. A careful selection of product ions is prominent because many of the analytes are isobars (present the same m/z for the precursor) and, as their chemistry is very similar, they elute at similar retention times. Extraction of water samples is generally needed in order to concentrate the sample and achieve good limits of detection (LOD) and quantification (LOQ). The method of preference to concentrate high volumes of water is solid phase extraction (SPE), which is generally time consuming and relatively expensive. Some examples of the stationary phases used in the literature are: reverse phase C-18 (Yokley et al., 2002), Carbopack B (Heberle et al., 2000), ENV (Vargo, 1998), ENV+ (Lehotay et al., 1998) and HLB (McConnell et al., 2007). Reverse phase C-18 cartridges, though commonly used in environmental analysis, present the disadvantage that polar analytes would breakthrough when using high sample volumes (Heberle et al, 2000). Carbopack B consists of graphitized carbon black sorbent, which is very effective for cleanup, but tends to highly retain analytes with aromatic groups and planar structures. ENV and ENV+ focus on extraction of polar to highly polar residues, and HLB (hydrophilic-lipophilic balanced reverse phase) presents a broad polarity range, which allows for the efficient extraction of polar and apolar analytes. Currently, HLB cartridge is the stationary phase of preference in environmental analysis. 2.4.2 Sucralose a tracer of contamination from urban sources Wastewater (WW) discharge and other point sources such as septic tanks leakage and sewer failures, can contribute to surface and groundwater quality degradation. WW 21 discharges are generally regulated and monitored; adequate levels of average daily flow, biological and nutrient loadings are established in order to avoid surface water contamination (US EPA, 2013b). The past several years many authors focus on how to identify and estimate the presence of WW in surface and ground water. Various WW pollutants such as nicotine derivatives (Buerge et al., 2008), carbamazepine and atrazine (Segura et. al, 2011) and artificial sweeteners (e.g., Buerge et al. 2009; Loos et al., 2009; Van Stempvoort et al., 2011a, 2011b; Oppenheimer et al., 2011, 2012; Soh et al., 2011) were evaluated as WW tracers. Sucralose, acesulfame, saccharin and cyclamate are artificial sweeteners, widely used in food and beverages as sugar substitutes (Kroger et al., 2006). They have been approved as sweeteners in the US in 1999, 1988 and 1977 (US FDA, 2013), respectively, except for cyclamate, which has been banned in the US for the past 43 years (Buerge et al., 2009). These compounds are characteristic for their specific anthropogenic nature, high solubility in water, low log Kow, relatively high consumption and scarce metabolism in humans (see Table 3) (Lange et al., 2012). Table 3. Physicochemical properties and acceptable daily intake information of selected artificial sweeteners (Lange et al., 2012) Name Solubility in water (g/L) log Kow ADI (mg/kg bw) Sucralose 283 (20?C) -1.00, -0.51 15 Saccharin sodium 4 0.91 5 Acesulfame potassium 270 (20?C) -1.33 9 Cyclamate 1000, 133 -1.61 - Note: ADI ? acceptable daily intake, bw ? body weight 22 Moreover, sucralose and acesulfame are persistent during conventional mechanical and biological treatments in WWTP (Scheurer et al., 2009). Scheurer et al. (2009) reported removal of 27 to 41 percent for acesulfame, 20 percent for sucralose and higher than 90 percent for saccharin and cyclamate. The Swedish Environmental Research Institute reported sucralose removal of less than 10 percent (Brorstr?m-Lund?n et al., 2008). Buerge et al. (2009) reported insignificant removal of acesulfame and sucralose, and higher than 90 percent removal of saccharin and cyclamate. When soil aquifer treatment (SAT) with residence times higher than 1.5 years is used, sucralose degrades significantly and acesulfame concentrations remain unchanged (Scheurer et al., 2009). Nevertheless, it is important to acknowledge that all above-mentioned literature cases showed such a high influent concentration of sweeteners than even after 90 percent removal, saccharin and cyclamate were detected at concentrations higher than 0.1 ?g/L in effluents. Moreover, sucralose and acesulfame were not found on sludge as expected due to their high water solubility (Buerge et al., 2011). Some drinking water treatment processes such as granular activated carbon (Soh et al., 2011; Scheurer et al., 2010; Minten et al., 2011) and reverse osmosis (Lee et al., 2012) removed sucralose to a moderate extent; ozonation was partly effective for acesulfame removal (Soh et al., 2011; Scheurer et al., 2010; Lee et al., 2012). Similarly, after treatment sucralose and acesulfame have been detected in finished drinking water (Buerge et al., 2009; Scheurer et. al, 2010; Mawhinney et al., 2011). Therefore, sucralose and acesulfame are expected to be found in the environment and are suitable as tracers of WW contamination. 23 Artificial sweeteners analysis in surface and ground water is a fairly new topic. Sample extraction generally involves a SPE concentration step. Gan et al. (2013) in a very thorough work evaluated ten SPE stationary phases (strong anion exchange (SAX), mixed-mode anion exchange (MAX), low carbon loading C-18, high carbon loading C- 18, phenyl, weak anion exchange (WAX), HLB, styrene-divinylbenzene and Waters Oasis WAX and HLB) combined with various buffers and elution solvents. The authors determined that using a WAX cartridge and eluting with methanol 1 mmol/L TRIS gave the best recoveries for the four artificial sweeteners of interest (Gan et al., 2013). Scheurer et al. (2009) also tested several stationary phases (ENV+, C-18, Bond Elut PPL, mixed-mode cation exchange (Strata X), weak anion exchange (Strata X-AW) and Oasis HLB, WAX, MAX and mixed-mode cation exchange (MCX)) but obtained the best recoveries for 7 artificial sweeteners with styrol-divinylbenzene (Bakerbond SDB) and methanol elution. In the case of sucralose analysis Oasis HLB is the stationary phase of preference with no pH adjustment necessary (Oppenheimer et al., 2011; Mawhinney et al. 2011; Ferrer and Thurman, 2010; Loos et al., 2009; Brorstr?m-Lund?n et al., 2008). The analysis of artificial sweeteners is done using LC-MS and LC-MS/MS. Some of the difficulties encountered when analyzing this type of analytes were: (1) the poor fragmentation in negative mode compared with positive (Loos et al., 2009); (2) the formation of sodium adducts that produce low fragmentation, hindering identification; and (3) the high suppression due to matrix effects, which renders the use of isotopically labeled standards indispensable (Lange et al., 2012). All these issues should be taken into account and resolved, if possible, for their potential use as tracers. 24 Chapter 3: Materials and Methods 3.1 Materials All reference standards were stated to be of purity equal or higher than 95 percent. Metolachlor oxanilic acid (MET-OXA), alachlor oxanilic acid (ALA-OXA), acetochlor ethanesulfonic acid (ACT-ESA), 2,4-dichlorophenoxyacetic acid (2,4-D), desethyl- desisopropyl-atrazine (CAAT), atrazine-desisopropyl (CEAT), atrazine-desethyl (CIAT) and atrazine-2-hydroxy (OIET) were obtained from EPA National Standard Pesticide Repository (Ft. Meade, MD). Alachlor-d13 (ALA-d13) and metolachlor-2-hydroxy (MET- OH) were obtained from Crescent Chemical Co. (Islandia, NY). Sucralose (SUC), acesulfame potassium (ACE), saccharin (SAC), triphenylphosphate (TPP) and atrazine-d5 (ATZ-d5) were obtained from Sigma-Aldrich (St. Louis, MO). Terbuthylazine (TBZ), atrazine (ATZ), metolachlor (MET), metolachlor ethanesulfonic acid (MESA), alachlor ethanesulfonic acid (ALA-ESA), acetochlor oxanilic acid (ACT-OXA), acetochlor (ACT) and alachlor (ALA) were obtained from Chem Service (West Chester, PA). 13C-Glucose (13C-GLU) and 13C-2,4-D were obtained from Cambridge Isotope Laboratories (Tewksbury, MA). Metolachlor-d6 (MET-d6), sucralose-d6 (SUC-d6) and acesulfame-d4 (ACE-d4) were obtained from US Biological (Salem, MA). Cyclamate sodium (CYL) was obtained from Supelco (Bellefonte, PA). Chemical structures of each analyte under study are shown in Figure 2. 25 Figure 2. Chemical structures of the analytes under study MET MESA MET-OH MET-OXA ALA ALA-ESA ALA-OXA ACT ACT-ESA ACETOCHLOR OA CAAT CEAT CIAT OIET 2,4-D ATZ TBZ 26 Reagent grade water was prepared using a Picotech UV-Plus (Durham, NC) system. High quality ultrapure water, used for UHPLC-MS/MS analysis, was prepared with a Barnstead RO system obtained from Thermo Scientific (Mariette, OH). Methanol (MeOH) and acetonitrile (MeCN) were HPLC reagent grade obtained from Fisher Scientific (Fair Lawn, NJ). Formic acid 88 percent purity and sulfuric acid 99.9 percent were obtained from Fisher Scientific and Sigma-Aldrich, respectively. Glass microfiber GF/D (150 mm diameter, 2.7 ?m pore size) and GF/F (90 mm diameter, 0.7 ?m pore size) filters, used for water samples filtration, were obtained from Whatman (Florham Park, NJ). Sample filtration previous to injection was done using a 1mL syringe obtained from BD (Franklin Lakes, NJ) with a 13 mm, 0.2 ?m PVDF syringe filter obtained from Waters (Milford, MA). OASIS HLB cartridges for solid phase extraction were also obtained from Waters. Stock solutions were prepared in MeOH, except for CAAT and OIET for which up to 10 percent of H2O was added to improve solubility. Spiking and surrogate solutions were also prepared in MeOH. Working solutions for reagent only and matrix matched calibration curve were prepared in MeOH and H2O to reach an approximate final composition of 50:50 (v/v) MeOH-H2O. Maps of the watersheds under study were done using ArcGIS Software Release 10 from ESRI (Redlands, CA). 27 3.2 Sites selection for Choptank River watersheds In this study, 13 sampling sites were chosen (see Figure 3). The selection was done in order to assess six subwatersheds (non-tidal) and seven sites situated on tidal areas. The sites were selected in order to assess the whole length of the river. Regarding the subwatersheds and following the classification reported by Hively et al. (2011), Long Marsh and Beaverdam are poorly drained uplands, German Branch is a mixture of poorly and well drained uplands and Cordova is a well drained upland. As stated in the Literature Review, well-drained uplands are generally used for agricultural activities, while poorly drained uplands present lower agricultural activity and urban development, and a minor increase on forested land (Hively et al., 2011). The other seven sites are mostly representative of urban areas. Two sites (Horn Point and Oxford Laboratory) were chosen near the mouth of the river and two sites at 50 Bridge were selected next to Cambridge WWTP, 50 Bridge replicates were taken closer to the shore than the sample taken at 50 Bridge further point. The sites of Preston Landing, Frazier Point, Swing Bridge and Kingston Landing cover the middle region of the river and include Easton WWTP. 3.3 Sites selection for Anacostia River watersheds Sampling sites over the Anacostia watershed were selected to comprehend 9 subwatersheds and one tidal site at the National Arboretum (see Figure 4). Locations were chosen to be as close as possible to the subwatershed outlet. This area is quite different compared to Choptank River, the land use is predominately urban and there are only two minor municipal WWTPs in the area. 28 Figure 3. Choptank River sampling and WWTPs locations 29 Figure 4. Anacostia River sampling locations 30 3.4 Sample collection Environmental measurements were obtained for each sampling site, using a YSI 556 Multiparameter Sonde (Yellow Spring, Ohio) to determine temperature, conductivity, total dissolved solids, dissolved oxygen and pH. A GPS, with an accuracy of 10 m, was used to determine on site coordinates. Water samples for nutrient analysis were collected using a peristaltic pump. The tubing used for collection was Teflon, which is a low binding material, avoiding loss of analytes. The samples were placed into 2, previously acid washed, 250 mL glass jars. One jar was used for the analysis of ortho- phosphorus, nitrate and nitrite, which required the addition of 0.25 mL of H2SO4 for sample preservation. The second jar was used for the analysis of total phosphorus (TP) and total Kjeldahl nitrogen (TKN) for which no preservative was added. Water samples for organic tracers analysis were collected at approximately 0.1 m of depth, using a stainless steel metal bucket and stored into stainless steel containers. Three washes with river water were done before the sample was collected. A travel blank sample, consisting of reagent grade water, was taken during the trip and treated the same way as other samples. The samples collected were conserved in ice during the sampling trip and stored in the laboratory fridge at 4?C overnight prior extraction. 3.5 Nutrient analysis Samples collected for nutrient analysis were externally analyzed by ENVIRO- CHEM LABORATORIES, INC. Nutrient concentrations were determined using EPA and Standard methods. Briefly, Total Kjheldal Nitrogen (TKN), which accounts for the nitrogen from ammonia and other biological compounds, was determined using the 31 method EPA 351.2 (US EPA, 2013c) where the sample is acid digested in the presence of H2SO4 and high temperatures for 2.5 hours; the digested sample is later diluted and analyzed using flow injection analysis with a colorimetric detector. The reporting limit (RL) was 0.4 mg/L as N. Nitrate and nitrite concentration was determined using the method SM 4500NO3-F (APHA, 1998), which consists on reducing nitrate into nitrite in presence of cadmium, then adding a color reagent that will form an azo dye and analyzing the solution with a colorimetric detector. The RL was 0.05 mg/L as N. TP and ortho phosphorus (OP) were determined following EPA 365.1 (US EPA, 2013c), in both cases ammonium molybdate and antimony potassium are used in order to develop a blue color. When OP is measured no digestion is needed, in the case of TP an ammonium persulfate digestion for 30-40 min is necessary; the RLs were 0.01 and 0.05 mg/L as P, respectively. 3.6 Extraction of organic tracers A 2-step filtration system was used as previously described (McConnell et al., 2007). Briefly, the filtration consisted on passing the sample through 2 stainless steel filter holders with glass microfiber filters of 2.7 ?m and 0.7 ?m, which removed sequentially bigger and smaller particles, avoiding possible filter clogs. Submersible pumps fitted with Teflon tubing were used to pass the water through the filtration system. The initial 200 mL, equivalent to the dead volume of the system, were discarded and then 2 L were collected. In between samples, 200 to 300 mL of a 50:50 (v/v) mixture of MeOH-H2O was used to clean the system. After the sample was filtered, 100 ?L of a 10 ?g/mL surrogate solution was spiked into 1L of water subsample to reach a final 32 concentration of 1 ?g/L. The sample was extracted by solid phase extraction using OASIS HLB 500 mg cartridges. The cartridges were conditioned with 5 mL of MeOH, 5 mL of MeCN and 5 mL of H2O. Then the subsample (1L) was loaded under vacuum suction at an average flow rate of 7 mL/min and the cartridge was left to dry for 7 min. The sample was subsequently eluted with 10 mL of MeOH followed by 5 mL of MeCN at a flow rate of 1mL/min. The combined eluent was concentrated to 0.5 mL under a gentle N2 flow at 40?C using a Zymark TurboVap LV system (Hopkinton, MA, USA). Concentrated extracts were spiked with 10 uL of a 25 ?g/mL TPP (QC) solution, 100 ?L of a 10 ?g/mL internal standard (IS) solution, and 390 ?L of H2O to reach a final composition of 50:50 (v/v) MeOH:H2O. Then samples were diluted 1/10 with 50:50 (v/v) MeOH:H2O. Prior to injection in the UHPLC-MS/MS, 1 mL of the diluted extract was transferred into a 1 mL syringe and filtered with 0.22?m PVDF filters. Recovery tests were done by spiking a 1L subsample with 50, 100 and 200 ?L of a 10 ?g/mL standard solution and 5, 10 and 20 ?L of a 100 ?g/mL of MET-OH solution, to reach final concentrations of 0.5, 1 and 2 ?g/L, which were named low, medium and high spiking levels, respectively. MET-OH had to be added separately, due to be commercially available only at a concentration of 100 ?g/mL. All recovery samples were also spiked with 100 ?L of a 10 ?g/mL IS solution. The ISs selected (SUC-d6, ACE-d4, ATZ-d5, 13C-2,4-D and MET-d6) were chosen in order to represent artificial sweeteners, triazines, phenoxyacetic and chloroacetanilide herbicides under study. The selected surrogates, TBZ and ALA-d13, were used for method extraction evaluation when doing natural samples. 33 3.7 LC-MS/MS conditions A Waters UHPLC-MS/MS Acquity Xevo-TQS (Milford, MA) was used for analysis. The analyte ionization was performed using electrospray with fast polarity switching. The system was controlled by MassLynx software. Optimization of MS/MS parameters was done by infusion of each individual analyte and using Intellistart software in positive and negative mode. The tuning process consisted on infusing a standard solution of 0.5 ?g/mL prepared in 2 different solvent mixtures: (1) 50:50 (v/v) MeCN:H2O 0.1 percent formic acid; and (2) 50:50 (v/v) MeCN:5mM of ammonia acetate (NH4Ac) in H2O. Cone voltage determination was done ramping the voltage from 2 to 100 V and choosing the value that generates the most intense precursor ([M+H]+ or [M- H]-) ion. Optimal collision energy (CE) for each product ion, was determined by setting the collision gas to 20 L/h and ramping voltage from 2 to 80 eV, until each transition reached their highest intensity. Lowest m/z cut off was 40. Other parameters set were: 3.0 kV capillary voltage, 150?C source temperature, 350?C desolvation gas temperature, 150 L/h cone gas and 650 L/h desolvation gas. The UHPLC separation was done using a Waters Acquity reversed-phase ethylene bridged hybrid, BEH C18, column (100 mm long, 2.1 mm i.d., 1.7 ?m particle size), protected with a BEH C18 guard column (5 mm long, 2.1 mm i.d., 1.7 ?m particle size) and a mobile phase consisting of 0.1 percent formic acid in both water (A) and MeOH (B). The gradient shown in Figure 5 was used to achieve separation; the initial conditions were five percent B held for 0.5 min, then B was increased linearly to 40 percent in a time span of 1 min and again increased to 50 percent in 4.5 min. The isocratic conditions 50:50 (A:B) were held for 2 min, followed by an increase of B to 100 percent in 1 min 34 and held on 100 percent for 2 min. Re-equilibration conditions were set during the last 1.8 min and the column was equilibrated. The total run time was of 13 min. Flow rate was 0.45 mL/min, column temperature was 40?C and injection volume was 10 ?L. The autosampler temperature was kept at 12?C. Table 4 shows the retention times and the optimized MS/MS parameters for analysis. Figure 5. Gradient used in UHPLC to achieve separation of the analytes. A ? Water 0.1 percent formic acid and B ? MeOH 0.1 percent formic acid. Sequences of injections were set up in order to avoid carry over. In the case of recovery tests, reagent only and blanks were injected first, followed by a calibration curve of 11 points and spikes from low to high level. Finally, another calibration curve was injected at the end of the sequence. Injections of 50:50 (v/v) MeOH:H2O were done in between sets of spikes and after the calibration curve. When natural samples were injected blanks were also injected first, followed by a calibration curve and a matrix matched calibration curve. Each sample was injected 3 times and 50:50 (v/v) MeOH:H2O were injected in between samples. The 25 ng/L standard was chosen as a quality assurance - quality control (QA/QC) sample and injected every 20 injection. 35 Table 4. Optimized MS/MS parameters, ionization modes used and retention times for the analytes under study. Analytes Molecular Formula MW Rt (min) Ionization mode Precursor ion (m/z) Cone (V) Product ions (m/z) Quant. Ion CE (eV) Qual. Ion 1 CE (eV) Qual. Ion 2 CE (eV) Acesulfame C4H5KNO4S 202 1.46 ES - 162 4 82 14 78 30 Sucralose C12H19Cl3O8 396 1.68 ES - 395 42 359 10 Saccharin C7H5NO3S 183 1.84 ES - 182 46 106 16 42 20 62 16 OIET C8H15N5O 197 2.12 ES + 198 54 114 22 86 22 156 18 Cyclamate C6H12NNaO3S 201 2.14 ES - 178 4 80 22 96 20 CEAT C5H8ClN5 173 2.27 ES + 174 12 79 24 104 22 96 18 CAAT C3H4ClN5 145 2.80 ES + 146 32 79 16 104 16 110 14 CIAT C6H10ClN5 187 2.81 ES + 188 22 79 24 104 24 146 14 Acetochlor ESA C14H20NNaO5S 337 5.09 ES - 314 46 80 30 121 20 Alachlor ESA C14H20NNaO5S 337 5.09 ES - 314 6 80 28 121 22 Metolachlor ESA C15H22NO5S.Na 351 5.39 ES - 328 8 80 32 121 22 135 26 Atrazine C8H14ClN5 215 5.42 ES + 216 22 104 26 96 24 174 18 2,4-D C8H6Cl2O3 220 6.17 ES - 219 4 161 12 125 28 89 34 Metolachlor OXA C15H21NO4 279 6.46 ES - 278 6 206 12 174 16 158 18 Metolachlor OH C15H23NO3 265 7.28 ES + 266 2 176 24 148 28 234 14 Acetochlor C14H20ClNO2 269 9.23 ES + 270 20 148 20 133 28 224 8 Alachlor C14H20ClNO2 269 9.24 ES + 270 22 238 12 162 16 Metolachlor C15H22ClNO2 283 9.28 ES + 284 22 252 12 176 26 73 26 Acetochlor OXA C14H19NO4 265 n/a ES - 264 4 146 10 144 28 129 46 Alachlor OXA C14H19NO4 265 n/a ES - 264 6 160 12 158 30 143 36 IS Acesulfame-d4 C4D4KNO4S 205 1.45 ES - 166 4 86 12 78 26 Sucralose-d6 C12H13D6Cl3O8 403 2.23 ES - 401 44 365 10 Atrazine-d5 C8H9ClD5N5 220 5.36 ES + 221 52 179 16 101 24 79 24 13C-2,4-D C2H6Cl2O3-13C6 227 6.17 ES - 225 6 167 14 Metolachlor-d6 C15H16D6ClNO2 289 9.28 ES + 290 20 258 16 182 26 135 32 QC TPP C18H15O4P 326 n/a ES + 327 30 152 36 215 26 77 36 Surrogates Terbuthylazine C9H16ClN5 229 8.06 ES + 230 22 96 26 79 26 174 16 Alachlor-d13 C14H7D13ClNO2 282 9.21 ES + 283 20 251 24 13C6-Glucose 13C6H12O6 186 n/a ES - 185 54 139 16 157 12 92 6 Note: Rt ? retention times, IS ? Internal Standard, QC ? Quality Control, n/a ? not applicable 36 Chapter 4: Results and Discussion 4.1 MS and chromatographic optimization Optimization was done by individual infusion, in positive and negative mode, of the initial set of 29 standards. Two different mobile phase modifiers, formic acid and ammonium acetate, were evaluated to determine their ability to increase ionization in the MS ion source. In total, 116 infusions were done, precursor and product ions were defined and their signal intensities compared. The vast majority of the analytes under study presented better ionization when using formic acid as modifier. Regarding ionization mode selection, 15 of the 29 analytes performed better in negative mode, which is advantageous, as it is well known that negative mode presents lower interferences and hence higher sensitivity. In this study, a maximum of 3 product ions per precursor were chosen. In general when developing an MS/MS method, the quantitation (Quant) ion is the most intense product ion, followed by the first and second qualitative (Qual) ions, which are used for identification purposes only. Nevertheless, the instrument used presented high sensitivity and many Quant ions chosen saturated the detector response at concentrations as low as 100 ng/L (in the vial). The use of these ions for further study would significantly reduce the dynamic range of the method. Possible ways to overcome this difficulty could be to re-infuse and determine different ions, if available, or to re-order the ions previously selected, assigning as Quant a less intense ion. In the case of CEAT, CIAT, OIET and ATZ, the least intense ion was selected as the Quant; and for TBZ and MET-OH the second most intense ion was selected. Note that the ion ratios of these compounds would 37 be affected when injected at high concentrations. Ultimately, ions were re-ordered and a broader dynamic range was obtained. Four analytes (SUC, SUC-d6, 13C-2,4-D and ALA- d13) presented only one product ion. This observation is quite significant for SUC, because the lack of ion ratios makes the identification and quantification very difficult, as many other compounds in the environment could interfere and give false positives. Another significant challenge was the presence of 3 pairs of isobaric compounds: ALA ? ACT, ALA-ESA ? ACT-ESA and ALA-OXA ? ACT-OXA. The pair consisting of ALA and ACT could be differentiated due to different MS/MS fragmentation pattern. However, ALA-ESA ? ACT-ESA, and ALA-OXA ? ACT-OXA, could not be resolved by MS/MS. Moreover, OXA and ESA metabolites have very similar chemical structures, which caused co-elutions during the chromatographic separation. Several gradients were tested but no significant separation was obtained, hence for each pair of analytes, only the sum could be reported. The chromatography was very good for all herbicides under study (see Figure 6), except the OXA metabolites, which showed poor peak shape. In order to avoid tailing or peak splitting, high flow rate and 40?C column temperature were used, but no significant improvement was achieved. Hence, OXA metabolites were removed from the final method. The artificial sweeteners eluted earlier in the chromatogram, as expected due to their high polarity. ACE and SAC presented peak splitting, which was not improved with any of the different elution gradients tested. In the case of ACE, peak splitting has been observed previously when ammonium formate is used in the mobile phase, and was improved after changing the modifier to ammonium acetate (Ord??ez et al., 2012). Also, the observation of a broad SAC peak was previously explained by SAC and residual 38 silanol group interactions on the stationary phase (Ferrer and Thurman, 2010). A possible way to address this issue could be changing the column to an Acquity HSS T3, which is also a reverse phase column, but its chemistry was modified to specifically improve peak shape and separation of polar analytes (Waters, 2013). As seen in Figure 6 artificial sweeteners presented lower intensities compared to the herbicides. The analyte TPP, chosen as the instrument QC standard, presented a very high sensitivity, it easily saturated the detector and from the first injection done presented systematic carry over. Hence, under these conditions TPP was inappropriate to be used as QC. The infusion of the proposed surrogate 13C-GLU showed a very weak and instable ion formation; when tested during injections no peak was detected for any transition selected. Figure 6. Total ion chromatogram of a mix standard solution at a concentration of 100 ng/L in 50:50 (v/v) MeOH:H2O. 39 4.2 Method validation The validation of an analytical method requires the evaluation of method sensitivity, linearity, dynamic range, accuracy, precision and the determination of limit of detection (LOD) and quantification (LOQ). 4.2.1 Sensitivity and linearity assessment Sensitivity assessment consists on evaluating the presence of interferences by blank samples analysis. When working with environmental samples, the likelihood to have a ?blank? river water sample available is very low or non-existent. In this study, reagent water was used as blank. The limitation associated with using reagent water is that real matrix interferences are overlooked. However, ion ratio determination and comparison with matrix-matched (MM) standards could be used to evaluate interferences. This approach will be better explained in the following sections. Calibration curves were obtained and evaluated with and without forcing them through zero. All R2 were higher than 0.99, except for ALA and ACT that presented a linear range (R2 = 0.988) only until 50 ng/L (in the vial). Either if the calibration curve was or was not forced through zero, slopes were very similar. Nevertheless, the calculated concentrations obtained from the calibration curve forced through zero showed lower differences from the expected concentrations. Therefore, all quantifications were done with calibration curves forced through zero. 40 4.2.2 Identification and quantification criteria Identification is a qualitative approach to inform whether a compound is present or not in a sample. The use of mass spectrometry makes identification of analytes possible due to its high selectivity, as the m/z measured is directly related to the structure of the analytes under study. Basically, identification is evaluated by comparing ion ratios, which are constant for a certain compound under defined analytical conditions. The identification criteria used in this study was based on criteria set by USDA Food Safety and Inspection Service for veterinary drugs analysis in foods (Lehotay et al., 2012; Geis-Asteggiante et al., 2013). Though this work centers on environmental samples, applying the criteria could be useful for increasing the confidence of the results obtained. Briefly, a positive sample is considered identified when a chromatographic peak is present ?6s from the retention time (Rt) of the standard, all transitions have similar peak shape than the standard and the Quant ion signal to noise ratio is higher than three. If two Qual ions are available, three ion ratios can be estimated and sample ion ratios should be within ? 20% of the standard ion ratios. If only one Qual ion is available, then only one ion ratio can be estimated and sample ion ratio should be within ? 10% . Reagent water samples should not present interferences and carry over should not be observed. For method validation, identification is acceptable when the number of false negatives is equal or lower than 10 percent. Ion ratios were determined using calibration curve data. The calibration curve was injected twice (n=22) and ion ratios were calculated (see Table 5). Notation used for ion ratios (2/1), (3/1) and (3/2) refers to (Qual 1/Quant), (Qual 2/Quant) and (Qual 2/Qual 1), respectively. However, note that the ion ratios were calculated in order to reach 41 percentages lower than 100 percent, i.e. in some cases (1/2) was calculated instead of (2/1). Data treatment form spiked samples showed acceptable identification for all analytes, except ACE at low spiking level. In the case of OIET, ATZ and MET-OH, the second Qual saturates the detector at 200 ng/L (in the vial), hence only one ion ratio was considered for concentrations higher than 200 ng/L. ACE presented 40 percent false negatives at the low spiking level, which falls outside the acceptability criteria, but identification could be done for levels of 1 ?g/L or higher. Based on these results, the method is able to adequately identify 16 of 17 compounds at any of the spiking levels tested. Hence, ion ratios and standard deviations (SD) from contemporarily injected calibration curves will be used to identify the analytes of interest in natural samples. After proper identification, quantification of the analyte found is desired. The criteria for quantification required recoveries between 70 and 120 percent and relative standard deviations (RSDs) equal or lower than 20 percent. The lowest calibration limit (LCL) was used, instead estimating LOD and LOQ, and represents the lowest level that can be reported. Acceptable LCL needed to demonstrate signal to noise ratios higher than 10 and a percentage difference between the calculated and the expected concentration lower than 30 percent. 42 Table 5. Average ion ratios and standard deviation (SD) obtained from calibration curve standards (n=22). Analytes Ion Ratios Ratio (2/1) SD Ratio (3/1) SD Ratio (3/2) SD Acesulfame 11% 3% Saccharin 10% 7% 106% 9% 10% 7% OIET 56% 6% 41% 8% 73% 9% Cyclamate 1% 1% CEAT 91% 7% 76% 3% 83% 6% CAAT 82% 5% 51% 7% 62% 9% CIAT 86% 6% 27% 4% 23% 4% Acetochlor ESA + Alachlor ESA 68% 2% Metolachlor ESA 64% 4% 10% 3% 16% 6% Atrazine 80% 4% 33% 11% 41% 11% 2,4-D 8% 3% 2% 2% 15% 7% Metolachlor OH 63% 8% 21% 9% 13% 6% Acetochlor 54% 4% 16% 6% 29% 11% Alachlor 42% 5% Metolachlor 31% 3% 3% 2% 9% 6% Acesulfame-d4 17% 1% Atrazine-d5 51% 1% 33% 1% 65% 1% Metolachlor-d6 63% 2% 15% 2% 24% 3% Terbuthylazine 80% 0% Note: SD ? standard deviation. 4.2.3 Recoveries and precision An extension of McConnell et al. (2007) extraction method, form 9 to 17 analytes, was evaluated. Previous results shown good recoveries for 7 analytes. Recovery tests were done in order to evaluate the accuracy and precision of the extended method. Spiking levels were chosen after careful assessment of previous findings in the literature and considering the sensitivity of the instrumentation. Ultimately, 0.5, 1 and 2 ?g/L were chosen and named low, medium and high levels, respectively. 43 Results were the same whether corrected or not against the ISs added, which means that there were no significant matrix effects (ME) or volume variations. The lack of ME was expected as reagent water was used as matrix. All the internal standards and surrogates, except ALA-d13, presented good recoveries. In the case of ALA-d13 the recovery was 67 percent, which was borderline low but still good for a surrogate standard. Moreover, RSDs of each IS (n = 40) was lower than 20 percent, which demonstrated good instrument repeatability. Recoveries obtained for the low spiking level were acceptable, except for metolachlor that showed a recovery of 123 percent. Higher RSDs were obtained for the low spiking level, as expected. However, for the ESA metabolites the opposite trend was observed, due to one medium and one high replicate that gave recoveries of 60 and 67 percent, respectively. This deviation from the other 4 replicates may be due loading or elution speed variations. As the average recoveries and RSDs were not significantly affected, the replicates were not removed from the data set. Overall, 14 out of 17 analytes fell inside the quantification acceptable range (see Table 6). The relative standard deviations (RSDs) were lower than 15 percent for all spiking levels. These results demonstrated that the method was accurate and precise. ACE, CYC and SAC were not extracted effectively, showing recoveries lower than one percent. These compounds are more polar than the herbicides previously studied; therefore loading a 1 L sample could cause breakthrough and the concomitant loss of analytes (Gan et al., 2013). It has been demonstrated that artificial sweeteners recoveries were good when weak anion exchange (WAX) is used as stationary phase (Huntscha et al. 2012; Gan et al. 2013). Hence, as the ultimate goal is to reach a single 44 multi-residue method, the author recommends evaluating the efficiency of WAX for herbicides extraction. Other possible stationary phase to test on herbicides would be styrol-divinylbenzene (SDB), which proved to be effective for pharmaceuticals and artificial sweeteners extraction previously (Scheurer et al., 2009). Also, sequential SPE could be used to improve artificial sweeteners recoveries. Two cartridges with diverse separation chemistry could be used sequentially, e.g. first cartridge could be HLB and the second WAX, so when the sample is loaded the HLB stationary phase would not retain ACE, SAC and CYC, but WAX would selectively retain them. 45 Table 6. Percent recoveries (%Rec) and relative standard deviation (%RSD) for low, medium and high spiking levels (n=5 each). Values in bold are outside the acceptable range of recoveries (70 ? 120 percent). Analyte Rt (min) Low level 0.5 ?g/L (n=5) Medium level 1 ?g/L (n=5) High level 2 ?g/L (n=5) Overall (n=15) %Rec %RSD %Rec %RSD %Rec %RSD %Rec %RSD Acesulfame-d4 1.44 n/a n/a Acesulfame 1.45 nd n/a nd n/a nd n/a n/a n/a Saccharin 1.84 nd n/a nd n/a nd n/a n/a n/a Cyclamate 2.13 nd n/a nd n/a nd n/a n/a n/a OIET 2.14 112% 12% 112% 6% 110% 5% 110% 9% Sucralose-d6 2.22 92% 16% Sucralose 2.24 89% 12% 94% 8% 119% 13% 96% 13% CEAT 2.27 105% 8% 110% 4% 119% 6% 109% 7% CAAT 2.8 107% 9% 109% 4% 112% 6% 107% 7% CIAT 2.81 109% 9% 111% 4% 113% 6% 109% 7% Alachlor ESA + Acetochlor ESA 4.99 94% 10% 90% 19% 95% 13% 89% 15% Metolachlor ESA 5.27 96% 9% 90% 19% 99% 14% 91% 15% Atrazine-d5 5.35 97% 2% Atrazine 5.41 102% 8% 104% 7% 109% 4% 104% 7% 13C-2.4-D 6.15 91% 7% 2.4-D 6.16 99% 10% 105% 5% 110% 4% 103% 8% Metolachlor OH 7.28 96% 7% 86% 6% 88% 5% 88% 9% Terbuthylazine 8.06 97% 11% Alachlor-d13 9.21 67% 15% Acetochlor 9.23 95% 8% 96% 4% 102% 2% 98% 6% Alachlor 9.24 101% 9% 95% 6% 102% 3% 99% 7% Metolachlor-d6 9.28 99% 3% Metolachlor 9.29 123% 12% 108% 8% 113% 3% 113% 11% Note: Rt ? retention time, nd ? not detected, n/a ? not applicable. 46 4.2.4 Evaluation of matrix effects (MEs) MEs were estimated by slope comparison of a calibration curve prepared in solvent only (SO) and a calibration curve prepared in matrix, called matrix-matched (MM). There are many ways to estimate MEs; in this study the calculation used was %ME = (slope MM ? slope SO)/(slope SO)*100. Hence, negative ME refers to signal suppression and positive to signal enhancement due to matrix presence. The ME suppression is considered significant when ME is lower than -20 percent; and ME enhancement is significant when ME is higher than 20 percent. In order to prepare the MM calibration curve, equal volume of each of the real samples were combined to prepare 7 L of mixed ?river matrix?. The 7 MM samples were processed with all the other samples and spiked with standards before the dilution and injection steps. The approach of mixing all the samples collected was a good alternative to preparing a MM calibration curve for each matrix, which would be very tedious and costly. However, it is important to notice that the ME shown in Table 7 are not for individual sites and, hence, some samples may contain higher or lower MEs. In the case of Choptank River, OIET, SUC, MESA and 2,4-D presented a low enhancement, as ME were lower or equal to 30 percent. In the case of Anacostia River, ACE, ALA and MET presented significant suppression effects. In general, when assessing ME in LC-MS analysis suppression of signal is a typical phenomenon, however, enhancement has been observed in drinking water analysis, as reported by US EPA in Method 535 (US EPA, 2013c). Therefore, for all analytes inside the acceptable range, ME corrections would not be needed, preventing the tedious and costly MM calibration elaboration. Even when correction by IS was done for the same un-labeled standards or other standards of similar 47 chemistry, results did not improve. In the case of sucralose and metolachlor, quantification improves only slightly when correcting by the correspondent IS. Moreover, the ion ratios obtained for the MM calibration curve standards were compared to the SO calibration curve and no significant variations were observed. This is important because if matrix interferences where present the ion ratios would be affected. Interferences affect low concentration standards more greatly than high concentration standards, as its signal contribution is more significant. When the low standard ion ratio is compared to the ion ratio of standards at higher concentrations a deviation can be observed. This trend could be used for matrix interference assessment. Table 7. Matrix effects observed for the ?river matrix? sample consisting of a mix of all the samples collected. Values in bold refers to significant ME (ME < - 20% and ME > 20%) Analyte ME (%) Choptank Anacostia River River Acesulfame 7% 12% Saccharin 4% 6% Cyclamate 5% 0% OIET 23% 7% Sucralose 30% 8% CEAT 2% -5% CAAT 6% 6% CIAT 3% -7% Alachlor ESA + Acetochlor ESA 6% 11% Metolachlor ESA 22% 21% Atrazine 6% 0% 2.4-D 25% 10% Metolachlor OH -7% -6% Acetochlor 13% -44% Alachlor 13% Metolachlor 8% -42% 48 Ultimately, the extended method allowed for the analysis of all the herbicides of interest and sucralose. A comparable, but slightly lower sensitivity was achieved for parent compounds that were previously analyzed by GC-MS. Therefore, the extended method avoids the need of two extraction methods and analytical instruments, reducing cost and time of analysis (note that run time was reduced to half). 4.3 Choptank River analysis Data collected during sampling is summarized in Table 8. Time of sampling and coordinates are shown for each sampling site. No significant rainfall events (higher than 10 mm) were registered two days before sampling and discharge rate at the USGS stations were lower than 5 m3/s; hence, the study was done at base flow conditions (Hively et al., 2011). DO was measured and readings were all higher than the criteria for instantaneous minimum DO in shallow waters (3 mg/L) (Chesapeake Bay Program (U.S.), 2003). Measured pHs were also inside the water quality criteria (US EPA, 2013a). Conductivity was determined in order to estimate water salinity. Discharge rates were obtained from the corresponding USGS monitoring stations at the time of sampling and used to estimate loads. The USDA National Agricultural Statistics Service reported that in 2013, corn planting started the first week of April and was completed by the first week of June. Soybeans were planted in mid-May and, due to persistent rains, the planting period was extended until the end of July (USDA-NASS, 2013). Soils were fertilized and herbicides applied during the planting period; metolachlor and atrazine were applied to corn, and metolachlor was used for soybean plantations (Hively et al. 2011). 49 Table 8. Water quality data, coordinates and discharge rate for Choptank River watershed by location sampled. Site ID Date (mm/dd/yy) Time Stage Gauge (ft) Water temp (?C) Cond (mS/cm) Total Dissolved Solids (g/L) DO (%) DO (mg/L) pH Coordinates Discharge (ft3/s) (hh:mm) EST/EDT Latitude Longitude Horn Point 7/22/13 9:47 AM None 29.75 12.97 7.733 78.2 5.76 8.05 38? 35' 36.72"N 76? 7' 43.39"W 50 Bridge 1 7/22/13 10:37 AM None 30.58 10.76 6.327 71.0 5.16 8.68 38? 34' 18.64"N 76? 3' 43.77"W 50 Bridge 2 7/22/13 10:37 AM None 30.54 10.82 6.362 82.5 6.00 8.71 38? 34' 18.64"N 76? 3' 43.77"W 50 Bridge further point 7/22/13 11:07 AM None 30.35 10.41 6.138 66.7 4.88 8.80 38? 34' 27.81"N 76? 3' 36.80"W NOAA 7/22/13 12:02 PM None 30.40 14.91 8.780 86.8 6.25 8.52 38? 40' 44.95"N 76? 10' 27.38"W Preston Landing 7/22/13 1:09 PM None 31.89 2.291 1.316 63.3 4.60 7.73 38? 40' 48.14"N 75? 57' 1.72"W Frazier Point 7/22/13 1:57 PM None 31.40 1.108 0.642 59.6 4.44 7.54 38? 42' 33.21"N 75? 59' 29.56"W Swing Bridge 7/22/13 2:19 PM None 31.17 0.296 0.172 59.7 4.42 7.35 38? 45' 27.04"N 75? 59' 53.10"W Kingston Landing 7/22/13 2:45 PM None 31.22 0.150 0.087 44.4 3.23 6.97 38? 46' 50.09"N 75? 57' 59.10"W Cordova 7/22/13 3:12 PM 40 21.85 0.310 0.214 76.3 6.69 7.25 38? 53' 29.13"N 75? 57' 36.22"W 78* Tuckahoe 7/22/13 4:19 PM None 26.28 0.178 0.113 89.2 7.16 7.62 38? 58' 1.74"N 75? 56' 34.55"W 78* German Branch 7/22/13 3:55 PM 10 22.24 0.203 0.138 75.0 6.51 6.89 39? 0' 33.42"N 75? 56' 13.83"W 78* Long Marsh 7/22/13 5:42 PM 45 26.12 0.150 0.095 104.5 8.43 6.76 39? 4' 5.18"N 75? 51' 9.94"W 77* Beaver Dam 7/22/13 5:25 PM 50 22.98 0.161 0.109 164.6 14.12 6.99 39? 4' 27.71"N 75? 51' 56.08"W 78* Greensboro 7/22/13 4:53 PM 3.3 26.20 0.134 0.085 83.3 6.74 7.31 38? 59' 50.36"N 75? 47' 9.32"W 135? Note: * Discharge (ft3/s) obtained from USGS station 01491500, ? Discharge (ft3/s) obtained from USGS station 01491000. (USGS, 2013); DO ? dissolved oxygen. 50 4.3.1 Nutrients levels and fate Nutrient concentrations were determined for each site; Table 9 shows the TKN, nitrate+nitrite, OP and TP concentrations found. In surface water nitrite oxidizes to nitrate readily, contributing only a small fraction of the nitrate+nitrite concentration, hence the author will now on refer to it as nitrate. Also, note that TN is the summation of TKN and nitrate. Nitrate levels obtained for the upper subwatersheds are slightly high for summer season, but still in agreement with previous findings (Hively et al., 2011). Cordova presented the highest nitrate concentrations (7.95 mg/L as N), as expected for a WDU in an intense agricultural area. Long Marsh and Beaver Dam nitrate levels were lower than Cordova, which was also expected, as both are PDU where denitrification and plant uptake is significant; and a higher percentage of forested land is present. In the tidal region, Whitall et al. (2010) reported that during summer months nitrate and salinity presented a curvilinear relationship due to biological uptake. However, in this study nitrate and salinity presented a negative strong linear correlation (R2 = 0.991, see Figure 7a), which would mean that nitrate is being diluted as it moves toward the mouth of the river without any significant input, uptake or degradation happening after entering to the river. More sampling points in between Cordova, Greensboro and Kingston Landing would help to better support this observation. Note that nitrate is under the reporting limit when it reaches the mouth. The levels observed for OP (dissolved phosphorus) in the upper subwatersheds were higher than previously reported 2-years averages and maximums by Hively et al. (2011). German Branch was the site with the highest OP concentration (0.2 mg/L as P), 51 and concentrations decreased towards the mouth of the river. In the tidal region, the OP findings were in agreement with levels reported by Whitall et al. (2010). The higher concentrations were recorded in 4 locations near Easton WWTP. The relationship between OP and salinity was also a negative linear correlation (R2 = 0.963, see Figure 7a), which could also relate to a dilution effect. However, comparing nitrate and OP concentrations of tidal and watershed regions, the level of OP in tidal sites was similar or higher than for the watershed, but nitrate was significantly lower. If dilution was the only effect over OP an increase would not be expected near Easton WWTP location, therefore it could be presumed that point sources were contributing to the observed OP level. Overall, it was expected to observe nutrients concentrations slightly higher than anticipated due to the extended planting period for soybeans, which were 98% planted at the sampling date (USDA-NASS, 2013). Also, heavy rains were recorded for the upper subwatersheds 9 days before sampling, which could have caused an increase on OP concentrations due to runoff. This work shows only a snapshot of the Choptank River, and though it can be compared to previous findings for discussion purposes, more sampling dates and locations, would be needed to better assess trends. 4.3.2 Herbicides and artificial sweeteners fate In order to inform results of natural samples, surrogates, QA/QC, IS and calibration curves should be check for any deviation. Possible carryover issues or presence of interferences in the laboratory and travel blanks should also be evaluated. The method performed very well, surrogates recoveries and RSDs were acceptable and comparable to the ones previously obtained during recovery tests. QA/QC and IS showed good precision (RSDs lower than 20 percent), also accuracy was good 52 during the run as the QA/QC reported the expected concentration (250 ng/L) with a maximum difference of 25 percent, without corrections for ME. Calibration curves were linear and the slope differences between the one acquired at the beginning and at end of the sequence were lower than 20 percent, except for CYC and SUC. These two artificial sweeteners presented 32 and 36 percent slope difference, respectively. As the QA/QC standard had a good performance (low RSD) and was accurately determined by the first calibration curve, SUC quantification was done using the first calibration curve. Moreover, corrections with SUC-d6 did not help the quantification; actually it caused an increase in RSDs due to the variability of the IS (RSD = 19%). It was observed that SUC ionization was variable at levels lower than 250 ng/L and the IS was added at 100 ng/L. Significant carryover (higher than one percent) was not detected. The analyte concentrations in laboratory and travel blanks were below the LCL in all cases, except for MET. In the case of MET, laboratory and travel blanks showed interference for the first 2 product ions with an ion ratio comparable to the standard, but completely lacking the third transition, even though the concentration in the sample was estimated as 100 ng/L. A good approach to determine if the interference is MET would be re-analyzing the sample using scan mode for acquisition and looking for the precursor ion isotopic pattern. As MET contains one chlorine, it should show two peaks at m/z = 284 and m/z = 286 corresponding to the [M+H]+ containing 35Cl and 37Cl, respectively. Ultimately, the interference signal of the blank was subtracted from all samples. Nonetheless, the source of the interference should be determined and avoided, if possible. As the interference is present on the laboratory blank, it could be a laboratory contamination in the reagent water, the extraction solvents or in the lot of OASIS HLB cartridges used. The odds of 53 observing an interference of equal [M+H]+ are high for small molecules, but the fact that 2 ions were present and their ion ratio was consistent with MET reduces the possibilities significantly. A reasonable approach to propose possible interferences would be to use MassLynx Software to estimate all possible molecular formulas for each mass observed (the software does not take into account the charge) and query for a broad spectrum of elements (C, H, N, O, Cl, F, Br, S). The software will provide several possible molecular formulas for the fragments and after comparing their elemental composition; one or more formulas for the precursor could be determined. However, this process is very tedious and it would require testing standards of the proposed compounds to check retention time similarities with MET. The best option to identify the interference observed is to analyze the sample using a high-resolution instrument, such as a time of flight mass spectrometer, which allows for accurate mass determination of the interference precursor and product ions, simultaneously observing isotopic patterns. 54 Table 9. Quantified nutrients, herbicides, herbicides metabolites and sucralose in Choptank River surface water by location sampled. Analyte Rt (min) LCL (ng/L) Organic compounds concentrations found (ng/L) NOAA Horn Point 50 Bridge 1 50 Bridge 2 50 Bridge further pt Preston Landing Frazier Point Swing Bridge Kingston Landing 1 Kingston Landing 2 OIET 2.12 50 80 105 151 129 141 187 161 164 147 166 Sucralose 2.24 250 453 461 382 309 386 < LCL < LCL < LCL < LCL < LCL CEAT 2.27 5 61 87 120 103 111 81 69 60 50 53 CAAT 2.80 5 85 112 154 134 154 133 104 91 84 91 CIAT 2.81 0.5 83 108 144 127 141 124 97 94 79 88 Alachlor ESA + Acetochlor ESA 5.09 10 106 134 196 166 176 400 232 240 215 250 Metolachlor ESA 5.39 1 654 824 1195 1020 1118 2002 1643 1593 1431 1703 Atrazine 5.42 5 375 476 625 550 561 427 290 214 159 181 2.4-D 6.17 10 19 22* 21* 18* 18* 21* 43* 104* 169 195 Metolachlor OH 7.28 1 29 37 47 42 44 39 30 36 33 39 Acetochlor 9.23 50 < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL Alachlor 9.24 50 < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL Metolachlor 9.28 10 < LCL 84 333 318 273 1106 809 1166 1307 1465 RL (mg/L) Nutrient concentrations found Kjeldahl Nitrogen (mg/L as N) 0.4 0.8 0.8 0.7 0.8 0.8 0.7 0.8 1.0 0.6 0.9 Nitrate & Nitrite (mg/L as N) 0.05 < RL < RL 0.064 0.078 0.23 0.971 1.06 1.14 1.2 1.25 Ortho Phosphorus (mg/L as P) 0.01 0.03 0.03 0.03 0.04 0.04 0.12 0.17 0.17 0.17 0.17 Total Phosphorus (mg/L as P) 0.05 < RL 0.05 0.07 0.06 0.07 0.15 0.18 0.19 0.22 0.22 Note: Rt ? retention times, LCL ? lowest calibration limit, RL ? reporting limit, * Not identified 55 Table 9. Quantified nutrients, herbicides, herbicides metabolites and sucralose in Choptank River surface water by location sampled. (Continued) Analyte Rt (min) LCL (ng/L) Organic compounds concentrations found (ng/L) Cordova Tuckahoe 1 Tuckahoe 2 German Branch Beaver Dam Long Marsh Greensboro 1 Greensboro 2 OIET 2.12 50 129 116 112 102 71 90 134 118 Sucralose 2.24 250 < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL CEAT 2.27 5 172 49 45 52 30 15 24 21 CAAT 2.80 5 261 164 153 154 111 40 42 37 CIAT 2.81 0.5 254 155 148 148 109 37 42 37 Alachlor ESA + Acetochlor ESA 5.09 10 885 578 540 556 642 356 402 336 Metolachlor ESA 5.39 1 5758 4830 4626 4385 5891 4855 2690 2294 Atrazine 5.42 5 148 74 71 76 36 14 60 51 2.4-D 6.17 10 < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL Metolachlor OH 7.28 1 10 10 9 5 7 12 14 12 Acetochlor 9.23 50 < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL Alachlor 9.24 50 < LCL < LCL < LCL < LCL < LCL < LCL < LCL < LCL Metolachlor 9.28 10 246 441 482 122 233 529 407 351 RL (mg/L) Nutrient concentrations found Kjeldahl Nitrogen (mg/L as N) 0.4 0.7 0.6 1.0 0.6 0.6 1.3 0.6 8.7 Nitrate & Nitrite (mg/L as N) 0.05 7.95 5.46 5.13 5.49 5.17 2.28 1.43 1.5 Ortho Phosphorus (mg/L as P) 0.01 0.1 0.11 0.1 0.2 0.09 0.15 0.17 0.16 Total Phosphorus (mg/L as P) 0.05 0.09 0.12 0.12 0.17 0.09 0.13 0.14 0.14 Note: Rt ? retention times, LCL ? lowest calibration limit, RL ? reporting limit 56 Figure 7. Concentration of a) nitrate and OP; b) MET and MESA; c) ATZ; and d) SUC versus salinity. Linear trends and R2 are shown for each analyte. As shown in Table 9, ATZ, MET and their metabolites were identified and quantified at concentrations higher than the LCL for all sites. ATZ concentrations were higher for tidal sites and ranged from 0.17 to 0.60 ?g/L. The subwatersheds presented ATZ levels lower than 0.08 ?g/L, except for Cordova, where ATZ was 0.15 ?g/L. The metabolites CAAT, CIAT, CEAT and OIET were present in the subwatersheds at levels significantly higher than ATZ. Cordova presented a concentration of CEAT and a CEAT/ATZ ratio higher than other subwatersheds; this could be related to simazine co- application in corn plantations, which would also produce CEAT as metabolite. In the tidal region, an interesting pattern for ATZ was observed (see Figure 8); the 57 concentration increased from the mouth of the river until the maximum was reached at 50 Bridge, near Cambridge WWTP outfall. In order to evaluate mixing effects due to salinity gradients, ATZ was plotted versus salinity (see Figure 7b), two strong and opposite linear correlations were observed depending if the water was oligohaline (0.5 ? 5 ppt) or mesohaline (5 ? 18 ppt). At the times 50 Bridge, Horn Point and NOAA were sampled the tide was low and water was exiting the river, so if a significant level of ATZ was entering to the river through the WWTP a decrease towards the mouth of the river would be observed. Conversely, for the rest of the samples the tide was high and water was entering from the Bay, hence a decrease of concentration from the source towards the Kingston Landing would be observed. Benotti et al. (2009) has reported that ATZ is widely used in the US and it has been found in surface water influenced by WW at concentrations as high as 0.87 ?g/L, even in places with no agricultural activities. Therefore, the pattern observed could be related to a point-source input of ATZ, which may be affected by the tide. Moreover, not only ATZ was found at relatively high concentrations in the mouth of the Choptank River, MET was also found at concentrations as high as 1.5 ?g/L. Another possible explanation for this observation could be the entrance of parent pesticide from the Bay. Susquehanna River, a major tributary and contributor of freshwater to the Chesapeake Bay it is surrounded of a vast agricultural activity, which could contribute to ATZ and MET. However, Liu et al. (2002) and McConnell et al. (2007) had found ATZ and MET present near Choptank River, but at levels lower than 0.1 ?g/L. Lastly, volatilization and aerial deposition could also be considered as a possible ATZ and MET contributor. Conditions were adequate for volatilization, warm temperatures and significant rain the week previous to sampling, left 58 soils wet increasing the possibility for volatilization losses. (Prueger et al., 2005; Kuang et al., 2003). Figure 8. Concentrations (?g/L) found for a) ATZ and its metabolites and b) for ATZ and MET by site sampled. MESA concentrations were higher in the subwatersheds, with the highest findings observed at Beaver Dam (5.9 ?g/L) and Cordova (5.8 ?g/L) a PDU and WDU soils, respectively. These levels were slightly higher than previous findings for summer period by Hively et al. (2011), which could be related to the extended planting period in 2013. German Branch and Long Marsh also located on PDU soils showed lower MESA concentrations as expected for hydric soils. MET represented less than 15 percent of 59 MESA at the non-tidal sites, which was expected as MESA is formed in aerobic or unsaturated soils and transported into groundwater. Lower areas of the Choptank River presented an increased percentage of MET, reaching almost equal levels compared to MESA at Kingston Landing and decreasing toward the mouth of the river. Possible explanations for this observation were suggested above. MET and MESA plotted versus salinity showed a strong linear negative correlation with R2 of 0.911 and 0.818, respectively (see Figure 7c); comparable with McConnell et al. (2007) results. As previously demonstrated by McCarty et al. (2013), MESA presented a good correlation to nitrate (R2 = 0.978, see Figure 9), which supports the hypothesis that MESA could be a good tracer of agricultural nitrate. Moreover, MESA was poorly correlated to OP (R2 = 0.047), which could be explained by the presence of other sources such as Easton WWTP and/or other WWTPs located under Greensboro site. Note that if the locations near Easton WWTP were not taken into account when plotting OP versus MESA, a strong linear correlation (R2 = 0.951) was observed. MET-OH was found in all samples at levels lower than 50 ng/L, hence it was not significantly formed. Figure 9. Concentration of MESA versus a) nitrate and b) OP. Linear trends and R2 are shown for each analyte. 60 The herbicides ACT and ALA were not identified, but their ESA metabolites were present for all sites at concentrations higher than the LCL, although considerably lower than MESA. Moreover, 2,4-D was quantified in nine sites, but only two, NOAA and Kingston Bridge, passed the identification criteria. The fact that some samples failed to pass the criteria could be related to the low ion ratios associated to 2,4-D. Usually, ion ratios lower than 10 percent are undesired, as they are strongly affected by analyte concentration and ionization variability. In the case of artificial sweeteners analysis, the method was not suitable for ACE quantification and identification was not possible as it was limited to concentrations higher than 1 ?g/L. CYC was not identified in any of the sites under study, which was expected as it has been banned in the US for many years. Moreover, even though SAC could not be quantified using this method due to its low recovery, it was identified in all the sites, except NOAA, Swing Bridge, Tuckahoe, German Branch and Long Marsh. SAC was expected to be found in the tidal region as many WWTP discharge over the river. In the case of Beaver Dam, SAC presence may be a false positive or a positive finding explained by a septic tank leakage. However, SAC stability in septic tanks is very low. Additionally, to determine if it is a false positive confirmation of the results would be needed by an orthogonal analysis, such as LC-DAD. Nonetheless, the addition of identification criteria increased the confidence of the results and proved to be very useful for cases where quantification could not be done. SUC was only detected at NOAA, Horn Point and 50 Bridge, with concentrations ranging from 0.31 to 0.46 ?g/L. When evaluating sucralose versus salinity, a weak 61 positive linear correlation (R2 = 0.608, see Figure 7d) was observed; however, the interpretation of this result is very limited as only 5 points (three at 50 Bridge) were found in a small range of salinity. Also, SUC should be compared to nitrate and TN concentrations, but as nitrate was lower than the RL for NOAA and Horn Point comparison was not possible. In the case of SUC and OP, a weak negative linear correlation (R2 = 0.563, see Figure 10) was observed, but as previously stated more points would be needed to better assess trends. The high method LCL limited the amount of samples that could be quantified, i.e. the author assumed that SUC would also be found in the locations near Easton WWTP, such as SAC was identified in these locations. The lack of an ion ratio to allow for identification evaluation was also a draw back. Figure 10. Concentration of SUC versus OP. Linear trend and R2 are shown. Therefore, the main limitations of the method when quantifying sucralose were related to ionization variability at concentrations lower than 250 ng/L and the formation of only one product ion. Also, IS performance was not adequate because it was added at 100 ng/L. In order to obtain lower LCL, samples could be re-injected without 1/10 dilution. However, MEs, carryover and possible instrument contamination due to the presence of other 62 analytes at very high concentrations should be assessed first. Another approach is a post- column infusion of a solution with NH4 + or TRIS buffer during the beginning of the run. Scheurer et al. (2009) recommended TRIS buffer as the modifier that gave the greater signal enhancement for artificial sweeteners ionization. The post-column infusion technique has the disadvantage that it requires an automated system, which is not available in relatively older LC-MS/MS instruments. In our study, the infusion with ammonium acetate gave higher intensities for SUC, but the majority of the analytes performed better when formic acid was used. Multi-residue methods consists on extracting and analyzing compounds with very different physicochemical properties, hence, it is expected to observe different grades of performance for the various analytes. 4.4 Anacostia River analysis Data collected during sampling is summarized in Table 10. As stated previously, time of sampling and coordinates are shown for each sampling site. Discharge rates obtained from the corresponding USGS monitoring stations were low and no significant rainfall events occurred close to the sampling date. Hence, the study was also done at base flow conditions. DO and pH measured were all adequate. 4.4.1 Nutrients levels and fate Nutrients results were lower than the average previously observed for the month of August during the years 2008 to 2011 at the USGS station 01649190, 01649500 and 01651000 (USGS, 2013) (see Figure 4 for USGS station locations and Table 11 for results). Nitrate was the highest at Paper Mill Rd (1.06 mg/L as N) situated near the outlet of Indian Creek and the lowest at Research Rd (0.28 mg/L as N) situated near the outlet 63 of Beaverdam Creek. Even though Research Rd presented the lowest nitrate, TKN was the highest measured (2.3 mg/L as N). TKN is a measurement of organic nitrogen and ammonia, which could be related to WWTP discharge into the waterway. BARC East Side WWTP is located down river, but very close to Research Rd location, which may explain the high TKN level observed. North Drive Bridge, situated near the outlet of Little Paint Branch, was the following site on nitrate concentration importance with 0.74 mg/L as N. Replicates were taken for this site and even though the nitrate presented good precision, TKN was not reproducible, pointing to an analytical or sampling error. The nitrate levels found for these 3 sites were expected to be the highest because they are part of BARC where research on agriculture is done and fertilizers and herbicides are applied. Only Research Rd presented OP higher than RL (0.04 mg/L as P). The difference on OP levels could be related to the fact that Research Rd presents a higher percentage of agricultural activities or due to the presence of BARC-East Side WWTP. Moreover, Berwyn Rd site was selected to sample after Indian and Beaverdam Creek combines; this site had the highest OP level measured of 0.12 mg/L as P and nitrate level was also high (0.92 mg/L as N). This observation is reasonable as Berwyn Rd was influenced by BARC-East Side WWTP located just below Research Rd. Another possibility that could explain the spike on OP may be a localized sewer leakage. In order to evaluate Little Paint Branch and Paint Branch subwatersheds combined, UMD site was selected; nitrate level was 0.59 mg/L as N and OP was still under RL, hence there were no significant nutrient inputs from the University of Maryland and BARC-West Side WWTP. Anacostia River Park and Greenbelt National Park, presented low nitrate concentration and OP lower than RL. These subwatersheds present a higher percentage of forest and no 64 significant agriculture. These riparian forested areas may reduce the amount of nitrate due to plant uptake and denitrification. All the previously named sites sampled combined into the Northeast Branch, where a sample was collected at Riverdale Rd. West subwatersheds were also sampled at Sligo Creek and then at Skateboard, which combines the Northwest Branch and Sligo Creek flow. For these sites the nitrate and OP concentrations were in between the mainly forested and mainly agricultural areas. Sligo Creek is a mainly urban subwatershed, it has no agricultural activities and forested areas are lower than 10 percent. Hence, it could be considered a good marker for urban nutrient inputs. The last sampled point was the National Arboretum a location after all subwatersheds combined. The levels observed in this location were lower than the rest possibly due to dilution. Considering the land use in the Anacostia watershed (see Table 2), the relationship between nitrate and percentage of agricultural land was evaluated and a very weak negative liner relationship was observed (R2 = 0.360). However, if Research Rd is removed no relationship is observed. In the case of OP, its relationship with residential and industrial land use was evaluated and a relatively strong negative linear relationship was observed (R2 = 0.669). However, only 3 sites presented information on OP and land use simultaneously, hence this relationship needs to be re-assessed in future studies. 65 Table 10. Water quality data, coordinates and discharge rates for Anacostia River watershed by location sampled. Site ID Date (mm/dd/yy) Time Stage Gauge (ft) Water temp. (?C) Conductivity (mS/cm) Total Dissolved Solids (g/L) DO (%) DO (mg/L) pH Coordinates Discharge (ft3/s) (hh:mm) EST/EDT Latitude Longitude North Drive Bridge 8/5/13 10:02 AM None 19.86 0.38 0.270 107.0 9.75 8.07 39? 1' 44.10"N 76?55'46.91"W Research Rd 8/5/13 10:38 AM None 20.95 0.18 0.123 63.0 5.58 7.65 39? 1' 25.64"N 76?52'41.83"W Powder Mill Rd 8/5/13 11:11 AM None 20.79 0.37 0.262 105.7 9.46 7.68 39? 2' 0.78"N 76?54'8.60"W Berwyn Rd 8/5/13 12:44 PM None 22.72 0.29 0.194 75.3 6.42 8.01 38?59'36.26"N 76?55'10.91"W UMD 8/5/13 12:20 PM None 22.97 0.32 0.216 97.2 8.35 8.36 38?59'25.19"N 76?56'6.51"W Greenbelt Park 8/5/13 5:07 PM None 22.22 0.335 0.230 93.5 8.14 8.07 38?58'51.40"N 76?53'48.84"W Arboretum 8/5/13 2:08 PM None 26.24 0.326 0.207 58.3 4.71 7.54 38?54'47.33"N 76?57'14.89"W Skateboard Park 8/5/13 3:01 PM None 25.90 0.387 0.247 143.7 11.67 7.93 38?56'44.04"N 76?56'50.35"W 1.17? Sligo Creek 8/5/13 3:51 PM None 24.37 0.508 0.337 110.9 9.34 8.63 38?58'15.38"N 76?58'48.36"W 1.2* Anacostia Park 8/5/13 4:44 PM None 22.12 0.283 0.195 63.5 5.52 7.95 38?58'16.25"N 76?54'57.93"W Riverdale Rd 8/5/13 4:08 PM None 24.27 0.317 0.209 130.9 10.92 8.67 38?57'37.55"N 76?55'33.67"W 17? Note: ?Discharge (ft3/s) obtained from USGS station 1651000, *Discharge (ft3/s) obtained from USGS station 1650800, ?Discharge (ft3/s) obtained from USGS station 1649500. (USGS, 2013); DO ? dissolved oxygen. 66 4.4.2 Herbicides and artificial sweeteners fate Similarly to Choptank River analysis, QA/QC, IS and calibration curves were checked. Surrogates presented acceptable recoveries and RSDs, IS showed acceptable RSDs, with SUC presenting the highest (RSD = 19%). QA/QC had good repeatability and good accuracy for all analytes except SUC, which presented good precision (RSD = 2%) but was underestimated by 40 percent. Correction with the IS or changing the calibration by not forcing it through zero did not change the results. As SUC is highly stable, the bias observed could not be related to analyte degradation. A wrong addition of the standard was also not possible, as all the standards were in one mix and only SUC presented the bias. A problem in the injection volume is also not possible as the rest of the analytes showed good performance. Moreover, ME could not be assumed to cause the problem because the IS was not able to correct for it. The identity of this bias is not clear and needs to be further studied. Nonetheless, SUC results are still useful to evaluate trends. No interferences were found in the laboratory or travel blanks at levels higher than the LCL and no significant carryover was observed. A summary of the results is shown in Table 11. ATZ and its metabolites were found in all the sites at concentrations lower than 50 ng/L (see Figure 11). In all cases, except Research Rd and Skateboard, ATZ had the highest concentration compared to its metabolites. Apart from crop usage of ATZ, it is also used in forestry and recreational turf. A USGS report on pesticides in groundwater in Anacostia River showed that ATZ was found at a maximum concentration of 106 ng/L in well water. Simazine was also found at 22 ng/L and CIAT, CEAT and OIET were also found and at lower 67 concentrations than the parent herbicide. Well water was also analyzed for MET, which was present at a maximum concentration of 53 ng/L (Koterba et al., 2010). Therefore, the levels observed were reasonable and comparable to groundwater herbicide levels. Figure 11. Concentrations (?g/L) found for a) ATZ and its metabolites and b) for MET, MESA and SUC by site sampled. MET and MESA were present in all sites at levels higher than 70 ng/L (see Figure 11). MET levels were equal or higher than MESA, except for Research Rd and Berwyn Rd. Subwatersheds with agricultural activities would require a higher application of MET; hence, Research Rd, Powder Mill Rd, North Dr Bridge should show the highest MET and MESA concentrations, which was observed. Moreover, the high presence of 68 MET compared to MESA could also be related to the percentage of impervious surface. Beaverdam Creek subwatershed has almost no impervious surface and contains well- drained soils, therefore MESA formation would be more favorable than in areas such as Sligo Creek. UMD presents a significantly higher MET level (0.37 ?g/L) compared to all other sites, which could be explained by the presence of a golf course located near the sampling site, as MET is used on turf grass. The fact that MESA was found at all locations sampled could be related to transport of MESA through the well-drained soils into the surficial aquifer, which is the major component of base flow in the river during the summer. Considering the land use of the subwatersheds under study (see Table 2), MESA was found to present a strong positive linear correlation with agricultural land use (R2 = 0.854, see Figure 12), and no significant relationship with residential areas. Moreover, MESA and forested land presented a weak positive linear correlation (R2 = 0.349) that was considerably affected by Greenbelt National Park site, which presented a very low concentration of MESA. If this site is removed the correlation becomes strong (R2 = 0.874). However, confounding with agricultural use could cause this apparent positive correlation, as most of the sites that are forested also presented agriculture, except for Greenbelt National Park, Sligo Creek and Riverdale. If the relationship between forest and agricultural land use is plotted a strong positive linear relationship (R2 = 0.910) is found, hence the variables are collinear, which explains the confounding observed for MESA. The attempt to relate transport of nitrate and MESA was unsuccessful as only one site was located in the tidal region. In future experiments more sites in the tidal region should be selected. Also, it would be interesting to evaluate nitrate, MESA, SUC and 69 ACE content in groundwater. Koterba et al. (2010) has already reported the presence of MET in groundwater and the presence MESA would be expected as soils in the watershed are generally well-drained and would allow for the transport of MESA and nitrate to the surficial aquifer. Figure 12. Concentration of MESA versus percentage of land used in agriculture. Linear trend and R2 are shown. The herbicides ALA and ACE were not identified but their ESA metabolites were found at levels lower than 0.2 ?g/L in all samples. As previously observed for Choptank samples, 2,4-D was not identified in Sligo Creek, Riverdale Rd, UMD and Powder Mill Rd. The National Arboretum showed the highest 2,4-D concentration of 0.7 ?g/L, followed by the Anacostia Park and Greenbelt National Park. Note that 2,4-D is an herbicide used in lawns, turf grass and forestry applications; hence its presence is not unexpected. 70 In the case of the artificial sweeteners, SAC was identified in all samples except for North Dr Bridge, Greenbelt National Park and Riverdale. In such an urban environment, SAC presence is expected as SAC is vastly consumed in the US. An interesting point of discussion was the positive identification of CYC in Anacostia Park, Greenbelt National Park and Skateboard; which should not happen as CYC has been banned for many years. CYC has only one ion ratio of 1%, and as the criteria for one ion ratio would accept all compounds with the correct m/z that present an ion ratio higher than zero and up to 11 percent, it could be identifying interferences. Note that the identification criteria were set to reduce false negative rate, but by doing so the false positive rate increases. Also, this observation supports the idea that three ion ratios, if available, increase the identification confidence, even though it requires more time for optimization and data treatment. SUC was found in 6 out of 11 sites at levels higher than the LCL. The relationship between SUC and nitrate was evaluated and a weak positive linear correlation was observed (R2 = 0.322), also when TN is considered the R2 increases to 0.547. When attempting to evaluate the relationship of SUC with OP, only 4 sites had results for SUC and OP simultaneously, which plotted revealed no significant correlation (R2 = 0.034). Nevertheless, OP and SUC could be related by associating how many sites presented OP and SUC at the same time and relate their presence with the site land use and population. OP was found in 6 sites from which 4 also had SUC, those 4 sites were Berwyn Rd, Sligo Creek, Riverdale and the National Arboretum. The site at Berwyn Rd was influenced by agriculture and wastewater or a sewage leak. Conversely, Sligo Creek was an urban area 71 with no significant agriculture. Riverdale Rd presented the combined influences of agricultural, forested and urban land. As OP and SUC presented no clear trend, the normalization of SUC by population (P) of each watershed was done and OP versus SUC/P was plotted. As shown in Figure 13 a strong positive linear correlation (R2 = 0.852, see Figure 13a) was observed. This is logical, as the amount of SUC present in wastewater will be related to the amount of population that produce the waste. Hence it was observed that the higher the amount of SUC per person found the higher the amount the OP detected. When evaluating the relationship between SUC and residential and industrial land use a positive linear correlation (R2 = 0.479, see Figure 13b) was observed. Note that as stated before more sampling is necessary to better evaluate this relationship as in this study only 3 points presented OP, SUC and land use data. Additionally, SUC correlated negatively with the percentage of forested area (R2 = 0.672, see Figure 13c), but as forested area and residential and industrial areas also present collinearity, confounding could cause the observation. Ultimately, SUC was found mainly in residential sites and related to OP when normalized by population on the subwatershed under study. Further sampling and considering season variations, would be needed to strength the assessment of SUC as a tracer of anthropogenic contamination of surface water. However, initial trends have been observed supporting the hypothesis that SUC could be used as a tracer of wastewater. 72 Figure 13. Relationship of: a) OP concentration versus SUC concentration normalized by population in each subwatershed; b) SUC concentration versus residential and industrial land use; c) SUC concentration versus forested land percentage. 73 Table 11. Quantified nutrients, herbicides, herbicides metabolites and sucralose in Anacostia River surface water by location sampled. Note: Rt ? retention times, LCL ? lowest calibration limit, RL ? reporting limit, * Not identified Analyte Rt (min) LCL (ng/L) Organic compounds concentrations found (ng/L) Greenbelt Park Anacostia Park Sligo Creek Skateboard Riverdale Rd Arboretum 1 Arboretum 2 OIET 2.14 5 7 8 7 7 18 12 13 Sucralose 2.24 100 125 < LCL 412 250 166 225 247 CEAT 2.27 5 5 13 6 7 19 11 11 CAAT 2.80 5 8 24 12 21 31 21 24 CIAT 2.81 0.5 8 21 12 20 28 19 21 Alachlor ESA + Acetochlor ESA 4.99 20 17 51 14 38 105 56 55 Metolachlor ESA 5.27 5 38 113 73 85 341 159 159 Atrazine 5.41 5 13 39 14 14 42 24 28 2.4-D 6.16 10 352 435 23* 177 54* 708 710 Metolachlor OH 7.28 1 < LCL 1.0 < LCL < LCL 2.0 1.3 1.5 Acetochlor 9.23 50 < LCL < LCL < LCL < LCL < LCL < LCL < LCL Alachlor 9.24 50 < LCL < LCL < LCL < LCL < LCL < LCL < LCL Metolachlor 9.29 50 156 149 163 148 394 218 260 RL (mg/L) Nutrient concentrations found Kjeldahl Nitrogen (mg/L as N) 0.4 < RL 1 0.6 0.5 0.6 0.6 0.8 Nitrate & Nitrite (mg/L as N) 0.05 0.33 0.32 0.71 0.55 0.51 0.33 0.32 Ortho Phosphorus (mg/L as P) 0.01 < RL 0.02 0.04 < RL 0.03 0.02 0.02 Total Phosphorus (mg/L as P) 0.05 < RL < RL 0.06 < RL 0.05 0.06 0.07 74 Table 11. Quantified nutrients, herbicides, herbicides metabolites and sucralose in Anacostia River surface water by location sampled. (Continued) Note: Rt ? retention times, LCL ? lowest calibration limit, RL ? reporting limit, * Not identified Analyte Rt (min) LCL (ng/L) Organic compounds concentrations found (ng/L) North Dr Bridge 1 North Dr Bridge 2 Research Rd Powder Mill Rd Berwyn Rd UMD OIET 2.14 5 10 10 34 8 21 11 Sucralose 2.24 100 < LCL < LCL < LCL < LCL 273 < LCL CEAT 2.27 5 20 20 22 11 14 13 CAAT 2.80 5 26 23 18 24 17 22 CIAT 2.81 0.5 23 22 20 23 17 21 Alachlor ESA + Acetochlor ESA 4.99 20 123 126 134 179 148 64 Metolachlor ESA 5.27 5 304 303 1188 213 533 214 Atrazine 5.41 5 33 33 18 30 23 26 2.4-D 6.16 10 < LCL < LCL 114 56* 30 21* Metolachlor OH 7.28 1 < LCL < LCL 2.2 < LCL 1.9 1.1 Acetochlor 9.23 50 < LCL < LCL < LCL < LCL < LCL < LCL Alachlor 9.24 50 < LCL < LCL < LCL < LCL < LCL < LCL Metolachlor 9.29 50 318 296 187 203 186 566 RL (mg/L) Nutrient concentrations found Kjeldahl Nitrogen (mg/L as N) 0.4 0.6 1.9 2.3 1.1 0.4 0.8 Nitrate & Nitrite (mg/L as N) 0.05 0.74 0.73 0.28 1.06 0.92 0.59 Ortho Phosphorus (mg/L as P) 0.01 < RL < RL 0.04 < RL 0.12 < RL Total Phosphorus (mg/L as P) 0.05 < RL < RL 0.07 < RL 0.11 < RL 75 4.5. Estimation of daily loads and comparison with TMDLs Daily loads were estimated for TN and TP as a theoretical exercise for those sites where flow rate was available. The equation used for calculation is shown in the Appendix A.4; note that the main assumptions done were that the flow rate would not present a significant variability during the day, the TN and TP measured were representative of the average daily concentration and were constant along the river column at the specified location. As shown in Table 12 all sites in either Anacostia or Choptank River were under their respective TMDLs. Table 12. Daily loads estimated for the watersheds with discharge flow available (m3/s). Note: # TMDLs obtained from US EPA (2013a). * local TMDLs were obtained from Miller et al. (2013). CHOPTANK RIVER Site ID Discharge (m3/s) TN TP (kg/d) (kg/d) Cordova 2.2 1162 32 German Branch 2.2 387 27 Tuckahoe 1 2.2 1156 23 Tuckahoe 2 2.2 1165 23 Greensboro 1 3.8 - 46 Greensboro 2 3.8 - 30 Beaver Dam 2.2 683 25 Long Marsh 2.2 315 28 TMDL (kg/d)# 1792 193 ANACOSTIA RIVER Site ID Discharge (m3/s) TN TP (kg/d) (kg/d) Skateboard Park 0.033 3 - Sligo Creek 0.034 4 0.2 Riverdale Rd 0.5 46 2.1 TMDL (kg/d)* 191 19 76 It is important to notice that TMDLs are carefully estimated by determining allocations for point and non-point sources and adding a margin of safety for which various models are used in order to account for strong weather events and seasonal variations (US EPA, 2010a). Therefore, the results obtained were expected as the study was done during the summer period and under base flow conditions. When TMDLs are developed the determination of sources type and its relative importance in nutrient loadings is assessed using land use information, satellite observations, known point-source locations, possible natural presence and several watershed loading models (US EPA, 1999). Defining unique tracers that differentiate between agricultural (non-point sources) and anthropogenic (point sources) loadings could be of significant assistance for TMDLs determination. Allocations and regulation are generally more easily done and applied at point sources where influent and effluent nutrients concentrations and flows are well known. Nevertheless, other point sources such as unexpected septic systems leakage could be missed. The use of a tracer such as SUC or ACE could be helpful to determine other unexpected anthropogenic sources. Moreover, the magnitude of non-point sources such as agriculture or atmospheric deposition is difficult to quantify; e.g. groundwater transports nitrate that could come from crop plantations and/or septic tanks or sewer leakage into the river, simultaneous measurement of tracers and nitrate could help to assess the nitrate source(s) and determine which source contributes more to the nitrate enrichment. In this way nutrient load allocations will be better justified, allowing for a fair enforcement and the improvement of restoration efforts at the sources that needs it the most. 77 Chapter 5: Conclusions A previously developed extraction method for herbicide metabolites was successfully extended to analyze for herbicide, herbicide metabolites and artificial sweeteners by LC-MS/MS. The analytical method developed was able to identify 16 and quantify 14 out of the 17 analytes under study, in 13 minutes run time. Quantification was possible for all herbicides and sucralose, but not for other artificial sweeteners. The addition of identification capabilities increased the confidence of the results and helped assess analytes that could not be quantified. The developed method will allow for the analysis of previously extracted and stored samples from Choptank River in a retrospective study. Recommendations for method improvement were stated during the discussion and the infusion of TRIS buffer will be considered when archive sample are analyzed. Moreover, matrix effects assessment allowed for a better understanding of the results obtained in natural samples and to recognize whether isotopically labeled internal standards were needed. Choptank River results obtained were comparable to previous studies. Hence, the extended method proved to be effective and could substitute the two methods that were previously used for the analysis of river samples. Nutrients and herbicides followed previously described trends, except for the lack of biological degradation observed for nitrate. Sucralose was determined only in urbanized areas; however, its high LCL and variable ionization limited the evaluation of trends and comparisons with nutrient levels. MESA as expected showed to be a good tracer for agricultural nitrate loadings. 78 Anacostia River results were very interesting; to the best of my knowledge this is the first study that analyzed nutrients, herbicides and sucralose simultaneously in surface water, covering all the major subwatersheds. Nitrate and ortho phosphorus were lower than average at the USGS stations for the month of August. No trends were observed for nitrate and MESA. The results obtained for sucralose seemed promising even though the data collected was limited. In the case of ortho phosphorus a preliminary linear trend was observed when considering sucralose consumption per capita, but more sampling is needed in order to better support this observation. Overall, MESA was found at higher levels in agricultural areas and sucralose was found only in urbanized areas. This work provides proof of concept that sucralose and MESA could be used as tracers of urban and agricultural nutrient loadings. Regarding other analytes under study, metolachlor findings in Anacostia River watershed were of concern, as the levels found were comparable to Choptank River, though Anacostia watershed is not a highly agricultural area. Hence, better management practices and education are necessary for metolachlor application by the general public to lawns and grass turf in recreational areas. The author recommends that in future works a new sampling site located in Northwest Branch, before its combination with Sligo Creek, could be added as this subwatershed has 9 percent of land used for agriculture, but contrary to Beaverdam it does not present any WWTP that discharge into the river. Also, the final method should be improved in order to include acesulfame because this compound is generally found at 79 higher levels than sucralose and is more stable in groundwater. The addition of groundwater sampling would allow for a more comprehensive view of the nutrients fate in the watersheds. Moreover, sampling during storm events would be very interesting to better study possible relationships between runoff of pollutants and land use, and to evaluate the behavior of the WWTPs at the USDA in Beltsville and their impact on water quality. 80 Appendices APPENDIX A ? Equations and calculations A.1 Recovery percentage: % = ? ? A.2 Ion ratios: % = ? Identification criteria: 1) Rt falls inside ? 0.1 2) 2 transitions available: ion ratio falls inside ( ? 10%) 3) 3 transitions available: ion ratio falls inside ( ? 20%) As shown in the following appendices if the analyte falls inside the criteria the cell will show a number 1. Conversely, when the criteria are not met a 0 will appear. Carry over and interferences should also be checked. A.3 Matrix Effects: % = ! ? MM ? matrix matched, SO ? solvent only A.4 Nutrient loads: = ? ? ? ? . 81 APPENDIX B ? Recovery test raw data Quantify Compound Summary Report Printed Mon Oct 21 14:09:34 2013 Compound 1: CAAT Compound 1: CAAT yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 0 2 2013OCT20_RO Blank 7.976 0 3 2013OCT20_Blk_1 Blank 0 4 2013OCT20_Blk_2 Blank 0 5 2013OCT20_0-01_Std Standard 0.01 0 0.01 6 2013OCT20_0-05_Std Standard 0.05 0 0.05 7 2013OCT20_0-1_Std Standard 0.1 45.576 0 0.10 8 2013OCT20_0-5_Std Standard 0.5 2.8 1258.228 1199.623 672.946 1 0.50 29% 9 2013OCT20_1_Std Standard 1 2.8 2262.06 1835.016 745.286 1 1.00 16% 10 2013OCT20_5_Std Standard 5 2.8 13016.637 10103.697 6896.179 1 5 33% 11 2013OCT20_10_Std Standard 10 2.8 24177.07 18928.414 13083.33 1 10 24% 12 2013OCT20_25_Std Standard 25 2.8 59734.621 47366.344 30596.385 1 25 22% 13 2013OCT20_50_Std Standard 50 2.8 108978.461 86704.016 59483.414 1 50 12% 14 2013OCT20_100_Std Standard 100 2.8 206410.047 166655.563 109063.266 1 100 6% 15 2013OCT20_200_Stds Standard 200 2.8 380945.625 316710.406 208743.313 1 200 -3% 16 2013OCT20_SolvA_3 2.81 297.349 39.822 189.452 0 17 2013OCT20_Surrogate 76.566 0 18 2013OCT20_SolvA_4 67.932 221.393 0 19 2013OCT20_SolvA_5 6.898 0 %Recovery 20 2013OCT20_Lo_1 Recovery 50 2.8 119666 96744.133 64575.59 1 Low-Spk1 119% 21 2013OCT20_Lo_2 Recovery 50 2.81 94626.695 76465.164 51026.531 1 Low-Spk2 93% 22 2013OCT20_Lo_3 Recovery 50 2.8 112090.602 91909.891 59345.551 1 Low-Spk3 111% 23 2013OCT20_Lo_4 Recovery 50 2.8 114921.273 94113.039 62514.672 1 Low-Spk4 114% 24 2013OCT20_Lo_5 Recovery 50 2.8 101253.258 83244.359 53009.203 1 Low-Spk5 100% 25 2013OCT20_SolvA_6 54.866 2.647 0 26 2013OCT20_SolvA_7 17.552 0 27 2013OCT20_Mid_1 Recovery 100 2.8 205103.609 167792.703 112619.992 1 Mid-Spk1 104% 28 2013OCT20_Mid_2 Recovery 100 2.8 228606.328 188004.328 124912.375 1 Mid-Spk2 117% 29 2013OCT20_Mid_3 Recovery 100 2.8 219529.609 183427.625 120279.375 1 Mid-Spk3 112% 30 2013OCT20_Mid_4 Recovery 100 2.81 211683.688 177614.906 115212.219 1 Mid-Spk4 108% 31 2013OCT20_Mid_5 Recovery 100 2.81 208852.188 173721.672 114611.141 1 Mid-Spk5 106% 32 2013OCT20_SolvA_8 21.394 0 33 2013OCT20_SolvA_9 124.523 0 34 2013OCT20_Std Dil 200_1 2.8 272602.125 230098.25 151622.375 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 135.319 0 82 36 2013OCT20_Dil_Hi_1 Recovery 100 2.8 285925.656 234011.375 159088.797 1 Hi-Dil-Spk1 105% 37 2013OCT20_Dil_Hi_2 Recovery 100 2.8 290359.75 242261.078 161071.063 1 Hi-Dil-Spk2 107% 38 2013OCT20_Dil_Hi_3 Recovery 100 2.8 293984.094 243651.734 159788.813 1 Hi-Dil-Spk3 108% 39 2013OCT20_Dil_Hi_4 Recovery 100 2.8 309332.906 257327.203 168681.875 1 Hi-Dil-Spk4 114% 40 2013OCT20_Dil_Hi_5 Recovery 100 2.8 333996.625 274530.25 183202.141 1 Hi-Dil-Spk5 123% 41 2013OCT20_SolvA_11 15.866 0 42 2013OCT20_Std Dil 200_2 2.8 275637.438 226878.203 151444.234 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 119.761 55.983 0 44 2013OCT20_Hi_1 Recovery 200 2.8 389104.938 325976 216856.672 1 Hi-Spk1 100% 45 2013OCT20_Hi_2 Recovery 200 2.8 394432.281 329592.063 222818.859 1 Hi-Spk2 102% 46 2013OCT20_Hi_3 Recovery 200 2.81 395871.438 331984.969 217604.172 1 Hi-Spk3 102% 47 2013OCT20_Hi_4 Recovery 200 2.8 407442.188 344944.906 228877.047 1 Hi-Spk4 105% 48 2013OCT20_Hi_5 Recovery 200 2.8 454533.406 372436.313 250546.594 1 Hi-Spk5 117% 49 2013OCT20_SolvA_13 0 50 2013OCT20_SolvA_14 0 51 2013OCT20_0-01_Std_2 Standard 0.01 0 52 2013OCT20_0-05_Std_2 Standard 0.05 0 53 2013OCT20_0-1_Std_2 Standard 0.1 2.81 585.77 332.903 153.601 0 54 2013OCT20_0-5_Std_2 Standard 0.5 2.81 1185.524 1065.666 732.184 1 55 2013OCT20_1_Std_2 Standard 1 2.8 1989.696 1645.446 975.7 1 56 2013OCT20_5_Std_2 Standard 5 2.8 13537.404 10898.75 7379.012 1 57 2013OCT20_10_Std_2 Standard 10 2.81 24124.383 19791.512 13220.268 1 58 2013OCT20_25_Std_2 Standard 25 2.8 59380.137 48922.34 31755.867 1 59 2013OCT20_50_Std_2 Standard 50 2.8 103704.438 84635.398 56616.828 1 60 2013OCT20_100_Std_2 Standard 100 2.8 201336.641 165784.969 110487.328 1 61 2013OCT20_200_Std_2 Standard 200 2.8 375376.5 310194.375 206465.484 1 62 2013OCT20_SolvA_15 0 63 2013OCT20_Surrogate_2 0 64 2013OCT20_SolvA_16 0 Compound 2: CEAT Compound 2: CEAT yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 0 2 2013OCT20_RO Blank 0 3 2013OCT20_Blk_1 Blank 0 4 2013OCT20_Blk_2 Blank 0 5 2013OCT20_0-01_Std Standard 0.01 0 0.01 6 2013OCT20_0-05_Std Standard 0.05 2.27 415.948 288.159 0 0.05 7 2013OCT20_0-1_Std Standard 0.1 2.27 783.495 977.3 0 0.10 8 2013OCT20_0-5_Std Standard 0.5 2.27 3172.609 4093.334 4117.87 1 0.50 -2% 9 2013OCT20_1_Std Standard 1 2.27 7066.682 8217.298 10083.586 1 1.00 9% 10 2013OCT20_5_Std Standard 5 2.27 38501.289 41801.289 51135.555 1 5 18% 11 2013OCT20_10_Std Standard 10 2.27 75157.578 79005.523 98707.969 1 10 15% 12 2013OCT20_25_Std Standard 25 2.27 184398.266 193083.141 241247.594 1 25 13% 13 2013OCT20_50_Std Standard 50 2.27 353342.969 359302.969 443901.75 1 50 9% 14 2013OCT20_100_Std Standard 100 2.27 672305.875 693774.563 854653.938 1 100 3% 83 15 2013OCT20_200_Stds Standard 200 2.27 1280402.875 1340838.5 1664210.75 1 200 -2% 16 2013OCT20_SolvA_3 79.021 341.964 0 17 2013OCT20_Surrogate 89.709 0 18 2013OCT20_SolvA_4 397.311 0 19 2013OCT20_SolvA_5 68.308 329.526 0 %Recovery 20 2013OCT20_Lo_1 Recovery 50 2.27 389348.063 391261.781 494563.906 1 Low-Spk1 117% 21 2013OCT20_Lo_2 Recovery 50 2.27 312626.844 323419.625 395297.313 1 Low-Spk2 93% 22 2013OCT20_Lo_3 Recovery 50 2.27 353612.875 355322.719 445947.688 1 Low-Spk3 106% 23 2013OCT20_Lo_4 Recovery 50 2.27 371739.406 378923.25 468915.969 1 Low-Spk4 112% 24 2013OCT20_Lo_5 Recovery 50 2.27 326706.938 330432.969 405236.938 1 Low-Spk5 98% 25 2013OCT20_SolvA_6 631.341 0 26 2013OCT20_SolvA_7 442.059 0 27 2013OCT20_Mid_1 Recovery 100 2.27 688387.188 698957.625 858849.188 1 Mid-Spk1 105% 28 2013OCT20_Mid_2 Recovery 100 2.27 771417.188 786523.125 971656.688 1 Mid-Spk2 118% 29 2013OCT20_Mid_3 Recovery 100 2.27 724581.938 741948.188 919239.875 1 Mid-Spk3 111% 30 2013OCT20_Mid_4 Recovery 100 2.27 700286.5 705506.875 890112.063 1 Mid-Spk4 107% 31 2013OCT20_Mid_5 Recovery 100 2.27 702370.75 719883.375 888406.625 1 Mid-Spk5 108% 32 2013OCT20_SolvA_8 248.929 51.959 0 33 2013OCT20_SolvA_9 98.889 636.495 0 34 2013OCT20_Std Dil 200_1 2.27 863870.438 890767.313 1090265.875 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 110.365 606.261 0 36 2013OCT20_Dil_Hi_1 Recovery 100 2.27 892507.875 940061.875 1152075.5 1 Hi-Dil-Spk1 103% 37 2013OCT20_Dil_Hi_2 Recovery 100 2.27 911045.688 968415.813 1166124.5 1 Hi-Dil-Spk2 106% 38 2013OCT20_Dil_Hi_3 Recovery 100 2.27 914504.438 966411 1157969.875 1 Hi-Dil-Spk3 106% 39 2013OCT20_Dil_Hi_4 Recovery 100 2.27 975007.625 1016709.438 1228555.75 1 Hi-Dil-Spk4 113% 40 2013OCT20_Dil_Hi_5 Recovery 100 2.27 1049443.25 1123380.375 1362598.625 1 Hi-Dil-Spk5 122% 41 2013OCT20_SolvA_11 746.247 237.411 0 42 2013OCT20_Std Dil 200_2 2.27 874455 903508.563 1093108.75 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 97.253 277.281 0 44 2013OCT20_Hi_1 Recovery 200 2.27 1405790.5 1458119.625 1791898.125 1 Hi-Spk1 109% 45 2013OCT20_Hi_2 Recovery 200 2.27 1399396.875 1451796.375 1747705.625 1 Hi-Spk2 108% 46 2013OCT20_Hi_3 Recovery 200 2.27 1396335.5 1447514.5 1808063.75 1 Hi-Spk3 108% 47 2013OCT20_Hi_4 Recovery 200 2.27 1488477.5 1537366.75 1910745.125 1 Hi-Spk4 115% 48 2013OCT20_Hi_5 Recovery 200 2.27 1606128.625 1664021.5 2050174.625 1 Hi-Spk5 124% 49 2013OCT20_SolvA_13 1441.216 1045.293 0 50 2013OCT20_SolvA_14 395.324 0 51 2013OCT20_0-01_Std_2 Standard 0.01 230.623 0 52 2013OCT20_0-05_Std_2 Standard 0.05 2.28 583.969 420.059 0 53 2013OCT20_0-1_Std_2 Standard 0.1 2.27 792.733 487.627 0 54 2013OCT20_0-5_Std_2 Standard 0.5 2.27 3570.871 3865.621 5819.084 1 55 2013OCT20_1_Std_2 Standard 1 2.27 7266.933 7183.409 8854.171 1 56 2013OCT20_5_Std_2 Standard 5 2.27 40080.723 41788.316 49634.91 1 57 2013OCT20_10_Std_2 Standard 10 2.27 75684.57 81840.563 96552.172 1 58 2013OCT20_25_Std_2 Standard 25 2.27 188794.484 199185.391 250625.922 1 59 2013OCT20_50_Std_2 Standard 50 2.27 343328.406 363094.688 444769.656 1 60 2013OCT20_100_Std_2 Standard 100 2.27 694518.938 712060.188 891550.75 1 84 61 2013OCT20_200_Std_2 Standard 200 2.27 1330697.75 1359474.625 1703041.5 1 62 2013OCT20_SolvA_15 195.483 384.417 0 63 2013OCT20_Surrogate_2 130.945 0 64 2013OCT20_SolvA_16 183.919 12.803 0 Compound 3: CIAT Compound 3: CIAT yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 85.631 15.497 #DIV/0! 2 2013OCT20_RO Blank 1029.752 #DIV/0! 3 2013OCT20_Blk_1 Blank 2.81 2463.316 1964.605 9243.589 1 4 2013OCT20_Blk_2 Blank 2.81 1258.965 1124.885 5805.205 1 5 2013OCT20_0-01_Std Standard 0.01 195.824 1338.714 0 6 2013OCT20_0-05_Std Standard 0.05 2.8 1168.122 1056.462 4685.404 1 0.05 12% 7 2013OCT20_0-1_Std Standard 0.1 2.8 3689.747 2546.417 13178.251 1 0.10 77% 8 2013OCT20_0-5_Std Standard 0.5 2.8 12292.964 11401.799 53151.461 1 0.50 18% 9 2013OCT20_1_Std Standard 1 2.81 23619.771 20844.785 100445.07 1 1.00 13% 10 2013OCT20_5_Std Standard 5 2.81 146623.719 125769.68 558098.563 1 5 41% 11 2013OCT20_10_Std Standard 10 2.81 280421 242700.469 1070687.375 1 10 35% 12 2013OCT20_25_Std Standard 25 2.81 646204.688 555985.438 2501321.75 1 25 24% 13 2013OCT20_50_Std Standard 50 2.81 1186433.75 1031127.813 4627194 1 50 14% 14 2013OCT20_100_Std Standard 100 2.8 2185845 1915146.625 7787849 1 100 5% 15 2013OCT20_200_Stds Standard 200 2.8 4052984 3594802.5 10582010 1 200 -3% 16 2013OCT20_SolvA_3 2.81 275.155 363.115 2112.156 1 17 2013OCT20_Surrogate 146.059 511.7 0 18 2013OCT20_SolvA_4 2.8 111.957 299.33 0 19 2013OCT20_SolvA_5 220.35 253.999 0 %Recovery 20 2013OCT20_Lo_1 Recovery 50 2.81 1287274.125 1131657.875 5043359.5 1 Low-Spk1 121% 21 2013OCT20_Lo_2 Recovery 50 2.81 997580.25 863581.688 3788629.5 1 Low-Spk2 92% 22 2013OCT20_Lo_3 Recovery 50 2.81 1208021.5 1059032.875 4698365.5 1 Low-Spk3 113% 23 2013OCT20_Lo_4 Recovery 50 2.81 1251938.375 1099486.125 4883571 1 Low-Spk4 117% 24 2013OCT20_Lo_5 Recovery 50 2.81 1113198.5 975221.5 4303801 1 Low-Spk5 104% 25 2013OCT20_SolvA_6 834.754 0 26 2013OCT20_SolvA_7 2.79 511.109 169.113 997.904 0 27 2013OCT20_Mid_1 Recovery 100 2.81 2258754.25 1990316.125 7752882 1 Mid-Spk1 108% 28 2013OCT20_Mid_2 Recovery 100 2.81 2470544.75 2205434.25 8147580.5 1 Mid-Spk2 118% 29 2013OCT20_Mid_3 Recovery 100 2.81 2311234.5 2058838 7918762.5 1 Mid-Spk3 111% 30 2013OCT20_Mid_4 Recovery 100 2.81 2241418.75 1979973.375 7725296 1 Mid-Spk4 107% 31 2013OCT20_Mid_5 Recovery 100 2.81 2275064.5 2024494 7890510.5 1 Mid-Spk5 109% 32 2013OCT20_SolvA_8 2.81 435.881 168.284 2107.568 1 33 2013OCT20_SolvA_9 2.83 242.451 145.893 1365.393 0 34 2013OCT20_Std Dil 200_1 2.81 3127388.5 2770348 9360774 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 2.81 490.721 325.188 1816.922 1 36 2013OCT20_Dil_Hi_1 Recovery 100 2.81 3258795.5 2914638 9428854 1 Hi-Dil-Spk1 104% 37 2013OCT20_Dil_Hi_2 Recovery 100 2.81 3317454.5 2963927.5 9452466 1 Hi-Dil-Spk2 106% 38 2013OCT20_Dil_Hi_3 Recovery 100 2.81 3302634.75 2954490.25 9385968 1 Hi-Dil-Spk3 106% 39 2013OCT20_Dil_Hi_4 Recovery 100 2.81 3489434.5 3115916.5 9675330 1 Hi-Dil-Spk4 112% 85 40 2013OCT20_Dil_Hi_5 Recovery 100 2.81 3800662 3394636.25 9991555 1 Hi-Dil-Spk5 122% 41 2013OCT20_SolvA_11 2.79 405.228 523.414 2010.658 1 42 2013OCT20_Std Dil 200_2 2.81 3149322 2810184.75 9242747 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 43.362 192.841 0 44 2013OCT20_Hi_1 Recovery 200 2.81 4221547 3761716.5 10322884 1 Hi-Spk1 102% 45 2013OCT20_Hi_2 Recovery 200 2.81 4344650 3855550.5 10617671 1 Hi-Spk2 105% 46 2013OCT20_Hi_3 Recovery 200 2.81 4262171 3853692 10546113 1 Hi-Spk3 103% 47 2013OCT20_Hi_4 Recovery 200 2.81 4409088 3959446 10478779 1 Hi-Spk4 107% 48 2013OCT20_Hi_5 Recovery 200 2.81 4908160 4370887.5 10798885 1 Hi-Spk5 119% 49 2013OCT20_SolvA_13 2.81 922.317 948.466 2620.002 1 50 2013OCT20_SolvA_14 2.83 591.174 380 349.587 0 51 2013OCT20_0-01_Std_2 Standard 0.01 288.86 1167.527 0 52 2013OCT20_0-05_Std_2 Standard 0.05 2.82 1209.195 1287.684 4957.394 1 53 2013OCT20_0-1_Std_2 Standard 0.1 2.8 3376.089 2552.232 13293.232 1 54 2013OCT20_0-5_Std_2 Standard 0.5 2.81 13797.839 11408.416 50351.43 1 55 2013OCT20_1_Std_2 Standard 1 2.81 24755.975 21565.498 93485.344 1 56 2013OCT20_5_Std_2 Standard 5 2.81 146288 123704.133 541080.188 1 57 2013OCT20_10_Std_2 Standard 10 2.81 274016.688 235844.766 1028407.063 1 58 2013OCT20_25_Std_2 Standard 25 2.81 654372.188 578205.188 2482768.75 1 59 2013OCT20_50_Std_2 Standard 50 2.81 1162715.625 1024756.438 4438171.5 1 60 2013OCT20_100_Std_2 Standard 100 2.8 2219679.75 1960627.75 7827258 1 61 2013OCT20_200_Std_2 Standard 200 2.81 4134005.25 3687232.25 10467846 1 62 2013OCT20_SolvA_15 59.453 753.194 #DIV/0! 63 2013OCT20_Surrogate_2 2.8 286.439 162.316 536.471 0 64 2013OCT20_SolvA_16 276.326 1501.76 #DIV/0! Compound 4: OIET Compound 4: OIET yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 2.11 1003.646 1454.886 2132.5 0 2 2013OCT20_RO Blank 2.15 601.476 728.998 800.043 0 3 2013OCT20_Blk_1 Blank 427.861 1109.476 0 4 2013OCT20_Blk_2 Blank 2.14 441.323 675.587 1346.151 1 5 2013OCT20_0-01_Std Standard 0.01 2.14 1045.999 2347.157 2641.3 1 0.01 269% 6 2013OCT20_0-05_Std Standard 0.05 2.13 2215.703 4221.731 5772.011 1 0.05 56% 7 2013OCT20_0-1_Std Standard 0.1 2.14 4115.08 8048.595 12189.408 1 0.10 45% 8 2013OCT20_0-5_Std Standard 0.5 2.13 18085.811 31942.469 48282.395 1 0.50 28% 9 2013OCT20_1_Std Standard 1 2.14 36379.918 62490.438 93589.305 1 1.00 28% 10 2013OCT20_5_Std Standard 5 2.14 107443.781 190032.938 276279.906 1 5 -24% 11 2013OCT20_10_Std Standard 10 2.14 199816.297 360751.281 519755.25 1 10 -29% 12 2013OCT20_25_Std Standard 25 2.14 526782.688 942878.438 1408137.75 1 25 -26% 13 2013OCT20_50_Std Standard 50 2.14 1412124.75 2506919.25 3671745.25 1 50 0% 14 2013OCT20_100_Std Standard 100 2.13 2888709.5 5069080 6544256.5 1 100 2% 15 2013OCT20_200_Stds Standard 200 2.14 5665272 7809984 8467760 1 200 0% 16 2013OCT20_SolvA_3 2.14 598.154 1372.323 2009.964 1 17 2013OCT20_Surrogate 2.14 470.432 725.056 1179.782 1 18 2013OCT20_SolvA_4 234.001 319.084 0 86 19 2013OCT20_SolvA_5 2.13 779.068 534.259 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 2.14 1741426.25 3103699.25 4542380.5 1 Low-Spk1 124% 21 2013OCT20_Lo_2 Recovery 50 2.14 1622958.625 2901804 4219265 1 Low-Spk2 116% 22 2013OCT20_Lo_3 Recovery 50 2.14 1599225.375 2859715.25 4182931.75 1 Low-Spk3 114% 23 2013OCT20_Lo_4 Recovery 50 2.14 1673461.75 3019717.5 4353575.5 1 Low-Spk4 119% 24 2013OCT20_Lo_5 Recovery 50 2.14 1191895.75 2108508.75 3077275.75 1 Low-Spk5 86% 25 2013OCT20_SolvA_6 2.14 287.949 591.964 847.54 1 26 2013OCT20_SolvA_7 424.822 924.867 0 27 2013OCT20_Mid_1 Recovery 100 2.14 2963414.25 5202250.5 6487812 1 Mid-Spk1 105% 28 2013OCT20_Mid_2 Recovery 100 2.14 3448847.5 5758025.5 7056416 1 Mid-Spk2 122% 29 2013OCT20_Mid_3 Recovery 100 2.14 3033985.5 5284930.5 6611572.5 1 Mid-Spk3 107% 30 2013OCT20_Mid_4 Recovery 100 2.14 3308349 5572236 6859055.5 1 Mid-Spk4 117% 31 2013OCT20_Mid_5 Recovery 100 2.14 3068511.5 5246790.5 6576795 1 Mid-Spk5 109% 32 2013OCT20_SolvA_8 2.14 422.127 1681.124 1683.97 0 33 2013OCT20_SolvA_9 733.492 1367.03 0 34 2013OCT20_Std Dil 200_1 2.14 3625631.75 5877988 7294635.5 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 936.25 2376.348 0 36 2013OCT20_Dil_Hi_1 Recovery 100 2.14 3676405 5979876.5 7345524 1 Hi-Dil-Spk1 101% 37 2013OCT20_Dil_Hi_2 Recovery 100 2.14 3519430.75 5743852 7274539 1 Hi-Dil-Spk2 97% 38 2013OCT20_Dil_Hi_3 Recovery 100 2.14 3973051.75 6264636 7577615 1 Hi-Dil-Spk3 110% 39 2013OCT20_Dil_Hi_4 Recovery 100 2.14 4092383.25 6457460 7704681.5 1 Hi-Dil-Spk4 113% 40 2013OCT20_Dil_Hi_5 Recovery 100 2.14 4302242.5 6616354 7847378.5 1 Hi-Dil-Spk5 119% 41 2013OCT20_SolvA_11 2.14 1068.524 855.574 3287.978 0 42 2013OCT20_Std Dil 200_2 2.14 3587845.25 5915772 7300940 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 2.14 885.323 1864.909 2480.21 1 44 2013OCT20_Hi_1 Recovery 200 2.14 5762103 7806691.5 8561290 1 Hi-Spk1 101% 45 2013OCT20_Hi_2 Recovery 200 2.14 5577947 7640868.5 8462045 1 Hi-Spk2 98% 46 2013OCT20_Hi_3 Recovery 200 2.14 6022559 8042607.5 8702580 1 Hi-Spk3 106% 47 2013OCT20_Hi_4 Recovery 200 2.14 6245686.5 8069078 8811420 0 Hi-Spk4 110% 48 2013OCT20_Hi_5 Recovery 200 2.14 6300963 8169991 8893430 0 Hi-Spk5 111% 49 2013OCT20_SolvA_13 2.12 1481.051 2332.011 4993.162 0 50 2013OCT20_SolvA_14 2.13 1295.845 1707.394 2981.911 1 51 2013OCT20_0-01_Std_2 Standard 0.01 2.13 964.765 2293.904 2943.622 1 52 2013OCT20_0-05_Std_2 Standard 0.05 2.13 2192.072 4825.955 6570.065 1 53 2013OCT20_0-1_Std_2 Standard 0.1 2.13 4567.367 8339.729 12234.82 1 54 2013OCT20_0-5_Std_2 Standard 0.5 2.13 18869.23 32180.588 45523.133 1 55 2013OCT20_1_Std_2 Standard 1 2.14 35852.313 63940.613 93328.266 1 56 2013OCT20_5_Std_2 Standard 5 2.13 107744 188201.281 277274.813 1 57 2013OCT20_10_Std_2 Standard 10 2.13 203906.375 355507.188 521402 1 58 2013OCT20_25_Std_2 Standard 25 2.13 543297.813 975553.875 1383454.125 1 59 2013OCT20_50_Std_2 Standard 50 2.13 1407242.125 2471949.75 3642615.75 1 60 2013OCT20_100_Std_2 Standard 100 2.13 2948018.25 5170458 6538136 1 61 2013OCT20_200_Std_2 Standard 200 2.14 5702328.5 7728742.5 8492683 1 62 2013OCT20_SolvA_15 2.14 1163.382 1579.843 3200.378 1 63 2013OCT20_Surrogate_2 2.13 467.464 2390.7 1581.656 0 64 2013OCT20_SolvA_16 566.548 1094.708 0 87 Compound 5: Atrazine Compound 5: Atrazine yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 137.176 #DIV/0! 2 2013OCT20_RO Blank 5.41 882.031 1331.144 3924.588 1 3 2013OCT20_Blk_1 Blank 5.42 8431.158 9378.713 29153.504 1 4 2013OCT20_Blk_2 Blank 5.41 5559.839 5680.042 17733.59 1 5 2013OCT20_0-01_Std Standard 0.01 5.41 1630.961 2083.22 5551.66 1 0.01 208% 6 2013OCT20_0-05_Std Standard 0.05 5.41 4026.463 5233.563 12826.558 1 0.05 52% 7 2013OCT20_0-1_Std Standard 0.1 5.41 6781.475 9683.013 26484.848 1 0.10 28% 8 2013OCT20_0-5_Std Standard 0.5 5.41 30834.508 40060.609 110107.594 1 0.50 17% 9 2013OCT20_1_Std Standard 1 5.41 62820.531 78837.867 230984.297 1 1.00 19% 10 2013OCT20_5_Std Standard 5 5.41 311491.094 387509.719 1088920.625 1 5 18% 11 2013OCT20_10_Std Standard 10 5.41 607146 751324.625 2122048 1 10 15% 12 2013OCT20_25_Std Standard 25 5.41 1523138.375 1879446.75 5330925.5 1 25 15% 13 2013OCT20_50_Std Standard 50 5.41 2905205 3576907 9870623 1 50 10% 14 2013OCT20_100_Std Standard 100 5.41 5558347 6835383.5 13438513 1 100 5% 15 2013OCT20_200_Stds Standard 200 5.41 10342082 11682553 15936867 0 200 -2% 16 2013OCT20_SolvA_3 473.654 2348.669 0 17 2013OCT20_Surrogate 5.41 3326.807 4354.109 12498.012 1 18 2013OCT20_SolvA_4 114.526 717.033 0 19 2013OCT20_SolvA_5 5.43 182.279 254.795 516.49 1 %Recovery 20 2013OCT20_Lo_1 Recovery 50 5.41 3068328.25 3775764.75 10293343 1 Low-Spk1 114% 21 2013OCT20_Lo_2 Recovery 50 5.41 2741919.25 3387418.25 9393866 1 Low-Spk2 102% 22 2013OCT20_Lo_3 Recovery 50 5.41 2682157.25 3270923.75 9387948 1 Low-Spk3 100% 23 2013OCT20_Lo_4 Recovery 50 5.41 2872147 3497926 9793223 1 Low-Spk4 107% 24 2013OCT20_Lo_5 Recovery 50 5.41 2405866.5 2950294.75 8367722 1 Low-Spk5 89% 25 2013OCT20_SolvA_6 295.064 869.447 0 26 2013OCT20_SolvA_7 410.99 929.762 0 27 2013OCT20_Mid_1 Recovery 100 5.41 5189540.5 6459893 13150176 1 Mid-Spk1 98% 28 2013OCT20_Mid_2 Recovery 100 5.41 6201140.5 7607733 13910524 1 Mid-Spk2 117% 29 2013OCT20_Mid_3 Recovery 100 5.41 5547153.5 6765988.5 13452804 1 Mid-Spk3 105% 30 2013OCT20_Mid_4 Recovery 100 5.42 5185106 6346703.5 13075441 1 Mid-Spk4 98% 31 2013OCT20_Mid_5 Recovery 100 5.42 5537213 6813969.5 13321073 1 Mid-Spk5 104% 32 2013OCT20_SolvA_8 1133.621 2457.117 0 33 2013OCT20_SolvA_9 5.43 265.44 470.301 1422.874 1 34 2013OCT20_Std Dil 200_1 5.42 5395992.5 6626809 13220740 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 5.4 338.278 660.603 1625.692 1 36 2013OCT20_Dil_Hi_1 Recovery 100 5.41 5976505.5 7264668 13811186 1 Hi-Dil-Spk1 111% 37 2013OCT20_Dil_Hi_2 Recovery 100 5.41 5718677 6996378.5 13619189 1 Hi-Dil-Spk2 106% 38 2013OCT20_Dil_Hi_3 Recovery 100 5.41 5704524 6999661 13640972 1 Hi-Dil-Spk3 106% 39 2013OCT20_Dil_Hi_4 Recovery 100 5.41 6158776 7545298 14025984 1 Hi-Dil-Spk4 114% 40 2013OCT20_Dil_Hi_5 Recovery 100 5.41 6607240.5 8107558 14222654 1 Hi-Dil-Spk5 123% 41 2013OCT20_SolvA_11 5.41 470.579 494.968 2519.204 1 42 2013OCT20_Std Dil 200_2 5.41 5461313 6669786 13379517 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 158.518 1047.46 0 88 44 2013OCT20_Hi_1 Recovery 200 5.41 11007814 12250565 16225548 0 Hi-Spk1 105% 45 2013OCT20_Hi_2 Recovery 200 5.41 10607407 11990993 16085897 0 Hi-Spk2 101% 46 2013OCT20_Hi_3 Recovery 200 5.42 10735590 12013531 16044252 0 Hi-Spk3 102% 47 2013OCT20_Hi_4 Recovery 200 5.42 11304528 12515838 16314415 0 Hi-Spk4 107% 48 2013OCT20_Hi_5 Recovery 200 5.41 11701008 12730231 16585168 0 Hi-Spk5 111% 49 2013OCT20_SolvA_13 5.42 1005.207 1398.989 4222.919 1 50 2013OCT20_SolvA_14 5.41 587.874 556.119 2758.19 0 51 2013OCT20_0-01_Std_2 Standard 0.01 5.41 1583.457 2208.13 6103.768 1 52 2013OCT20_0-05_Std_2 Standard 0.05 5.41 3997.715 5121.472 15191.853 1 53 2013OCT20_0-1_Std_2 Standard 0.1 5.41 8354.903 9315.196 27922.66 1 54 2013OCT20_0-5_Std_2 Standard 0.5 5.41 32229.559 41362.465 115150.641 1 55 2013OCT20_1_Std_2 Standard 1 5.41 63199.305 76661.625 224546.188 1 56 2013OCT20_5_Std_2 Standard 5 5.42 321805.594 393444.438 1119716 1 57 2013OCT20_10_Std_2 Standard 10 5.42 634136.938 762374.563 2151005.5 1 58 2013OCT20_25_Std_2 Standard 25 5.42 1575063.25 1945583.75 5463805 1 59 2013OCT20_50_Std_2 Standard 50 5.41 2879749.5 3584411.75 9969751 1 60 2013OCT20_100_Std_2 Standard 100 5.41 5651105 6866274 13598170 1 61 2013OCT20_200_Std_2 Standard 200 5.41 10390557 11785430 16039990 0 62 2013OCT20_SolvA_15 5.41 599.042 845.129 2566.329 1 63 2013OCT20_Surrogate_2 5.41 3576.969 5417.428 14509.438 1 64 2013OCT20_SolvA_16 5.43 793.53 647.135 1482.623 0 Compound 6: Atrazine-d5 Pk Area yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? 1 2013OCT20_SolvA_2 133.704 71.203 #DIV/0! 0 2 2013OCT20_RO Blank 5.36 14071236 7146364 4641555 1 14071236 3 2013OCT20_Blk_1 Blank 5.36 13879354 6767667.5 4495014.5 1 13879354 4 2013OCT20_Blk_2 Blank 5.35 13534627 6496595.5 4236962 1 13534627 5 2013OCT20_0-01_Std Standard 0.01 5.35 14072183 7070105 4589707 1 14072183 6 2013OCT20_0-05_Std Standard 0.05 5.35 14131258 7002664.5 4577172.5 1 14131258 7 2013OCT20_0-1_Std Standard 0.1 5.35 14583250 7714185.5 5082353.5 1 14583250 8 2013OCT20_0-5_Std Standard 0.5 5.34 14241397 7500766 4823868 1 14241397 9 2013OCT20_1_Std Standard 1 5.35 14303683 7484290.5 4839317.5 1 14303683 10 2013OCT20_5_Std Standard 5 5.35 14263220 7407167.5 4847702.5 1 14263220 11 2013OCT20_10_Std Standard 10 5.35 14131824 7326345.5 4718546.5 1 14131824 12 2013OCT20_25_Std Standard 25 5.35 14278298 7215078 4703758 1 14278298 13 2013OCT20_50_Std Standard 50 5.35 14277573 7360074 4836788.5 1 14277573 14 2013OCT20_100_Std Standard 100 5.35 14025659 6772134.5 4368550.5 1 14025659 15 2013OCT20_200_Stds Standard 200 5.35 14008474 6977603 4486499.5 1 14008474 16 2013OCT20_SolvA_3 5.33 2427.425 1633.848 249.645 0 2427 17 2013OCT20_Surrogate 5.35 1819.292 507.589 79.383 0 1819 18 2013OCT20_SolvA_4 5.31 2058.259 253.629 14.23 0 2058 19 2013OCT20_SolvA_5 5.32 3302.94 585.992 276.204 0 3303 20 2013OCT20_Lo_1 Recovery 50 5.35 14159938 7168700.5 4617954.5 1 14159938 %Recovery 21 2013OCT20_Lo_2 Recovery 50 5.35 13771277 6585943 4217298 1 13771277 22 2013OCT20_Lo_3 Recovery 50 5.35 13746499 6540419 4247333 1 13746499 89 23 2013OCT20_Lo_4 Recovery 50 5.35 13895516 6851258 4429300 1 13895516 24 2013OCT20_Lo_5 Recovery 50 5.35 13121657 5894725 3797636.75 1 13121657 25 2013OCT20_SolvA_6 5.33 1177.31 1208.495 584.287 1 1177 26 2013OCT20_SolvA_7 5.33 2392.927 504.95 25.374 0 2393 27 2013OCT20_Mid_1 Recovery 100 5.35 13564549 6335991 4074852.5 1 13564549 28 2013OCT20_Mid_2 Recovery 100 5.35 14351932 7452341.5 4844231.5 1 14351932 29 2013OCT20_Mid_3 Recovery 100 5.35 13857040 6695475 4352510.5 1 13857040 30 2013OCT20_Mid_4 Recovery 100 5.35 13475064 6227883.5 3973247.5 1 13475064 31 2013OCT20_Mid_5 Recovery 100 5.36 13852868 6509840.5 4155707.75 1 13852868 32 2013OCT20_SolvA_8 5.34 2842.249 2107.054 39.411 0 2842 33 2013OCT20_SolvA_9 5.34 2787.8 1647.837 830.941 1 2788 34 2013OCT20_Std Dil 200_1 5.35 10823842 3682411.25 2336150.25 1 10823842 35 2013OCT20_SolvA_10 5.34 3141.005 245.956 785.478 0 3141 36 2013OCT20_Dil_Hi_1 Recovery 100 5.35 10973655 3768213 2399267.5 1 10973655 37 2013OCT20_Dil_Hi_2 Recovery 100 5.35 10583289 3556855 2323762.75 1 10583289 38 2013OCT20_Dil_Hi_3 Recovery 100 5.35 10671455 3555547 2317192.25 1 10671455 39 2013OCT20_Dil_Hi_4 Recovery 100 5.35 11234583 3943307.75 2527363.25 1 11234583 40 2013OCT20_Dil_Hi_5 Recovery 100 5.35 11414676 4145388.75 2672847.25 1 11414676 41 2013OCT20_SolvA_11 5.34 3098.507 283.922 336.887 0 3099 42 2013OCT20_Std Dil 200_2 5.35 10865143 3711892.25 2396754.75 1 10865143 43 2013OCT20_SolvA_12 5.34 2687.328 376.66 884.114 0 2687 44 2013OCT20_Hi_1 Recovery 200 5.35 13920966 6930955.5 4430370.5 1 13920966 45 2013OCT20_Hi_2 Recovery 200 5.35 13701190 6613948 4170300.5 1 13701190 46 2013OCT20_Hi_3 Recovery 200 5.35 13822219 6632227 4265019 1 13822219 47 2013OCT20_Hi_4 Recovery 200 5.35 14109764 7245787 4643282.5 1 14109764 48 2013OCT20_Hi_5 Recovery 200 5.35 14270829 7507981.5 4834356.5 1 14270829 49 2013OCT20_SolvA_13 5.34 2740.4 649.046 442.655 1 2740 50 2013OCT20_SolvA_14 5.33 2702.861 107.78 407.886 0 2703 51 2013OCT20_0-01_Std_2 Standard 0.01 5.35 14047174 7113910.5 4619000 1 14047174 52 2013OCT20_0-05_Std_2 Standard 0.05 5.35 14135714 7070868.5 4596215 1 14135714 53 2013OCT20_0-1_Std_2 Standard 0.1 5.35 14550500 7847149.5 5015668.5 1 14550500 54 2013OCT20_0-5_Std_2 Standard 0.5 5.35 14308094 7382597 4794828.5 1 14308094 55 2013OCT20_1_Std_2 Standard 1 5.35 14380443 7475775 4806116 1 14380443 56 2013OCT20_5_Std_2 Standard 5 5.36 14459125 7474981 4823033 1 14459125 57 2013OCT20_10_Std_2 Standard 10 5.36 14430314 7316822.5 4680483.5 1 14430314 58 2013OCT20_25_Std_2 Standard 25 5.36 14464568 7238143.5 4747982 1 14464568 59 2013OCT20_50_Std_2 Standard 50 5.35 14375085 7328730.5 4719812 1 14375085 60 2013OCT20_100_Std_2 Standard 100 5.35 14011984 6751985.5 4423659.5 1 14011984 61 2013OCT20_200_Std_2 Standard 200 5.35 14048414 6913252.5 4493552 1 14048414 62 2013OCT20_SolvA_15 5.34 2293.411 87.045 589.764 0 2293 63 2013OCT20_Surrogate_2 5.31 1139.889 373.229 58.664 0 1140 64 2013OCT20_SolvA_16 5.34 1924.598 73.768 90.058 0 1925 Compound 7: Terbuthylazine Pk Area yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? 1 2013OCT20_SolvA_2 76.264 #DIV/0! 0 90 2 2013OCT20_RO Blank 150.119 #DIV/0! 0 3 2013OCT20_Blk_1 Blank 8.05 5378929.5 4339581.5 #DIV/0! 5378930 4 2013OCT20_Blk_2 Blank 8.04 5186315 4179073.75 #DIV/0! 5186315 5 2013OCT20_0-01_Std Standard 0.01 293.216 92.907 #DIV/0! 0 6 2013OCT20_0-05_Std Standard 0.05 131.546 100.639 #DIV/0! 0 7 2013OCT20_0-1_Std Standard 0.1 175.643 135.578 #DIV/0! 0 8 2013OCT20_0-5_Std Standard 0.5 198.876 71.551 #DIV/0! 0 9 2013OCT20_1_Std Standard 1 146.672 180.039 #DIV/0! 0 10 2013OCT20_5_Std Standard 5 60.163 189.869 #DIV/0! 0 11 2013OCT20_10_Std Standard 10 206.706 197.238 #DIV/0! 0 12 2013OCT20_25_Std Standard 25 136.189 54.132 #DIV/0! 0 13 2013OCT20_50_Std Standard 50 121.93 89.668 #DIV/0! 0 14 2013OCT20_100_Std Standard 100 195.562 12.844 #DIV/0! 0 15 2013OCT20_200_Stds Standard 200 236.974 91.276 #DIV/0! 0 16 2013OCT20_SolvA_3 60.127 139.357 #DIV/0! 0 17 2013OCT20_Surrogate 8.04 5256130.5 4181704.5 #DIV/0! 5256131 18 2013OCT20_SolvA_4 340.589 107.315 #DIV/0! 0 19 2013OCT20_SolvA_5 275.959 129.431 #DIV/0! 0 20 2013OCT20_Lo_1 Recovery 50 8.04 5358896.5 4295857 #DIV/0! 5358897 21 2013OCT20_Lo_2 Recovery 50 8.04 5050968 4046150.25 #DIV/0! 5050968 22 2013OCT20_Lo_3 Recovery 50 8.04 4923552 3937702.5 #DIV/0! 4923552 23 2013OCT20_Lo_4 Recovery 50 8.04 5158885 4141747 #DIV/0! 5158885 24 2013OCT20_Lo_5 Recovery 50 8.04 4369149.5 3527381 #DIV/0! 4369150 25 2013OCT20_SolvA_6 222.731 72.111 #DIV/0! 0 26 2013OCT20_SolvA_7 189.085 167.959 #DIV/0! 0 27 2013OCT20_Mid_1 Recovery 100 8.04 4734681 3804680.5 #DIV/0! 4734681 28 2013OCT20_Mid_2 Recovery 100 8.04 5790431.5 4641998.5 #DIV/0! 5790432 29 2013OCT20_Mid_3 Recovery 100 8.04 4766470.5 3844249.75 #DIV/0! 4766471 30 2013OCT20_Mid_4 Recovery 100 8.05 4240226.5 3399249.5 #DIV/0! 4240227 31 2013OCT20_Mid_5 Recovery 100 8.05 4970085 3984099.75 #DIV/0! 4970085 32 2013OCT20_SolvA_8 271.458 198.868 #DIV/0! 0 33 2013OCT20_SolvA_9 168.327 270.337 #DIV/0! 0 34 2013OCT20_Std Dil 200_1 144.717 111.983 #DIV/0! 0 35 2013OCT20_SolvA_10 139.501 43.224 #DIV/0! 0 36 2013OCT20_Dil_Hi_1 Recovery 100 8.04 2854739.5 2283367.25 #DIV/0! 2854740 37 2013OCT20_Dil_Hi_2 Recovery 100 8.05 2870475 2291496 #DIV/0! 2870475 38 2013OCT20_Dil_Hi_3 Recovery 100 8.04 2724351.25 2180393 #DIV/0! 2724351 39 2013OCT20_Dil_Hi_4 Recovery 100 8.04 2950024.25 2357484.25 #DIV/0! 2950024 40 2013OCT20_Dil_Hi_5 Recovery 100 8.04 3208019.75 2538594.75 #DIV/0! 3208020 41 2013OCT20_SolvA_11 311.768 647.709 #DIV/0! 0 42 2013OCT20_Std Dil 200_2 223.203 91.293 #DIV/0! 0 43 2013OCT20_SolvA_12 303.104 92.526 #DIV/0! 0 44 2013OCT20_Hi_1 Recovery 200 8.04 5531316 4435204 #DIV/0! 5531316 45 2013OCT20_Hi_2 Recovery 200 8.04 5593917.5 4435921 #DIV/0! 5593918 46 2013OCT20_Hi_3 Recovery 200 8.04 5272749 4192317.75 #DIV/0! 5272749 47 2013OCT20_Hi_4 Recovery 200 8.04 5725226 4577333.5 #DIV/0! 5725226 91 48 2013OCT20_Hi_5 Recovery 200 8.04 6063934.5 4851210 #DIV/0! 6063935 49 2013OCT20_SolvA_13 988.661 542.906 #DIV/0! 0 50 2013OCT20_SolvA_14 238.894 380.262 #DIV/0! 0 51 2013OCT20_0-01_Std_2 Standard 0.01 298.366 351.723 #DIV/0! 0 52 2013OCT20_0-05_Std_2 Standard 0.05 175.887 135.93 #DIV/0! 0 53 2013OCT20_0-1_Std_2 Standard 0.1 219.392 106.605 #DIV/0! 0 54 2013OCT20_0-5_Std_2 Standard 0.5 131.425 49.635 #DIV/0! 0 55 2013OCT20_1_Std_2 Standard 1 331.919 169.925 #DIV/0! 0 56 2013OCT20_5_Std_2 Standard 5 127.466 112.05 #DIV/0! 0 57 2013OCT20_10_Std_2 Standard 10 83.909 68.617 #DIV/0! 0 58 2013OCT20_25_Std_2 Standard 25 123.429 58.517 #DIV/0! 0 59 2013OCT20_50_Std_2 Standard 50 402.278 63.793 #DIV/0! 0 60 2013OCT20_100_Std_2 Standard 100 351.467 106.674 #DIV/0! 0 61 2013OCT20_200_Std_2 Standard 200 224.908 65.473 #DIV/0! 0 62 2013OCT20_SolvA_15 115.568 25.41 #DIV/0! 0 63 2013OCT20_Surrogate_2 8.04 5404533.5 4326248.5 #DIV/0! 5404534 64 2013OCT20_SolvA_16 142.708 179.588 #DIV/0! 0 Compound 8: Metolachlor OH Compound 8: Metolachlor OH yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 20.491 #DIV/0! 2 2013OCT20_RO Blank 98.593 392.576 #DIV/0! 3 2013OCT20_Blk_1 Blank 176.368 3267.505 #DIV/0! 4 2013OCT20_Blk_2 Blank 92.566 9.17 #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 98.737 1349.776 0 6 2013OCT20_0-05_Std Standard 0.05 7.26 3534.742 1628.284 18717.91 1 0.05 46% 7 2013OCT20_0-1_Std Standard 0.1 7.27 5535.732 2654.427 34359.082 1 0.10 14% 8 2013OCT20_0-5_Std Standard 0.5 7.27 23555.324 15689.161 152506.609 1 0.50 -3% 9 2013OCT20_1_Std Standard 1 7.29 47883.551 30483.123 301541.063 1 1.00 -1% 10 2013OCT20_5_Std Standard 5 7.28 224753.328 163899.938 1479781.5 1 5 -7% 11 2013OCT20_10_Std Standard 10 7.28 475047.094 319200.875 2877092.75 1 10 -2% 12 2013OCT20_25_Std Standard 25 7.28 1190010.125 797955.5 6940322 1 25 -2% 13 2013OCT20_50_Std Standard 50 7.28 2456357 1645807 12673563 1 50 1% 14 2013OCT20_100_Std Standard 100 7.27 4332309 2854919 17463598 1 100 -11% 15 2013OCT20_200_Stds Standard 200 7.28 9974508 6572470 21772464 1 200 3% 16 2013OCT20_SolvA_3 203.818 603.329 #DIV/0! 17 2013OCT20_Surrogate 19.108 649.666 #DIV/0! 18 2013OCT20_SolvA_4 98.602 414.225 #DIV/0! 19 2013OCT20_SolvA_5 232.555 1326.571 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 7.28 2477908.25 1636078.625 12717733 1 Low-Spk1 103% 21 2013OCT20_Lo_2 Recovery 50 7.28 2189177 1456355 11696594 1 Low-Spk2 91% 22 2013OCT20_Lo_3 Recovery 50 7.28 2507306.5 1672209 12930750 1 Low-Spk3 104% 23 2013OCT20_Lo_4 Recovery 50 7.28 2243689.75 1482048.75 11904941 1 Low-Spk4 93% 24 2013OCT20_Lo_5 Recovery 50 7.28 2073453 1362792.125 11133877 1 Low-Spk5 87% 25 2013OCT20_SolvA_6 78.845 181.584 #DIV/0! 26 2013OCT20_SolvA_7 72.049 1085.847 #DIV/0! 92 27 2013OCT20_Mid_1 Recovery 100 7.28 4048251.25 2670316.5 16996724 1 Mid-Spk1 84% 28 2013OCT20_Mid_2 Recovery 100 7.28 4473572 2960790 17705974 1 Mid-Spk2 92% 29 2013OCT20_Mid_3 Recovery 100 7.28 4155123.25 2733697.75 17236404 1 Mid-Spk3 86% 30 2013OCT20_Mid_4 Recovery 100 7.29 3820838 2538617.75 16682273 1 Mid-Spk4 79% 31 2013OCT20_Mid_5 Recovery 100 7.29 4404856 2885695 17628344 1 Mid-Spk5 91% 32 2013OCT20_SolvA_8 125.229 1905.477 #DIV/0! 33 2013OCT20_SolvA_9 315.158 1915.462 #DIV/0! 34 2013OCT20_Std Dil 200_1 7.29 5368746.5 3531841 #DIV/0! Hi-Dil-Std 35 2013OCT20_SolvA_10 123.808 241.245 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 7.28 4288625 2827425 23.19 0 Hi-Dil-Spk1 80% 37 2013OCT20_Dil_Hi_2 Recovery 100 7.28 4216571.5 2780397.5 58.786 0 Hi-Dil-Spk2 79% 38 2013OCT20_Dil_Hi_3 Recovery 100 7.28 4173309 2738707.75 6.393 0 Hi-Dil-Spk3 78% 39 2013OCT20_Dil_Hi_4 Recovery 100 7.28 4460803.5 2919849.25 61.447 0 Hi-Dil-Spk4 83% 40 2013OCT20_Dil_Hi_5 Recovery 100 7.28 4915836 3221895.25 150.396 0 Hi-Dil-Spk5 92% 41 2013OCT20_SolvA_11 58.598 452.916 #DIV/0! 42 2013OCT20_Std Dil 200_2 7.28 5316403 3521170.5 41.305 0 Hi-Dil-Std 43 2013OCT20_SolvA_12 149.244 1276.469 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 7.28 7865633.5 5181233.5 2.632 0 Hi-Spk1 81% 45 2013OCT20_Hi_2 Recovery 200 7.28 7768065 5118977.5 21.529 0 Hi-Spk2 80% 46 2013OCT20_Hi_3 Recovery 200 7.28 7685784.5 5054268.5 3.382 0 Hi-Spk3 79% 47 2013OCT20_Hi_4 Recovery 200 7.28 8203581.5 5360160.5 #DIV/0! Hi-Spk4 84% 48 2013OCT20_Hi_5 Recovery 200 7.28 8902056 5830678 51.116 0 Hi-Spk5 91% 49 2013OCT20_SolvA_13 274.926 617.945 #DIV/0! 50 2013OCT20_SolvA_14 158.613 814.429 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 152.388 4119.321 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 7.28 2136.048 2168.46 20103.086 1 53 2013OCT20_0-1_Std_2 Standard 0.1 7.28 5424.521 2766.392 38311.883 1 54 2013OCT20_0-5_Std_2 Standard 0.5 7.27 24199.414 15659.106 166540.484 1 55 2013OCT20_1_Std_2 Standard 1 7.28 48068.93 31513.955 327678.906 1 56 2013OCT20_5_Std_2 Standard 5 7.28 241654.516 160923.359 1600783.5 1 57 2013OCT20_10_Std_2 Standard 10 7.28 468019.25 313837.281 3013105 1 58 2013OCT20_25_Std_2 Standard 25 7.29 1171755.875 783436.75 7297896 1 59 2013OCT20_50_Std_2 Standard 50 7.28 2351521.75 1540262.25 12736419 1 60 2013OCT20_100_Std_2 Standard 100 7.27 4148427 2720450.75 6.548 0 61 2013OCT20_200_Std_2 Standard 200 7.27 9635134 6305855.5 84.299 0 62 2013OCT20_SolvA_15 284.673 3142.151 #DIV/0! 63 2013OCT20_Surrogate_2 322.677 907.516 #DIV/0! 64 2013OCT20_SolvA_16 18.166 3197.177 #DIV/0! #DIV/0! Compound 9: Alachlor Compound 9: Alachlor yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 0 2 2013OCT20_RO Blank 0 3 2013OCT20_Blk_1 Blank 0 4 2013OCT20_Blk_2 Blank 0 93 5 2013OCT20_0-01_Std Standard 0.01 1014.121 0 6 2013OCT20_0-05_Std Standard 0.05 0 7 2013OCT20_0-1_Std Standard 0.1 1250.09 0 8 2013OCT20_0-5_Std Standard 0.5 9.22 11397.256 4296.831 1 0.50 140% 9 2013OCT20_1_Std Standard 1 9.23 20612.42 6332.254 1 1.00 117% 10 2013OCT20_5_Std Standard 5 9.24 106510.211 45246.199 1 5 125% 11 2013OCT20_10_Std Standard 10 9.24 185209.063 82953.055 1 10 95% 12 2013OCT20_25_Std Standard 25 9.24 397576.969 176136.828 1 25 68% 13 2013OCT20_50_Std Standard 50 9.24 634746.125 294678.156 1 50 34% 14 2013OCT20_100_Std Standard 100 9.24 1135689.875 499070.813 1 100 20% 15 2013OCT20_200_Stds Standard 200 9.24 1737314.25 764955.313 1 200 -8% 16 2013OCT20_SolvA_3 268.264 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 #DIV/0! One point 19 2013OCT20_SolvA_5 48.635 #DIV/0! %Rec 20 2013OCT20_Lo_1 Recovery 50 9.24 696903.438 304457.563 1 Low-Spk1 110% 21 2013OCT20_Lo_2 Recovery 50 9.24 553808.188 242233.984 1 Low-Spk2 87% 22 2013OCT20_Lo_3 Recovery 50 9.24 631845.438 293108 1 Low-Spk3 100% 23 2013OCT20_Lo_4 Recovery 50 9.24 705716 308098.188 1 Low-Spk4 111% 24 2013OCT20_Lo_5 Recovery 50 9.24 616728.875 270259.5 1 Low-Spk5 97% 25 2013OCT20_SolvA_6 325.236 #DIV/0! 26 2013OCT20_SolvA_7 23.955 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 9.24 1110230.5 478611.906 1 Mid-Spk1 98% 28 2013OCT20_Mid_2 Recovery 100 9.24 1171715.25 498992.031 1 Mid-Spk2 103% 29 2013OCT20_Mid_3 Recovery 100 9.24 1029155.75 447179.969 1 Mid-Spk3 91% 30 2013OCT20_Mid_4 Recovery 100 9.24 986039.438 427147.281 1 Mid-Spk4 87% 31 2013OCT20_Mid_5 Recovery 100 9.24 1097931.625 461573.844 1 Mid-Spk5 97% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 78.108 #DIV/0! 34 2013OCT20_Std Dil 200_1 9.24 1433015.125 624439.313 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 43.627 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 9.24 1418304 607045.125 1 Hi-Dil-Spk1 37 2013OCT20_Dil_Hi_2 Recovery 100 9.24 1427016.5 638757.313 1 Hi-Dil-Spk2 38 2013OCT20_Dil_Hi_3 Recovery 100 9.24 1435338.375 622851.5 1 Hi-Dil-Spk3 39 2013OCT20_Dil_Hi_4 Recovery 100 9.24 1439092.125 621407.688 1 Hi-Dil-Spk4 40 2013OCT20_Dil_Hi_5 Recovery 100 9.24 1587812.5 671928.313 1 Hi-Dil-Spk5 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 9.24 1417129.125 623996.375 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 564.829 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 9.24 1707755.25 750923.875 1 Hi-Spk1 98% 45 2013OCT20_Hi_2 Recovery 200 9.24 1751771.75 777723.25 1 Hi-Spk2 101% 46 2013OCT20_Hi_3 Recovery 200 9.24 1744134.375 748909.625 1 Hi-Spk3 100% 47 2013OCT20_Hi_4 Recovery 200 9.24 1746563.125 767368.875 1 Hi-Spk4 101% 48 2013OCT20_Hi_5 Recovery 200 9.24 1886743.875 803476.625 1 Hi-Spk5 109% 49 2013OCT20_SolvA_13 28.811 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 94 51 2013OCT20_0-01_Std_2 Standard 0.01 134.861 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 631.099 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 1017.742 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 9.22 10908.514 3639.183 1 55 2013OCT20_1_Std_2 Standard 1 9.23 18233.824 7302.37 1 56 2013OCT20_5_Std_2 Standard 5 9.24 100911.305 41817.594 1 57 2013OCT20_10_Std_2 Standard 10 9.24 180227.047 76757.484 1 58 2013OCT20_25_Std_2 Standard 25 9.24 402227.375 177877.375 1 59 2013OCT20_50_Std_2 Standard 50 9.24 672301.313 295585.125 1 60 2013OCT20_100_Std_2 Standard 100 9.24 1089298.625 486188.469 1 61 2013OCT20_200_Std_2 Standard 200 9.24 1673925.125 739633.313 1 62 2013OCT20_SolvA_15 7.13 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 10: Acetochlor Compound 10: Acetochlor yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 9.22 3325.083 2482.105 402.113 1 2 2013OCT20_RO Blank 563.597 #DIV/0! 3 2013OCT20_Blk_1 Blank 9.23 12466.979 7093.674 1867.16 1 4 2013OCT20_Blk_2 Blank 9.23 4153.274 1031.075 951.077 0 5 2013OCT20_0-01_Std Standard 0.01 9.21 896.115 442.735 0 0.01 28% 6 2013OCT20_0-05_Std Standard 0.05 9.22 5534.034 3228.808 1360.593 1 0.05 58% 7 2013OCT20_0-1_Std Standard 0.1 9.23 19725.33 10679.584 1999.774 1 0.10 181% 8 2013OCT20_0-5_Std Standard 0.5 9.23 78060.258 40750.719 13904.614 1 0.50 122% 9 2013OCT20_1_Std Standard 1 9.23 135294.875 68410.164 21161.385 1 1.00 93% 10 2013OCT20_5_Std Standard 5 9.23 842331.125 418263.281 137102.781 1 5 140% 11 2013OCT20_10_Std Standard 10 9.23 1506884.125 794958.875 259069.234 1 10 115% 12 2013OCT20_25_Std Standard 25 9.23 3443825.75 1803086.125 581161.938 1 25 96% 13 2013OCT20_50_Std Standard 50 9.23 5787504.5 3041040.25 902268.188 1 50 65% 14 2013OCT20_100_Std Standard 100 9.23 9204563 5110163.5 1687554.375 1 100 31% 15 2013OCT20_200_Stds Standard 200 9.23 12118015 7778040.5 2588176.25 1 200 -14% 16 2013OCT20_SolvA_3 9.22 10614.971 5939.835 2184.826 1 17 2013OCT20_Surrogate 9.22 2668.317 2068.216 0 18 2013OCT20_SolvA_4 9.22 1518.226 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 9.23 5848357 3113707.5 999542.188 1 Low-Spk1 158% 21 2013OCT20_Lo_2 Recovery 50 9.23 4720871.5 2456314 804687.813 1 Low-Spk2 124% 22 2013OCT20_Lo_3 Recovery 50 9.23 5679418.5 3009537.25 975234.188 1 Low-Spk3 153% 23 2013OCT20_Lo_4 Recovery 50 9.23 5892159.5 3143624.25 1003967.688 1 Low-Spk4 160% 24 2013OCT20_Lo_5 Recovery 50 9.23 5329116.5 2762730.75 885155.813 1 Low-Spk5 142% 25 2013OCT20_SolvA_6 #DIV/0! 26 2013OCT20_SolvA_7 9.22 3812.327 958.447 0 27 2013OCT20_Mid_1 Recovery 100 9.23 9038907 5017958 1658398 1 Mid-Spk1 128% 28 2013OCT20_Mid_2 Recovery 100 9.23 9444178 5227846 1724978.25 1 Mid-Spk2 134% 29 2013OCT20_Mid_3 Recovery 100 9.23 8577929 4612681 1549790.5 1 Mid-Spk3 121% 95 30 2013OCT20_Mid_4 Recovery 100 9.23 8427967 4559861.5 1479324.5 1 Mid-Spk4 119% 31 2013OCT20_Mid_5 Recovery 100 9.23 8904920 4895613.5 1622190.5 1 Mid-Spk5 126% 32 2013OCT20_SolvA_8 9.23 8324.701 4603.628 1605.448 1 33 2013OCT20_SolvA_9 9.24 2418.319 1805.653 0 34 2013OCT20_Std Dil 200_1 9.23 10930204 6535502.5 2043269.375 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 9.23 6598.234 2641.906 949.177 1 36 2013OCT20_Dil_Hi_1 Recovery 100 9.23 10903770 6565083 2080741 1 Hi-Dil-Spk1 100% 37 2013OCT20_Dil_Hi_2 Recovery 100 9.23 10981733 6614008.5 2080903.5 1 Hi-Dil-Spk2 101% 38 2013OCT20_Dil_Hi_3 Recovery 100 9.23 10887784 6516951 2055207.25 1 Hi-Dil-Spk3 100% 39 2013OCT20_Dil_Hi_4 Recovery 100 9.23 11111891 6682470.5 2122666.75 1 Hi-Dil-Spk4 102% 40 2013OCT20_Dil_Hi_5 Recovery 100 9.23 11559908 7143617.5 2279927.25 1 Hi-Dil-Spk5 106% 41 2013OCT20_SolvA_11 9.23 10719.858 6890.268 1676.463 1 42 2013OCT20_Std Dil 200_2 9.23 10977319 6587400.5 2060049.875 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 9.23 4855.945 1274.346 0 44 2013OCT20_Hi_1 Recovery 200 9.23 12208575 7806254 2581432.5 1 Hi-Spk1 88% 45 2013OCT20_Hi_2 Recovery 200 9.23 12322441 7950684 2576742.5 1 Hi-Spk2 89% 46 2013OCT20_Hi_3 Recovery 200 9.23 12105381 7680695 2598181.25 1 Hi-Spk3 88% 47 2013OCT20_Hi_4 Recovery 200 9.23 12271604 7931512.5 2611406.5 1 Hi-Spk4 89% 48 2013OCT20_Hi_5 Recovery 200 9.23 12801709 8541101 2764857 1 Hi-Spk5 93% 49 2013OCT20_SolvA_13 9.23 21327.811 9667.24 2149.017 1 50 2013OCT20_SolvA_14 9.23 8604.898 4991.211 0 51 2013OCT20_0-01_Std_2 Standard 0.01 9.22 2488.112 1401.529 457.304 1 52 2013OCT20_0-05_Std_2 Standard 0.05 9.23 7156.343 4027.376 591.022 1 53 2013OCT20_0-1_Std_2 Standard 0.1 9.23 20794.893 8654.202 2932.661 1 54 2013OCT20_0-5_Std_2 Standard 0.5 9.23 76046.289 40153.121 10041.328 1 55 2013OCT20_1_Std_2 Standard 1 9.23 140177.672 66299.031 22630.953 1 56 2013OCT20_5_Std_2 Standard 5 9.23 858183.188 419467.813 135629.969 1 57 2013OCT20_10_Std_2 Standard 10 9.23 1557895.375 756726.438 244785.844 1 58 2013OCT20_25_Std_2 Standard 25 9.23 3506912.75 1683193.875 572700.75 1 59 2013OCT20_50_Std_2 Standard 50 9.23 5835952.5 2926569.25 1005942.25 1 60 2013OCT20_100_Std_2 Standard 100 9.23 9214854 4957942 1649507.375 1 61 2013OCT20_200_Std_2 Standard 200 9.23 12060478 7689099 2601085 1 62 2013OCT20_SolvA_15 9.22 14157.565 5509.091 865.674 1 63 2013OCT20_Surrogate_2 633.723 215.198 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 11: Alachlor-d13 Pk Area yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? 1 2013OCT20_SolvA_2 #DIV/0! 0 2 2013OCT20_RO Blank #DIV/0! 0 3 2013OCT20_Blk_1 Blank 9.21 51104.672 #DIV/0! 51105 4 2013OCT20_Blk_2 Blank 9.21 49994.301 #DIV/0! 49994 5 2013OCT20_0-01_Std Standard 0.01 #DIV/0! 0 6 2013OCT20_0-05_Std Standard 0.05 #DIV/0! 0 7 2013OCT20_0-1_Std Standard 0.1 #DIV/0! 0 8 2013OCT20_0-5_Std Standard 0.5 9.12 80.306 #DIV/0! 80 96 9 2013OCT20_1_Std Standard 1 #DIV/0! 0 10 2013OCT20_5_Std Standard 5 #DIV/0! 0 11 2013OCT20_10_Std Standard 10 #DIV/0! 0 12 2013OCT20_25_Std Standard 25 #DIV/0! 0 13 2013OCT20_50_Std Standard 50 #DIV/0! 0 14 2013OCT20_100_Std Standard 100 #DIV/0! 0 15 2013OCT20_200_Stds Standard 200 #DIV/0! 0 16 2013OCT20_SolvA_3 #DIV/0! 0 17 2013OCT20_Surrogate 9.22 51791.293 #DIV/0! 51791 18 2013OCT20_SolvA_4 #DIV/0! 0 19 2013OCT20_SolvA_5 9.24 741.34 #DIV/0! 741 20 2013OCT20_Lo_1 Recovery 50 9.21 36718.289 #DIV/0! 36718 21 2013OCT20_Lo_2 Recovery 50 9.21 25437.146 #DIV/0! 25437 22 2013OCT20_Lo_3 Recovery 50 9.21 39636.551 #DIV/0! 39637 23 2013OCT20_Lo_4 Recovery 50 9.21 38643.484 #DIV/0! 38643 24 2013OCT20_Lo_5 Recovery 50 9.21 35194.648 #DIV/0! 35195 25 2013OCT20_SolvA_6 #DIV/0! 0 26 2013OCT20_SolvA_7 #DIV/0! 0 27 2013OCT20_Mid_1 Recovery 100 9.2 27558.393 #DIV/0! 27558 28 2013OCT20_Mid_2 Recovery 100 9.2 33685.355 #DIV/0! 33685 29 2013OCT20_Mid_3 Recovery 100 9.2 26520.006 #DIV/0! 26520 30 2013OCT20_Mid_4 Recovery 100 9.2 23822.91 #DIV/0! 23823 31 2013OCT20_Mid_5 Recovery 100 9.21 28635.643 #DIV/0! 28636 32 2013OCT20_SolvA_8 #DIV/0! 0 33 2013OCT20_SolvA_9 #DIV/0! 0 34 2013OCT20_Std Dil 200_1 #DIV/0! 0 35 2013OCT20_SolvA_10 #DIV/0! 0 36 2013OCT20_Dil_Hi_1 Recovery 100 9.2 18592.439 #DIV/0! 18592 37 2013OCT20_Dil_Hi_2 Recovery 100 9.2 18917.605 #DIV/0! 18918 38 2013OCT20_Dil_Hi_3 Recovery 100 9.2 16842.447 #DIV/0! 16842 39 2013OCT20_Dil_Hi_4 Recovery 100 9.2 19131.482 #DIV/0! 19131 40 2013OCT20_Dil_Hi_5 Recovery 100 9.2 20564.414 #DIV/0! 20564 41 2013OCT20_SolvA_11 #DIV/0! 0 42 2013OCT20_Std Dil 200_2 #DIV/0! 0 43 2013OCT20_SolvA_12 #DIV/0! 0 44 2013OCT20_Hi_1 Recovery 200 9.2 20608.961 #DIV/0! 20609 45 2013OCT20_Hi_2 Recovery 200 9.2 24923.004 #DIV/0! 24923 46 2013OCT20_Hi_3 Recovery 200 9.2 24392.33 #DIV/0! 24392 47 2013OCT20_Hi_4 Recovery 200 9.2 23742.91 #DIV/0! 23743 48 2013OCT20_Hi_5 Recovery 200 9.2 28178.305 #DIV/0! 28178 49 2013OCT20_SolvA_13 #DIV/0! 0 50 2013OCT20_SolvA_14 #DIV/0! 0 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 0 52 2013OCT20_0-05_Std_2 Standard 0.05 #DIV/0! 0 53 2013OCT20_0-1_Std_2 Standard 0.1 #DIV/0! 0 54 2013OCT20_0-5_Std_2 Standard 0.5 #DIV/0! 0 97 55 2013OCT20_1_Std_2 Standard 1 #DIV/0! 0 56 2013OCT20_5_Std_2 Standard 5 #DIV/0! 0 57 2013OCT20_10_Std_2 Standard 10 #DIV/0! 0 58 2013OCT20_25_Std_2 Standard 25 #DIV/0! 0 59 2013OCT20_50_Std_2 Standard 50 #DIV/0! 0 60 2013OCT20_100_Std_2 Standard 100 #DIV/0! 0 61 2013OCT20_200_Std_2 Standard 200 #DIV/0! 0 62 2013OCT20_SolvA_15 #DIV/0! 0 63 2013OCT20_Surrogate_2 9.22 47294.063 #DIV/0! 47294 64 2013OCT20_SolvA_16 #DIV/0! 0 Compound 12: Metolachlor Compound 12: Metolachlor yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 9.3 48683.727 7137.025 282.248 0 2 2013OCT20_RO Blank 9.34 7098.41 3013.271 58.755 0 3 2013OCT20_Blk_1 Blank 9.21 357012.719 102072.961 0 4 2013OCT20_Blk_2 Blank 9.21 332857.594 90254.094 79.224 0 5 2013OCT20_0-01_Std Standard 0.01 213.768 0 6 2013OCT20_0-05_Std Standard 0.05 520.527 0 7 2013OCT20_0-1_Std Standard 0.1 231.198 0 8 2013OCT20_0-5_Std Standard 0.5 9.28 14760.59 5580.409 17.518 1 0.50 23% 9 2013OCT20_1_Std Standard 1 9.29 26565.717 6954.47 1645.757 1 1.00 11% 10 2013OCT20_5_Std Standard 5 9.29 151541.656 43943.984 3700.083 1 5 27% 11 2013OCT20_10_Std Standard 10 9.29 287365.781 83349.219 7292.619 1 10 20% 12 2013OCT20_25_Std Standard 25 9.29 653268.375 202446.422 15654.897 1 25 9% 13 2013OCT20_50_Std Standard 50 9.29 1193235.75 375810.219 29448.641 1 50 0% 14 2013OCT20_100_Std Standard 100 9.29 2380491.75 744404.75 58011.984 1 100 -1% 15 2013OCT20_200_Stds Standard 200 9.29 4787227 1359819.625 106898.008 1 200 0% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate 9.21 340701.313 89203.141 243.756 0 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 4.449 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 9.29 1627725.5 491485.031 30393.801 1 Low-Spk1 135% 21 2013OCT20_Lo_2 Recovery 50 9.29 1165960.875 356331.219 25161.307 1 Low-Spk2 96% 22 2013OCT20_Lo_3 Recovery 50 9.28 1582226.125 470080.188 30742.295 1 Low-Spk3 131% 23 2013OCT20_Lo_4 Recovery 50 9.29 1635955.625 482929.531 33256.633 1 Low-Spk4 136% 24 2013OCT20_Lo_5 Recovery 50 9.28 1420315.125 427054.031 28169.451 1 Low-Spk5 118% 25 2013OCT20_SolvA_6 9.627 103.17 #DIV/0! 26 2013OCT20_SolvA_7 104.266 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 9.29 2694924.75 824868 60192.813 1 Mid-Spk1 112% 28 2013OCT20_Mid_2 Recovery 100 9.29 2882160.75 878452.438 63758.445 1 Mid-Spk2 120% 29 2013OCT20_Mid_3 Recovery 100 9.29 2465908 763652.188 55113.648 1 Mid-Spk3 103% 30 2013OCT20_Mid_4 Recovery 100 9.29 2299703.5 689100.625 50956.117 1 Mid-Spk4 96% 31 2013OCT20_Mid_5 Recovery 100 9.29 2601183.5 788831.5 54443.223 1 Mid-Spk5 108% 32 2013OCT20_SolvA_8 260.004 #DIV/0! 33 2013OCT20_SolvA_9 33.455 #DIV/0! 98 34 2013OCT20_Std Dil 200_1 9.29 4256472 1059534.25 78788.828 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 16.855 351.77 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 9.28 4480312 1170912.125 83084.375 1 Hi-Dil-Spk1 105% 37 2013OCT20_Dil_Hi_2 Recovery 100 9.28 4551054 1150678 85878.586 1 Hi-Dil-Spk2 107% 38 2013OCT20_Dil_Hi_3 Recovery 100 9.28 4474275.5 1135544.25 79942.086 1 Hi-Dil-Spk3 105% 39 2013OCT20_Dil_Hi_4 Recovery 100 9.28 4613371.5 1201896.75 91422.422 1 Hi-Dil-Spk4 108% 40 2013OCT20_Dil_Hi_5 Recovery 100 9.29 4898427.5 1306601.5 94052.047 1 Hi-Dil-Spk5 115% 41 2013OCT20_SolvA_11 207.377 79.815 #DIV/0! 42 2013OCT20_Std Dil 200_2 9.29 4283180 1034073.813 79253.359 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 88.514 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 9.28 5044683 1474107.625 106965.313 1 Hi-Spk1 106% 45 2013OCT20_Hi_2 Recovery 200 9.29 5229228.5 1518718.25 113332.219 1 Hi-Spk2 109% 46 2013OCT20_Hi_3 Recovery 200 9.29 5069921.5 1437155.25 104826.773 1 Hi-Spk3 106% 47 2013OCT20_Hi_4 Recovery 200 9.29 5214112 1541559 115471.406 1 Hi-Spk4 109% 48 2013OCT20_Hi_5 Recovery 200 9.29 5554011.5 1699903.5 128947.406 1 Hi-Spk5 116% 49 2013OCT20_SolvA_13 282.909 #DIV/0! 50 2013OCT20_SolvA_14 625.159 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 9.29 15262.316 6068.624 399.158 1 55 2013OCT20_1_Std_2 Standard 1 9.29 22017.432 7307.577 877.023 1 56 2013OCT20_5_Std_2 Standard 5 9.29 148989.719 43888.258 5318.574 1 57 2013OCT20_10_Std_2 Standard 10 9.29 269831.188 80325.727 6001.611 1 58 2013OCT20_25_Std_2 Standard 25 9.29 656723.125 196568.516 14254.84 1 59 2013OCT20_50_Std_2 Standard 50 9.29 1185465.625 371498.031 27067.344 1 60 2013OCT20_100_Std_2 Standard 100 9.29 2321589 725702.813 53614.168 1 61 2013OCT20_200_Std_2 Standard 200 9.29 4731144.5 1347719.5 105435.344 1 62 2013OCT20_SolvA_15 518.52 29.222 #DIV/0! 63 2013OCT20_Surrogate_2 9.21 323337.406 90252.281 0 64 2013OCT20_SolvA_16 143.765 #DIV/0! Compound 13: Metolachlor-d6 Pk Area yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? 1 2013OCT20_SolvA_2 #DIV/0! 0 2 2013OCT20_RO Blank 9.28 8260206.5 5405040.5 1301157.375 1 8260207 3 2013OCT20_Blk_1 Blank 9.28 8052377 5176789.5 1234224.25 1 8052377 4 2013OCT20_Blk_2 Blank 9.28 7767975.5 4786230.5 1089770.125 1 7767976 5 2013OCT20_0-01_Std Standard 0.01 9.28 7317027.5 4501626.5 1006081.375 1 7317028 6 2013OCT20_0-05_Std Standard 0.05 9.28 7382853.5 4586292 1026036.5 1 7382854 7 2013OCT20_0-1_Std Standard 0.1 9.28 8496429 5616310.5 1674703 1 8496429 8 2013OCT20_0-5_Std Standard 0.5 9.28 8012669.5 5204606.5 1472159 1 8012670 9 2013OCT20_1_Std Standard 1 9.28 7832346.5 4804292.5 1055223.5 1 7832347 10 2013OCT20_5_Std Standard 5 9.28 8224516 5421118.5 1300617.375 1 8224516 11 2013OCT20_10_Std Standard 10 9.28 8116567 5210795 1227689 1 8116567 12 2013OCT20_25_Std Standard 25 9.28 7929929.5 5031555 1142726 1 7929930 99 13 2013OCT20_50_Std Standard 50 9.28 7946620 4884087 1094188.625 1 7946620 14 2013OCT20_100_Std Standard 100 9.28 7648769 4723861.5 1036726.438 1 7648769 15 2013OCT20_200_Stds Standard 200 9.28 7784769.5 4492874 968987.875 1 7784770 16 2013OCT20_SolvA_3 #DIV/0! 0 17 2013OCT20_Surrogate #DIV/0! 0 18 2013OCT20_SolvA_4 #DIV/0! 0 19 2013OCT20_SolvA_5 15.988 #DIV/0! 0 20 2013OCT20_Lo_1 Recovery 50 9.28 8012627.5 5007881.5 1148451.625 1 8012628 %Recovery 21 2013OCT20_Lo_2 Recovery 50 9.28 7254469 4152441.75 845104.875 1 7254469 22 2013OCT20_Lo_3 Recovery 50 9.28 7939215.5 4977692.5 1118047.375 1 7939216 23 2013OCT20_Lo_4 Recovery 50 9.28 8067758.5 5077108 1138094 1 8067759 24 2013OCT20_Lo_5 Recovery 50 9.28 7595959 4563495.5 993526.438 1 7595959 25 2013OCT20_SolvA_6 #DIV/0! 0 26 2013OCT20_SolvA_7 #DIV/0! 0 27 2013OCT20_Mid_1 Recovery 100 9.28 7910449 4669886.5 1032352.188 1 7910449 28 2013OCT20_Mid_2 Recovery 100 9.28 7981060.5 4997518.5 1134411.625 1 7981061 29 2013OCT20_Mid_3 Recovery 100 9.28 7496211 4426611.5 969803.563 1 7496211 30 2013OCT20_Mid_4 Recovery 100 9.28 7410264.5 4235544.5 888621.938 1 7410265 31 2013OCT20_Mid_5 Recovery 100 9.28 7834939.5 4484500 958540.563 1 7834940 32 2013OCT20_SolvA_8 14.968 #DIV/0! 0 33 2013OCT20_SolvA_9 #DIV/0! 0 34 2013OCT20_Std Dil 200_1 9.28 7343023 3004930 723932.75 1 7343023 35 2013OCT20_SolvA_10 44.404 #DIV/0! 0 36 2013OCT20_Dil_Hi_1 Recovery 100 9.28 7165043 2964109.75 742553.375 1 7165043 37 2013OCT20_Dil_Hi_2 Recovery 100 9.28 7266191 2997411.5 728761.313 1 7266191 38 2013OCT20_Dil_Hi_3 Recovery 100 9.28 7201724 2967104.75 717083.625 1 7201724 39 2013OCT20_Dil_Hi_4 Recovery 100 9.28 7300763 3174763 752871.813 1 7300763 40 2013OCT20_Dil_Hi_5 Recovery 100 9.28 7660004 3326387.75 792072.875 1 7660004 41 2013OCT20_SolvA_11 #DIV/0! 0 42 2013OCT20_Std Dil 200_2 9.28 7312089 3042688.75 727022 1 7312089 43 2013OCT20_SolvA_12 #DIV/0! 0 44 2013OCT20_Hi_1 Recovery 200 9.28 7661658 4389657 945706 1 7661658 45 2013OCT20_Hi_2 Recovery 200 9.28 7767795.5 4427653 945806.875 1 7767796 46 2013OCT20_Hi_3 Recovery 200 9.28 7784726.5 4351684 911825.25 1 7784727 47 2013OCT20_Hi_4 Recovery 200 9.28 7797139.5 4522333 963375.313 1 7797140 48 2013OCT20_Hi_5 Recovery 200 9.28 8073659 4783522.5 1064096.375 1 8073659 49 2013OCT20_SolvA_13 #DIV/0! 0 50 2013OCT20_SolvA_14 9.105 #DIV/0! 0 51 2013OCT20_0-01_Std_2 Standard 0.01 9.28 7367260.5 4441722.5 952512.625 1 7367261 52 2013OCT20_0-05_Std_2 Standard 0.05 9.28 7394022 4581182 1007486.438 1 7394022 53 2013OCT20_0-1_Std_2 Standard 0.1 9.28 8295432 5496136.5 1302093.5 1 8295432 54 2013OCT20_0-5_Std_2 Standard 0.5 9.28 7811327.5 4980289 1134259.5 1 7811328 55 2013OCT20_1_Std_2 Standard 1 9.28 7640214 4677064.5 1055864.25 1 7640214 56 2013OCT20_5_Std_2 Standard 5 9.28 8135894.5 5336103 1215860.75 1 8135895 57 2013OCT20_10_Std_2 Standard 10 9.28 8016580.5 5003577.5 1157210.5 1 8016581 58 2013OCT20_25_Std_2 Standard 25 9.28 7893512.5 4832475 1113516.875 1 7893513 100 59 2013OCT20_50_Std_2 Standard 50 9.28 7810099 4829008.5 1116844.375 1 7810099 60 2013OCT20_100_Std_2 Standard 100 9.28 7602103 4601369 1008414.813 1 7602103 61 2013OCT20_200_Std_2 Standard 200 9.28 7765892.5 4457285 965031.438 1 7765893 62 2013OCT20_SolvA_15 177.261 #DIV/0! 0 63 2013OCT20_Surrogate_2 #DIV/0! 0 64 2013OCT20_SolvA_16 #DIV/0! 0 Compound 15: Acesulfame Compound 15: Acesulfame yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 #DIV/0! 2 2013OCT20_RO Blank #DIV/0! 3 2013OCT20_Blk_1 Blank #DIV/0! 4 2013OCT20_Blk_2 Blank #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 0 6 2013OCT20_0-05_Std Standard 0.05 0 7 2013OCT20_0-1_Std Standard 0.1 0 8 2013OCT20_0-5_Std Standard 0.5 1.43 1167.272 53.713 1 0.50 -16% 9 2013OCT20_1_Std Standard 1 1.46 2408.083 146.707 1 1.00 -13% 10 2013OCT20_5_Std Standard 5 1.45 15890.887 1976.567 1 5 14% 11 2013OCT20_10_Std Standard 10 1.45 33734.234 3375.953 1 10 21% 12 2013OCT20_25_Std Standard 25 1.45 86745.156 10012.978 1 25 25% 13 2013OCT20_50_Std Standard 50 1.45 151706.031 21558.586 1 50 9% 14 2013OCT20_100_Std Standard 100 1.45 292530.438 40786.277 1 100 5% 15 2013OCT20_200_Stds Standard 200 1.45 542428.438 70385.703 1 200 -2% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 1.44 1865.606 85.513 1 Low-Spk1 -4% 21 2013OCT20_Lo_2 Recovery 50 1.44 2587.387 204.477 1 Low-Spk2 -4% 22 2013OCT20_Lo_3 Recovery 50 1.45 2085.871 0 Low-Spk3 -4% 23 2013OCT20_Lo_4 Recovery 50 1.46 2747.435 127.724 1 Low-Spk4 -4% 24 2013OCT20_Lo_5 Recovery 50 1.46 1946.227 0 Low-Spk5 -4% 25 2013OCT20_SolvA_6 #DIV/0! 26 2013OCT20_SolvA_7 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 1.44 4443.394 214.084 1 Mid-Spk1 -1% 28 2013OCT20_Mid_2 Recovery 100 1.46 5074.051 500.949 1 Mid-Spk2 -1% 29 2013OCT20_Mid_3 Recovery 100 1.43 4726.055 348.936 1 Mid-Spk3 -1% 30 2013OCT20_Mid_4 Recovery 100 1.45 5505.646 133.593 1 Mid-Spk4 -1% 31 2013OCT20_Mid_5 Recovery 100 1.45 5146.759 537.966 1 Mid-Spk5 -1% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 #DIV/0! 34 2013OCT20_Std Dil 200_1 1.45 250701.063 28909.242 1 Hi-Dil-Std 101 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 1.45 3906.105 288.461 1 Hi-Dil-Spk1 -2% 37 2013OCT20_Dil_Hi_2 Recovery 100 1.46 2304.003 0 Hi-Dil-Spk2 -2% 38 2013OCT20_Dil_Hi_3 Recovery 100 1.44 3254.499 246.377 1 Hi-Dil-Spk3 -2% 39 2013OCT20_Dil_Hi_4 Recovery 100 1.44 3717.5 336.511 1 Hi-Dil-Spk4 -2% 40 2013OCT20_Dil_Hi_5 Recovery 100 1.45 3281.896 64.475 1 Hi-Dil-Spk5 -2% 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 1.45 260372.063 34186.203 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 1.44 8751.907 954.003 1 Hi-Spk1 0% 45 2013OCT20_Hi_2 Recovery 200 1.45 6140.084 112.961 1 Hi-Spk2 0% 46 2013OCT20_Hi_3 Recovery 200 1.44 7812.132 833.235 1 Hi-Spk3 0% 47 2013OCT20_Hi_4 Recovery 200 1.45 8133.792 559.928 1 Hi-Spk4 0% 48 2013OCT20_Hi_5 Recovery 200 1.45 7782.074 648.458 1 Hi-Spk5 0% 49 2013OCT20_SolvA_13 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 1.44 1072.837 84.727 1 55 2013OCT20_1_Std_2 Standard 1 1.46 2860.551 180.165 1 56 2013OCT20_5_Std_2 Standard 5 1.45 16602.762 1900.035 1 57 2013OCT20_10_Std_2 Standard 10 1.45 30578.49 3796.104 1 58 2013OCT20_25_Std_2 Standard 25 1.45 84076.633 9866.3 1 59 2013OCT20_50_Std_2 Standard 50 1.45 153769.031 17536.432 1 60 2013OCT20_100_Std_2 Standard 100 1.45 280461.938 38375.211 1 61 2013OCT20_200_Std_2 Standard 200 1.45 531747.563 67590.063 1 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 16: Acesulfame-d4 Pk Area yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? 1 2013OCT20_SolvA_2 #DIV/0! 0 2 2013OCT20_RO Blank 1.44 202584.922 36288.16 1 202585 3 2013OCT20_Blk_1 Blank 1.44 3798.095 454.899 1 3798 4 2013OCT20_Blk_2 Blank 1.45 2930.102 236.112 1 2930 5 2013OCT20_0-01_Std Standard 0.01 1.43 211603.5 39186.563 1 211604 6 2013OCT20_0-05_Std Standard 0.05 1.44 217154.563 38081.711 1 217155 7 2013OCT20_0-1_Std Standard 0.1 1.43 213508.25 38698.086 1 213508 8 2013OCT20_0-5_Std Standard 0.5 1.43 227754.266 40372.07 1 227754 9 2013OCT20_1_Std Standard 1 1.44 230314.469 38476.695 1 230314 10 2013OCT20_5_Std Standard 5 1.44 218592.016 38138.742 1 218592 11 2013OCT20_10_Std Standard 10 1.44 212837.5 34739.809 1 212838 12 2013OCT20_25_Std Standard 25 1.44 209597.703 37460.375 1 209598 13 2013OCT20_50_Std Standard 50 1.44 210777.141 37124.422 1 210777 102 14 2013OCT20_100_Std Standard 100 1.44 185497.688 31257.68 1 185498 15 2013OCT20_200_Stds Standard 200 1.43 180094.063 27519.172 1 180094 16 2013OCT20_SolvA_3 #DIV/0! 0 17 2013OCT20_Surrogate #DIV/0! 0 18 2013OCT20_SolvA_4 #DIV/0! 0 19 2013OCT20_SolvA_5 #DIV/0! 0 20 2013OCT20_Lo_1 Recovery 50 1.43 2893.251 403.21 1 2893 %Recovery 21 2013OCT20_Lo_2 Recovery 50 1.44 3212.792 367.699 1 3213 22 2013OCT20_Lo_3 Recovery 50 1.43 2953.428 219.288 1 2953 23 2013OCT20_Lo_4 Recovery 50 1.43 3283.299 715.345 1 3283 24 2013OCT20_Lo_5 Recovery 50 1.45 2040.314 410.587 1 2040 25 2013OCT20_SolvA_6 #DIV/0! 0 26 2013OCT20_SolvA_7 #DIV/0! 0 27 2013OCT20_Mid_1 Recovery 100 1.44 2641.292 348.373 1 2641 28 2013OCT20_Mid_2 Recovery 100 1.44 3324.147 182.014 1 3324 29 2013OCT20_Mid_3 Recovery 100 1.44 2567.373 462.136 1 2567 30 2013OCT20_Mid_4 Recovery 100 1.43 2905.803 472.763 1 2906 31 2013OCT20_Mid_5 Recovery 100 1.44 2772.783 421.51 1 2773 32 2013OCT20_SolvA_8 #DIV/0! 0 33 2013OCT20_SolvA_9 #DIV/0! 0 34 2013OCT20_Std Dil 200_1 1.44 84536.328 15170.613 1 84536 35 2013OCT20_SolvA_10 #DIV/0! 0 36 2013OCT20_Dil_Hi_1 Recovery 100 1.45 1128.941 0 1129 37 2013OCT20_Dil_Hi_2 Recovery 100 1.44 714.824 0 715 38 2013OCT20_Dil_Hi_3 Recovery 100 1.45 687.276 87.462 1 687 39 2013OCT20_Dil_Hi_4 Recovery 100 1.43 881.903 0 882 40 2013OCT20_Dil_Hi_5 Recovery 100 1.42 794.467 0 794 41 2013OCT20_SolvA_11 #DIV/0! 0 42 2013OCT20_Std Dil 200_2 1.44 85655.008 13198.221 1 85655 43 2013OCT20_SolvA_12 #DIV/0! 0 44 2013OCT20_Hi_1 Recovery 200 1.43 3059.426 188.532 1 3059 45 2013OCT20_Hi_2 Recovery 200 1.41 1520.324 161.145 0 1520 46 2013OCT20_Hi_3 Recovery 200 1.42 1839.536 56.798 0 1840 47 2013OCT20_Hi_4 Recovery 200 1.42 1776.824 223.588 0 1777 48 2013OCT20_Hi_5 Recovery 200 1.43 2424.945 126.302 1 2425 49 2013OCT20_SolvA_13 #DIV/0! 0 50 2013OCT20_SolvA_14 #DIV/0! 0 51 2013OCT20_0-01_Std_2 Standard 0.01 1.44 205169.422 33328.387 1 205169 52 2013OCT20_0-05_Std_2 Standard 0.05 1.44 213379.625 35038.695 1 213380 53 2013OCT20_0-1_Std_2 Standard 0.1 1.44 206376.063 33537.156 1 206376 54 2013OCT20_0-5_Std_2 Standard 0.5 1.43 207853.734 27068.436 1 207854 55 2013OCT20_1_Std_2 Standard 1 1.44 213096.188 35942.492 1 213096 56 2013OCT20_5_Std_2 Standard 5 1.44 208932.688 33658.473 1 208933 57 2013OCT20_10_Std_2 Standard 10 1.44 194985.813 30807.178 1 194986 58 2013OCT20_25_Std_2 Standard 25 1.44 205806.906 36761.395 1 205807 59 2013OCT20_50_Std_2 Standard 50 1.44 203225.688 36213.938 1 203226 103 60 2013OCT20_100_Std_2 Standard 100 1.44 185080.406 32861.734 1 185080 61 2013OCT20_200_Std_2 Standard 200 1.43 174566.109 28795.65 1 174566 62 2013OCT20_SolvA_15 #DIV/0! 0 63 2013OCT20_Surrogate_2 #DIV/0! 0 64 2013OCT20_SolvA_16 #DIV/0! 0 Compound 17: Cyclamate Compound 17: Cyclamate yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 #DIV/0! 2 2013OCT20_RO Blank 2.16 40.938 0 3 2013OCT20_Blk_1 Blank 2.15 59.861 0 4 2013OCT20_Blk_2 Blank 2.14 108.43 0 5 2013OCT20_0-01_Std Standard 0.01 2.13 65.89 1.206 1 6 2013OCT20_0-05_Std Standard 0.05 2.14 439.637 0 0.05 43% 7 2013OCT20_0-1_Std Standard 0.1 2.13 1037.729 6.851 1 0.10 69% 8 2013OCT20_0-5_Std Standard 0.5 2.13 3587.293 16.928 1 0.50 17% 9 2013OCT20_1_Std Standard 1 2.13 9447.8 74.029 1 1.00 54% 10 2013OCT20_5_Std Standard 5 2.13 40472.227 644.923 1 5 32% 11 2013OCT20_10_Std Standard 10 2.13 77380.961 1132.05 1 10 26% 12 2013OCT20_25_Std Standard 25 2.13 192584.047 2874.481 1 25 25% 13 2013OCT20_50_Std Standard 50 2.14 369361.188 6415.423 1 50 20% 14 2013OCT20_100_Std Standard 100 2.13 665030.563 12428.019 1 100 8% 15 2013OCT20_200_Stds Standard 200 2.13 1182615.875 24044.752 1 200 -4% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 2.14 5899.86 204.237 1 Low-Spk1 -4% 21 2013OCT20_Lo_2 Recovery 50 2.14 6481.89 226.44 1 Low-Spk2 -4% 22 2013OCT20_Lo_3 Recovery 50 2.14 4323.108 215.323 1 Low-Spk3 -5% 23 2013OCT20_Lo_4 Recovery 50 2.14 6978.401 373.038 1 Low-Spk4 -4% 24 2013OCT20_Lo_5 Recovery 50 2.14 4535.662 105.89 1 Low-Spk5 -5% 25 2013OCT20_SolvA_6 2.16 144.565 0 26 2013OCT20_SolvA_7 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 2.14 10793.196 818.834 1 Mid-Spk1 -1% 28 2013OCT20_Mid_2 Recovery 100 2.14 13094.874 1178.666 1 Mid-Spk2 -1% 29 2013OCT20_Mid_3 Recovery 100 2.14 11826.216 941.6 1 Mid-Spk3 -1% 30 2013OCT20_Mid_4 Recovery 100 2.14 12309.439 1147.029 1 Mid-Spk4 -1% 31 2013OCT20_Mid_5 Recovery 100 2.14 10519.631 928.247 1 Mid-Spk5 -1% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 #DIV/0! 34 2013OCT20_Std Dil 200_1 2.14 506588.656 11142.769 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 2.14 9662.328 1242.193 1 Hi-Dil-Spk1 -2% 37 2013OCT20_Dil_Hi_2 Recovery 100 2.14 6606.197 1136.656 1 Hi-Dil-Spk2 -3% 38 2013OCT20_Dil_Hi_3 Recovery 100 2.14 8586.986 1390.485 1 Hi-Dil-Spk3 -2% 104 39 2013OCT20_Dil_Hi_4 Recovery 100 2.14 9310.684 1733.032 1 Hi-Dil-Spk4 -2% 40 2013OCT20_Dil_Hi_5 Recovery 100 2.14 10327.351 1712.132 1 Hi-Dil-Spk5 -2% 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 2.14 492223.438 10164.466 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 2.12 107.018 0 44 2013OCT20_Hi_1 Recovery 200 2.14 21408.836 3266.251 1 Hi-Spk1 0% 45 2013OCT20_Hi_2 Recovery 200 2.14 15927.097 2961.678 1 Hi-Spk2 0% 46 2013OCT20_Hi_3 Recovery 200 2.14 21653.037 3360.947 1 Hi-Spk3 0% 47 2013OCT20_Hi_4 Recovery 200 2.14 23939.77 3661.102 1 Hi-Spk4 0% 48 2013OCT20_Hi_5 Recovery 200 2.14 23503.506 3724.079 1 Hi-Spk5 0% 49 2013OCT20_SolvA_13 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 2.14 505.881 0 53 2013OCT20_0-1_Std_2 Standard 0.1 2.14 1048.834 0 54 2013OCT20_0-5_Std_2 Standard 0.5 2.14 3895.83 57.991 1 55 2013OCT20_1_Std_2 Standard 1 2.14 8686.971 198.558 1 56 2013OCT20_5_Std_2 Standard 5 2.13 37669.715 469.969 1 57 2013OCT20_10_Std_2 Standard 10 2.14 69883.414 1183.639 1 58 2013OCT20_25_Std_2 Standard 25 2.14 182483.125 3573.969 1 59 2013OCT20_50_Std_2 Standard 50 2.14 350509.531 6649.867 1 60 2013OCT20_100_Std_2 Standard 100 2.14 633671.5 11918.054 1 61 2013OCT20_200_Std_2 Standard 200 2.14 1126548.25 24134.182 1 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 18: saccharine Compound 18: saccharine yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 #DIV/0! 2 2013OCT20_RO Blank #DIV/0! 3 2013OCT20_Blk_1 Blank 23.283 #DIV/0! 4 2013OCT20_Blk_2 Blank #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 0 6 2013OCT20_0-05_Std Standard 0.05 0 7 2013OCT20_0-1_Std Standard 0.1 1.84 76.12 70.821 0 8 2013OCT20_0-5_Std Standard 0.5 1.84 420.026 527.603 0 9 2013OCT20_1_Std Standard 1 1.83 908.716 21.271 998.142 1 10 2013OCT20_5_Std Standard 5 1.83 5023.087 698.586 5547.447 1 5 32% 11 2013OCT20_10_Std Standard 10 1.83 10294.299 1555.479 10403.491 1 10 36% 12 2013OCT20_25_Std Standard 25 1.84 25021.693 3842.9 24957.461 1 25 32% 13 2013OCT20_50_Std Standard 50 1.84 44469 6835.376 46778.395 1 50 17% 14 2013OCT20_100_Std Standard 100 1.83 80991.914 12575.164 83667.195 1 100 7% 15 2013OCT20_200_Stds Standard 200 1.84 146674.516 24182.607 152851.516 1 200 -3% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 105 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 1.84 2767.562 430.438 2864.489 1 Low-Spk1 -7% 21 2013OCT20_Lo_2 Recovery 50 1.85 2442.336 292.294 2916.823 1 Low-Spk2 -8% 22 2013OCT20_Lo_3 Recovery 50 1.84 2115.313 271.965 2387.727 1 Low-Spk3 -9% 23 2013OCT20_Lo_4 Recovery 50 1.84 3117.304 530.032 3054.294 1 Low-Spk4 -6% 24 2013OCT20_Lo_5 Recovery 50 1.84 1785.594 29.488 2227.428 1 Low-Spk5 -10% 25 2013OCT20_SolvA_6 #DIV/0! 26 2013OCT20_SolvA_7 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 1.83 4885.042 618.696 4647.616 1 Mid-Spk1 -1% 28 2013OCT20_Mid_2 Recovery 100 1.84 5936.519 925.69 6721.154 1 Mid-Spk2 1% 29 2013OCT20_Mid_3 Recovery 100 1.85 5576.903 789.261 5907.181 1 Mid-Spk3 0% 30 2013OCT20_Mid_4 Recovery 100 1.84 5828.876 971.037 6221.254 1 Mid-Spk4 1% 31 2013OCT20_Mid_5 Recovery 100 1.84 4888.458 688.389 5296.659 1 Mid-Spk5 -1% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 #DIV/0! 34 2013OCT20_Std Dil 200_1 1.84 63845.324 10128.342 70083.797 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 1.85 3759.677 474.509 3793.169 1 Hi-Dil-Spk1 -3% 37 2013OCT20_Dil_Hi_2 Recovery 100 1.84 2592.433 457.496 2959.805 1 Hi-Dil-Spk2 -5% 38 2013OCT20_Dil_Hi_3 Recovery 100 1.84 3351.085 391.736 3476.677 1 Hi-Dil-Spk3 -3% 39 2013OCT20_Dil_Hi_4 Recovery 100 1.84 3890.882 378.4 3890.028 1 Hi-Dil-Spk4 -2% 40 2013OCT20_Dil_Hi_5 Recovery 100 1.84 3820.581 510.79 4005.987 1 Hi-Dil-Spk5 -2% 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 1.84 64919.32 10008.92 68861.25 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 1.84 9539.101 1338.98 9619.849 1 Hi-Spk1 3% 45 2013OCT20_Hi_2 Recovery 200 1.84 6536.526 857.246 7070.003 1 Hi-Spk2 1% 46 2013OCT20_Hi_3 Recovery 200 1.84 8503.311 1143.138 8862.166 1 Hi-Spk3 2% 47 2013OCT20_Hi_4 Recovery 200 1.84 8650.919 1384.949 9127.903 1 Hi-Spk4 2% 48 2013OCT20_Hi_5 Recovery 200 1.84 8662.518 812.309 8422.462 1 Hi-Spk5 2% 49 2013OCT20_SolvA_13 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 1.83 435.872 454.453 0 55 2013OCT20_1_Std_2 Standard 1 1.84 742.917 999.528 0 56 2013OCT20_5_Std_2 Standard 5 1.84 4771.268 569.097 5450.008 1 57 2013OCT20_10_Std_2 Standard 10 1.83 8823.247 1592.014 10129.372 1 58 2013OCT20_25_Std_2 Standard 25 1.83 24740.971 3677.604 25908.313 1 59 2013OCT20_50_Std_2 Standard 50 1.84 40805.191 6362.845 43606.117 1 60 2013OCT20_100_Std_2 Standard 100 1.83 79398.859 12046.532 82182.18 1 61 2013OCT20_200_Std_2 Standard 200 1.84 139223.281 22569.133 148796.594 1 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 106 64 2013OCT20_SolvA_16 #DIV/0! Compound 19: 2.4-D Compound 19: 2.4-D yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 463.121 #DIV/0! 2 2013OCT20_RO Blank #DIV/0! 3 2013OCT20_Blk_1 Blank #DIV/0! 4 2013OCT20_Blk_2 Blank 66.367 #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 0 6 2013OCT20_0-05_Std Standard 0.05 0 7 2013OCT20_0-1_Std Standard 0.1 0 8 2013OCT20_0-5_Std Standard 0.5 6.17 1267.588 107.625 0 9 2013OCT20_1_Std Standard 1 6.18 2685.082 148.083 6.921 1 1.00 9% 10 2013OCT20_5_Std Standard 5 6.17 15086.901 1681.479 149.352 1 5 23% 11 2013OCT20_10_Std Standard 10 6.16 29260.26 2869.107 200.665 1 10 19% 12 2013OCT20_25_Std Standard 25 6.15 73960.328 6021.511 1290.048 1 25 21% 13 2013OCT20_50_Std Standard 50 6.15 139395.859 10837.955 2569.639 1 50 14% 14 2013OCT20_100_Std Standard 100 6.15 259347.969 22332.135 4456.779 1 100 6% 15 2013OCT20_200_Stds Standard 200 6.15 477557.406 43219.922 9121.994 1 200 -3% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 5.506 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 6.15 148560.656 12911.081 3142.942 1 Low-Spk1 117% 21 2013OCT20_Lo_2 Recovery 50 6.15 123868.656 10697.262 2322.598 1 Low-Spk2 96% 22 2013OCT20_Lo_3 Recovery 50 6.15 120672.703 10580.753 2203.321 1 Low-Spk3 93% 23 2013OCT20_Lo_4 Recovery 50 6.15 131817.219 11823.49 2836.348 1 Low-Spk4 103% 24 2013OCT20_Lo_5 Recovery 50 6.15 112393.766 10271.267 2002.963 1 Low-Spk5 86% 25 2013OCT20_SolvA_6 47.808 #DIV/0! 26 2013OCT20_SolvA_7 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 6.15 253094.781 21737.459 5014.403 1 Mid-Spk1 102% 28 2013OCT20_Mid_2 Recovery 100 6.15 283728.969 23932.355 6468.854 1 Mid-Spk2 115% 29 2013OCT20_Mid_3 Recovery 100 6.15 263234.313 23773.199 5212.628 1 Mid-Spk3 106% 30 2013OCT20_Mid_4 Recovery 100 6.16 246883.109 21985.951 4472.765 1 Mid-Spk4 100% 31 2013OCT20_Mid_5 Recovery 100 6.17 254608.781 22406.58 5225.468 1 Mid-Spk5 103% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 55.546 #DIV/0! 34 2013OCT20_Std Dil 200_1 6.17 252431.75 22721.539 5062.756 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 6.15 278407.656 24588.365 5079.601 1 Hi-Dil-Spk1 111% 37 2013OCT20_Dil_Hi_2 Recovery 100 6.15 252938.547 21711.029 5622.619 1 Hi-Dil-Spk2 100% 38 2013OCT20_Dil_Hi_3 Recovery 100 6.16 265058 23183.137 5343.359 1 Hi-Dil-Spk3 105% 39 2013OCT20_Dil_Hi_4 Recovery 100 6.15 287246.219 25689.061 6062.337 1 Hi-Dil-Spk4 114% 40 2013OCT20_Dil_Hi_5 Recovery 100 6.16 289991.438 26366.609 5737.39 1 Hi-Dil-Spk5 115% 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 6.15 249644.047 24098.314 5368.3 1 Hi-Dil-Std 107 43 2013OCT20_SolvA_12 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 6.15 528550.313 46480.75 10672.082 1 Hi-Spk1 109% 45 2013OCT20_Hi_2 Recovery 200 6.16 475060.281 43767.992 9268.388 1 Hi-Spk2 98% 46 2013OCT20_Hi_3 Recovery 200 6.16 501243.313 44670.359 10316.452 1 Hi-Spk3 103% 47 2013OCT20_Hi_4 Recovery 200 6.15 535977.875 47140.16 10132.882 1 Hi-Spk4 110% 48 2013OCT20_Hi_5 Recovery 200 6.16 524845.75 43512.039 9543.643 1 Hi-Spk5 108% 49 2013OCT20_SolvA_13 110.95 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 109.632 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 29.138 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 103.552 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 6.15 1798.386 37.404 121.789 1 55 2013OCT20_1_Std_2 Standard 1 6.17 2675.144 317.7 0 56 2013OCT20_5_Std_2 Standard 5 6.16 15137.047 1196.314 460.903 1 57 2013OCT20_10_Std_2 Standard 10 6.16 26310.174 2452.242 352.227 1 58 2013OCT20_25_Std_2 Standard 25 6.16 71324.102 6291.097 833.712 1 59 2013OCT20_50_Std_2 Standard 50 6.15 128125.344 11927.884 2771.765 1 60 2013OCT20_100_Std_2 Standard 100 6.15 251619.172 22307.658 4970.124 1 61 2013OCT20_200_Std_2 Standard 200 6.15 465230.906 44620.555 9811.837 1 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 20: 13C-2.4-D Name Type Std. Conc RT Area 1? Area 2? Area 1 2013OCT20_SolvA_2 2 2013OCT20_RO Blank 6.15 386694.719 3 2013OCT20_Blk_1 Blank 6.15 391003.375 4 2013OCT20_Blk_2 Blank 6.15 325205.781 5 2013OCT20_0-01_Std Standard 0.01 6.15 369973.813 6 2013OCT20_0-05_Std Standard 0.05 6.15 365813.219 7 2013OCT20_0-1_Std Standard 0.1 6.15 399646.344 8 2013OCT20_0-5_Std Standard 0.5 6.15 383498.219 9 2013OCT20_1_Std Standard 1 6.16 386929.5 10 2013OCT20_5_Std Standard 5 6.16 373436 11 2013OCT20_10_Std Standard 10 6.16 369635.688 12 2013OCT20_25_Std Standard 25 6.16 378027 13 2013OCT20_50_Std Standard 50 6.16 376515.75 14 2013OCT20_100_Std Standard 100 6.15 341566.656 15 2013OCT20_200_Stds Standard 200 6.15 337517.969 16 2013OCT20_SolvA_3 6.11 183.729 17 2013OCT20_Surrogate 18 2013OCT20_SolvA_4 19 2013OCT20_SolvA_5 20 2013OCT20_Lo_1 Recovery 50 6.15 372853.781 21 2013OCT20_Lo_2 Recovery 50 6.16 321248.75 22 2013OCT20_Lo_3 Recovery 50 6.16 319542.594 108 23 2013OCT20_Lo_4 Recovery 50 6.16 334533.875 24 2013OCT20_Lo_5 Recovery 50 6.16 285477.656 25 2013OCT20_SolvA_6 26 2013OCT20_SolvA_7 27 2013OCT20_Mid_1 Recovery 100 6.16 319097.094 28 2013OCT20_Mid_2 Recovery 100 6.16 368519.813 29 2013OCT20_Mid_3 Recovery 100 6.16 344483.25 30 2013OCT20_Mid_4 Recovery 100 6.16 317054.594 31 2013OCT20_Mid_5 Recovery 100 6.16 329384.563 32 2013OCT20_SolvA_8 33 2013OCT20_SolvA_9 34 2013OCT20_Std Dil 200_1 6.16 180248.641 35 2013OCT20_SolvA_10 36 2013OCT20_Dil_Hi_1 Recovery 100 6.16 180891.031 37 2013OCT20_Dil_Hi_2 Recovery 100 6.16 163675.281 38 2013OCT20_Dil_Hi_3 Recovery 100 6.16 176508.078 39 2013OCT20_Dil_Hi_4 Recovery 100 6.16 189645.016 40 2013OCT20_Dil_Hi_5 Recovery 100 6.16 182639.563 41 2013OCT20_SolvA_11 42 2013OCT20_Std Dil 200_2 6.16 179457.094 43 2013OCT20_SolvA_12 44 2013OCT20_Hi_1 Recovery 200 6.16 351063.813 45 2013OCT20_Hi_2 Recovery 200 6.16 308069.344 46 2013OCT20_Hi_3 Recovery 200 6.16 329029.281 47 2013OCT20_Hi_4 Recovery 200 6.16 350155.75 48 2013OCT20_Hi_5 Recovery 200 6.16 349860.25 49 2013OCT20_SolvA_13 50 2013OCT20_SolvA_14 51 2013OCT20_0-01_Std_2 Standard 0.01 6.15 367863.25 52 2013OCT20_0-05_Std_2 Standard 0.05 6.15 359039.031 53 2013OCT20_0-1_Std_2 Standard 0.1 6.15 388489.5 54 2013OCT20_0-5_Std_2 Standard 0.5 6.15 374407.375 55 2013OCT20_1_Std_2 Standard 1 6.16 375188.281 56 2013OCT20_5_Std_2 Standard 5 6.16 363717.781 57 2013OCT20_10_Std_2 Standard 10 6.16 368273.875 58 2013OCT20_25_Std_2 Standard 25 6.16 356723.156 59 2013OCT20_50_Std_2 Standard 50 6.16 362933.031 60 2013OCT20_100_Std_2 Standard 100 6.15 330735.75 61 2013OCT20_200_Std_2 Standard 200 6.15 338136.188 62 2013OCT20_SolvA_15 63 2013OCT20_Surrogate_2 64 2013OCT20_SolvA_16 Compound 22: AlachlorESA Compound 22: AlachlorESA m/z 80 m/z 160 m/z 121 yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 #DIV/0! 109 2 2013OCT20_RO Blank #DIV/0! 3 2013OCT20_Blk_1 Blank #DIV/0! 4 2013OCT20_Blk_2 Blank #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 0 6 2013OCT20_0-05_Std Standard 0.05 0 7 2013OCT20_0-1_Std Standard 0.1 0 8 2013OCT20_0-5_Std Standard 0.5 5 4463.124 489.244 2907.557 1 1.00 16% 9 2013OCT20_1_Std Standard 1 5 8739.387 1051.894 6065.498 1 2.00 13% 10 2013OCT20_5_Std Standard 5 4.99 42760.785 4702.048 30803.453 1 10 11% 11 2013OCT20_10_Std Standard 10 4.98 83474.523 8942.25 58667.91 1 20 8% 12 2013OCT20_25_Std Standard 25 4.99 215577.484 23419.539 150331.031 1 50 12% 13 2013OCT20_50_Std Standard 50 4.99 406605.094 45684.926 288990.438 1 100 5% 14 2013OCT20_100_Std Standard 100 4.98 792565.125 89488.203 570528.625 1 200 3% 15 2013OCT20_200_Stds Standard 200 4.98 1523286.75 171146.219 1103317.125 1 400 -1% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 4.99 438738 49252.938 315642.469 1 Low-Spk1 112% 21 2013OCT20_Lo_2 Recovery 50 4.98 359612.438 39549.461 255557.813 1 Low-Spk2 91% 22 2013OCT20_Lo_3 Recovery 50 4.98 368886.469 40407.816 261333.703 1 Low-Spk3 94% 23 2013OCT20_Lo_4 Recovery 50 4.99 340423.438 37521.547 245755.453 1 Low-Spk4 86% 24 2013OCT20_Lo_5 Recovery 50 4.99 341600.094 37178.398 243184.766 1 Low-Spk5 87% 25 2013OCT20_SolvA_6 #DIV/0! 26 2013OCT20_SolvA_7 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 4.99 458270.344 49560.391 325640.875 1 Mid-Spk1 59% 28 2013OCT20_Mid_2 Recovery 100 4.98 836223.813 94765.945 603973.125 1 Mid-Spk2 108% 29 2013OCT20_Mid_3 Recovery 100 4.99 752977.313 83330.75 544104.125 1 Mid-Spk3 97% 30 2013OCT20_Mid_4 Recovery 100 4.99 690401.438 75458.219 487420.344 1 Mid-Spk4 89% 31 2013OCT20_Mid_5 Recovery 100 4.99 732849.375 82027.688 524564.625 1 Mid-Spk5 95% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 #DIV/0! 34 2013OCT20_Std Dil 200_1 4.99 739327.688 80382.883 528616.125 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 4.99 684119.375 76435.781 488184.313 1 Hi-Dil-Spk1 92% 37 2013OCT20_Dil_Hi_2 Recovery 100 4.99 735582.625 80859.07 525155.5 1 Hi-Dil-Spk2 99% 38 2013OCT20_Dil_Hi_3 Recovery 100 4.99 613729.25 66765.453 441631.781 1 Hi-Dil-Spk3 83% 39 2013OCT20_Dil_Hi_4 Recovery 100 4.99 621740.563 67637.75 439924.25 1 Hi-Dil-Spk4 84% 40 2013OCT20_Dil_Hi_5 Recovery 100 4.99 496445.781 55364.543 356337.563 1 Hi-Dil-Spk5 67% 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 4.99 738065.688 81238.961 530257.75 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 4.99 1418843.375 157369.016 1018471.063 1 Hi-Spk1 92% 45 2013OCT20_Hi_2 Recovery 200 4.99 1515089.125 167527.672 1099798.375 1 Hi-Spk2 99% 46 2013OCT20_Hi_3 Recovery 200 4.99 1264049.875 140734.266 901873.125 1 Hi-Spk3 82% 47 2013OCT20_Hi_4 Recovery 200 4.99 1265547.375 138768.391 916938.813 1 Hi-Spk4 82% 110 48 2013OCT20_Hi_5 Recovery 200 4.99 1014003.75 111633.523 724410.375 1 Hi-Spk5 66% 49 2013OCT20_SolvA_13 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 52 2013OCT20_0-05_Std_2 Standard 0.05 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 5.03 4714.414 385.621 2902.885 1 55 2013OCT20_1_Std_2 Standard 1 5.03 8999.618 843.15 6489.494 1 56 2013OCT20_5_Std_2 Standard 5 5.02 43967.035 4904.281 30660.787 1 57 2013OCT20_10_Std_2 Standard 10 4.99 85523.992 8960.527 59492.586 1 58 2013OCT20_25_Std_2 Standard 25 5 211044.203 22181.732 149826.219 1 59 2013OCT20_50_Std_2 Standard 50 5 398167.031 42648.234 282573.781 1 60 2013OCT20_100_Std_2 Standard 100 4.99 801411.125 88071.383 567128.938 1 61 2013OCT20_200_Std_2 Standard 200 4.99 1501346.875 168835.094 1079719 1 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 24: Metolachlor ESA Compound 24: Metolachlor ESA yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 #DIV/0! 2 2013OCT20_RO Blank #DIV/0! 3 2013OCT20_Blk_1 Blank #DIV/0! 4 2013OCT20_Blk_2 Blank #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 0 6 2013OCT20_0-05_Std Standard 0.05 5.26 627.878 0 0.05 128% 7 2013OCT20_0-1_Std Standard 0.1 5.26 775.056 180.579 0 0.10 40% 8 2013OCT20_0-5_Std Standard 0.5 5.26 2950.073 2184.044 136.313 1 0.50 7% 9 2013OCT20_1_Std Standard 1 5.27 6168.148 3667.976 916.502 1 1.00 12% 10 2013OCT20_5_Std Standard 5 5.27 29374.859 19253.162 1774.744 1 5 6% 11 2013OCT20_10_Std Standard 10 5.27 57925.609 38509.809 5515.06 1 10 5% 12 2013OCT20_25_Std Standard 25 5.27 148794.875 93797.023 17980.941 1 25 8% 13 2013OCT20_50_Std Standard 50 5.27 286631.406 172956.344 30581.441 1 50 4% 14 2013OCT20_100_Std Standard 100 5.26 566152.25 354294.75 62913.371 1 100 3% 15 2013OCT20_200_Stds Standard 200 5.26 1092459.625 683586.625 121401.422 1 200 -1% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 5.27 316060.219 195978.531 33495.789 1 Low-Spk1 114% 21 2013OCT20_Lo_2 Recovery 50 5.27 261579.469 171608.453 28964.613 1 Low-Spk2 94% 22 2013OCT20_Lo_3 Recovery 50 5.27 266132.375 168161.281 29766.105 1 Low-Spk3 95% 23 2013OCT20_Lo_4 Recovery 50 5.27 251957.813 151470.891 26906.02 1 Low-Spk4 90% 24 2013OCT20_Lo_5 Recovery 50 5.27 245821.25 148926.75 28508.387 1 Low-Spk5 88% 25 2013OCT20_SolvA_6 #DIV/0! 26 2013OCT20_SolvA_7 #DIV/0! 111 27 2013OCT20_Mid_1 Recovery 100 5.27 331260.25 208034.281 35135.465 1 Mid-Spk1 60% 28 2013OCT20_Mid_2 Recovery 100 5.27 615535.625 384710.594 69455.969 1 Mid-Spk2 111% 29 2013OCT20_Mid_3 Recovery 100 5.27 541766.125 342867.469 59348.637 1 Mid-Spk3 98% 30 2013OCT20_Mid_4 Recovery 100 5.28 489038.469 306546.906 55453.125 1 Mid-Spk4 88% 31 2013OCT20_Mid_5 Recovery 100 5.28 524185.688 330851.281 55934.781 1 Mid-Spk5 95% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 #DIV/0! 34 2013OCT20_Std Dil 200_1 5.28 522288.531 320211.156 53174.207 1 Hi-Dil-Std 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 5.28 497920.375 311609.969 51406.594 1 Hi-Dil-Spk1 95% 37 2013OCT20_Dil_Hi_2 Recovery 100 5.28 534852.438 337054 58805.309 1 Hi-Dil-Spk2 102% 38 2013OCT20_Dil_Hi_3 Recovery 100 5.28 449787.375 280865.375 51501.289 1 Hi-Dil-Spk3 86% 39 2013OCT20_Dil_Hi_4 Recovery 100 5.28 454494.281 280763.094 51313.023 1 Hi-Dil-Spk4 87% 40 2013OCT20_Dil_Hi_5 Recovery 100 5.28 353613.313 225159.797 38916.613 1 Hi-Dil-Spk5 67% 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 5.28 521528.844 328827.031 56655.809 1 Hi-Dil-Std 43 2013OCT20_SolvA_12 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 5.28 1029914.188 641406.563 112627.648 1 Hi-Spk1 93% 45 2013OCT20_Hi_2 Recovery 200 5.28 1136442.625 704021.125 116782.398 1 Hi-Spk2 103% 46 2013OCT20_Hi_3 Recovery 200 5.28 930664.563 584085 103677.039 1 Hi-Spk3 84% 47 2013OCT20_Hi_4 Recovery 200 5.28 934121.563 583059.813 101837.461 1 Hi-Spk4 85% 48 2013OCT20_Hi_5 Recovery 200 5.28 730747.125 448844.656 78383.773 1 Hi-Spk5 66% 49 2013OCT20_SolvA_13 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 5.28 187.354 231.979 0 52 2013OCT20_0-05_Std_2 Standard 0.05 5.28 469.503 206.244 0 53 2013OCT20_0-1_Std_2 Standard 0.1 5.3 417.786 426.482 0 54 2013OCT20_0-5_Std_2 Standard 0.5 5.29 2697.642 1489.306 523.268 1 55 2013OCT20_1_Std_2 Standard 1 5.29 6218.25 4586.158 552.008 1 56 2013OCT20_5_Std_2 Standard 5 5.29 29995.012 19867.434 3213.635 1 57 2013OCT20_10_Std_2 Standard 10 5.29 61306.277 38517.516 6345.833 1 58 2013OCT20_25_Std_2 Standard 25 5.29 151675.703 98509.508 16493.461 1 59 2013OCT20_50_Std_2 Standard 50 5.29 282656.656 183765.688 29242.131 1 60 2013OCT20_100_Std_2 Standard 100 5.28 559473.625 353776.125 61748.313 1 61 2013OCT20_200_Std_2 Standard 200 5.28 1082412.125 677419.625 121183.977 1 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 5.24 169.703 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 25: Sucralose Compound 25: Sucralose yes=1,no=0 Name Type Std. Conc RT Area 1? Area 2? Area Ident'd? Conc (ng/g) %diff 1 2013OCT20_SolvA_2 #DIV/0! 2 2013OCT20_RO Blank #DIV/0! 3 2013OCT20_Blk_1 Blank #DIV/0! 4 2013OCT20_Blk_2 Blank #DIV/0! 5 2013OCT20_0-01_Std Standard 0.01 0 112 6 2013OCT20_0-05_Std Standard 0.05 0 7 2013OCT20_0-1_Std Standard 0.1 0 8 2013OCT20_0-5_Std Standard 0.5 0 9 2013OCT20_1_Std Standard 1 0 10 2013OCT20_5_Std Standard 5 2.23 175.396 309.628 0 5 10% 11 2013OCT20_10_Std Standard 10 2.24 345.022 328.995 0 10 8% 12 2013OCT20_25_Std Standard 25 2.24 822.621 218.126 0 25 3% 13 2013OCT20_50_Std Standard 50 2.24 1883.25 187.853 0 50 18% 14 2013OCT20_100_Std Standard 100 2.24 3341.492 131.385 0 100 5% 15 2013OCT20_200_Stds Standard 200 2.24 6221.944 318.607 258.089 0 200 -2% 16 2013OCT20_SolvA_3 #DIV/0! 17 2013OCT20_Surrogate #DIV/0! 18 2013OCT20_SolvA_4 #DIV/0! 19 2013OCT20_SolvA_5 #DIV/0! %Recovery 20 2013OCT20_Lo_1 Recovery 50 2.24 1489.378 155.211 0 Low-Spk1 89% 21 2013OCT20_Lo_2 Recovery 50 2.24 1440.8 383.861 79.797 0 Low-Spk2 86% 22 2013OCT20_Lo_3 Recovery 50 2.24 1729.151 373.258 99.506 0 Low-Spk3 104% 23 2013OCT20_Lo_4 Recovery 50 2.24 1573.251 271.651 62.829 0 Low-Spk4 94% 24 2013OCT20_Lo_5 Recovery 50 2.24 1231.655 125.049 0 Low-Spk5 72% 25 2013OCT20_SolvA_6 #DIV/0! 26 2013OCT20_SolvA_7 #DIV/0! 27 2013OCT20_Mid_1 Recovery 100 2.24 2768.517 423.166 149.01 0 Mid-Spk1 86% 28 2013OCT20_Mid_2 Recovery 100 2.24 3477.918 386.762 132.674 0 Mid-Spk2 108% 29 2013OCT20_Mid_3 Recovery 100 2.24 2977.513 429.323 98.996 0 Mid-Spk3 92% 30 2013OCT20_Mid_4 Recovery 100 2.24 3015.635 300.497 100.417 0 Mid-Spk4 93% 31 2013OCT20_Mid_5 Recovery 100 2.24 2867.791 296.601 84.179 0 Mid-Spk5 89% 32 2013OCT20_SolvA_8 #DIV/0! 33 2013OCT20_SolvA_9 #DIV/0! 34 2013OCT20_Std Dil 200_1 2.24 2207.746 134.101 160.714 0 Hi-Dil-Std 35 2013OCT20_SolvA_10 #DIV/0! 36 2013OCT20_Dil_Hi_1 Recovery 100 2.24 2930.686 115.45 150.14 0 Hi-Dil-Spk1 37 2013OCT20_Dil_Hi_2 Recovery 100 2.24 3156.855 132.374 76.759 0 Hi-Dil-Spk2 38 2013OCT20_Dil_Hi_3 Recovery 100 2.24 3206.854 63.211 211.593 0 Hi-Dil-Spk3 39 2013OCT20_Dil_Hi_4 Recovery 100 2.23 2889.231 211.931 116.505 0 Hi-Dil-Spk4 40 2013OCT20_Dil_Hi_5 Recovery 100 2.24 3296.791 165.899 187.997 0 Hi-Dil-Spk5 41 2013OCT20_SolvA_11 #DIV/0! 42 2013OCT20_Std Dil 200_2 2.24 2697.857 0 Hi-Dil-Std 43 2013OCT20_SolvA_12 #DIV/0! 44 2013OCT20_Hi_1 Recovery 200 2.24 6242.916 420.534 483.091 0 Hi-Spk1 99% 45 2013OCT20_Hi_2 Recovery 200 2.24 5864.692 430.743 0 Hi-Spk2 93% 46 2013OCT20_Hi_3 Recovery 200 2.24 5798.147 455.84 303.906 0 Hi-Spk3 92% 47 2013OCT20_Hi_4 Recovery 200 2.24 7531.979 344.686 0 Hi-Spk4 119% 48 2013OCT20_Hi_5 Recovery 200 2.24 7765.408 232.282 961.858 0 Hi-Spk5 123% 49 2013OCT20_SolvA_13 #DIV/0! 50 2013OCT20_SolvA_14 #DIV/0! 51 2013OCT20_0-01_Std_2 Standard 0.01 #DIV/0! 113 52 2013OCT20_0-05_Std_2 Standard 0.05 #DIV/0! 53 2013OCT20_0-1_Std_2 Standard 0.1 #DIV/0! 54 2013OCT20_0-5_Std_2 Standard 0.5 #DIV/0! 55 2013OCT20_1_Std_2 Standard 1 #DIV/0! 56 2013OCT20_5_Std_2 Standard 5 2.24 74.011 110.547 0 57 2013OCT20_10_Std_2 Standard 10 2.24 306.552 280.679 0 58 2013OCT20_25_Std_2 Standard 25 2.24 896.121 340.598 1 59 2013OCT20_50_Std_2 Standard 50 2.23 1765.331 210.901 0 60 2013OCT20_100_Std_2 Standard 100 2.24 2794.202 156.215 273.953 0 61 2013OCT20_200_Std_2 Standard 200 2.24 6689.718 365.696 166.053 0 62 2013OCT20_SolvA_15 #DIV/0! 63 2013OCT20_Surrogate_2 #DIV/0! 64 2013OCT20_SolvA_16 #DIV/0! Compound 26: Sucralose-d6 Name Type Std. Conc RT Area 1? Area 2? Area 1 2013OCT20_SolvA_2 2 2013OCT20_RO Blank 2.22 3590.298 3 2013OCT20_Blk_1 Blank 2.23 2878.638 4 2013OCT20_Blk_2 Blank 2.23 2422.799 5 2013OCT20_0-01_Std Standard 0.01 2.22 2903.235 6 2013OCT20_0-05_Std Standard 0.05 2.22 2486.114 7 2013OCT20_0-1_Std Standard 0.1 2.22 3016.804 8 2013OCT20_0-5_Std Standard 0.5 2.22 2913.839 9 2013OCT20_1_Std Standard 1 2.23 2861.819 10 2013OCT20_5_Std Standard 5 2.23 2948.735 11 2013OCT20_10_Std Standard 10 2.23 3234.051 12 2013OCT20_25_Std Standard 25 2.22 2680.855 13 2013OCT20_50_Std Standard 50 2.22 3272.881 14 2013OCT20_100_Std Standard 100 2.22 2704.754 15 2013OCT20_200_Stds Standard 200 2.23 2621.411 16 2013OCT20_SolvA_3 17 2013OCT20_Surrogate 18 2013OCT20_SolvA_4 19 2013OCT20_SolvA_5 20 2013OCT20_Lo_1 Recovery 50 2.23 3110.242 21 2013OCT20_Lo_2 Recovery 50 2.23 2188.595 22 2013OCT20_Lo_3 Recovery 50 2.22 3045.15 23 2013OCT20_Lo_4 Recovery 50 2.22 2901.623 24 2013OCT20_Lo_5 Recovery 50 2.22 2061.039 25 2013OCT20_SolvA_6 26 2013OCT20_SolvA_7 27 2013OCT20_Mid_1 Recovery 100 2.22 2073.652 28 2013OCT20_Mid_2 Recovery 100 2.22 2628.699 29 2013OCT20_Mid_3 Recovery 100 2.23 2914.037 30 2013OCT20_Mid_4 Recovery 100 2.23 2381.389 31 2013OCT20_Mid_5 Recovery 100 2.23 2893.751 114 32 2013OCT20_SolvA_8 33 2013OCT20_SolvA_9 34 2013OCT20_Std Dil 200_1 2.23 1119.215 35 2013OCT20_SolvA_10 36 2013OCT20_Dil_Hi_1 Recovery 100 2.23 1135.795 37 2013OCT20_Dil_Hi_2 Recovery 100 2.22 1098.588 38 2013OCT20_Dil_Hi_3 Recovery 100 2.22 1228.605 39 2013OCT20_Dil_Hi_4 Recovery 100 2.22 1309.365 40 2013OCT20_Dil_Hi_5 Recovery 100 2.23 1036.93 41 2013OCT20_SolvA_11 42 2013OCT20_Std Dil 200_2 2.23 873.075 43 2013OCT20_SolvA_12 44 2013OCT20_Hi_1 Recovery 200 2.22 1953.756 45 2013OCT20_Hi_2 Recovery 200 2.23 2763.445 46 2013OCT20_Hi_3 Recovery 200 2.23 3126.713 47 2013OCT20_Hi_4 Recovery 200 2.22 3217.482 48 2013OCT20_Hi_5 Recovery 200 2.23 3250.438 49 2013OCT20_SolvA_13 50 2013OCT20_SolvA_14 51 2013OCT20_0-01_Std_2 Standard 0.01 2.22 2791.705 52 2013OCT20_0-05_Std_2 Standard 0.05 2.22 2558.223 53 2013OCT20_0-1_Std_2 Standard 0.1 2.22 3252.653 54 2013OCT20_0-5_Std_2 Standard 0.5 2.22 2966.792 55 2013OCT20_1_Std_2 Standard 1 2.22 3104.886 56 2013OCT20_5_Std_2 Standard 5 2.22 2751.804 57 2013OCT20_10_Std_2 Standard 10 2.22 3045.837 58 2013OCT20_25_Std_2 Standard 25 2.22 3378.786 59 2013OCT20_50_Std_2 Standard 50 2.23 3124.938 60 2013OCT20_100_Std_2 Standard 100 2.22 2892.33 61 2013OCT20_200_Std_2 Standard 200 2.23 2647.48 62 2013OCT20_SolvA_15 63 2013OCT20_Surrogate_2 64 2013OCT20_SolvA_16 115 APPENDIX C ? Nutrient Analysis report C.1 Data provided by ENVIRO-CHEM LABORATORIES, INC. for Choptank River samples Lab# SampleID TestName Flag Reported Result Units Calc_ RDL ECL029601-001 Horn Pt. Lab Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029601-001 Horn Pt. Lab Nitrate & Nitrite < 0.050 mg/L 0.050 ECL029601-001 Horn Pt. Lab Phosphorus, Ortho, P 0.03 mg/L P 0.01 ECL029601-001 Horn Pt. Lab Phosphorus, P 0.05 mg/L P 0.05 ECL029601-002 50 Bridge1 Kjeldahl Nitrogen 0.7 mg/L 0.4 ECL029601-002 50 Bridge1 Nitrate & Nitrite 0.064 mg/L 0.050 ECL029601-002 50 Bridge1 Phosphorus, Ortho, P 0.03 mg/L P 0.01 ECL029601-002 50 Bridge1 Phosphorus, P 0.07 mg/L P 0.05 ECL029601-003 50 Bridge 2 Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029601-003 50 Bridge 2 Nitrate & Nitrite 0.078 mg/L 0.050 ECL029601-003 50 Bridge 2 Phosphorus, Ortho, P 0.04 mg/L P 0.01 ECL029601-003 50 Bridge 2 Phosphorus, P 0.06 mg/L P 0.05 ECL029601-004 50 Bridge Further Pt Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029601-004 50 Bridge Further Pt Nitrate & Nitrite 0.230 mg/L 0.050 ECL029601-004 50 Bridge Further Pt Phosphorus, Ortho, P 0.04 mg/L P 0.01 ECL029601-004 50 Bridge Further Pt Phosphorus, P 0.07 mg/L P 0.05 ECL029601-005 NOAA-Oxford Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029601-005 NOAA-Oxford Nitrate & Nitrite < 0.050 mg/L 0.050 ECL029601-005 NOAA-Oxford Phosphorus, Ortho, P 0.03 mg/L P 0.01 ECL029601-005 NOAA-Oxford Phosphorus, P < 0.05 mg/L P 0.05 ECL029601-006 Frazier Pt Ln Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029601-006 Frazier Pt Ln Nitrate & Nitrite 1.06 mg/L 0.050 ECL029601-006 Frazier Pt Ln Phosphorus, Ortho, P 0.17 mg/L P 0.01 ECL029601-006 Frazier Pt Ln Phosphorus, P 0.18 mg/L P 0.05 ECL029601-007 Swing bridge Kjeldahl Nitrogen 1.0 mg/L 0.4 ECL029601-007 Swing bridge Nitrate & Nitrite 1.14 mg/L 0.050 ECL029601-007 Swing bridge Phosphorus, Ortho, P 0.17 mg/L P 0.01 ECL029601-007 Swing bridge Phosphorus, P 0.19 mg/L P 0.05 ECL029601-008 Kingston Landing 1 Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029601-008 Kingston Landing 1 Nitrate & Nitrite 1.20 mg/L 0.050 ECL029601-008 Kingston Landing 1 Phosphorus, Ortho, P 0.17 mg/L P 0.01 ECL029601-008 Kingston Landing 1 Phosphorus, P 0.22 mg/L P 0.05 ECL029601-009 Kingston Landing 2 Kjeldahl Nitrogen 0.9 mg/L 0.4 ECL029601-009 Kingston Landing 2 Nitrate & Nitrite 1.25 mg/L 0.050 116 Lab# SampleID TestName Flag Reported Result Units Calc_ RDL ECL029601-009 Kingston Landing 2 Phosphorus, Ortho, P 0.17 mg/L P 0.01 ECL029601-009 Kingston Landing 2 Phosphorus, P 0.22 mg/L P 0.05 ECL029601-010 Cordova Kjeldahl Nitrogen 0.7 mg/L 0.4 ECL029601-010 Cordova Nitrate & Nitrite 7.95 mg/L 0.250 ECL029601-010 Cordova Phosphorus, Ortho, P 0.10 mg/L P 0.01 ECL029601-010 Cordova Phosphorus, P 0.09 mg/L P 0.05 ECL029601-011 German Branch Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029601-011 German Branch Nitrate & Nitrite 5.49 mg/L 0.250 ECL029601-011 German Branch Phosphorus, Ortho, P 0.20 mg/L P 0.01 ECL029601-011 German Branch Phosphorus, P 0.17 mg/L P 0.05 ECL029601-012 Tuckahoe gage 1 Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029601-012 Tuckahoe gage 1 Nitrate & Nitrite 5.46 mg/L 0.250 ECL029601-012 Tuckahoe gage 1 Phosphorus, Ortho, P 0.11 mg/L P 0.01 ECL029601-012 Tuckahoe gage 1 Phosphorus, P 0.12 mg/L P 0.05 ECL029601-013 Tuckahoe gage 2 Kjeldahl Nitrogen 1.0 mg/L 0.4 ECL029601-013 Tuckahoe gage 2 Nitrate & Nitrite 5.13 mg/L 0.250 ECL029601-013 Tuckahoe gage 2 Phosphorus, Ortho, P 0.10 mg/L P 0.01 ECL029601-013 Tuckahoe gage 2 Phosphorus, P 0.12 mg/L P 0.05 ECL029601-014 Greensboro 1 Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029601-014 Greensboro 1 Nitrate & Nitrite 1.43 mg/L 0.050 ECL029601-014 Greensboro 1 Phosphorus, Ortho, P 0.17 mg/L P 0.01 ECL029601-014 Greensboro 1 Phosphorus, P 0.14 mg/L P 0.05 ECL029601-015 Greensboro gage 2 Kjeldahl Nitrogen 8.7 mg/L 0.4 ECL029601-015 Greensboro gage 2 Nitrate & Nitrite 1.50 mg/L 0.050 ECL029601-015 Greensboro gage 2 Phosphorus, Ortho, P 0.16 mg/L P 0.01 ECL029601-015 Greensboro gage 2 Phosphorus, P 0.14 mg/L P 0.05 ECL029601-016 Beaver Dam Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029601-016 Beaver Dam Nitrate & Nitrite 5.17 mg/L 0.250 ECL029601-016 Beaver Dam Phosphorus, Ortho, P 0.09 mg/L P 0.01 ECL029601-016 Beaver Dam Phosphorus, P 0.09 mg/L P 0.05 ECL029601-017 Long Marsh Kjeldahl Nitrogen 1.3 mg/L 0.4 ECL029601-017 Long Marsh Nitrate & Nitrite 2.28 mg/L 0.100 ECL029601-017 Long Marsh Phosphorus, Ortho, P 0.15 mg/L P 0.01 ECL029601-017 Long Marsh Phosphorus, P 0.13 mg/L P 0.05 ECL029601-018 Preston Landing Kjeldahl Nitrogen 0.7 mg/L 0.4 ECL029601-018 Preston Landing Nitrate & Nitrite 0.971 mg/L 0.050 ECL029601-018 Preston Landing Phosphorus, Ortho, P 0.12 mg/L P 0.01 ECL029601-018 Preston Landing Phosphorus, P 0.15 mg/L P 0.05 117 C.2 Data provided by ENVIRO-CHEM LABORATORIES, INC. for Anacostia River samples Lab# SampleID TestName Flag Reported Result Units Calc_ RDL ECL029713-001 North Dr Bridge 1 Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029713-001 North Dr Bridge 1 Nitrate & Nitrite 0.739 mg/L 0.050 ECL029713-001 North Dr Bridge 1 Phosphorus, Ortho, P < 0.01 mg/L P 0.01 ECL029713-001 North Dr Bridge 1 Phosphorus, P < 0.05 mg/L P 0.05 ECL029713-002 North Dr Bridge 2 Kjeldahl Nitrogen 1.9 mg/L 0.4 ECL029713-002 North Dr Bridge 2 Nitrate & Nitrite 0.733 mg/L 0.050 ECL029713-002 North Dr Bridge 2 Phosphorus, Ortho, P < 0.01 mg/L P 0.01 ECL029713-002 North Dr Bridge 2 Phosphorus, P < 0.05 mg/L P 0.05 ECL029713-003 Research Rd Bridge Kjeldahl Nitrogen 2.3 mg/L 0.4 ECL029713-003 Research Rd Bridge Nitrate & Nitrite 0.279 mg/L 0.050 ECL029713-003 Research Rd Bridge Phosphorus, Ortho, P 0.04 mg/L P 0.01 ECL029713-003 Research Rd Bridge Phosphorus, P 0.07 mg/L P 0.05 ECL029713-004 Powder Mill Rd Kjeldahl Nitrogen 1.1 mg/L 0.4 ECL029713-004 Powder Mill Rd Nitrate & Nitrite 1.06 mg/L 0.050 ECL029713-004 Powder Mill Rd Phosphorus, Ortho, P < 0.01 mg/L P 0.01 ECL029713-004 Powder Mill Rd Phosphorus, P < 0.05 mg/L P 0.05 ECL029713-005 UMD Paint Branch Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029713-005 UMD Paint Branch Nitrate & Nitrite 0.594 mg/L 0.050 ECL029713-005 UMD Paint Branch Phosphorus, Ortho, P < 0.01 mg/L P 0.01 ECL029713-005 UMD Paint Branch Phosphorus, P < 0.05 mg/L P 0.05 ECL029713-006 Berwyn Rd Kjeldahl Nitrogen 0.4 mg/L 0.4 ECL029713-006 Berwyn Rd Nitrate & Nitrite 0.918 mg/L 0.050 ECL029713-006 Berwyn Rd Phosphorus, Ortho, P 0.12 mg/L P 0.01 ECL029713-006 Berwyn Rd Phosphorus, P 0.11 mg/L P 0.05 ECL029713-007 Arboretum 1 Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029713-007 Arboretum 1 Nitrate & Nitrite 0.325 mg/L 0.050 ECL029713-007 Arboretum 1 Phosphorus, Ortho, P 0.02 mg/L P 0.01 ECL029713-007 Arboretum 1 Phosphorus, P 0.06 mg/L P 0.05 ECL029713-008 Arboretum 2 Kjeldahl Nitrogen 0.8 mg/L 0.4 ECL029713-008 Arboretum 2 Nitrate & Nitrite 0.316 mg/L 0.050 ECL029713-008 Arboretum 2 Phosphorus, Ortho, P 0.02 mg/L P 0.01 ECL029713-008 Arboretum 2 Phosphorus, P 0.07 mg/L P 0.05 ECL029713-009 Skateboard Park Kjeldahl Nitrogen 0.5 mg/L 0.4 ECL029713-009 Skateboard Park Nitrate & Nitrite 0.545 mg/L 0.050 ECL029713-009 Skateboard Park Phosphorus, Ortho, P < 0.01 mg/L P 0.01 ECL029713-009 Skateboard Park Phosphorus, P < 0.05 mg/L P 0.05 ECL029713-010 Sligo Creek Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029713-010 Sligo Creek Nitrate & Nitrite 0.714 mg/L 0.050 ECL029713-010 Sligo Creek Phosphorus, Ortho, P 0.04 mg/L P 0.01 ECL029713-010 Sligo Creek Phosphorus, P 0.06 mg/L P 0.05 118 Lab# SampleID TestName Flag Reported Result Units Calc_ RDL ECL029713-011 Riverdale Rd Gage Kjeldahl Nitrogen 0.6 mg/L 0.4 ECL029713-011 Riverdale Rd Gage Nitrate & Nitrite 0.507 mg/L 0.050 ECL029713-011 Riverdale Rd Gage Phosphorus, Ortho, P 0.03 mg/L P 0.01 ECL029713-011 Riverdale Rd Gage Phosphorus, P 0.05 mg/L P 0.05 ECL029713-012 Anacostia River Park Kjeldahl Nitrogen 1.0 mg/L 0.4 ECL029713-012 Anacostia River Park Nitrate & Nitrite 0.316 mg/L 0.050 ECL029713-012 Anacostia River Park Phosphorus, Ortho, P 0.02 mg/L P 0.01 ECL029713-012 Anacostia River Park Phosphorus, P < 0.05 mg/L P 0.05 ECL029713-013 Greenbelt National Park Kjeldahl Nitrogen < 0.4 mg/L 0.4 ECL029713-013 Greenbelt National Park Nitrate & Nitrite 0.332 mg/L 0.050 ECL029713-013 Greenbelt National Park Phosphorus, Ortho, P < 0.01 mg/L P 0.01 ECL029713-013 Greenbelt National Park Phosphorus, P < 0.05 mg/L P 0.05 119 APPENDIX D ? Organic compounds analysis D.1 Raw data for Choptank River analysis - IS correction is not shown in this data sheet Quantify Compound Summary Report Printed Sat Oct 26 17:04:03 2013 Compound 1: CAAT yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 4 2013OCT23_C_0-01_Std Standard 0.01 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 0 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 2.81 1204.757 609.685 544.08 0 0.6 13% 8 2013OCT23_C_1_Std Standard 1 2.81 2104.363 2382.87 1216.161 1 1.0 -2% 9 2013OCT23_C_5_Std Standard 5 2.8 14408.657 12242.26 7991.858 1 6.7 35% 10 2013OCT23_C_10_Std Standard 10 2.8 28251.971 21822.729 15999.914 1 13.2 32% 11 2013OCT23_C_25_Std Standard 25 2.8 65849.43 56548.211 37094.398 1 30.8 23% 12 2013OCT23_C_50_Std Standard 50 2.81 115848.75 96666.82 66877.094 1 54.2 8% 13 2013OCT23_C_100_Std Standard 100 2.8 223560.297 190121.734 126339.594 1 104.5 4% 14 2013OCT23_C_200_Stds Standard 200 2.8 419590.938 354410 244200.656 1 196.1 -2% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.06 19% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.1 9% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.5 -2% 19 2013OCT23_C_MM_0 2.8 26653.865 21652.756 14399.435 1 1.1 12% 20 2013OCT23_C_MM_1 2.81 28182.771 24135.266 16152.917 1 6.5 31% 21 2013OCT23_C_MM_5 2.81 40491.066 33503.32 23060.367 1 12.4 24% 22 2013OCT23_C_MM_10 2.81 57214.406 51441.043 35320.375 1 30.5 22% 23 2013OCT23_C_MM_25 2.81 90221.82 77626.5 49816.344 1 54.5 9% 24 2013OCT23_C_MM_50 2.8 139154 117332.156 79913.359 1 106.7 7% 25 2013OCT23_C_MM_100 2.81 250269.969 207323.656 143077.406 1 194.3 -3% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 2.81 17480.754 14916.272 9982.586 1 81.71 77.34 29 2013OCT23_C_NOAA_2 2.8 18244.525 15283.295 10996.505 1 85.28 80.71 30 2013OCT23_C_NOAA_3 2.81 18766.676 15372.759 10474.016 1 87.72 83.02 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 2.81 23407.467 19852.598 13357.563 1 109.41 103.56 120 34 2013OCT23_C_HornPt_2 2.8 23851.072 20733.523 14419.374 1 111.49 105.52 35 2013OCT23_C_HornPt_3 2.81 24608.176 19402.209 13411.159 1 115.02 108.87 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.81 31460.58 28216.275 17599.971 1 147.05 139.18 39 2013OCT23_C_50Bridge1_2 2.8 34022.766 27706.016 19231.205 1 159.03 150.52 40 2013OCT23_C_50Bridge1_3 2.8 33216.391 27662.531 18171.641 1 155.26 146.95 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.81 28079.766 23042.787 15961.15 1 131.25 124.23 44 2013OCT23_C_50Bridge2_2 2.8 28531.063 25118.17 16912.352 1 133.36 126.22 45 2013OCT23_C_50Bridge2_3 2.8 29550.621 23852.865 16460.223 1 138.13 130.73 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 2.8 64261.148 55348.395 34891.699 1 300.37 284.30 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 2.81 31911.697 27982.961 19350.703 1 149.16 141.18 52 2013OCT23_C_50BridgeFurtherPt_2 2.81 33798.898 28053.521 19058.516 1 157.98 149.53 53 2013OCT23_C_50BridgeFurtherPt_3 2.81 32860.266 28048.488 18757.143 1 153.60 145.38 54 2013OCT23_C_SolvA_17 2.83 38.788 69.716 #DIV/0! 55 2013OCT23_C_SolvA_18 2.82 24 101.536 1.8 0 56 2013OCT23_C_PrestonLn_1 2.81 28698.781 24596.613 15469.331 1 134.14 126.97 57 2013OCT23_C_PrestonLn_2 2.81 27855.941 23452.443 15080.468 1 130.20 123.24 58 2013OCT23_C_PrestonLn_3 2.81 28577.959 23124.34 15805.576 1 133.58 126.43 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 2.8 23011.879 20923.4 14240.95 1 107.56 101.81 62 2013OCT23_C_FrazierPt_2 2.81 22906.502 20913.223 13672.276 1 107.07 101.34 63 2013OCT23_C_FrazierPt_3 2.81 21015.18 18356.229 13121.146 1 98.23 92.97 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.81 19790.973 17304.98 11925.104 1 92.51 87.56 67 2013OCT23_C_SwingBridge_2 2.81 19911.727 15178.619 11168.537 1 93.07 88.09 68 2013OCT23_C_SwingBridge_3 2.81 18960.984 16435.627 11290.146 1 88.63 83.88 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 27.411 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 2.81 18103.125 14594.866 10125.265 1 84.62 80.09 72 2013OCT23_C_KingstonLn1_2 2.81 17212.232 15065.25 9435.597 1 80.45 76.15 73 2013OCT23_C_KingstonLn1_3 2.81 18425.389 13550.225 10186.422 1 86.12 81.51 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 2.8 66139.734 56932.766 34809.605 1 309.15 292.61 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 121 79 2013OCT23_C_KingstonLn2_1 2.81 18979.955 16117.502 11199.882 1 88.72 83.97 80 2013OCT23_C_KingstonLn2_2 2.81 19967.318 16579.646 10825.82 1 93.33 88.34 81 2013OCT23_C_KingstonLn2_3 2.81 19301.928 16379.572 10991.693 1 90.22 85.39 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.81 57527.961 48895.129 32888.758 1 268.90 254.51 85 2013OCT23_C_Cordova_2 2.81 58034.203 49112.871 32778.012 1 271.26 256.75 86 2013OCT23_C_Cordova_3 2.81 52210.676 50087.879 33098.879 1 244.04 230.98 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 2.81 35540.289 27868.736 18057.646 1 166.12 157.23 90 2013OCT23_C_Tuckahoe1_2 2.81 34533.219 28398.57 19818.553 1 161.42 152.78 91 2013OCT23_C_Tuckahoe1_3 2.81 34975.98 29393.93 20058.242 1 163.49 154.74 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.81 33147.445 27113.154 18209.252 1 154.94 146.65 95 2013OCT23_C_Tuckahoe2_2 2.8 32404.422 27297.34 18091.537 1 151.47 143.36 96 2013OCT23_C_Tuckahoe2_3 2.81 32822.18 28701.525 19435.32 1 153.42 145.21 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 2.81 32658.262 26400.953 18191.129 1 152.65 144.48 100 2013OCT23_C_GermanBranch_2 2.81 31512.279 26771.674 19120.4 1 147.30 139.41 101 2013OCT23_C_GermanBranch_3 2.8 34401.375 29856.799 18959.135 1 160.80 152.19 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 2.81 63452.043 56320.156 36430.453 1 296.59 280.72 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.81 8580.815 7602.498 4872.409 1 40.11 37.96 108 2013OCT23_C_Greensboro1_2 2.81 9294.429 7998.598 5436.337 1 43.44 41.12 109 2013OCT23_C_Greensboro1_3 2.81 8993.007 8136.841 5125.828 1 42.04 39.79 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 2.81 6909.001 5515.761 4481.456 1 32.29 30.57 113 2013OCT23_C_Greensboro2_2 2.8 8246.975 6969.08 4356.497 1 38.55 36.49 114 2013OCT23_C_Greensboro2_3 2.81 8478.981 6226.953 4498.729 1 39.63 37.51 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 2.81 24204.359 19536.365 13994.83 1 113.14 107.08 118 2013OCT23_C_BeaverDam_2 2.81 23903.883 20190.535 13142.173 1 111.73 105.75 119 2013OCT23_C_BeaverDam_3 2.81 23408.627 20187.896 12046.573 1 109.42 103.56 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 2.83 49.647 83.643 38.663 0 122 2013OCT23_C_LongMarsh_1 2.81 8618.714 7349.813 5062.386 1 40.29 38.13 123 2013OCT23_C_LongMarsh_2 2.81 8343.265 7027.552 5018.913 1 39.00 36.91 122 124 2013OCT23_C_LongMarsh_3 2.81 8661.595 7795.072 4790.066 1 40.49 38.32 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 2.76 21.954 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 2.81 127.064 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 2.81 233.906 236.113 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 2.82 1043.745 638.059 448.441 1 131 2013OCT23_C_1_Std_2 Standard 1 2.8 2402.286 1745.19 1232.647 1 132 2013OCT23_C_5_Std_2 Standard 5 2.81 13995.333 11971.979 8125.361 1 133 2013OCT23_C_10_Std_2 Standard 10 2.81 26466.184 22076.299 16176.564 1 134 2013OCT23_C_25_Std_2 Standard 25 2.81 65218.637 55690.145 36414.648 1 135 2013OCT23_C_50_Std_2 Standard 50 2.81 116660.539 99863.055 70290.398 1 136 2013OCT23_C_100_Std_2 Standard 100 2.81 228293.063 196546.766 132532.609 1 137 2013OCT23_C_200_Stds_2 Standard 200 2.81 415751.531 370016.594 252026.094 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 2: CEAT yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 4 2013OCT23_C_0-01_Std Standard 0.01 106.305 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 2.29 640.885 488.568 0 0.08 57% 6 2013OCT23_C_0-1_Std Standard 0.1 2.27 1287.582 1080.078 0 0.16 58% 7 2013OCT23_C_0-5_Std Standard 0.5 2.27 4641.432 4390.525 6883.583 1 0.6 14% 8 2013OCT23_C_1_Std Standard 1 2.27 8385.866 9145.592 10881.422 1 1.0 3% 9 2013OCT23_C_5_Std Standard 5 2.27 49755.855 52853.262 61385.602 1 6.1 22% 10 2013OCT23_C_10_Std Standard 10 2.27 95272.82 99986.516 124765.68 1 11.7 17% 11 2013OCT23_C_25_Std Standard 25 2.27 235253.453 247002.766 295123.406 1 28.8 15% 12 2013OCT23_C_50_Std Standard 50 2.27 419283.406 440115.563 532024.938 1 51.4 3% 13 2013OCT23_C_100_Std Standard 100 2.27 819318.688 859523.813 1039630.688 1 100.4 0% 14 2013OCT23_C_200_Stds Standard 200 2.27 1636921 1743563.75 2072733.5 1 200.6 0% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.00 -100% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.1 12% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.6 17% 19 2013OCT23_C_MM_0 2.27 60590.023 63194.316 71077.828 1 1.0 3% 20 2013OCT23_C_MM_1 2.27 66200.992 69998.398 86351.336 1 5.9 19% 21 2013OCT23_C_MM_5 2.27 104673.992 106462.883 132933.141 1 11.5 15% 22 2013OCT23_C_MM_10 2.27 175349.813 184284.5 217299.172 1 28.4 14% 23 2013OCT23_C_MM_25 2.27 280825.813 299348.625 350425.406 1 51.8 4% 123 24 2013OCT23_C_MM_50 2.27 471502.25 504003.875 608607.063 1 101.8 2% 25 2013OCT23_C_MM_100 2.27 890956.813 949036.125 1140849.75 1 196.3 -2% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 2.27 47437.949 52873.188 59292.684 1 58.15 56.91 29 2013OCT23_C_NOAA_2 2.27 50307.18 53431.063 66113.93 1 61.66 60.35 30 2013OCT23_C_NOAA_3 2.27 51657.105 53107.027 64979.664 1 63.32 61.97 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 2.27 67817.297 73861.656 87581.453 1 83.13 81.35 34 2013OCT23_C_HornPt_2 2.27 71535.688 75571.695 88444.539 1 87.69 85.81 35 2013OCT23_C_HornPt_3 2.27 73406.688 76408.609 88819.07 1 89.98 88.06 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.27 95673.188 95055.555 120056.281 1 117.27 114.77 39 2013OCT23_C_50Bridge1_2 2.27 97563.672 103120.93 124889.039 1 119.59 117.04 40 2013OCT23_C_50Bridge1_3 2.27 100329.555 104277.977 126427.141 1 122.98 120.36 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.27 80783.219 84715.75 102199.594 1 99.02 96.91 44 2013OCT23_C_50Bridge2_2 2.27 85028.383 88429.703 104737.008 1 104.22 102.00 45 2013OCT23_C_50Bridge2_3 2.27 85674.156 91945.172 111145.781 1 105.02 102.77 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 2.27 227884.516 232002.297 284652.563 1 279.33 273.37 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 2.27 92279.781 101464.625 112327.695 1 113.11 110.70 52 2013OCT23_C_50BridgeFurtherPt_2 2.27 91720.453 100366.391 114070.836 1 112.43 110.03 53 2013OCT23_C_50BridgeFurtherPt_3 2.27 88570.891 90645.813 113396.922 1 108.57 106.25 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 2.27 67797.43 74110.242 84972.633 1 83.10 81.33 57 2013OCT23_C_PrestonLn_2 2.27 63985.406 72221.109 86081.781 1 78.43 76.76 58 2013OCT23_C_PrestonLn_3 2.27 66223.422 70412.016 80234.656 1 81.17 79.44 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 2.27 56947.52 59231.176 68259.656 1 69.80 68.31 62 2013OCT23_C_FrazierPt_2 2.27 57925.383 58376.172 69466.953 1 71.00 69.49 63 2013OCT23_C_FrazierPt_3 2.27 52916.973 57870.344 69123.234 1 64.86 63.48 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.27 49148.074 50191.098 61213.043 1 60.24 58.96 67 2013OCT23_C_SwingBridge_2 2.27 47940.949 52773.184 63115.809 1 58.76 57.51 68 2013OCT23_C_SwingBridge_3 2.27 49556.238 49191.918 56906.621 1 60.74 59.45 124 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 2.27 41974.316 43172.961 51335.094 1 51.45 50.35 72 2013OCT23_C_KingstonLn1_2 2.27 40004.012 44299.645 51619.289 1 49.04 47.99 73 2013OCT23_C_KingstonLn1_3 2.27 40975.914 42805.836 49335.91 1 50.23 49.15 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 2.27 231439.656 248165.875 290464.688 1 283.69 277.64 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 2.27 43489.66 47011.293 55311.617 1 53.31 52.17 80 2013OCT23_C_KingstonLn2_2 2.27 44170.902 47610.527 57238.672 1 54.14 52.99 81 2013OCT23_C_KingstonLn2_3 2.27 43216.836 45934.402 54482.215 1 52.97 51.84 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.27 141549.484 142444.156 176624.375 1 173.51 169.80 85 2013OCT23_C_Cordova_2 2.27 142099.484 148173.516 177089.375 1 174.18 170.46 86 2013OCT23_C_Cordova_3 2.27 138530.141 147147.484 180932.5 1 169.80 166.18 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 2.27 39276.219 41122.859 49913.441 1 48.14 47.12 90 2013OCT23_C_Tuckahoe1_2 2.27 41967.246 41905.699 52381.387 1 51.44 50.34 91 2013OCT23_C_Tuckahoe1_3 2.27 38223.477 42161.348 50739.652 1 46.85 45.85 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.27 35075.168 38777.887 45690.672 1 42.99 42.08 95 2013OCT23_C_Tuckahoe2_2 2.27 37784.406 39185.863 46912.582 1 46.31 45.33 96 2013OCT23_C_Tuckahoe2_3 2.27 37917.805 41359.285 46757.172 1 46.48 45.49 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 2.27 41826.398 44262.438 52315.035 1 51.27 50.17 100 2013OCT23_C_GermanBranch_2 2.27 41894.844 42647.711 51038.152 1 51.35 50.26 101 2013OCT23_C_GermanBranch_3 2.27 43083.875 45107.32 53455.281 1 52.81 51.68 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 2.27 224243.969 239361.875 282527.281 1 274.87 269.00 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.27 20979.215 19965.549 25200.82 1 25.72 25.17 108 2013OCT23_C_Greensboro1_2 2.27 20083.766 21627.693 25139.697 1 24.62 24.09 109 2013OCT23_C_Greensboro1_3 2.27 17425.174 21471.822 25399.154 1 21.36 20.90 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 2.27 15886.255 18107.77 22415.047 1 19.47 19.06 113 2013OCT23_C_Greensboro2_2 2.27 17912.246 19125.303 22017.781 1 21.96 21.49 125 114 2013OCT23_C_Greensboro2_3 2.27 18580.057 18168.434 22737.727 1 22.77 22.29 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 2.27 26456.475 25682.658 30631.24 1 32.43 31.74 118 2013OCT23_C_BeaverDam_2 2.27 23850.143 25252.092 30840.145 1 29.23 28.61 119 2013OCT23_C_BeaverDam_3 2.27 23322.129 25195.854 30001.99 1 28.59 27.98 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 2.27 12649.552 12600.854 17576.65 1 15.51 15.17 123 2013OCT23_C_LongMarsh_2 2.27 12596.099 12495.932 18931.727 0 15.44 15.11 124 2013OCT23_C_LongMarsh_3 2.27 11435.961 11625.428 16814.291 1 14.02 13.72 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 307.579 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 2.28 915.582 983.867 0 130 2013OCT23_C_0-5_Std_2 Standard 0.5 2.27 4762.862 5273.463 5668.942 1 131 2013OCT23_C_1_Std_2 Standard 1 2.27 8388.966 8827.628 10509.34 1 132 2013OCT23_C_5_Std_2 Standard 5 2.27 48474.887 49232.516 60396.922 1 133 2013OCT23_C_10_Std_2 Standard 10 2.27 93958.141 98847.195 115395.328 1 134 2013OCT23_C_25_Std_2 Standard 25 2.27 231538.188 232198.594 279978.219 1 135 2013OCT23_C_50_Std_2 Standard 50 2.27 422526.25 439840.875 526594.688 1 136 2013OCT23_C_100_Std_2 Standard 100 2.27 830319.875 870215.875 1043079.125 1 137 2013OCT23_C_200_Stds_2 Standard 200 2.27 1601782.375 1655357.75 1980504.5 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 3: CIAT yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 4 2013OCT23_C_0-01_Std Standard 0.01 2.81 356.335 270.704 897.74 0 0.01 35% 5 2013OCT23_C_0-05_Std Standard 0.05 2.81 1166.604 1048.925 5583.207 0 0.04 -12% 6 2013OCT23_C_0-1_Std Standard 0.1 2.81 3731.542 3206.139 14874.568 0 0.14 41% 7 2013OCT23_C_0-5_Std Standard 0.5 2.81 14994.227 13826.915 58961.699 1 0.6 14% 8 2013OCT23_C_1_Std Standard 1 2.8 28899.178 27539.635 110891.727 1 1.1 9% 9 2013OCT23_C_5_Std Standard 5 2.81 186100.344 168901.688 665817.563 1 7.1 41% 10 2013OCT23_C_10_Std Standard 10 2.81 355655.625 316193.406 1258640.25 1 13.5 35% 11 2013OCT23_C_25_Std Standard 25 2.81 845607.5 784246 3074254.5 1 32.0 28% 12 2013OCT23_C_50_Std Standard 50 2.81 1474421.875 1343870.125 5252935.5 1 55.9 12% 13 2013OCT23_C_100_Std Standard 100 2.81 2723044.5 2468900.25 8683873 1 103.2 3% 126 14 2013OCT23_C_200_Stds Standard 200 2.8 5106366.5 4878599 0 193.5 -3% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.04 -20% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.1 46% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.6 24% 19 2013OCT23_C_MM_0 2.81 304427.813 282522 1115773.5 1 1.2 16% 20 2013OCT23_C_MM_1 2.81 339907.469 314039.906 1223423.5 1 6.8 36% 21 2013OCT23_C_MM_5 2.81 458187.281 431816 1677207 1 12.8 28% 22 2013OCT23_C_MM_10 2.81 727086.875 667536.188 2687030 1 31.1 24% 23 2013OCT23_C_MM_25 2.81 1041946.188 945595.25 3826453.75 1 54.0 8% 24 2013OCT23_C_MM_50 2.81 1676783.375 1518385.5 5982376.5 1 107.5 8% 25 2013OCT23_C_MM_100 2.81 2997436.25 2718151.75 9131586 1 196.7 -2% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 2.81 210840.781 195196.094 766578.125 1 79.88 77.31 29 2013OCT23_C_NOAA_2 2.81 222762.188 204027.109 787565.125 1 84.40 81.68 30 2013OCT23_C_NOAA_3 2.81 224915.625 200861.266 825353.563 1 85.22 82.47 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 2.81 279727.813 246515.438 1030619.188 1 105.98 102.57 34 2013OCT23_C_HornPt_2 2.81 288825.719 266027.25 1044627.813 1 109.43 105.90 35 2013OCT23_C_HornPt_3 2.81 289652.219 270900.906 1031509.375 1 109.75 106.21 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.81 373664.938 336099.875 1377733.625 1 141.58 137.01 39 2013OCT23_C_50Bridge1_2 2.8 376200.969 358401.75 1436582.375 1 142.54 137.94 40 2013OCT23_C_50Bridge1_3 2.81 387206.594 363246.25 1471760.875 1 146.71 141.98 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.81 325215.906 306480.688 1174852.125 1 123.22 119.25 44 2013OCT23_C_50Bridge2_2 2.8 330480.438 301696.625 1239558.125 1 125.21 121.18 45 2013OCT23_C_50Bridge2_3 2.81 352390.75 322800.844 1260232.375 1 133.52 129.21 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 2.81 778925.875 727246.188 2824667 1 295.12 285.61 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 2.81 375279.156 346319.063 1374277.875 1 142.19 137.60 52 2013OCT23_C_50BridgeFurtherPt_2 2.81 373134.969 346441.438 1375507.625 1 141.38 136.82 53 2013OCT23_C_50BridgeFurtherPt_3 2.81 368958.469 319826.156 1317654.625 1 139.79 135.29 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 2.81 335598.094 305695.906 1203065.75 1 127.15 123.05 57 2013OCT23_C_PrestonLn_2 2.81 323652.906 303637.938 1195542.25 1 122.63 118.67 58 2013OCT23_C_PrestonLn_3 2.81 319402.781 297615.563 1174945.125 1 121.02 117.12 59 2013OCT23_C_SolvA_19 #DIV/0! 127 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 2.81 250889.828 213258.109 908247.563 1 95.06 91.99 62 2013OCT23_C_FrazierPt_2 2.81 261959.531 242318 934043.75 1 99.25 96.05 63 2013OCT23_C_FrazierPt_3 2.81 255309.969 231463.141 934610.813 1 96.73 93.61 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.81 242613.547 225274.625 857811.625 1 91.92 88.96 67 2013OCT23_C_SwingBridge_2 2.81 251018.766 229822.344 883993.313 1 95.11 92.04 68 2013OCT23_C_SwingBridge_3 2.81 252500.094 232541.438 895414.813 1 95.67 92.58 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 2.81 210585.078 193451.141 759845.813 1 79.79 77.22 72 2013OCT23_C_KingstonLn1_2 2.81 210062.625 191641.891 756946 1 79.59 77.02 73 2013OCT23_C_KingstonLn1_3 2.81 207547.703 189991.578 740625.688 1 78.64 76.10 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 2.81 847971.938 773983.375 3089053.5 1 321.28 310.93 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 2.81 231807.359 211102.469 848751.75 1 87.83 85.00 80 2013OCT23_C_KingstonLn2_2 2.81 233745.953 217426.922 860758.313 1 88.56 85.71 81 2013OCT23_C_KingstonLn2_3 2.81 233177.297 213582.375 836256.313 1 88.35 85.50 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.81 656642.313 621405.313 2474352.25 1 248.79 240.77 85 2013OCT23_C_Cordova_2 2.81 690916.875 634857.5 2520489 1 261.78 253.34 86 2013OCT23_C_Cordova_3 2.81 660127.5 617896.375 2416466 1 250.11 242.05 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 2.81 409241 375020.313 1444138.5 1 155.06 150.06 90 2013OCT23_C_Tuckahoe1_2 2.81 416628.688 386223.375 1484277 1 157.85 152.77 91 2013OCT23_C_Tuckahoe1_3 2.81 404415.781 382872.438 1474163 1 153.23 148.29 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.81 386728.438 358872.844 1375122.75 1 146.53 141.80 95 2013OCT23_C_Tuckahoe2_2 2.81 396365.281 367551.063 1437674.5 1 150.18 145.34 96 2013OCT23_C_Tuckahoe2_3 2.81 386371.594 373126.25 1462295.75 1 146.39 141.67 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 2.81 378308 350384.75 1396645.375 1 143.34 138.71 100 2013OCT23_C_GermanBranch_2 2.81 390128.719 359714.5 1393279 1 147.81 143.05 101 2013OCT23_C_GermanBranch_3 2.81 401129.281 376462.625 1488229.75 1 151.98 147.08 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 2.81 789463 746279.938 2896827.5 1 299.12 289.47 128 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.81 110497.859 99087.055 407169.656 1 41.87 40.52 108 2013OCT23_C_Greensboro1_2 2.81 111370.891 102548.453 413990 1 42.20 40.84 109 2013OCT23_C_Greensboro1_3 2.81 110998.883 104029.547 400925.375 1 42.06 40.70 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 2.81 92289.961 84229.18 327298.875 1 34.97 33.84 113 2013OCT23_C_Greensboro2_2 2.81 97865.078 89321.273 325577.719 1 37.08 35.88 114 2013OCT23_C_Greensboro2_3 2.81 99559.844 92095.359 364504.438 1 37.72 36.51 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 2.81 290574.125 276529.75 1053710.375 1 110.09 106.54 118 2013OCT23_C_BeaverDam_2 2.81 282275.031 263781.375 1074946.25 1 106.95 103.50 119 2013OCT23_C_BeaverDam_3 2.81 289368.469 264392.5 1023029.813 1 109.64 106.10 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 2.81 93498.93 83107.492 347188.875 1 35.43 34.28 123 2013OCT23_C_LongMarsh_2 2.81 98742.609 88819.375 363375.656 1 37.41 36.21 124 2013OCT23_C_LongMarsh_3 2.81 97530.07 88426.984 350802.938 1 36.95 35.76 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 219.106 977.407 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 2.81 1053.773 1382.053 5292.256 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 2.81 3858.992 3227.094 13293.586 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 2.81 16308.924 13820.356 52662.438 1 131 2013OCT23_C_1_Std_2 Standard 1 2.81 30495.625 27695.398 110086.945 1 132 2013OCT23_C_5_Std_2 Standard 5 2.81 179201.859 164046.422 638566.5 1 133 2013OCT23_C_10_Std_2 Standard 10 2.81 337126.781 313553.438 1224132.25 1 134 2013OCT23_C_25_Std_2 Standard 25 2.81 819970.813 744546.063 2928745 1 135 2013OCT23_C_50_Std_2 Standard 50 2.81 1424827 1368214.5 5447929.5 1 136 2013OCT23_C_100_Std_2 Standard 100 2.81 2837327.25 2538455.5 8728683 1 137 2013OCT23_C_200_Stds_2 Standard 200 2.81 5190979.5 4654784 10898907 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 4: OIET yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 #DIV/0! 2 2013OCT23_C_Lab Blk 2.14 666.42 1707.022 1112.695 0 3 2013OCT23_C_Travel Blk 2.12 997.776 1653.492 2262.747 1 4 2013OCT23_C_0-01_Std Standard 0.01 2.13 1311.675 2018.138 3332.427 1 0.04 295% 129 5 2013OCT23_C_0-05_Std Standard 0.05 2.13 2706.838 4819.656 7257.608 1 0.08 63% 6 2013OCT23_C_0-1_Std Standard 0.1 2.12 5761.291 9231.213 11310.72 1 0.17 73% 7 2013OCT23_C_0-5_Std Standard 0.5 2.12 22168.789 37343.918 54643.379 1 0.7 34% 8 2013OCT23_C_1_Std Standard 1 2.12 43223.402 77217.422 109505.07 1 1.3 30% 9 2013OCT23_C_5_Std Standard 5 2.12 124901.945 217824.875 328040.719 1 3.8 -25% 10 2013OCT23_C_10_Std Standard 10 2.12 250751.688 415674.938 608037.938 1 7.6 -24% 11 2013OCT23_C_25_Std Standard 25 2.12 644110.25 1109999.625 1629903.125 1 19.4 -22% 12 2013OCT23_C_50_Std Standard 50 2.12 1720025.625 2853264.25 4273637.5 1 51.8 4% 13 2013OCT23_C_100_Std Standard 100 2.12 3540513.25 5630794 7080851.5 1 106.6 7% 14 2013OCT23_C_200_Stds Standard 200 2.13 6664363 8247614 9298159 1 200.7 0% 15 2013OCT23_C_SolvA_2 2.13 3353.329 6738.71 9244.816 1 0.04 268% 16 2013OCT23_C_Surrogate_1 2.13 686.417 1433.082 2142.137 1 0.09 83% 17 2013OCT23_C_SolvA_3 2.11 581.789 1632.349 2243.055 1 0.1 41% 18 2013OCT23_C_SolvA_4 2.11 658.065 1694.913 1381.69 0 0.6 26% 19 2013OCT23_C_MM_0 2.12 432482.688 730625.375 1083478.375 1 1.3 35% 20 2013OCT23_C_MM_1 2.13 446420.031 757153.188 1117407.25 1 4.0 -21% 21 2013OCT23_C_MM_5 2.13 650987.75 1094836.375 1602156.375 1 7.5 -25% 22 2013OCT23_C_MM_10 2.13 1015092.188 1654143.125 2446910.5 1 20.1 -19% 23 2013OCT23_C_MM_25 2.13 1519368.625 2551179.75 3737855.5 1 52.2 4% 24 2013OCT23_C_MM_50 2.12 2229295 3872386.25 5353806 1 111.1 11% 25 2013OCT23_C_MM_100 2.13 4605684 6585317.5 7942729 1 191.1 -4% 26 2013OCT23_C_SolvA_5 2.13 1191.695 1828.76 1417.692 0 Forced (0,0) MM 27 2013OCT23_C_SolvA_6 475.561 1061.018 0 (ng/L in sample) 28 2013OCT23_C_NOAA_1 2.13 259589.453 437361.406 644662.688 1 78.17 63.55 29 2013OCT23_C_NOAA_2 2.12 262361.5 446492.781 667231.625 1 79.01 64.23 30 2013OCT23_C_NOAA_3 2.13 271415.813 456167.406 667480 1 81.74 66.45 31 2013OCT23_C_SolvA_7 2.13 467.847 807.358 867.003 1 32 2013OCT23_C_SolvA_8 2.12 2806.221 4655.694 6567.489 1 33 2013OCT23_C_HornPt_1 2.13 340158.469 576347.063 852882.625 1 102.44 83.28 34 2013OCT23_C_HornPt_2 2.12 352286.844 592009.813 882164.063 1 106.09 86.25 35 2013OCT23_C_HornPt_3 2.12 357950.813 608240.5 875215.438 1 107.79 87.63 36 2013OCT23_C_SolvA_9 2.14 966.268 862.753 1856.462 0 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.13 492821.688 826603.125 1217557.25 1 148.41 120.65 39 2013OCT23_C_50Bridge1_2 2.12 507927.438 858174.563 1269750.375 1 152.96 124.35 40 2013OCT23_C_50Bridge1_3 2.12 506476.625 863751.313 1267435.75 1 152.52 123.99 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 792.187 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.13 418409.375 700756.563 1039913.375 1 126.00 102.43 44 2013OCT23_C_50Bridge2_2 2.12 424611.25 724356.063 1054648.125 1 127.87 103.95 45 2013OCT23_C_50Bridge2_3 2.12 446477.688 736411.875 1081196.25 1 134.45 109.30 46 2013OCT23_C_SolvA_13 2.1 434.523 1440.263 968.599 0 47 2013OCT23_C_SolvA_14 2.13 2036 4094.925 5944.736 1 48 2013OCT23_C_QC_Std25_1 2.12 628092.438 1076255 1574739 1 189.15 153.77 49 2013OCT23_C_SolvA_15 2.13 1046.567 26.804 1852.005 0 50 2013OCT23_C_SolvA_16 2.14 779.937 1372.569 #DIV/0! 130 51 2013OCT23_C_50BridgeFurtherPt_1 2.13 455602.375 764652.313 1125111.875 1 137.20 111.54 52 2013OCT23_C_50BridgeFurtherPt_2 2.13 471397.156 788829.375 1162092.75 1 141.96 115.41 53 2013OCT23_C_50BridgeFurtherPt_3 2.13 477465.031 796483.75 1176797.75 1 143.79 116.89 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 2.12 603602.875 1048035.25 1528828.625 1 181.77 147.77 57 2013OCT23_C_PrestonLn_2 2.13 623554.375 1069041.5 1555625 1 187.78 152.66 58 2013OCT23_C_PrestonLn_3 2.13 638376.438 1075498.375 1578021.375 1 192.24 156.28 59 2013OCT23_C_SolvA_19 1481.384 #DIV/0! 60 2013OCT23_C_SolvA_20 2.13 2722.964 4737.191 5336.402 1 61 2013OCT23_C_FrazierPt_1 2.12 519760.469 873639.563 1275267.5 1 156.52 127.25 62 2013OCT23_C_FrazierPt_2 2.12 538689.688 916227.813 1316283.625 1 162.22 131.88 63 2013OCT23_C_FrazierPt_3 2.13 543830.813 899846.813 1325876.375 1 163.77 133.14 64 2013OCT23_C_SolvA_21 139.608 1765.225 0 65 2013OCT23_C_SolvA_22 1479.143 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.12 530324.313 886361.25 1321186 1 159.70 129.83 67 2013OCT23_C_SwingBridge_2 2.12 541063.5 931189.625 1353939.875 1 162.94 132.46 68 2013OCT23_C_SwingBridge_3 2.13 561077.313 939276.125 1382330.25 1 168.96 137.36 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 2.13 491802.375 817532.313 1182777.375 1 148.10 120.40 72 2013OCT23_C_KingstonLn1_2 2.13 488330.25 815295.313 1199261.75 1 147.06 119.55 73 2013OCT23_C_KingstonLn1_3 2.13 481988.156 815041.75 1189144.875 1 145.15 118.00 74 2013OCT23_C_SolvA_25 2.13 578.28 1175.792 #DIV/0! 75 2013OCT23_C_SolvA_26 2.13 2452.827 4109.656 5050.909 1 76 2013OCT23_C_QC_Std25_2 2.12 641135.813 1075535.625 1542818.125 1 193.07 156.96 77 2013OCT23_C_SolvA_27 2.12 739.712 1982.299 1652.559 0 78 2013OCT23_C_SolvA_28 1166.487 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 2.13 544920.938 889438.188 1312889.375 1 164.10 133.40 80 2013OCT23_C_KingstonLn2_2 2.13 556029.5 939795.813 1374131.75 1 167.44 136.12 81 2013OCT23_C_KingstonLn2_3 2.13 557536.938 926106.063 1392600.375 1 167.90 136.49 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.12 420259.813 697852.25 1007340.375 1 126.56 102.89 85 2013OCT23_C_Cordova_2 2.13 434289.719 720723.25 1059328.375 1 130.78 106.32 86 2013OCT23_C_Cordova_3 2.13 431576.344 722619.5 1056639.75 1 129.97 105.66 87 2013OCT23_C_SolvA_31 1064.465 #DIV/0! 88 2013OCT23_C_SolvA_32 2.13 2432.98 4060.191 5690.148 1 89 2013OCT23_C_Tuckahoe1_1 2.12 373030.031 617906.438 915881.813 1 112.34 91.32 90 2013OCT23_C_Tuckahoe1_2 2.12 388509.125 654620.063 948321.188 1 117.00 95.11 91 2013OCT23_C_Tuckahoe1_3 2.13 398770.406 663666.438 976115.938 1 120.09 97.63 92 2013OCT23_C_SolvA_33 1643.032 #DIV/0! 93 2013OCT23_C_SolvA_34 1271.833 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.13 366228.406 613280.75 885678.875 1 110.29 89.66 95 2013OCT23_C_Tuckahoe2_2 2.12 375653.25 629884.125 914650 1 113.13 91.97 131 96 2013OCT23_C_Tuckahoe2_3 2.13 374152.594 633657.625 922369.438 1 112.67 91.60 97 2013OCT23_C_SolvA_35 626.225 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 2.12 324570.5 549147.063 808248.938 1 97.74 79.46 100 2013OCT23_C_GermanBranch_2 2.13 343011.125 570404.813 834452.75 1 103.30 83.97 101 2013OCT23_C_GermanBranch_3 2.12 349513.875 575445.875 851451.938 1 105.25 85.57 102 2013OCT23_C_SolvA_37 797.65 #DIV/0! 103 2013OCT23_C_SolvA_38 2.13 2743.465 2828.984 5919.915 0 104 2013OCT23_C_QC_Std25_3 2.12 647203.313 1095668.5 1581267.875 1 194.90 158.45 105 2013OCT23_C_SolvA_39 1630.002 2089.975 0 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.13 440982.281 730414 1100649.5 1 132.80 107.96 108 2013OCT23_C_Greensboro1_2 2.13 456653.25 756051.938 1106758.5 1 137.52 111.80 109 2013OCT23_C_Greensboro1_3 2.13 439137.5 755846.125 1108683.25 1 132.24 107.51 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 2.13 376545.719 635226.313 934999.25 1 113.39 92.18 113 2013OCT23_C_Greensboro2_2 2.12 396968.625 671989.875 986734.938 1 119.54 97.18 114 2013OCT23_C_Greensboro2_3 2.12 401832.438 675556.188 984636.375 1 121.01 98.37 115 2013OCT23_C_SolvA_43 1067.808 #DIV/0! 116 2013OCT23_C_SolvA_44 2.13 2034.192 3902.278 5055.436 1 117 2013OCT23_C_BeaverDam_1 2.13 232758.016 391229.094 562988.938 1 70.09 56.98 118 2013OCT23_C_BeaverDam_2 2.13 238950.656 400463.281 584530.938 1 71.96 58.50 119 2013OCT23_C_BeaverDam_3 2.13 231376.047 392750.031 577780.25 1 69.68 56.64 120 2013OCT23_C_SolvA_45 2.12 799.437 1748.925 1605.068 1 121 2013OCT23_C_SolvA_46 737.276 #DIV/0! 122 2013OCT23_C_LongMarsh_1 2.12 285597.594 476755.688 704325.563 1 86.01 69.92 123 2013OCT23_C_LongMarsh_2 2.12 300034.813 497982.25 751737.125 1 90.35 73.45 124 2013OCT23_C_LongMarsh_3 2.12 306887.094 495580.438 745772.438 1 92.42 75.13 125 2013OCT23_C_SolvA_47 801.142 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 2.13 1220.749 1704.085 1866.067 1 128 2013OCT23_C_0-05_Std_2 Standard 0.05 2.12 3037.902 5115.725 6631.984 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 2.12 4677.725 9476.428 12404.361 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 2.13 20886.492 38350.621 55427.871 1 131 2013OCT23_C_1_Std_2 Standard 1 2.12 44678.285 78482.148 112165.438 1 132 2013OCT23_C_5_Std_2 Standard 5 2.12 131698.125 219707.828 316012.594 1 133 2013OCT23_C_10_Std_2 Standard 10 2.13 250592.516 416371.375 616763.188 1 134 2013OCT23_C_25_Std_2 Standard 25 2.12 668728.313 1129869.75 1617490.75 1 135 2013OCT23_C_50_Std_2 Standard 50 2.13 1732993.25 2855906.25 4173636.5 1 136 2013OCT23_C_100_Std_2 Standard 100 2.13 3689127 5570570.5 6971619.5 1 137 2013OCT23_C_200_Stds_2 Standard 200 2.13 6344434 8113778.5 9058673 1 138 2013OCT23_C_SolvA_49 2.13 2452.821 4955.921 9612.613 1 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 4.438 1270.478 0 141 2013OCT23_C_SolvA_51 2.13 2753.025 4265.868 6558.41 1 132 142 2013OCT23_C_SolvA_52 139.286 1516.55 0 143 2013OCT23_C_SolvA_53 914.606 #DIV/0! Compound 5: Atrazine yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 #DIV/0! 2 2013OCT23_C_Lab Blk 5.42 3994.094 5296.176 14769.479 1 3 2013OCT23_C_Travel Blk 5.42 4676.072 5927.044 15862.762 1 4 2013OCT23_C_0-01_Std Standard 0.01 5.42 1121.997 2303.412 5533.913 1 0.02 100% 5 2013OCT23_C_0-05_Std Standard 0.05 5.42 4001.677 5667.781 13898.791 1 0.07 42% 6 2013OCT23_C_0-1_Std Standard 0.1 5.42 8190.598 11209.205 29097.695 1 0.15 46% 7 2013OCT23_C_0-5_Std Standard 0.5 5.42 34575.07 41013.691 113877.773 1 0.6 23% 8 2013OCT23_C_1_Std Standard 1 5.41 69190.055 87181.031 229954.047 1 1.2 23% 9 2013OCT23_C_5_Std Standard 5 5.42 339919.563 449275.594 1144004.25 1 6.0 21% 10 2013OCT23_C_10_Std Standard 10 5.42 663913.063 805424.188 2231501.5 1 11.8 18% 11 2013OCT23_C_25_Std Standard 25 5.42 1645178.625 2099353 5548201.5 1 29.3 17% 12 2013OCT23_C_50_Std Standard 50 5.42 3001800.25 3907910.25 10076839 1 53.4 7% 13 2013OCT23_C_100_Std Standard 100 5.42 5915430.5 7294957.5 14238949 1 105.2 5% 14 2013OCT23_C_200_Stds Standard 200 5.41 10988120 12443750 16404503 0 195.5 -2% 15 2013OCT23_C_SolvA_2 5.41 866.601 1877.159 #DIV/0! 0.02 146% 16 2013OCT23_C_Surrogate_1 5.42 4143.94 4804.845 12790.332 1 0.08 56% 17 2013OCT23_C_SolvA_3 5.41 407.394 1143.675 #DIV/0! 0.1 33% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.6 28% 19 2013OCT23_C_MM_0 5.42 1511319.75 1888109.5 5228176.5 1 1.3 29% 20 2013OCT23_C_MM_1 5.42 1441686.5 1798410.5 4981394 1 6.5 30% 21 2013OCT23_C_MM_5 5.42 1804077.25 2239059.25 6017875.5 1 12.5 25% 22 2013OCT23_C_MM_10 5.43 2315044 2962181.5 8235096 1 30.9 24% 23 2013OCT23_C_MM_25 5.42 2984870.75 3810645.5 10145467 1 56.0 12% 24 2013OCT23_C_MM_50 5.42 4370208.5 5355170 12763647 1 107.8 8% 25 2013OCT23_C_MM_100 5.42 7515388.5 9214785 15614614 1 194.1 -3% 26 2013OCT23_C_SolvA_5 5.42 951.494 1302.873 2396.273 1 Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 5.42 2040142.875 2611662 7213569 1 362.95 342.31 29 2013OCT23_C_NOAA_2 5.41 2139089.75 2660349.5 7377681 1 380.55 358.91 30 2013OCT23_C_NOAA_3 5.42 2149458.75 2670264.25 7059265.5 1 382.40 360.65 31 2013OCT23_C_SolvA_7 893.889 #DIV/0! 32 2013OCT23_C_SolvA_8 5.44 486.813 537.23 #DIV/0! 33 2013OCT23_C_HornPt_1 5.42 2619081 3321295.75 8918240 1 465.94 439.45 34 2013OCT23_C_HornPt_2 5.41 2710320.75 3359256.25 9335343 1 482.18 454.76 35 2013OCT23_C_HornPt_3 5.41 2696722.25 3361213.5 9201732 1 479.76 452.48 36 2013OCT23_C_SolvA_9 5.42 419.926 1325.018 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 5.42 3488702.25 4150759.75 11092691 1 620.65 585.36 39 2013OCT23_C_50Bridge1_2 5.41 3537842 4301197 11420490 1 629.39 593.60 40 2013OCT23_C_50Bridge1_3 5.42 3519936.25 4347577.5 11495558 1 626.21 590.60 41 2013OCT23_C_SolvA_11 5.43 582.731 1835.712 #DIV/0! 133 42 2013OCT23_C_SolvA_12 5.41 654.961 693.745 #DIV/0! 43 2013OCT23_C_50Bridge2_1 5.42 3061061.5 3760583 10030504 1 544.57 513.61 44 2013OCT23_C_50Bridge2_2 5.41 3095804 3803706.75 10117088 1 550.75 519.44 45 2013OCT23_C_50Bridge2_3 5.42 3120102.5 3835823 10531745 1 555.08 523.51 46 2013OCT23_C_SolvA_13 5.42 531.869 812.015 1260.663 1 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 5.41 1691949.5 2140767.5 5690758.5 1 301.00 283.89 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 5.43 3088085.5 3670970.5 10500726 1 549.38 518.14 52 2013OCT23_C_50BridgeFurtherPt_2 5.42 3160335.75 3870379.75 10309574 1 562.23 530.26 53 2013OCT23_C_50BridgeFurtherPt_3 5.42 3206566.25 3745714 10321263 1 570.46 538.02 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 5.42 2376079.25 2948383.5 8279404.5 1 422.71 398.68 57 2013OCT23_C_PrestonLn_2 5.43 2403193.25 2937380.5 8467482 1 427.54 403.22 58 2013OCT23_C_PrestonLn_3 5.42 2428991.75 2997560.25 8208443 1 432.13 407.55 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 5.42 1610684.625 1973164.375 5542705.5 1 286.55 270.25 62 2013OCT23_C_FrazierPt_2 5.42 1645663.125 1994885.5 5642055 1 292.77 276.12 63 2013OCT23_C_FrazierPt_3 5.43 1638265.375 2002552.625 5677278 1 291.45 274.88 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 5.42 1204244.5 1488669.625 4092929.5 1 214.24 202.06 67 2013OCT23_C_SwingBridge_2 5.42 1213731.25 1509168.625 4105564.5 1 215.93 203.65 68 2013OCT23_C_SwingBridge_3 5.42 1187190 1484962.375 4077595 1 211.21 199.20 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 5.42 876200 1094293.25 3029249.25 1 155.88 147.02 72 2013OCT23_C_KingstonLn1_2 5.43 905006.563 1133225.25 3084510 1 161.00 151.85 73 2013OCT23_C_KingstonLn1_3 5.43 908150.375 1137856 3101375.75 1 161.56 152.38 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 5.42 1659761.75 2125980.75 5471297.5 1 295.28 278.49 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 5.43 1002349.813 1255200.125 3469910.75 1 178.32 168.18 80 2013OCT23_C_KingstonLn2_2 5.42 1018291.313 1276401 3376762 1 181.16 170.86 81 2013OCT23_C_KingstonLn2_3 5.42 1030720.75 1291997.75 3585575.5 1 183.37 172.94 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 5.42 829047.813 1038093.188 2799774.25 1 147.49 139.10 85 2013OCT23_C_Cordova_2 5.44 833152.938 1012544.125 2740850.75 1 148.22 139.79 86 2013OCT23_C_Cordova_3 5.43 826529.125 1053857.625 2823043 1 147.04 138.68 134 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 5.42 400732.688 500980.938 1407608.5 1 71.29 67.24 90 2013OCT23_C_Tuckahoe1_2 5.42 424413.875 530550.313 1429914.125 1 75.50 71.21 91 2013OCT23_C_Tuckahoe1_3 5.43 419805.844 520234.719 1457733.25 1 74.68 70.44 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 5.42 394600.25 503626.156 1367485.875 1 70.20 66.21 95 2013OCT23_C_Tuckahoe2_2 5.42 396548.531 515349.344 1387832.75 1 70.55 66.54 96 2013OCT23_C_Tuckahoe2_3 5.42 407064.656 517352.063 1384787 1 72.42 68.30 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 5.42 425982.531 544906.75 1449098.375 1 75.78 71.47 100 2013OCT23_C_GermanBranch_2 5.42 421974.25 546797.063 1490610.25 1 75.07 70.80 101 2013OCT23_C_GermanBranch_3 5.41 433269.563 554193 1497240.625 1 77.08 72.70 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 5.42 1696440.25 2146587.75 5470242 1 301.80 284.64 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 5.42 326435.219 409313.906 1142024 1 58.07 54.77 108 2013OCT23_C_Greensboro1_2 5.42 340497.813 429012.406 1163320.75 1 60.58 57.13 109 2013OCT23_C_Greensboro1_3 5.42 341864.688 430729.625 1164102 1 60.82 57.36 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 5.42 284101.125 366597.688 948392.563 1 50.54 47.67 113 2013OCT23_C_Greensboro2_2 5.42 283217.938 354290.5 1007456.125 1 50.39 47.52 114 2013OCT23_C_Greensboro2_3 5.42 288572.875 369698.156 994900.75 1 51.34 48.42 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 5.44 195232.828 261425.453 694288.438 1 34.73 32.76 118 2013OCT23_C_BeaverDam_2 5.44 207101.344 269190.125 686869.563 1 36.84 34.75 119 2013OCT23_C_BeaverDam_3 5.43 212565.172 256598.797 726179.125 1 37.82 35.67 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 5.42 76969.953 94063.969 262990.219 1 13.69 12.91 123 2013OCT23_C_LongMarsh_2 5.42 74624.234 95036.719 263747.031 1 13.28 12.52 124 2013OCT23_C_LongMarsh_3 5.42 76786.414 96423.164 264582.938 1 13.66 12.88 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 5.42 1380.038 2560.848 5568.199 1 128 2013OCT23_C_0-05_Std_2 Standard 0.05 5.43 4385.201 4484.544 13570.165 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 5.42 7456.821 10165.331 27824.443 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 5.42 35978.215 47358.297 122316.789 1 131 2013OCT23_C_1_Std_2 Standard 1 5.42 72358.953 95454.531 243645.469 1 132 2013OCT23_C_5_Std_2 Standard 5 5.42 366296.938 449975.188 1225618.25 1 135 133 2013OCT23_C_10_Std_2 Standard 10 5.42 699886.25 906557.063 2326161.75 1 134 2013OCT23_C_25_Std_2 Standard 25 5.43 1737345.125 2132719.75 5817927 1 135 2013OCT23_C_50_Std_2 Standard 50 5.43 3149316.75 3957298.25 10476279 1 136 2013OCT23_C_100_Std_2 Standard 100 5.43 6059397 7206535 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 5.43 10909799 12072278 #DIV/0! 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 5.42 4304.325 6254.83 12902.114 1 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 6: Atrazine-d5 yes=1,no=0 Ident'd? Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0.837 #DIV/0! 2 2013OCT23_C_Lab Blk 5.36 13356960 6832857.5 4199562 1 13854340 Avg 3 2013OCT23_C_Travel Blk 5.36 13968062 7509686.5 4683158.5 1 2% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 5.35 13767485 7297061.5 4596932.5 1 5 2013OCT23_C_0-05_Std Standard 0.05 5.36 13854340 7287431 4512335 1 6 2013OCT23_C_0-1_Std Standard 0.1 5.36 14149668 7826432.5 4969956.5 1 7 2013OCT23_C_0-5_Std Standard 0.5 5.36 13964643 7600396.5 4790484 1 8 2013OCT23_C_1_Std Standard 1 5.35 14033955 7743192.5 4867685 1 9 2013OCT23_C_5_Std Standard 5 5.35 14027941 7714844 4817403.5 1 10 2013OCT23_C_10_Std Standard 10 5.36 14168122 7510693.5 4718971 1 11 2013OCT23_C_25_Std Standard 25 5.36 14083242 7381817 4636417.5 1 12 2013OCT23_C_50_Std Standard 50 5.37 14260725 7587809.5 4691632 1 13 2013OCT23_C_100_Std Standard 100 5.36 13822237 7021053 4446957.5 1 14 2013OCT23_C_200_Stds Standard 200 5.35 13995367 7241861 4562594.5 1 15 2013OCT23_C_SolvA_2 5.34 3430.121 239.691 12.724 0 16 2013OCT23_C_Surrogate_1 5.36 2161.714 #DIV/0! 17 2013OCT23_C_SolvA_3 5.35 1733.499 #DIV/0! 18 2013OCT23_C_SolvA_4 5.35 1299.964 215.713 #DIV/0! 19 2013OCT23_C_MM_0 5.36 14139998 7064736.5 4367210 1 20 2013OCT23_C_MM_1 5.36 13706648 6523538 4050015.25 1 21 2013OCT23_C_MM_5 5.37 14053894 6876924.5 4264492 1 22 2013OCT23_C_MM_10 5.38 14964969 7799009 4865599 1 23 2013OCT23_C_MM_25 5.36 14373887 6983186.5 4419375.5 1 24 2013OCT23_C_MM_50 5.35 13978067 6926617.5 4420722 1 25 2013OCT23_C_MM_100 5.36 14593716 7405578 4584920.5 1 26 2013OCT23_C_SolvA_5 5.36 3079.891 #DIV/0! 27 2013OCT23_C_SolvA_6 5.36 2178.653 #DIV/0! 28 2013OCT23_C_NOAA_1 5.36 13708316 6958410.5 4379620.5 1 29 2013OCT23_C_NOAA_2 5.35 14114375 7186050.5 4433717 1 30 2013OCT23_C_NOAA_3 5.36 14048936 6976561.5 4370667.5 1 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 5.36 2515.312 4.844 #DIV/0! 136 33 2013OCT23_C_HornPt_1 5.36 13554813 6509059.5 4068227.25 1 34 2013OCT23_C_HornPt_2 5.35 14068463 6754152 4217999.5 1 35 2013OCT23_C_HornPt_3 5.35 13691924 6778966 4265425.5 1 36 2013OCT23_C_SolvA_9 5.34 3074.751 #DIV/0! 37 2013OCT23_C_SolvA_10 5.35 2620.545 #DIV/0! 38 2013OCT23_C_50Bridge1_1 5.36 14331288 7377142.5 4634091.5 1 39 2013OCT23_C_50Bridge1_2 5.35 14435484 7547725 4851802.5 1 40 2013OCT23_C_50Bridge1_3 5.35 14303994 7517357 4795072.5 1 41 2013OCT23_C_SolvA_11 5.36 3033.837 175.29 1047.969 0 42 2013OCT23_C_SolvA_12 5.35 1387.872 #DIV/0! 43 2013OCT23_C_50Bridge2_1 5.36 13740946 6416220.5 4026779.5 1 44 2013OCT23_C_50Bridge2_2 5.35 13593124 6462162.5 4129174.75 1 45 2013OCT23_C_50Bridge2_3 5.36 13712277 6590005.5 4056798.25 1 46 2013OCT23_C_SolvA_13 5.36 2815.114 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 5.35 13933665 7550656.5 4733031 1 49 2013OCT23_C_SolvA_15 5.33 2635.396 #DIV/0! 50 2013OCT23_C_SolvA_16 5.34 1634.54 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 5.37 13953864 6600411 4166594.25 1 52 2013OCT23_C_50BridgeFurtherPt_2 5.37 13926571 6622586 4194137.25 1 53 2013OCT23_C_50BridgeFurtherPt_3 5.36 14141434 6682322 4260637.5 1 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 5.36 14144676 6430814 4135234.5 1 57 2013OCT23_C_PrestonLn_2 5.37 14042932 6588171.5 4069615.75 1 58 2013OCT23_C_PrestonLn_3 5.36 13689622 6519070.5 4121400 1 59 2013OCT23_C_SolvA_19 5.34 2284.223 #DIV/0! 60 2013OCT23_C_SolvA_20 5.35 1606.064 #DIV/0! 61 2013OCT23_C_FrazierPt_1 5.36 13122242 5658013.5 3518816 1 62 2013OCT23_C_FrazierPt_2 5.37 13133589 5628360 3468939.5 1 63 2013OCT23_C_FrazierPt_3 5.37 13076728 5580227.5 3477551 1 64 2013OCT23_C_SolvA_21 5.35 2255.904 #DIV/0! 65 2013OCT23_C_SolvA_22 5.33 1967.886 #DIV/0! 66 2013OCT23_C_SwingBridge_1 5.36 13722357 6476288 4004509.25 1 67 2013OCT23_C_SwingBridge_2 5.36 13778718 6498823.5 4041697 1 68 2013OCT23_C_SwingBridge_3 5.37 13914794 6518563.5 4007713.5 1 69 2013OCT23_C_SolvA_23 5.36 2650.493 #DIV/0! 70 2013OCT23_C_SolvA_24 5.36 547.404 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 5.37 13511026 6210171 3856953.25 1 72 2013OCT23_C_KingstonLn1_2 5.37 13592791 6363859.5 3920928 1 73 2013OCT23_C_KingstonLn1_3 5.37 13861906 6420828.5 3951915.5 1 74 2013OCT23_C_SolvA_25 5.35 2991.943 #DIV/0! 75 2013OCT23_C_SolvA_26 5.38 1665.733 954.772 #DIV/0! 76 2013OCT23_C_QC_Std25_2 5.36 13858928 7203388.5 4466879.5 1 77 2013OCT23_C_SolvA_27 5.36 1890.153 #DIV/0! 137 78 2013OCT23_C_SolvA_28 5.37 1542.475 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 5.37 14476619 7038445 4382041 1 80 2013OCT23_C_KingstonLn2_2 5.37 14314378 7139980 4406062 1 81 2013OCT23_C_KingstonLn2_3 5.37 14302194 7264861.5 4519715.5 1 82 2013OCT23_C_SolvA_29 5.36 2482.266 797.277 #DIV/0! 83 2013OCT23_C_SolvA_30 5.36 1413.12 #DIV/0! 84 2013OCT23_C_Cordova_1 5.37 13363140 6182944.5 3901066.5 1 85 2013OCT23_C_Cordova_2 5.38 13590895 6266899.5 3874496.5 1 86 2013OCT23_C_Cordova_3 5.37 13518040 6380027.5 3961570.25 1 87 2013OCT23_C_SolvA_31 5.37 2099.955 589.405 #DIV/0! 88 2013OCT23_C_SolvA_32 5.36 2171.938 647.975 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 5.37 14036706 7096353 4425476.5 1 90 2013OCT23_C_Tuckahoe1_2 5.36 14035194 7417169.5 4476412.5 1 91 2013OCT23_C_Tuckahoe1_3 5.37 14327353 7289761.5 4521879 1 92 2013OCT23_C_SolvA_33 5.35 3339.043 791.213 #DIV/0! 93 2013OCT23_C_SolvA_34 5.34 2077.687 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 5.36 13859211 6751211 4292111.5 1 95 2013OCT23_C_Tuckahoe2_2 5.36 13964047 6919796 4329440.5 1 96 2013OCT23_C_Tuckahoe2_3 5.36 13954567 6918870.5 4308951.5 1 97 2013OCT23_C_SolvA_35 5.36 3537.059 #DIV/0! 98 2013OCT23_C_SolvA_36 5.36 1282.609 32.74 0 99 2013OCT23_C_GermanBranch_1 5.36 13509843 6503132 4036006.75 1 100 2013OCT23_C_GermanBranch_2 5.36 13857656 6719791 4192554.75 1 101 2013OCT23_C_GermanBranch_3 5.35 13647050 6726279.5 4177177.5 1 102 2013OCT23_C_SolvA_37 5.35 1733.338 751.904 #DIV/0! 103 2013OCT23_C_SolvA_38 5.36 1807.698 #DIV/0! 104 2013OCT23_C_QC_Std25_3 5.37 13999836 7336125 4565533 1 105 2013OCT23_C_SolvA_39 5.35 3491.871 #DIV/0! 106 2013OCT23_C_SolvA_40 5.36 1525.337 #DIV/0! 107 2013OCT23_C_Greensboro1_1 5.36 14227534 7362330 4630681.5 1 108 2013OCT23_C_Greensboro1_2 5.37 14481610 7512460.5 4711035.5 1 109 2013OCT23_C_Greensboro1_3 5.37 14849613 7540519 4818931 1 110 2013OCT23_C_SolvA_41 5.36 2003.767 #DIV/0! 111 2013OCT23_C_SolvA_42 5.37 1142.123 #DIV/0! 112 2013OCT23_C_Greensboro2_1 5.37 13579826 6417185 4036392.25 1 113 2013OCT23_C_Greensboro2_2 5.36 13821800 6676546.5 4216959 1 114 2013OCT23_C_Greensboro2_3 5.36 13714722 6573607.5 4124805.25 1 115 2013OCT23_C_SolvA_43 5.36 3291.572 519.818 0 116 2013OCT23_C_SolvA_44 5.36 2383.9 60.017 24.85 0 117 2013OCT23_C_BeaverDam_1 5.37 13844447 6944838.5 4211337.5 1 118 2013OCT23_C_BeaverDam_2 5.38 13957437 6805879.5 4161875 1 119 2013OCT23_C_BeaverDam_3 5.37 13886681 6913985 4240945 1 120 2013OCT23_C_SolvA_45 5.35 2825.38 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 5.36 13671985 6310705 3925710.75 1 138 123 2013OCT23_C_LongMarsh_2 5.36 13797191 6378323.5 3951037.25 1 124 2013OCT23_C_LongMarsh_3 5.36 13803212 6443287 3994934.25 1 125 2013OCT23_C_SolvA_47 5.35 2912.862 #DIV/0! 126 2013OCT23_C_SolvA_48 5.37 973.833 407.847 0 127 2013OCT23_C_0-01_Std_2 Standard 0.01 5.36 13757834 7160417.5 4446579 1 128 2013OCT23_C_0-05_Std_2 Standard 0.05 5.37 13844429 7125140.5 4458730 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 5.37 14275045 7809788 4921719 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 5.36 13828989 7526511.5 4649458 1 131 2013OCT23_C_1_Std_2 Standard 1 5.36 14207528 7803101 4924457 1 132 2013OCT23_C_5_Std_2 Standard 5 5.36 13999613 7510353 4752730 1 133 2013OCT23_C_10_Std_2 Standard 10 5.37 14096703 7422204.5 4661788.5 1 134 2013OCT23_C_25_Std_2 Standard 25 5.37 14100749 7461005.5 4611934 1 135 2013OCT23_C_50_Std_2 Standard 50 5.37 14137619 7359762 4653196.5 1 136 2013OCT23_C_100_Std_2 Standard 100 5.37 13829611 6895625.5 4252785 1 137 2013OCT23_C_200_Stds_2 Standard 200 5.37 14002094 7104564 4465899.5 1 138 2013OCT23_C_SolvA_49 5.36 2903.378 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 7: Terbuthylazine yes=1,no=0 Ident'd? Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! Samples 2 2013OCT23_C_Lab Blk 8.06 5238428 4144447.75 #DIV/0! 5893277 Overall Avg 3 2013OCT23_C_Travel Blk 8.06 5713749.5 4495536.5 #DIV/0! 11% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 #DIV/0! 97% Rec 5 2013OCT23_C_0-05_Std Standard 0.05 39.218 #DIV/0! Surrogate Std 6 2013OCT23_C_0-1_Std Standard 0.1 1259.013 #DIV/0! 6096160.25 Avg 7 2013OCT23_C_0-5_Std Standard 0.5 234.363 #DIV/0! 5% RSD 8 2013OCT23_C_1_Std Standard 1 591.845 #DIV/0! 9 2013OCT23_C_5_Std Standard 5 109.922 102.685 #DIV/0! 10 2013OCT23_C_10_Std Standard 10 0.272 285.336 #DIV/0! 11 2013OCT23_C_25_Std Standard 25 394.14 #DIV/0! 12 2013OCT23_C_50_Std Standard 50 87.267 #DIV/0! 13 2013OCT23_C_100_Std Standard 100 92.901 1547.979 #DIV/0! 14 2013OCT23_C_200_Stds Standard 200 186.844 4527.618 #DIV/0! 15 2013OCT23_C_SolvA_2 #DIV/0! 16 2013OCT23_C_Surrogate_1 8.07 5893311 4641217 #DIV/0! 17 2013OCT23_C_SolvA_3 653.626 #DIV/0! 18 2013OCT23_C_SolvA_4 8.15 11.104 43.342 308.067 #DIV/0! 19 2013OCT23_C_MM_0 8.06 6257286.5 4924479 #DIV/0! 20 2013OCT23_C_MM_1 8.07 5796436 4574937 #DIV/0! 21 2013OCT23_C_MM_5 8.07 6120340.5 4798777.5 #DIV/0! 22 2013OCT23_C_MM_10 8.08 7062270 5544175 #DIV/0! 139 23 2013OCT23_C_MM_25 8.06 6261337.5 4924288.5 #DIV/0! 24 2013OCT23_C_MM_50 8.05 6209145 4913715.5 #DIV/0! 25 2013OCT23_C_MM_100 8.06 6742713.5 5265839 #DIV/0! 26 2013OCT23_C_SolvA_5 242.181 478.606 #DIV/0! 27 2013OCT23_C_SolvA_6 59.346 1136.351 #DIV/0! 28 2013OCT23_C_NOAA_1 8.06 6042376.5 4757135.5 #DIV/0! 99% Rec 29 2013OCT23_C_NOAA_2 8.05 6110525 4820879 #DIV/0! 100% 30 2013OCT23_C_NOAA_3 8.06 6051465 4769264.5 #DIV/0! 99% 31 2013OCT23_C_SolvA_7 78.341 1490.248 #DIV/0! 32 2013OCT23_C_SolvA_8 377.304 #DIV/0! 33 2013OCT23_C_HornPt_1 8.06 5766951.5 4568617.5 #DIV/0! 95% Rec 34 2013OCT23_C_HornPt_2 8.04 5834865 4600429 #DIV/0! 96% 35 2013OCT23_C_HornPt_3 8.05 5899089.5 4619507 #DIV/0! 97% 36 2013OCT23_C_SolvA_9 47.375 2614.763 #DIV/0! 37 2013OCT23_C_SolvA_10 25.662 2445.814 #DIV/0! 38 2013OCT23_C_50Bridge1_1 8.05 6612161 5193767.5 #DIV/0! 108% Rec 39 2013OCT23_C_50Bridge1_2 8.04 6618214 5214592.5 #DIV/0! 109% 40 2013OCT23_C_50Bridge1_3 8.05 6583049 5196747.5 24553074 #DIV/0! 108% 41 2013OCT23_C_SolvA_11 8.07 45.132 115.228 5226.793 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 8.05 5694934.5 4490151 23770450 #DIV/0! 93% Rec 44 2013OCT23_C_50Bridge2_2 8.04 5784325.5 4504966.5 23822338 #DIV/0! 95% 45 2013OCT23_C_50Bridge2_3 8.05 5758420 4526794 23749080 #DIV/0! 94% 46 2013OCT23_C_SolvA_13 8.04 97.282 113.835 2039.922 #DIV/0! 47 2013OCT23_C_SolvA_14 8.11 315.074 4.608 140.062 #DIV/0! 48 2013OCT23_C_QC_Std25_1 8.07 30.721 2350.817 #DIV/0! 49 2013OCT23_C_SolvA_15 8.01 16.501 51.967 1308.29 #DIV/0! 50 2013OCT23_C_SolvA_16 8.07 66.681 1141.538 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 8.08 5207848 4096382.25 21988222 #DIV/0! 85% Rec 52 2013OCT23_C_50BridgeFurtherPt_2 8.07 5267324.5 4160452 21992884 #DIV/0! 86% 53 2013OCT23_C_50BridgeFurtherPt_3 8.06 5324431 4210642 23069434 #DIV/0! 87% 54 2013OCT23_C_SolvA_17 8.07 150.021 124.513 982.462 #DIV/0! 55 2013OCT23_C_SolvA_18 8.02 85.097 29.993 #DIV/0! 56 2013OCT23_C_PrestonLn_1 8.07 5541004 4359240.5 22493000 #DIV/0! 91% Rec 57 2013OCT23_C_PrestonLn_2 8.08 5554988 4350872.5 22301226 #DIV/0! 91% 58 2013OCT23_C_PrestonLn_3 8.06 5564661.5 4388738 23379510 #DIV/0! 91% 59 2013OCT23_C_SolvA_19 8.06 363.713 88.902 4890.146 #DIV/0! 60 2013OCT23_C_SolvA_20 8.01 73.917 179.947 460.202 #DIV/0! 61 2013OCT23_C_FrazierPt_1 8.06 4161659.75 3284876.25 21287600 #DIV/0! 68% Rec 62 2013OCT23_C_FrazierPt_2 8.07 4134707 3252171.25 20877110 #DIV/0! 68% 63 2013OCT23_C_FrazierPt_3 8.08 4127945.25 3271589.25 21370312 #DIV/0! 68% 64 2013OCT23_C_SolvA_21 8.09 390.765 64.12 1083.492 #DIV/0! 65 2013OCT23_C_SolvA_22 8.07 252.254 91.834 754.393 #DIV/0! 66 2013OCT23_C_SwingBridge_1 8.06 6083410.5 4782369 23000340 #DIV/0! 100% Rec 67 2013OCT23_C_SwingBridge_2 8.07 6028689 4735070 22901062 #DIV/0! 99% 140 68 2013OCT23_C_SwingBridge_3 8.07 6008430.5 4754499.5 23762194 #DIV/0! 99% 69 2013OCT23_C_SolvA_23 8.07 61.013 293.788 3929.162 #DIV/0! 70 2013OCT23_C_SolvA_24 8.05 13.32 56.685 174.343 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 8.08 5690947 4475375.5 22430418 #DIV/0! 93% Rec 72 2013OCT23_C_KingstonLn1_2 8.09 5692881.5 4452079.5 22272708 #DIV/0! 93% 73 2013OCT23_C_KingstonLn1_3 8.08 5740835.5 4489103.5 23262928 #DIV/0! 94% 74 2013OCT23_C_SolvA_25 8.08 189.935 52.95 7413.569 #DIV/0! 75 2013OCT23_C_SolvA_26 8.04 0.393 428.27 #DIV/0! 76 2013OCT23_C_QC_Std25_2 119.311 543.076 #DIV/0! 77 2013OCT23_C_SolvA_27 61.766 589.703 #DIV/0! 78 2013OCT23_C_SolvA_28 4.159 980.116 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 8.08 6395692.5 5004348 23852258 #DIV/0! 105% Rec 80 2013OCT23_C_KingstonLn2_2 8.07 6445768.5 5046291 23870900 #DIV/0! 106% 81 2013OCT23_C_KingstonLn2_3 8.07 6467812 5096029 23899234 #DIV/0! 106% 82 2013OCT23_C_SolvA_29 8.08 395.15 740.34 9349.536 #DIV/0! 83 2013OCT23_C_SolvA_30 8.05 465.116 5.304 1132.563 #DIV/0! 84 2013OCT23_C_Cordova_1 8.07 5402799.5 4260190 23151208 #DIV/0! 89% Rec 85 2013OCT23_C_Cordova_2 8.09 5481588.5 4240134 21962586 #DIV/0! 90% 86 2013OCT23_C_Cordova_3 8.07 5430179 4276963.5 23164014 #DIV/0! 89% 87 2013OCT23_C_SolvA_31 8.08 244.9 31.846 8180.896 #DIV/0! 88 2013OCT23_C_SolvA_32 8.03 584.12 430.457 3789.841 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 8.07 6592266.5 5178498 23288532 #DIV/0! 108% Rec 90 2013OCT23_C_Tuckahoe1_2 8.07 6600917.5 5210358.5 24291988 #DIV/0! 108% 91 2013OCT23_C_Tuckahoe1_3 8.07 6641442.5 5312541.5 23336848 #DIV/0! 109% 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 8.06 50.497 7.893 4020.917 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 8.06 6312000.5 4981127 24166576 #DIV/0! 104% Rec 95 2013OCT23_C_Tuckahoe2_2 8.06 6318835 4954180 23174994 #DIV/0! 104% 96 2013OCT23_C_Tuckahoe2_3 8.06 6284010.5 4957861 24142024 #DIV/0! 103% 97 2013OCT23_C_SolvA_35 8.08 69.914 43.786 10454.31 #DIV/0! 98 2013OCT23_C_SolvA_36 8.07 624.831 461.816 3086.685 #DIV/0! 99 2013OCT23_C_GermanBranch_1 8.06 5625856.5 4477853.5 23956770 #DIV/0! 92% Rec 100 2013OCT23_C_GermanBranch_2 8.05 5728602.5 4484997.5 24186042 #DIV/0! 94% 101 2013OCT23_C_GermanBranch_3 8.04 5751477.5 4517480.5 109303.641 #DIV/0! 94% 102 2013OCT23_C_SolvA_37 8.07 278.823 48.232 6383.152 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 8.09 1.919 172.927 327.06 #DIV/0! 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 8.1 60.013 94.754 1091.665 #DIV/0! 107 2013OCT23_C_Greensboro1_1 8.06 6988925.5 5485475 24553756 #DIV/0! 115% Rec 108 2013OCT23_C_Greensboro1_2 8.07 6980966.5 5532111.5 24424898 #DIV/0! 115% 109 2013OCT23_C_Greensboro1_3 8.06 7119629.5 5602423.5 24708462 #DIV/0! 117% 110 2013OCT23_C_SolvA_41 8.07 2.875 96.311 6339.999 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 8.07 6187979.5 4858712.5 22871928 #DIV/0! 102% Rec 141 113 2013OCT23_C_Greensboro2_2 8.05 6268174.5 4948856 23149436 #DIV/0! 103% 114 2013OCT23_C_Greensboro2_3 8.07 6258548 4877092 113133.563 #DIV/0! 103% 115 2013OCT23_C_SolvA_43 8.05 73.061 702.4 2499.78 #DIV/0! 116 2013OCT23_C_SolvA_44 8.08 290.769 62.036 2655.007 #DIV/0! 117 2013OCT23_C_BeaverDam_1 8.09 6514916.5 5092971 23181604 #DIV/0! 107% Rec 118 2013OCT23_C_BeaverDam_2 8.09 6533043 5128202.5 22960200 #DIV/0! 107% 119 2013OCT23_C_BeaverDam_3 8.07 6594009.5 5182635 24071368 #DIV/0! 108% 120 2013OCT23_C_SolvA_45 8.05 1131.31 101.222 9103.072 #DIV/0! 121 2013OCT23_C_SolvA_46 8.07 40.993 550.144 3138.875 #DIV/0! 122 2013OCT23_C_LongMarsh_1 8.05 5076872 3989680 23375844 #DIV/0! 83% Rec 123 2013OCT23_C_LongMarsh_2 8.05 5100644 3993153 22754734 #DIV/0! 84% 124 2013OCT23_C_LongMarsh_3 8.06 5082218 3996398.75 22734226 #DIV/0! 83% 125 2013OCT23_C_SolvA_47 8.08 25.036 77.013 6589.618 #DIV/0! 126 2013OCT23_C_SolvA_48 8.08 113.23 66.145 921.548 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 8.11 22.317 171.153 455.503 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 8.04 0.224 18.961 1151.247 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 8.07 395.466 174.872 3461.606 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 8.06 382.52 3102.997 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 8.11 238.788 83.31 3573.056 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 8.02 12.615 28.036 619.41 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 8.1 51.273 2963.405 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 8.09 340.174 2.181 2558.753 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 8.1 329.847 60.579 972.532 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 #DIV/0! 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 8.05 6299009.5 4964023 23846508 #DIV/0! 140 2013OCT23_C_SolvA_50 8.1 425.925 1646.65 #DIV/0! 141 2013OCT23_C_SolvA_51 8.11 46.27 90.46 1466.9 #DIV/0! 142 2013OCT23_C_SolvA_52 8.05 17.12 522.074 73.11 #DIV/0! 143 2013OCT23_C_SolvA_53 8.12 75.298 51.925 179.511 #DIV/0! Compound 8: Metolachlor OH yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 4 2013OCT23_C_0-01_Std Standard 0.01 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 7.28 4393.491 2829.617 40617.645 0 0.08 -18% 7 2013OCT23_C_0-5_Std Standard 0.5 7.27 23204.668 13959.017 190849.922 1 0.4 -13% 8 2013OCT23_C_1_Std Standard 1 7.28 46210.18 28851.219 391418.531 1 0.9 -14% 9 2013OCT23_C_5_Std Standard 5 7.28 236986.656 157629.813 1905670.125 1 4.4 -11% 10 2013OCT23_C_10_Std Standard 10 7.28 473957.469 313481.313 3648223.75 1 8.9 -11% 11 2013OCT23_C_25_Std Standard 25 7.29 1183227.25 762995.375 8653586 1 22.1 -12% 12 2013OCT23_C_50_Std Standard 50 7.29 2451916.5 1574158 14921116 1 45.8 -8% 142 13 2013OCT23_C_100_Std Standard 100 7.28 4352442.5 2792169.75 19121592 1 81.3 -19% 14 2013OCT23_C_200_Stds Standard 200 7.27 10741802 6864319 24179026 1 200.7 0% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.00 -100% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.1 -22% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.5 -10% 19 2013OCT23_C_MM_0 7.28 138032.172 87951.383 1003348.875 1 1.0 -1% 20 2013OCT23_C_MM_1 7.29 163608.625 110752.391 1264008.875 1 5.0 0% 21 2013OCT23_C_MM_5 7.29 373025.469 234011.578 2639835.25 1 9.9 -1% 22 2013OCT23_C_MM_10 7.3 707281.625 443898.75 4905288.5 1 24.6 -2% 23 2013OCT23_C_MM_25 7.29 1357490.25 869680.375 9110636 1 49.1 -2% 24 2013OCT23_C_MM_50 7.28 7138541.5 4546327.5 0 87.8 -12% 25 2013OCT23_C_MM_100 7.28 156186.75 96690.375 1137670.875 1 216.5 8% 26 2013OCT23_C_SolvA_5 1.446 230.9 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 74.393 528.003 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 7.29 152293.359 99952.586 1187297 1 28.46 30.60 29 2013OCT23_C_NOAA_2 7.28 153168.656 99447.484 1190057 1 28.62 30.77 30 2013OCT23_C_NOAA_3 7.29 152131.344 97292.594 1186785.625 1 28.43 30.57 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 35.85 0.545 #DIV/0! 33 2013OCT23_C_HornPt_1 7.29 196333.469 127751.797 1509107.375 1 36.69 39.45 34 2013OCT23_C_HornPt_2 7.27 197447.344 128551.578 1512720.5 1 36.90 39.67 35 2013OCT23_C_HornPt_3 7.27 195350.797 126412.883 1519661.5 1 36.51 39.25 36 2013OCT23_C_SolvA_9 103.519 23.289 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 7.28 253410.75 164013.047 1886084.625 1 47.36 50.91 39 2013OCT23_C_50Bridge1_2 7.27 252427.594 165420.016 1879475.875 1 47.17 50.72 40 2013OCT23_C_50Bridge1_3 7.28 253167.219 159105.125 1871529.375 1 47.31 50.86 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 7.28 229864.188 144243.313 1694734.625 1 42.96 46.18 44 2013OCT23_C_50Bridge2_2 7.27 223773.766 140214.813 1698311.625 1 41.82 44.96 45 2013OCT23_C_50Bridge2_3 7.28 226204.109 146503.156 1685717.75 1 42.27 45.45 46 2013OCT23_C_SolvA_13 61.964 224.057 #DIV/0! 47 2013OCT23_C_SolvA_14 62.153 403.428 #DIV/0! 48 2013OCT23_C_QC_Std25_1 7.27 1275174 822797.813 9575453 1 238.31 256.20 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 649.345 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 7.3 229296.625 147994.141 1728025 1 42.85 46.07 52 2013OCT23_C_50BridgeFurtherPt_2 7.29 235919.578 148153.922 1764931.25 1 44.09 47.40 53 2013OCT23_C_50BridgeFurtherPt_3 7.28 238627.047 148767.438 1801545 1 44.60 47.94 54 2013OCT23_C_SolvA_17 4.442 609.007 #DIV/0! 55 2013OCT23_C_SolvA_18 0.884 91.029 #DIV/0! 56 2013OCT23_C_PrestonLn_1 7.29 203558.063 124238.664 1492839.25 1 38.04 40.90 57 2013OCT23_C_PrestonLn_2 7.3 211868.063 133407.922 1522438.25 1 39.59 42.57 58 2013OCT23_C_PrestonLn_3 7.28 215711.188 133478.016 1540612.875 1 40.31 43.34 143 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 27.38 293.255 #DIV/0! 61 2013OCT23_C_FrazierPt_1 7.28 161468.063 102120.219 1175835.125 1 30.18 32.44 62 2013OCT23_C_FrazierPt_2 7.3 164798.234 102527.961 1196280.75 1 30.80 33.11 63 2013OCT23_C_FrazierPt_3 7.3 161517.813 102493.43 1202370.875 1 30.18 32.45 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 22.103 #DIV/0! 66 2013OCT23_C_SwingBridge_1 7.29 192381.094 120855.828 1417367.375 1 35.95 38.65 67 2013OCT23_C_SwingBridge_2 7.29 191804.281 118485.102 1410619.25 1 35.84 38.54 68 2013OCT23_C_SwingBridge_3 7.29 192609.344 122486.219 1400496 1 36.00 38.70 69 2013OCT23_C_SolvA_23 99.841 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 7.3 174078.281 112413.453 1316075.625 1 32.53 34.97 72 2013OCT23_C_KingstonLn1_2 7.3 169829.094 116472.086 1363812.25 1 31.74 34.12 73 2013OCT23_C_KingstonLn1_3 7.3 184173.281 112618.516 1377931.625 1 34.42 37.00 74 2013OCT23_C_SolvA_25 69.272 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 7.29 1253473.25 788578.5 9561829 1 234.25 251.84 77 2013OCT23_C_SolvA_27 45.766 #DIV/0! 78 2013OCT23_C_SolvA_28 20.131 151.903 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 7.3 200861.375 131057.961 1553913.375 1 37.54 40.36 80 2013OCT23_C_KingstonLn2_2 7.29 209947.672 136257.656 1575796.25 1 39.24 42.18 81 2013OCT23_C_KingstonLn2_3 7.28 207302.078 133747.375 1599099.75 1 38.74 41.65 82 2013OCT23_C_SolvA_29 1227.648 #DIV/0! 83 2013OCT23_C_SolvA_30 11.103 199.822 #DIV/0! 84 2013OCT23_C_Cordova_1 7.3 51355.457 31783.99 434401.719 1 9.60 10.32 85 2013OCT23_C_Cordova_2 7.3 53143.176 31920.029 435477.844 1 9.93 10.68 86 2013OCT23_C_Cordova_3 7.29 54410.773 33219.402 441856.813 1 10.17 10.93 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 7.3 50584.551 32687.506 432575.313 1 9.45 10.16 90 2013OCT23_C_Tuckahoe1_2 7.3 54685.684 34021.27 426648.875 1 10.22 10.99 91 2013OCT23_C_Tuckahoe1_3 7.29 52321.238 33876.539 453848.969 1 9.78 10.51 92 2013OCT23_C_SolvA_33 32.735 47.806 #DIV/0! 93 2013OCT23_C_SolvA_34 60.601 2071.497 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 7.29 49749.57 31840.174 410064 1 9.30 10.00 95 2013OCT23_C_Tuckahoe2_2 7.28 48478.613 32774.461 429444.5 1 9.06 9.74 96 2013OCT23_C_Tuckahoe2_3 7.28 51382.457 31600.48 427675.125 1 9.60 10.32 97 2013OCT23_C_SolvA_35 108.926 271.137 #DIV/0! 98 2013OCT23_C_SolvA_36 29.185 10.652 #DIV/0! 99 2013OCT23_C_GermanBranch_1 7.29 23252.088 14633.229 218950.891 1 4.35 4.67 100 2013OCT23_C_GermanBranch_2 7.28 26987.512 16329.647 223295.25 1 5.04 5.42 101 2013OCT23_C_GermanBranch_3 7.27 25897.475 15671.3 221622.469 1 4.84 5.20 102 2013OCT23_C_SolvA_37 716.231 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 144 104 2013OCT23_C_QC_Std25_3 7.3 1270519.25 824620.188 10133840 1 237.44 255.26 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 7.28 74558.898 47081.977 625469.438 1 13.93 14.98 108 2013OCT23_C_Greensboro1_2 7.29 77942.984 48270.137 622745.375 1 14.57 15.66 109 2013OCT23_C_Greensboro1_3 7.28 78386.219 47546.555 612838.938 1 14.65 15.75 110 2013OCT23_C_SolvA_41 81.657 131.452 #DIV/0! 111 2013OCT23_C_SolvA_42 4.464 933.783 #DIV/0! 112 2013OCT23_C_Greensboro2_1 7.29 62810.004 41241.793 546993.625 1 11.74 12.62 113 2013OCT23_C_Greensboro2_2 7.28 63349.461 41527.926 519103 1 11.84 12.73 114 2013OCT23_C_Greensboro2_3 7.28 66188.195 43297.152 545777.25 1 12.37 13.30 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 81.29 569.116 #DIV/0! 117 2013OCT23_C_BeaverDam_1 7.3 34427.227 21158.463 306474.875 1 6.43 6.92 118 2013OCT23_C_BeaverDam_2 7.31 37296.008 23392.758 308267.813 1 6.97 7.49 119 2013OCT23_C_BeaverDam_3 7.3 39456.355 23419.459 327978.125 1 7.37 7.93 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 7.29 62722.625 40947.664 522781 1 11.72 12.60 123 2013OCT23_C_LongMarsh_2 7.28 64713.266 41453.617 539615.563 1 12.09 13.00 124 2013OCT23_C_LongMarsh_3 7.28 65647.172 39249.762 535320.625 1 12.27 13.19 125 2013OCT23_C_SolvA_47 200.626 218.477 #DIV/0! 126 2013OCT23_C_SolvA_48 8.566 360.353 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 46.772 798.182 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 119.801 18174.881 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 7.3 4167.967 2454.377 49571.234 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 7.27 24148.633 15543.22 226669.734 1 131 2013OCT23_C_1_Std_2 Standard 1 7.28 52818.84 31925.969 457585.063 1 132 2013OCT23_C_5_Std_2 Standard 5 7.29 267122.656 172421.016 2286860 1 133 2013OCT23_C_10_Std_2 Standard 10 7.29 529077.188 333960.438 4353384.5 1 134 2013OCT23_C_25_Std_2 Standard 25 7.3 1313887.625 827245.875 10212592 1 135 2013OCT23_C_50_Std_2 Standard 50 7.3 2624732.5 1654050.5 16338397 1 136 2013OCT23_C_100_Std_2 Standard 100 7.3 4696824 2926549.75 79.579 0 137 2013OCT23_C_200_Stds_2 Standard 200 7.3 11583521 7251858.5 #DIV/0! 138 2013OCT23_C_SolvA_49 175.43 4228.198 #DIV/0! 139 2013OCT23_C_Surrogate_2 68.141 371.455 #DIV/0! 140 2013OCT23_C_SolvA_50 74.457 483.984 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 1.253 541.124 #DIV/0! 143 2013OCT23_C_SolvA_53 854.132 #DIV/0! Compound 9: Alachlor yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 145 4 2013OCT23_C_0-01_Std Standard 0.01 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 0 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 9.23 11516.416 4764.146 1 1.2 147% 8 2013OCT23_C_1_Std Standard 1 9.23 17319.912 8739.555 1 1.9 86% 9 2013OCT23_C_5_Std Standard 5 9.24 103633.984 45581.301 1 11.1 122% 10 2013OCT23_C_10_Std Standard 10 9.24 185469.984 84902.242 1 19.9 99% 11 2013OCT23_C_25_Std Standard 25 9.24 419438.938 189526.734 1 45.0 80% 12 2013OCT23_C_50_Std Standard 50 9.24 674233.313 307345.969 1 72.4 45% 13 2013OCT23_C_100_Std Standard 100 9.24 1124070.125 506496.531 1 120.6 21% 14 2013OCT23_C_200_Stds Standard 200 9.23 1716037.375 779049.938 1 184.1 -8% 15 2013OCT23_C_SolvA_2 1918.933 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.00 -100% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.0 -100% 18 2013OCT23_C_SolvA_4 #DIV/0! 1.3 150% 19 2013OCT23_C_MM_0 #DIV/0! 1.7 71% 20 2013OCT23_C_MM_1 9.24 17265.738 6542.662 1 11.3 125% 21 2013OCT23_C_MM_5 9.24 79923.82 36258.348 1 20.2 102% 22 2013OCT23_C_MM_10 9.24 174181.422 78545.492 1 44.5 78% 23 2013OCT23_C_MM_25 9.24 354238.594 169044.031 1 71.7 43% 24 2013OCT23_C_MM_50 9.24 582044.688 272913.094 1 112.0 12% 25 2013OCT23_C_MM_100 9.24 998569.625 451582.094 1 182.3 -9% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 #DIV/0! 0.00 0.00 29 2013OCT23_C_NOAA_2 #DIV/0! 0.00 0.00 30 2013OCT23_C_NOAA_3 #DIV/0! 0.00 0.00 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 #DIV/0! 0.00 0.00 34 2013OCT23_C_HornPt_2 1326.009 #DIV/0! 0.00 0.00 35 2013OCT23_C_HornPt_3 #DIV/0! 0.00 0.00 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 #DIV/0! 0.00 0.00 39 2013OCT23_C_50Bridge1_2 #DIV/0! 0.00 0.00 40 2013OCT23_C_50Bridge1_3 #DIV/0! 0.00 0.00 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 #DIV/0! 0.00 0.00 44 2013OCT23_C_50Bridge2_2 #DIV/0! 0.00 0.00 45 2013OCT23_C_50Bridge2_3 #DIV/0! 0.00 0.00 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 9.24 398554.844 190244.781 1 427.69 377.30 49 2013OCT23_C_SolvA_15 #DIV/0! 146 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 #DIV/0! 0.00 0.00 52 2013OCT23_C_50BridgeFurtherPt_2 #DIV/0! 0.00 0.00 53 2013OCT23_C_50BridgeFurtherPt_3 #DIV/0! 0.00 0.00 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 #DIV/0! 0.00 0.00 57 2013OCT23_C_PrestonLn_2 #DIV/0! 0.00 0.00 58 2013OCT23_C_PrestonLn_3 #DIV/0! 0.00 0.00 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 #DIV/0! 0.00 0.00 62 2013OCT23_C_FrazierPt_2 #DIV/0! 0.00 0.00 63 2013OCT23_C_FrazierPt_3 #DIV/0! 0.00 0.00 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2051.114 #DIV/0! 0.00 0.00 67 2013OCT23_C_SwingBridge_2 1948.851 #DIV/0! 0.00 0.00 68 2013OCT23_C_SwingBridge_3 1456.767 #DIV/0! 0.00 0.00 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 #DIV/0! 0.00 0.00 72 2013OCT23_C_KingstonLn1_2 #DIV/0! 0.00 0.00 73 2013OCT23_C_KingstonLn1_3 #DIV/0! 0.00 0.00 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 9.24 436719.781 199580.063 1 468.64 413.43 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 #DIV/0! 0.00 0.00 80 2013OCT23_C_KingstonLn2_2 #DIV/0! 0.00 0.00 81 2013OCT23_C_KingstonLn2_3 1470.374 #DIV/0! 0.00 0.00 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 #DIV/0! 0.00 0.00 85 2013OCT23_C_Cordova_2 #DIV/0! 0.00 0.00 86 2013OCT23_C_Cordova_3 #DIV/0! 0.00 0.00 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 1242.325 #DIV/0! 0.00 0.00 90 2013OCT23_C_Tuckahoe1_2 1577.232 #DIV/0! 0.00 0.00 91 2013OCT23_C_Tuckahoe1_3 93.544 #DIV/0! 0.00 0.00 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 1558.203 #DIV/0! 0.00 0.00 147 95 2013OCT23_C_Tuckahoe2_2 16.079 #DIV/0! 0.00 0.00 96 2013OCT23_C_Tuckahoe2_3 0.425 #DIV/0! 0.00 0.00 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 #DIV/0! 0.00 0.00 100 2013OCT23_C_GermanBranch_2 #DIV/0! 0.00 0.00 101 2013OCT23_C_GermanBranch_3 #DIV/0! 0.00 0.00 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 9.24 403725.969 181543.672 1 433.24 382.20 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 236.78 #DIV/0! 107 2013OCT23_C_Greensboro1_1 197.461 #DIV/0! 0.00 0.00 108 2013OCT23_C_Greensboro1_2 #DIV/0! 0.00 0.00 109 2013OCT23_C_Greensboro1_3 #DIV/0! 0.00 0.00 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 11.756 #DIV/0! 112 2013OCT23_C_Greensboro2_1 1169.619 #DIV/0! 0.00 0.00 113 2013OCT23_C_Greensboro2_2 #DIV/0! 0.00 0.00 114 2013OCT23_C_Greensboro2_3 #DIV/0! 0.00 0.00 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 #DIV/0! 0.00 0.00 118 2013OCT23_C_BeaverDam_2 #DIV/0! 0.00 0.00 119 2013OCT23_C_BeaverDam_3 #DIV/0! 0.00 0.00 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 #DIV/0! 0.00 0.00 123 2013OCT23_C_LongMarsh_2 #DIV/0! 0.00 0.00 124 2013OCT23_C_LongMarsh_3 #DIV/0! 0.00 0.00 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 815.844 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 9.23 11663.605 3795.662 0 131 2013OCT23_C_1_Std_2 Standard 1 9.23 15891.979 8664.979 1 132 2013OCT23_C_5_Std_2 Standard 5 9.24 105038.789 45403.039 1 133 2013OCT23_C_10_Std_2 Standard 10 9.24 187908.969 82339.648 1 134 2013OCT23_C_25_Std_2 Standard 25 9.24 414723.438 189850.719 1 135 2013OCT23_C_50_Std_2 Standard 50 9.24 668406.188 311272.375 1 136 2013OCT23_C_100_Std_2 Standard 100 9.24 1043713 506250.813 1 137 2013OCT23_C_200_Stds_2 Standard 200 9.24 1698413.25 773274.688 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 148 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 10: Acetochlor yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 4 2013OCT23_C_0-01_Std Standard 0.01 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 9.23 5430.279 2575.574 0 0.07 49% 6 2013OCT23_C_0-1_Std Standard 0.1 9.23 15678.784 9210.922 0 0.22 115% 7 2013OCT23_C_0-5_Std Standard 0.5 9.23 76097.797 35463.984 12331.438 1 1.0 109% 8 2013OCT23_C_1_Std Standard 1 9.23 139136.141 63006.453 22529.586 1 1.9 91% 9 2013OCT23_C_5_Std Standard 5 9.23 861703.813 411723.906 143276.484 1 11.8 137% 10 2013OCT23_C_10_Std Standard 10 9.23 1574370.625 769579.063 264132.188 1 21.6 116% 11 2013OCT23_C_25_Std Standard 25 9.23 3501204 1738501.25 604844.875 1 48.1 92% 12 2013OCT23_C_50_Std Standard 50 9.23 5870128.5 2905196.25 998154.438 1 80.7 61% 13 2013OCT23_C_100_Std Standard 100 9.23 9602249 5004794 1710665.625 1 131.9 32% 14 2013OCT23_C_200_Stds Standard 200 9.22 12546863 8009870.5 2661905.5 1 172.4 -14% 15 2013OCT23_C_SolvA_2 9.23 20050.385 6249.841 0 0.00 -100% 16 2013OCT23_C_Surrogate_1 9.22 3969.523 #DIV/0! 0.09 71% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.2 147% 18 2013OCT23_C_SolvA_4 #DIV/0! 1.1 111% 19 2013OCT23_C_MM_0 #DIV/0! 1.9 95% 20 2013OCT23_C_MM_1 9.23 125029.43 57164.926 21456.633 1 12.0 141% 21 2013OCT23_C_MM_5 9.23 603719 295568.844 105756.703 1 21.5 115% 22 2013OCT23_C_MM_10 9.23 1459676.125 721705.75 253945.938 1 47.3 89% 23 2013OCT23_C_MM_25 9.23 3105884.25 1387706.875 537132.625 1 83.5 67% 24 2013OCT23_C_MM_50 9.23 5188572.5 2557899.25 914815.375 1 132.7 33% 25 2013OCT23_C_MM_100 9.23 8796277 4350081.5 1488622.625 1 172.0 -14% 26 2013OCT23_C_SolvA_5 9.23 13457.919 5524.959 0 Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 #DIV/0! 0.00 0.00 29 2013OCT23_C_NOAA_2 #DIV/0! 0.00 0.00 30 2013OCT23_C_NOAA_3 #DIV/0! 0.00 0.00 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 #DIV/0! 0.00 0.00 34 2013OCT23_C_HornPt_2 #DIV/0! 0.00 0.00 35 2013OCT23_C_HornPt_3 #DIV/0! 0.00 0.00 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 #DIV/0! 0.00 0.00 39 2013OCT23_C_50Bridge1_2 #DIV/0! 0.00 0.00 40 2013OCT23_C_50Bridge1_3 #DIV/0! 0.00 0.00 149 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 #DIV/0! 0.00 0.00 44 2013OCT23_C_50Bridge2_2 #DIV/0! 0.00 0.00 45 2013OCT23_C_50Bridge2_3 #DIV/0! 0.00 0.00 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 9.23 3613030.25 1763718.5 623941.25 1 496.45 387.84 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 #DIV/0! 0.00 0.00 52 2013OCT23_C_50BridgeFurtherPt_2 #DIV/0! 0.00 0.00 53 2013OCT23_C_50BridgeFurtherPt_3 #DIV/0! 0.00 0.00 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 #DIV/0! 0.00 0.00 57 2013OCT23_C_PrestonLn_2 #DIV/0! 0.00 0.00 58 2013OCT23_C_PrestonLn_3 9.22 4794.007 #DIV/0! 0.66 0.51 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 #DIV/0! 0.00 0.00 62 2013OCT23_C_FrazierPt_2 #DIV/0! 0.00 0.00 63 2013OCT23_C_FrazierPt_3 #DIV/0! 0.00 0.00 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 #DIV/0! 0.00 0.00 67 2013OCT23_C_SwingBridge_2 #DIV/0! 0.00 0.00 68 2013OCT23_C_SwingBridge_3 #DIV/0! 0.00 0.00 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 1.5 #DIV/0! 0.00 0.00 72 2013OCT23_C_KingstonLn1_2 #DIV/0! 0.00 0.00 73 2013OCT23_C_KingstonLn1_3 #DIV/0! 0.00 0.00 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 9.23 3725577.5 1813041.25 646085.375 1 511.92 399.92 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 #DIV/0! 0.00 0.00 80 2013OCT23_C_KingstonLn2_2 #DIV/0! 0.00 0.00 81 2013OCT23_C_KingstonLn2_3 9.23 3500.273 1795.194 0 0.48 0.38 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 #DIV/0! 0.00 0.00 85 2013OCT23_C_Cordova_2 #DIV/0! 0.00 0.00 150 86 2013OCT23_C_Cordova_3 #DIV/0! 0.00 0.00 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 #DIV/0! 0.00 0.00 90 2013OCT23_C_Tuckahoe1_2 #DIV/0! 0.00 0.00 91 2013OCT23_C_Tuckahoe1_3 #DIV/0! 0.00 0.00 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 #DIV/0! 0.00 0.00 95 2013OCT23_C_Tuckahoe2_2 #DIV/0! 0.00 0.00 96 2013OCT23_C_Tuckahoe2_3 #DIV/0! 0.00 0.00 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 #DIV/0! 0.00 0.00 100 2013OCT23_C_GermanBranch_2 #DIV/0! 0.00 0.00 101 2013OCT23_C_GermanBranch_3 #DIV/0! 0.00 0.00 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 9.23 3603621.5 1722329 619219.188 1 495.16 386.83 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 #DIV/0! 0.00 0.00 108 2013OCT23_C_Greensboro1_2 #DIV/0! 0.00 0.00 109 2013OCT23_C_Greensboro1_3 #DIV/0! 0.00 0.00 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 #DIV/0! 0.00 0.00 113 2013OCT23_C_Greensboro2_2 #DIV/0! 0.00 0.00 114 2013OCT23_C_Greensboro2_3 #DIV/0! 0.00 0.00 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 #DIV/0! 0.00 0.00 118 2013OCT23_C_BeaverDam_2 #DIV/0! 0.00 0.00 119 2013OCT23_C_BeaverDam_3 #DIV/0! 0.00 0.00 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 #DIV/0! 0.00 0.00 123 2013OCT23_C_LongMarsh_2 #DIV/0! 0.00 0.00 124 2013OCT23_C_LongMarsh_3 #DIV/0! 0.00 0.00 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 9.23 6228.075 2696.442 1926.821 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 9.23 17967.531 8563.133 3304.383 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 9.23 76648.258 35837.285 11283.325 1 151 131 2013OCT23_C_1_Std_2 Standard 1 9.23 141823.047 64122.988 25044.852 1 132 2013OCT23_C_5_Std_2 Standard 5 9.23 876253.5 419781.656 142272.266 1 133 2013OCT23_C_10_Std_2 Standard 10 9.23 1563153.625 744692.438 267532.219 1 134 2013OCT23_C_25_Std_2 Standard 25 9.23 3441514.25 1739968.75 603879.813 1 135 2013OCT23_C_50_Std_2 Standard 50 9.23 6074762 2894048.5 1033047.25 1 136 2013OCT23_C_100_Std_2 Standard 100 9.23 9660980 5051087 1727103.25 1 137 2013OCT23_C_200_Stds_2 Standard 200 9.23 12519805 7650770.5 2671518 1 138 2013OCT23_C_SolvA_49 9.23 20655.924 7273.901 0 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 11: Alachlor-d13 yes=1,no=0 Ident'd? Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! Samples 2 2013OCT23_C_Lab Blk 9.21 46523.758 #DIV/0! 33533 Overall Avg 3 2013OCT23_C_Travel Blk 9.21 46907.531 #DIV/0! 23% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 #DIV/0! 67% Rec 5 2013OCT23_C_0-05_Std Standard 0.05 #DIV/0! Surrogate Std 6 2013OCT23_C_0-1_Std Standard 0.1 #DIV/0! 49319.137 Avg 7 2013OCT23_C_0-5_Std Standard 0.5 #DIV/0! 7% RSD 8 2013OCT23_C_1_Std Standard 1 #DIV/0! 9 2013OCT23_C_5_Std Standard 5 #DIV/0! 10 2013OCT23_C_10_Std Standard 10 #DIV/0! 11 2013OCT23_C_25_Std Standard 25 #DIV/0! 12 2013OCT23_C_50_Std Standard 50 #DIV/0! 13 2013OCT23_C_100_Std Standard 100 #DIV/0! 14 2013OCT23_C_200_Stds Standard 200 #DIV/0! 15 2013OCT23_C_SolvA_2 #DIV/0! 16 2013OCT23_C_Surrogate_1 9.22 51626.641 #DIV/0! 17 2013OCT23_C_SolvA_3 #DIV/0! 18 2013OCT23_C_SolvA_4 #DIV/0! 19 2013OCT23_C_MM_0 9.21 33240.938 #DIV/0! 20 2013OCT23_C_MM_1 9.21 32941.535 195.939 #DIV/0! 21 2013OCT23_C_MM_5 9.22 34406.051 264.097 #DIV/0! 22 2013OCT23_C_MM_10 9.22 40488.258 175.837 11.506 #DIV/0! 23 2013OCT23_C_MM_25 9.21 32981.848 55.02 861.545 #DIV/0! 24 2013OCT23_C_MM_50 9.21 24582.148 449.291 #DIV/0! 25 2013OCT23_C_MM_100 9.21 24404.48 257.595 #DIV/0! 26 2013OCT23_C_SolvA_5 #DIV/0! 27 2013OCT23_C_SolvA_6 #DIV/0! 28 2013OCT23_C_NOAA_1 9.22 35551.625 #DIV/0! 72% Rec 29 2013OCT23_C_NOAA_2 9.21 35056.551 179.492 #DIV/0! 71% 30 2013OCT23_C_NOAA_3 9.22 33568.039 451.246 #DIV/0! 68% 152 31 2013OCT23_C_SolvA_7 473.153 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 9.22 32701.857 3.574 505.76 #DIV/0! 66% Rec 34 2013OCT23_C_HornPt_2 9.21 30709.756 412.109 #DIV/0! 62% 35 2013OCT23_C_HornPt_3 9.21 29250.896 164.733 37.137 #DIV/0! 59% 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 9.21 33374.469 581.889 437.985 #DIV/0! 68% Rec 39 2013OCT23_C_50Bridge1_2 9.21 38174.383 #DIV/0! 77% 40 2013OCT23_C_50Bridge1_3 9.21 33726.91 92.394 71.509 #DIV/0! 68% 41 2013OCT23_C_SolvA_11 104.489 748.352 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 9.21 32870.809 #DIV/0! 67% Rec 44 2013OCT23_C_50Bridge2_2 9.21 28075.463 #DIV/0! 57% 45 2013OCT23_C_50Bridge2_3 9.21 33652.504 #DIV/0! 68% 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 #DIV/0! 49 2013OCT23_C_SolvA_15 263.412 382.096 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 9.22 25466.35 1394.337 #DIV/0! 52% Rec 52 2013OCT23_C_50BridgeFurtherPt_2 9.22 26063.291 86.941 802.723 #DIV/0! 53% 53 2013OCT23_C_50BridgeFurtherPt_3 9.21 23333.316 #DIV/0! 47% 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 112.874 147.009 #DIV/0! 56 2013OCT23_C_PrestonLn_1 9.22 32311.908 384.663 #DIV/0! 66% Rec 57 2013OCT23_C_PrestonLn_2 9.22 34514.676 746.027 #DIV/0! 70% 58 2013OCT23_C_PrestonLn_3 9.22 31852.17 621.477 411.271 #DIV/0! 65% 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 66.46 #DIV/0! 61 2013OCT23_C_FrazierPt_1 9.22 14276.366 #DIV/0! 29% Rec 62 2013OCT23_C_FrazierPt_2 9.22 17163.486 1343.24 #DIV/0! 35% 63 2013OCT23_C_FrazierPt_3 9.22 16434.934 #DIV/0! 33% 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 9.22 31897.246 494.623 #DIV/0! 65% Rec 67 2013OCT23_C_SwingBridge_2 9.22 33600.762 #DIV/0! 68% 68 2013OCT23_C_SwingBridge_3 9.22 37981.996 #DIV/0! 77% 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 9.22 30837.924 #DIV/0! 63% Rec 72 2013OCT23_C_KingstonLn1_2 9.22 33936.68 #DIV/0! 69% 73 2013OCT23_C_KingstonLn1_3 9.22 36609.414 #DIV/0! 74% 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 153 76 2013OCT23_C_QC_Std25_2 #DIV/0! 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 9.22 40163.629 298.689 #DIV/0! 81% Rec 80 2013OCT23_C_KingstonLn2_2 9.22 36696.164 #DIV/0! 74% 81 2013OCT23_C_KingstonLn2_3 9.22 33993.355 #DIV/0! 69% 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 98.295 380.465 #DIV/0! 84 2013OCT23_C_Cordova_1 9.22 34870.586 #DIV/0! 71% Rec 85 2013OCT23_C_Cordova_2 9.22 33399.035 121.987 377.713 #DIV/0! 68% 86 2013OCT23_C_Cordova_3 9.22 34012.316 594.067 #DIV/0! 69% 87 2013OCT23_C_SolvA_31 68.606 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 9.22 42013.078 46.096 240.665 #DIV/0! 85% Rec 90 2013OCT23_C_Tuckahoe1_2 9.21 39119.98 837.176 #DIV/0! 79% 91 2013OCT23_C_Tuckahoe1_3 9.22 42481.867 568.892 #DIV/0! 86% 92 2013OCT23_C_SolvA_33 228.561 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 9.22 42698.828 #DIV/0! 87% Rec 95 2013OCT23_C_Tuckahoe2_2 9.22 40178.387 604.732 #DIV/0! 81% 96 2013OCT23_C_Tuckahoe2_3 9.22 42184.184 4.601 #DIV/0! 86% 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 9.21 30158.084 #DIV/0! 61% Rec 100 2013OCT23_C_GermanBranch_2 9.22 36967.219 #DIV/0! 75% 101 2013OCT23_C_GermanBranch_3 9.21 28865.617 75.195 #DIV/0! 59% 102 2013OCT23_C_SolvA_37 523.411 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 #DIV/0! 105 2013OCT23_C_SolvA_39 91.224 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 9.22 39111.137 #DIV/0! 79% Rec 108 2013OCT23_C_Greensboro1_2 9.22 37272.508 #DIV/0! 76% 109 2013OCT23_C_Greensboro1_3 9.21 39591.676 #DIV/0! 80% 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 9.22 35205.074 218.589 #DIV/0! 71% Rec 113 2013OCT23_C_Greensboro2_2 9.21 30195.537 #DIV/0! 61% 114 2013OCT23_C_Greensboro2_3 9.21 38341.742 #DIV/0! 78% 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 4.987 #DIV/0! 117 2013OCT23_C_BeaverDam_1 9.21 42732.656 2.915 258.123 #DIV/0! 87% Rec 118 2013OCT23_C_BeaverDam_2 9.22 44411.629 589.327 #DIV/0! 90% 119 2013OCT23_C_BeaverDam_3 9.21 43385.637 373.632 #DIV/0! 88% 120 2013OCT23_C_SolvA_45 470.343 #DIV/0! 154 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 9.21 18038.301 272.994 #DIV/0! 37% Rec 123 2013OCT23_C_LongMarsh_2 9.22 16383.607 815.323 #DIV/0! 33% 124 2013OCT23_C_LongMarsh_3 9.22 18934.471 34.63 #DIV/0! 38% 125 2013OCT23_C_SolvA_47 265.03 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 16.449 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 42.708 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 175.551 359.676 #DIV/0! 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 9.21 47011.633 961.122 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 0.021 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 147.319 167.603 #DIV/0! Compound 12: Metolachlor yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 9.21 262823.625 79319.859 0 3 2013OCT23_C_Travel Blk 9.21 285766.563 89929.063 0 4 2013OCT23_C_0-01_Std Standard 0.01 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 1449.099 0 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 3773.882 0 0.0 -100% 8 2013OCT23_C_1_Std Standard 1 9.28 22842.809 8582.024 1466.507 1 1.0 -3% 9 2013OCT23_C_5_Std Standard 5 9.28 148054.906 44900.379 3963.209 1 6.3 26% 10 2013OCT23_C_10_Std Standard 10 9.29 277974.094 86311.469 6664.709 1 11.8 18% 11 2013OCT23_C_25_Std Standard 25 9.29 637932.875 196899.234 13422.568 1 27.0 8% 12 2013OCT23_C_50_Std Standard 50 9.29 1153829.625 360735.406 26718.148 1 48.9 -2% 13 2013OCT23_C_100_Std Standard 100 9.28 2380439.25 779246.75 55032.215 1 100.9 1% 14 2013OCT23_C_200_Stds Standard 200 9.28 4829822 1484592.875 134681.781 1 204.8 2% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 9.21 323852.844 98683.383 0 0.00 -100% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.0 -100% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.0 -100% 19 2013OCT23_C_MM_0 9.28 1592302.75 525857.75 43134.977 1 1.0 -4% 20 2013OCT23_C_MM_1 9.28 1545130.5 513316.563 33749.785 1 5.8 16% 155 21 2013OCT23_C_MM_5 9.28 1579155.125 531773 34134.785 1 11.2 12% 22 2013OCT23_C_MM_10 9.29 2748161.75 631447.625 40889.832 1 26.0 4% 23 2013OCT23_C_MM_25 9.28 2187132 719216.813 47716.98 1 48.2 -4% 24 2013OCT23_C_MM_50 9.28 2623755.75 845849.438 59846.98 1 92.9 -7% 25 2013OCT23_C_MM_100 9.28 4171444 1198232.875 82823.336 1 198.4 -1% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 9.21 273320.125 82715.273 0 115.88 107.61 29 2013OCT23_C_NOAA_2 9.21 257659.328 81958.523 0 109.24 101.44 30 2013OCT23_C_NOAA_3 9.21 255883.922 81182.422 0 108.49 100.74 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 9.27 449311.906 145150.078 5210.523 1 190.50 176.89 34 2013OCT23_C_HornPt_2 9.27 460712.875 152745.297 6485.028 1 195.33 181.38 35 2013OCT23_C_HornPt_3 9.27 448341.781 148730.172 5863.865 1 190.09 176.51 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 9.28 1049095.875 362239.969 18679.365 1 444.80 413.03 39 2013OCT23_C_50Bridge1_2 9.28 1104109.25 364122.875 24718.523 1 468.12 434.69 40 2013OCT23_C_50Bridge1_3 9.28 1054595.75 359175.781 21061.027 1 447.13 415.19 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 9.28 960780.875 326942.969 16855.605 1 407.35 378.26 44 2013OCT23_C_50Bridge2_2 9.28 959018.125 307860.438 18397.086 1 406.61 377.56 45 2013OCT23_C_50Bridge2_3 9.28 961855.313 318577.594 17258.715 1 407.81 378.68 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 9.28 665284.875 216882.594 14181.26 1 282.07 261.92 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 9.29 846834.688 278148.5 15994.796 1 359.04 333.40 52 2013OCT23_C_50BridgeFurtherPt_2 9.28 840229.5 261405.25 18963.432 1 356.24 330.80 53 2013OCT23_C_50BridgeFurtherPt_3 9.28 807577.25 249008.563 16445.752 1 342.40 317.94 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 9.29 2756244.5 898038 62637.539 1 1168.60 1085.13 57 2013OCT23_C_PrestonLn_2 9.29 2756906.75 929896.438 63595.066 1 1168.88 1085.39 58 2013OCT23_C_PrestonLn_3 9.29 2740635.25 920634.313 58145.309 1 1161.98 1078.99 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 9.28 1733410.625 563489.563 41311.691 1 734.93 682.44 62 2013OCT23_C_FrazierPt_2 9.29 1714604 584146.625 40204.594 1 726.96 675.04 63 2013OCT23_C_FrazierPt_3 9.29 1786293.5 592465.938 37873.758 1 757.35 703.26 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 156 66 2013OCT23_C_SwingBridge_1 9.29 3028477.5 1048720.375 70036.766 1 1284.02 1192.31 67 2013OCT23_C_SwingBridge_2 9.28 3091289.75 1050904.875 72422.773 1 1310.65 1217.04 68 2013OCT23_C_SwingBridge_3 9.29 2935768.5 987253.188 65313.949 1 1244.71 1155.81 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 9.28 3223399.75 1097021.875 79893.484 1 1366.66 1269.05 72 2013OCT23_C_KingstonLn1_2 9.29 3314181.75 1114798.875 71924.977 1 1405.15 1304.79 73 2013OCT23_C_KingstonLn1_3 9.29 3186258.75 1113673.625 71971.188 1 1350.91 1254.43 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 9.28 644637.625 224116.484 15472.832 1 273.31 253.79 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 9.29 3378535 1168829.25 76814.82 1 1432.44 1330.13 80 2013OCT23_C_KingstonLn2_2 9.28 4131836.5 1184703.375 64097.16 1 1751.82 1626.70 81 2013OCT23_C_KingstonLn2_3 9.29 3376228.5 1161877.5 76836.719 1 1431.46 1329.22 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 9.28 835380.5 267862.688 13945.438 1 354.19 328.89 85 2013OCT23_C_Cordova_2 9.28 770250.75 239366 11969.736 1 326.57 303.25 86 2013OCT23_C_Cordova_3 9.28 858706 273635.313 13700.256 1 364.08 338.07 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 9.29 1410064.375 489842.813 29450.631 1 597.84 555.14 90 2013OCT23_C_Tuckahoe1_2 9.28 1390677.125 485606.094 24981.578 1 589.62 547.51 91 2013OCT23_C_Tuckahoe1_3 9.28 1205541.875 428777.25 22318.754 1 511.13 474.62 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 9.28 1395503.25 456121.125 30428.674 1 591.67 549.41 95 2013OCT23_C_Tuckahoe2_2 9.28 1429876.75 463668.344 28771.633 1 606.24 562.94 96 2013OCT23_C_Tuckahoe2_3 9.29 1430418.75 483701.063 27131.166 1 606.47 563.16 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 9.28 512916.563 159011.781 6283.063 1 217.47 201.93 100 2013OCT23_C_GermanBranch_2 9.28 511644.75 168716.172 6839.768 1 216.93 201.43 101 2013OCT23_C_GermanBranch_3 9.27 520076.156 171007.203 5943.124 1 220.50 204.75 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 9.29 630511.813 198367.172 15159.373 1 267.33 248.23 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 9.28 1252312.125 402906.719 24575.313 1 530.96 493.03 108 2013OCT23_C_Greensboro1_2 9.28 1190945.875 389992.063 21771.41 1 504.94 468.87 109 2013OCT23_C_Greensboro1_3 9.28 1247934.625 401692.906 25855.914 1 529.10 491.31 110 2013OCT23_C_SolvA_41 #DIV/0! 157 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 9.29 1015930.875 326710.5 16870.477 1 430.74 399.97 113 2013OCT23_C_Greensboro2_2 9.28 1079600.25 351198.406 20413.484 1 457.73 425.04 114 2013OCT23_C_Greensboro2_3 9.28 1043069.188 337430.813 19519.863 1 442.24 410.66 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 9.28 816347.313 268379.5 13203.968 1 346.12 321.40 118 2013OCT23_C_BeaverDam_2 9.28 737083.063 232670.313 11861.467 1 312.51 290.19 119 2013OCT23_C_BeaverDam_3 9.28 823670.938 261982.938 11599.881 1 349.22 324.28 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 9.28 1269397.75 418550.25 26953.338 1 538.20 499.76 123 2013OCT23_C_LongMarsh_2 9.28 1265775.875 412632.594 28498.463 1 536.67 498.34 124 2013OCT23_C_LongMarsh_3 9.28 1241971 404876.469 25696.047 1 526.57 488.96 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 1267.747 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 4262.744 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 9.28 22542.957 9784.924 769.049 1 132 2013OCT23_C_5_Std_2 Standard 5 9.28 137088.172 44936.563 3228.109 1 133 2013OCT23_C_10_Std_2 Standard 10 9.29 264678.406 82277.898 6339.406 1 134 2013OCT23_C_25_Std_2 Standard 25 9.29 613551.375 188352.875 15357.544 1 135 2013OCT23_C_50_Std_2 Standard 50 9.29 1136894 371003.594 26901.303 1 136 2013OCT23_C_100_Std_2 Standard 100 9.29 2191936.5 700892.438 49064.785 1 137 2013OCT23_C_200_Stds_2 Standard 200 9.29 4680203.5 1356164.25 97428.711 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 9.21 305999.531 94900 0 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 13: Metolachlor-d6 yes=1,no=0 Ident'd? Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 5502.441 0 2 2013OCT23_C_Lab Blk 9.28 7648576 4902671 1303483.75 0 7348118 Avg 3 2013OCT23_C_Travel Blk 9.28 8113610.5 5515478.5 1554420.875 0 6% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 9.28 7334191 4684047.5 1208786 0 5 2013OCT23_C_0-05_Std Standard 0.05 9.28 7348118 4533270.5 978527.188 0 6 2013OCT23_C_0-1_Std Standard 0.1 9.28 8143414.5 5542901.5 1314162.25 0 7 2013OCT23_C_0-5_Std Standard 0.5 9.28 7813694.5 4885415 1078113.5 1 8 2013OCT23_C_1_Std Standard 1 9.28 7650946 4941744 1330600 1 9 2013OCT23_C_5_Std Standard 5 9.28 8099467.5 5412956 1537915.625 1 10 2013OCT23_C_10_Std Standard 10 9.28 8035962.5 5406278.5 1484895.125 1 158 11 2013OCT23_C_25_Std Standard 25 9.28 7756363.5 5051573.5 1143002.625 1 12 2013OCT23_C_50_Std Standard 50 9.28 7726023.5 4926999 1066751.125 1 13 2013OCT23_C_100_Std Standard 100 9.28 7566940 4790362.5 1247377.5 1 14 2013OCT23_C_200_Stds Standard 200 9.28 7676703 4815249 1216543.875 1 15 2013OCT23_C_SolvA_2 9.26 21629.311 7077.156 0 16 2013OCT23_C_Surrogate_1 #DIV/0! 17 2013OCT23_C_SolvA_3 #DIV/0! 18 2013OCT23_C_SolvA_4 #DIV/0! 19 2013OCT23_C_MM_0 9.28 7533076 4773892.5 1215707 1 20 2013OCT23_C_MM_1 9.28 7510840.5 4607302 996695.5 1 21 2013OCT23_C_MM_5 9.28 7304934.5 4498115.5 963502.813 1 22 2013OCT23_C_MM_10 9.28 8106247.5 5111032.5 1125524.375 1 23 2013OCT23_C_MM_25 9.28 7679010.5 4913732 1285456 1 24 2013OCT23_C_MM_50 9.28 7355905 4788756 1247358.75 1 25 2013OCT23_C_MM_100 9.28 7660466 4755090.5 1022919.625 1 26 2013OCT23_C_SolvA_5 7538.982 #DIV/0! 27 2013OCT23_C_SolvA_6 #DIV/0! 28 2013OCT23_C_NOAA_1 9.28 7440279.5 4659006 1008307.563 1 29 2013OCT23_C_NOAA_2 9.28 7500466 4839290 1252310.25 1 30 2013OCT23_C_NOAA_3 9.28 7381492 4759561 1253651.25 1 31 2013OCT23_C_SolvA_7 9.27 26326.205 7161.898 4374.86 0 32 2013OCT23_C_SolvA_8 9.27 10477.839 2008.261 4406.575 0 33 2013OCT23_C_HornPt_1 9.28 7289884.5 4511325 972375.688 1 34 2013OCT23_C_HornPt_2 9.28 7348949 4660004 1182019.75 1 35 2013OCT23_C_HornPt_3 9.27 7267715.5 4725126 1214168.375 1 36 2013OCT23_C_SolvA_9 9.27 19675.35 6397.252 4844.489 0 37 2013OCT23_C_SolvA_10 9.27 6527.269 2092.409 3730.85 0 38 2013OCT23_C_50Bridge1_1 9.28 7524683.5 4836214.5 1279196.625 1 39 2013OCT23_C_50Bridge1_2 9.28 7639530 4892984.5 1294793.5 1 40 2013OCT23_C_50Bridge1_3 9.28 7581060.5 4909116.5 1295146.875 1 41 2013OCT23_C_SolvA_11 9.27 21629.33 6170.686 2088.378 1 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 9.28 7015941 4468150.5 1151652.125 1 44 2013OCT23_C_50Bridge2_2 9.27 6997310 4539190 1148017.375 1 45 2013OCT23_C_50Bridge2_3 9.28 7145316 4467675 1134042 1 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 9.28 7799067 5189960.5 1427674.5 1 49 2013OCT23_C_SolvA_15 4989.765 #DIV/0! 50 2013OCT23_C_SolvA_16 1400.844 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 9.28 6907735 3241898.25 777714.688 1 52 2013OCT23_C_50BridgeFurtherPt_2 9.28 6798800 3200995.25 773037 1 53 2013OCT23_C_50BridgeFurtherPt_3 9.28 6767022 3269843 796240.375 1 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 9.28 7123201.5 4398359.5 936987.375 1 159 57 2013OCT23_C_PrestonLn_2 9.28 7166865.5 4317795 912928.313 1 58 2013OCT23_C_PrestonLn_3 9.28 7071901 4286814 889638.188 1 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 9.27 6018449.5 2470132.75 585936.125 1 62 2013OCT23_C_FrazierPt_2 9.27 5992177 2295011.75 555341.5 1 63 2013OCT23_C_FrazierPt_3 9.28 5904485.5 2304587.75 555032.938 1 64 2013OCT23_C_SolvA_21 4547.383 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 9.28 7466777 4592202 989153.875 1 67 2013OCT23_C_SwingBridge_2 9.28 7487562 4624757.5 1202671.375 1 68 2013OCT23_C_SwingBridge_3 9.28 7372688.5 4509710 972377.563 1 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 9.28 7284930.5 4572664.5 1156906.875 1 72 2013OCT23_C_KingstonLn1_2 9.28 7148123.5 4223561 861790.438 1 73 2013OCT23_C_KingstonLn1_3 9.28 7159707 3558353.25 849847.625 1 74 2013OCT23_C_SolvA_25 7217.988 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 9.28 7943362 5379306.5 1481009.75 1 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 9.28 7148704.5 4435527 932795.063 1 80 2013OCT23_C_KingstonLn2_2 9.28 7410778.5 4396118.5 945910.938 1 81 2013OCT23_C_KingstonLn2_3 9.28 7167935.5 4367175.5 923829.063 1 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 8.485 #DIV/0! 84 2013OCT23_C_Cordova_1 9.28 7288789 4331911 918896.125 1 85 2013OCT23_C_Cordova_2 9.28 7269939 4289416.5 868312.938 1 86 2013OCT23_C_Cordova_3 9.28 7172109 4295808.5 873234.875 1 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 9.28 7632332.5 4755402 1034129.063 1 90 2013OCT23_C_Tuckahoe1_2 9.28 7563471 4796234.5 1064496.5 1 91 2013OCT23_C_Tuckahoe1_3 9.28 7666283 4743562 1010859.75 1 92 2013OCT23_C_SolvA_33 466.075 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 9.28 7438296.5 4753862 1021783.188 1 95 2013OCT23_C_Tuckahoe2_2 9.28 7565270.5 4855088 1070822.5 1 96 2013OCT23_C_Tuckahoe2_3 9.28 7616794 4665026 997071.375 1 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 9.28 6809881.5 4216296 862939 1 100 2013OCT23_C_GermanBranch_2 9.28 7003872 4256276 867153.938 1 101 2013OCT23_C_GermanBranch_3 9.28 7032284 4523676.5 1118057.625 1 160 102 2013OCT23_C_SolvA_37 8.159 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 9.28 7725227 4903408.5 1079066.75 1 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 0.975 #DIV/0! 107 2013OCT23_C_Greensboro1_1 9.28 7449237 4857468.5 1079986.625 1 108 2013OCT23_C_Greensboro1_2 9.28 7580331.5 4752996.5 1028561.313 1 109 2013OCT23_C_Greensboro1_3 9.28 7435847 4905422.5 1090691.625 1 110 2013OCT23_C_SolvA_41 57.59 1339.823 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 9.28 7350119 4227936.5 846560.75 1 113 2013OCT23_C_Greensboro2_2 9.28 7117618.5 4419924.5 941708.938 1 114 2013OCT23_C_Greensboro2_3 9.28 6954306 4353068 915471.375 1 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 9.28 7267272.5 4432577.5 952710.313 1 118 2013OCT23_C_BeaverDam_2 9.28 7357692.5 4336508.5 914195.125 1 119 2013OCT23_C_BeaverDam_3 9.28 7156340.5 4464639.5 945386.938 1 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 5.884 #DIV/0! 122 2013OCT23_C_LongMarsh_1 9.27 6242030 2808936.25 672348.438 1 123 2013OCT23_C_LongMarsh_2 9.27 6196174 3399033.25 665481.063 1 124 2013OCT23_C_LongMarsh_3 9.27 6141146 3379055 655489.313 1 125 2013OCT23_C_SolvA_47 1081.78 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 9.28 7099696 4654841 1199678.625 1 128 2013OCT23_C_0-05_Std_2 Standard 0.05 9.28 7170102.5 4485661.5 972090.063 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 9.28 8028010 5447178 1255183.875 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 9.28 7688218 5035462.5 1114843.5 1 131 2013OCT23_C_1_Std_2 Standard 1 9.28 7512617 4865585.5 1313113.75 1 132 2013OCT23_C_5_Std_2 Standard 5 9.28 7919687 5386686 1286567.625 1 133 2013OCT23_C_10_Std_2 Standard 10 9.28 7795934.5 5202372 1178207.5 1 134 2013OCT23_C_25_Std_2 Standard 25 9.28 7587223.5 4987892 1133587.625 1 135 2013OCT23_C_50_Std_2 Standard 50 9.28 7752195.5 4948091 1051204.375 1 136 2013OCT23_C_100_Std_2 Standard 100 9.28 7515170.5 4549465.5 967171.75 1 137 2013OCT23_C_200_Stds_2 Standard 200 9.28 7609506.5 4377688 912435.5 1 138 2013OCT23_C_SolvA_49 518.595 #DIV/0! 139 2013OCT23_C_Surrogate_2 69.324 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 577.969 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 15: Acesulfame yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! 161 2 2013OCT23_C_Lab Blk #DIV/0! 3 2013OCT23_C_Travel Blk #DIV/0! 4 2013OCT23_C_0-01_Std Standard 0.01 #DIV/0! 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 2.003 #DIV/0! 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 #DIV/0! 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 1.46 1832.278 211.854 #DIV/0! 0.5 3% 8 2013OCT23_C_1_Std Standard 1 1.45 4675.893 #DIV/0! 1.3 32% 9 2013OCT23_C_5_Std Standard 5 1.46 21966.928 2664.441 #DIV/0! 6.2 24% 10 2013OCT23_C_10_Std Standard 10 1.46 46737.102 5308.45 #DIV/0! 13.2 32% 11 2013OCT23_C_25_Std Standard 25 1.46 114307.484 14627.596 #DIV/0! 32.3 29% 12 2013OCT23_C_50_Std Standard 50 1.46 199378.141 24443.262 #DIV/0! 56.3 13% 13 2013OCT23_C_100_Std Standard 100 1.46 389068.5 47674.426 #DIV/0! 109.8 10% 14 2013OCT23_C_200_Stds Standard 200 1.46 728292.563 93161.75 #DIV/0! 205.6 3% 15 2013OCT23_C_SolvA_2 0.339 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.03 -38% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.1 -30% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.4 -16% 19 2013OCT23_C_MM_0 1.46 1128.316 63.011 #DIV/0! 1.2 15% 20 2013OCT23_C_MM_1 1.45 3856.406 336.6 #DIV/0! 5.6 11% 21 2013OCT23_C_MM_5 1.46 20598.287 2881.145 #DIV/0! 11.3 13% 22 2013OCT23_C_MM_10 1.46 47036.035 5899.218 #DIV/0! 29.5 18% 23 2013OCT23_C_MM_25 1.46 97453.344 11941.418 #DIV/0! 52.5 5% 24 2013OCT23_C_MM_50 1.45 184641.813 22761.309 #DIV/0! 101.0 1% 25 2013OCT23_C_MM_100 1.45 383829.281 49875.25 #DIV/0! 185.1 -7% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 1.46 1741.143 95.445 #DIV/0! 4.92 4.58 29 2013OCT23_C_NOAA_2 1.47 1352.171 99.014 #DIV/0! 3.82 3.55 30 2013OCT23_C_NOAA_3 1.44 2002.628 84.338 #DIV/0! 5.65 5.26 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 1.46 1446.74 8.683 #DIV/0! 4.08 3.80 34 2013OCT23_C_HornPt_2 #DIV/0! 0.00 0.00 35 2013OCT23_C_HornPt_3 1.45 1359.639 31.808 #DIV/0! 3.84 3.57 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 1.43 1943.659 113.26 #DIV/0! 5.49 5.11 39 2013OCT23_C_50Bridge1_2 1.45 1912.92 120.507 #DIV/0! 5.40 5.03 40 2013OCT23_C_50Bridge1_3 1.47 1753.956 176.743 #DIV/0! 4.95 4.61 41 2013OCT23_C_SolvA_11 0.535 #DIV/0! 42 2013OCT23_C_SolvA_12 0.668 #DIV/0! 43 2013OCT23_C_50Bridge2_1 1.47 1026.734 38.341 #DIV/0! 2.90 2.70 44 2013OCT23_C_50Bridge2_2 1.45 1069.166 33.495 #DIV/0! 3.02 2.81 45 2013OCT23_C_50Bridge2_3 1.46 1419.913 28.414 #DIV/0! 4.01 3.73 46 2013OCT23_C_SolvA_13 0.033 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 162 48 2013OCT23_C_QC_Std25_1 1.45 104238.344 13102.042 #DIV/0! 294.25 273.99 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 1.45 1435.021 19.153 #DIV/0! 4.05 3.77 52 2013OCT23_C_50BridgeFurtherPt_2 1.46 1345.345 94.183 #DIV/0! 3.80 3.54 53 2013OCT23_C_50BridgeFurtherPt_3 1.44 994.507 101.342 #DIV/0! 2.81 2.61 54 2013OCT23_C_SolvA_17 0.388 #DIV/0! 55 2013OCT23_C_SolvA_18 0.114 #DIV/0! 56 2013OCT23_C_PrestonLn_1 1.44 676.375 21.544 #DIV/0! 1.91 1.78 57 2013OCT23_C_PrestonLn_2 1.46 228.572 10.674 #DIV/0! 0.65 0.60 58 2013OCT23_C_PrestonLn_3 1.45 494.36 31.116 #DIV/0! 1.40 1.30 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 1.44 259.806 #DIV/0! 0.73 0.68 62 2013OCT23_C_FrazierPt_2 1.45 373.768 1.329 #DIV/0! 1.06 0.98 63 2013OCT23_C_FrazierPt_3 1.44 404.496 #DIV/0! 1.14 1.06 64 2013OCT23_C_SolvA_21 0.358 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.324 #DIV/0! 0.00 0.00 67 2013OCT23_C_SwingBridge_2 #DIV/0! 0.00 0.00 68 2013OCT23_C_SwingBridge_3 1.47 196.619 #DIV/0! 0.56 0.52 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 #DIV/0! 0.00 0.00 72 2013OCT23_C_KingstonLn1_2 16.093 #DIV/0! 0.00 0.00 73 2013OCT23_C_KingstonLn1_3 0.433 #DIV/0! 0.00 0.00 74 2013OCT23_C_SolvA_25 0.803 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 1.46 99263.734 12676.81 #DIV/0! 280.21 260.91 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 #DIV/0! 0.00 0.00 80 2013OCT23_C_KingstonLn2_2 1.42 124.434 5.396 #DIV/0! 0.35 0.33 81 2013OCT23_C_KingstonLn2_3 1.44 114.65 0.152 #DIV/0! 0.32 0.30 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 1.46 485.275 30.401 #DIV/0! 1.37 1.28 85 2013OCT23_C_Cordova_2 1.46 718.935 76.452 #DIV/0! 2.03 1.89 86 2013OCT23_C_Cordova_3 1.46 719.058 64.387 #DIV/0! 2.03 1.89 87 2013OCT23_C_SolvA_31 0.373 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 0.604 #DIV/0! 0.00 0.00 90 2013OCT23_C_Tuckahoe1_2 1.356 #DIV/0! 0.00 0.00 91 2013OCT23_C_Tuckahoe1_3 1.45 110.523 4.224 #DIV/0! 0.31 0.29 92 2013OCT23_C_SolvA_33 0.331 #DIV/0! 163 93 2013OCT23_C_SolvA_34 4.916 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 1.46 24.392 0.43 #DIV/0! 0.07 0.06 95 2013OCT23_C_Tuckahoe2_2 0.813 #DIV/0! 0.00 0.00 96 2013OCT23_C_Tuckahoe2_3 0.106 #DIV/0! 0.00 0.00 97 2013OCT23_C_SolvA_35 0.46 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 1.46 160.032 6.27 #DIV/0! 0.45 0.42 100 2013OCT23_C_GermanBranch_2 1.47 98.748 0.43 #DIV/0! 0.28 0.26 101 2013OCT23_C_GermanBranch_3 1.43 143.095 0.918 #DIV/0! 0.40 0.38 102 2013OCT23_C_SolvA_37 0.148 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 1.46 105270.547 14062.16 #DIV/0! 297.17 276.70 105 2013OCT23_C_SolvA_39 0.422 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 1.4 985.601 51.244 #DIV/0! 2.78 2.59 108 2013OCT23_C_Greensboro1_2 1.44 1030.785 0.408 #DIV/0! 2.91 2.71 109 2013OCT23_C_Greensboro1_3 1.45 1185.215 28.561 #DIV/0! 3.35 3.12 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 1.46 728.904 25.616 #DIV/0! 2.06 1.92 113 2013OCT23_C_Greensboro2_2 1.44 812.366 17.304 #DIV/0! 2.29 2.14 114 2013OCT23_C_Greensboro2_3 1.47 968.63 35.892 #DIV/0! 2.73 2.55 115 2013OCT23_C_SolvA_43 0.026 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 #DIV/0! 0.00 0.00 118 2013OCT23_C_BeaverDam_2 #DIV/0! 0.00 0.00 119 2013OCT23_C_BeaverDam_3 #DIV/0! 0.00 0.00 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 #DIV/0! 0.00 0.00 123 2013OCT23_C_LongMarsh_2 #DIV/0! 0.00 0.00 124 2013OCT23_C_LongMarsh_3 1.32 0.426 #DIV/0! 0.00 0.00 125 2013OCT23_C_SolvA_47 0.813 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 0.444 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 1.46 109.368 1.433 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 1.43 249.505 11.621 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 1.46 1488.906 135.913 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 1.45 4086.188 267.743 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 1.45 19671.641 2294.319 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 1.46 40169.176 4354.484 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 1.46 104371.883 12320.736 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 1.46 185919.391 22980.879 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 1.46 357615.594 43460.172 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 1.46 655690.438 83004.742 #DIV/0! 138 2013OCT23_C_SolvA_49 0.007 #DIV/0! 164 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 0.831 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 16: Acesulfame-d4 yes=1,no=0 Ident'd? Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 1.44 257790.906 44058.867 0 293854 Avg 3 2013OCT23_C_Travel Blk 1.44 285370.063 49630.949 0 13% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 1.44 277660.531 47124.605 0 5 2013OCT23_C_0-05_Std Standard 0.05 1.45 293853.656 51899.031 0 6 2013OCT23_C_0-1_Std Standard 0.1 1.45 286306.563 48929.285 0 7 2013OCT23_C_0-5_Std Standard 0.5 1.45 298063.031 49471.832 0 8 2013OCT23_C_1_Std Standard 1 1.44 300524.406 48979.434 0 9 2013OCT23_C_5_Std Standard 5 1.44 293081.625 44744.09 0 10 2013OCT23_C_10_Std Standard 10 1.45 286176 44278.301 0 11 2013OCT23_C_25_Std Standard 25 1.45 287970.469 51409.34 0 12 2013OCT23_C_50_Std Standard 50 1.45 277235.969 47369.766 0 13 2013OCT23_C_100_Std Standard 100 1.44 251373.922 43088.672 0 14 2013OCT23_C_200_Stds Standard 200 1.44 249916.703 42605.418 0 15 2013OCT23_C_SolvA_2 #DIV/0! 16 2013OCT23_C_Surrogate_1 #DIV/0! 17 2013OCT23_C_SolvA_3 0.065 #DIV/0! 18 2013OCT23_C_SolvA_4 #DIV/0! 19 2013OCT23_C_MM_0 1.44 281091.719 48007.949 0 20 2013OCT23_C_MM_1 1.45 233870.891 41011.648 0 21 2013OCT23_C_MM_5 1.45 246108.578 44329.922 0 22 2013OCT23_C_MM_10 1.45 263861.25 47846.762 0 23 2013OCT23_C_MM_25 1.44 230145.984 38833.895 0 24 2013OCT23_C_MM_50 1.44 244609.766 44657.574 0 25 2013OCT23_C_MM_100 1.44 266358.531 41813.277 0 26 2013OCT23_C_SolvA_5 #DIV/0! 27 2013OCT23_C_SolvA_6 #DIV/0! 28 2013OCT23_C_NOAA_1 1.44 150775.5 28944.168 0 29 2013OCT23_C_NOAA_2 1.44 157388.094 27845.057 0 30 2013OCT23_C_NOAA_3 1.45 150256.594 26158.432 0 31 2013OCT23_C_SolvA_7 0.391 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 1.45 155257.984 28688.051 0 34 2013OCT23_C_HornPt_2 1.44 161734.781 28285.162 0 35 2013OCT23_C_HornPt_3 1.44 166366.031 29511.133 0 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 1.44 199268.984 35803.934 0 165 39 2013OCT23_C_50Bridge1_2 1.44 197541 34138.699 0 40 2013OCT23_C_50Bridge1_3 1.44 199472.047 34594.531 0 41 2013OCT23_C_SolvA_11 0.613 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 1.44 160068.453 26752.664 0 44 2013OCT23_C_50Bridge2_2 1.44 172755.094 28044.379 0 45 2013OCT23_C_50Bridge2_3 1.44 183690.219 33480.023 0 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 0.406 #DIV/0! 48 2013OCT23_C_QC_Std25_1 1.45 247835.063 42620.613 0 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 0.834 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 1.45 188965.578 33841.531 0 52 2013OCT23_C_50BridgeFurtherPt_2 1.45 176166.188 32029.744 0 53 2013OCT23_C_50BridgeFurtherPt_3 1.44 172516.172 28586.672 0 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 0.43 #DIV/0! 56 2013OCT23_C_PrestonLn_1 1.44 259703.391 45795.617 0 57 2013OCT23_C_PrestonLn_2 1.44 249700.266 40373.371 0 58 2013OCT23_C_PrestonLn_3 1.44 245461.859 39917.75 0 59 2013OCT23_C_SolvA_19 0.633 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 1.44 220965.594 38877.406 0 62 2013OCT23_C_FrazierPt_2 1.45 223102.734 37132.527 0 63 2013OCT23_C_FrazierPt_3 1.45 208986.797 34837.223 0 64 2013OCT23_C_SolvA_21 0.645 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 1.44 249025.109 45322.371 0 67 2013OCT23_C_SwingBridge_2 1.44 248927.828 43841.883 0 68 2013OCT23_C_SwingBridge_3 1.45 249566 40533.605 0 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 1.45 248124.922 40913.773 0 72 2013OCT23_C_KingstonLn1_2 1.45 232901.063 40375.734 0 73 2013OCT23_C_KingstonLn1_3 1.45 230031.25 39647.43 0 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 0.451 #DIV/0! 76 2013OCT23_C_QC_Std25_2 1.45 236046.172 40266.496 0 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 0.156 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 1.45 270176.844 46052.488 0 80 2013OCT23_C_KingstonLn2_2 1.44 259550.844 41627.941 0 81 2013OCT23_C_KingstonLn2_3 1.44 246897.188 43155.453 0 82 2013OCT23_C_SolvA_29 0.026 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 166 84 2013OCT23_C_Cordova_1 1.44 248854.203 43676.352 0 85 2013OCT23_C_Cordova_2 1.45 233815.031 40684.273 0 86 2013OCT23_C_Cordova_3 1.45 233638.578 40990 0 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 1.45 273731.781 46170.938 0 90 2013OCT23_C_Tuckahoe1_2 1.44 271310.688 47626.5 0 91 2013OCT23_C_Tuckahoe1_3 1.44 273030.969 47671.512 0 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 1.45 261388.969 45616.867 0 95 2013OCT23_C_Tuckahoe2_2 1.44 255389.719 41116.168 0 96 2013OCT23_C_Tuckahoe2_3 1.44 255133 43783.184 0 97 2013OCT23_C_SolvA_35 0.586 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 1.44 247031.188 42419.344 0 100 2013OCT23_C_GermanBranch_2 1.44 250943.688 43702.008 0 101 2013OCT23_C_GermanBranch_3 1.44 259541.438 40021.258 0 102 2013OCT23_C_SolvA_37 0.086 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 1.45 241633.891 40969.5 0 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 1.44 281598.281 45976.637 0 108 2013OCT23_C_Greensboro1_2 1.44 264232.719 43253.672 0 109 2013OCT23_C_Greensboro1_3 1.44 260162.531 44133.898 0 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 0.766 #DIV/0! 112 2013OCT23_C_Greensboro2_1 1.45 242256.922 39503.266 0 113 2013OCT23_C_Greensboro2_2 1.44 252928.641 41852.73 0 114 2013OCT23_C_Greensboro2_3 1.44 247730.328 40935.441 0 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 0.011 #DIV/0! 117 2013OCT23_C_BeaverDam_1 1.45 275467 47574.852 0 118 2013OCT23_C_BeaverDam_2 1.45 259533.063 41354.715 0 119 2013OCT23_C_BeaverDam_3 1.45 259623.625 44132.914 0 120 2013OCT23_C_SolvA_45 0.406 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 1.44 219204.281 38307.473 0 123 2013OCT23_C_LongMarsh_2 1.44 209884.859 35593.242 0 124 2013OCT23_C_LongMarsh_3 1.45 215018.75 37383.352 0 125 2013OCT23_C_SolvA_47 0.399 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 1.44 257770.172 45481.191 0 128 2013OCT23_C_0-05_Std_2 Standard 0.05 1.45 249120.219 41954.523 0 167 129 2013OCT23_C_0-1_Std_2 Standard 0.1 1.45 239533.734 39696.148 0 130 2013OCT23_C_0-5_Std_2 Standard 0.5 1.45 232370.859 40014.008 0 131 2013OCT23_C_1_Std_2 Standard 1 1.44 258191.672 45639.727 0 132 2013OCT23_C_5_Std_2 Standard 5 1.45 260382.125 45224.551 0 133 2013OCT23_C_10_Std_2 Standard 10 1.45 265064 45753.395 0 134 2013OCT23_C_25_Std_2 Standard 25 1.44 255326.391 46169.273 0 135 2013OCT23_C_50_Std_2 Standard 50 1.45 256770.688 41316.348 0 136 2013OCT23_C_100_Std_2 Standard 100 1.45 229643 38046.75 0 137 2013OCT23_C_200_Stds_2 Standard 200 1.45 215024.359 37712.57 0 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 0.341 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 0.23 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 17: Cyclamate yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! 2 2013OCT23_C_Lab Blk #DIV/0! 3 2013OCT23_C_Travel Blk 2.16 68.385 1.571 #DIV/0! 4 2013OCT23_C_0-01_Std Standard 0.01 #DIV/0! 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 2.14 244.543 0.318 #DIV/0! 0.05 2% 6 2013OCT23_C_0-1_Std Standard 0.1 2.14 443.115 #DIV/0! 0.09 -7% 7 2013OCT23_C_0-5_Std Standard 0.5 2.14 3321.708 24.367 #DIV/0! 0.7 39% 8 2013OCT23_C_1_Std Standard 1 2.14 6590.104 7.875 #DIV/0! 1.4 38% 9 2013OCT23_C_5_Std Standard 5 2.14 29908.135 464.791 #DIV/0! 6.3 25% 10 2013OCT23_C_10_Std Standard 10 2.14 59128.633 977.231 #DIV/0! 12.4 24% 11 2013OCT23_C_25_Std Standard 25 2.14 150318.703 2377.995 #DIV/0! 31.4 26% 12 2013OCT23_C_50_Std Standard 50 2.14 266742.938 5333.893 #DIV/0! 55.8 12% 13 2013OCT23_C_100_Std Standard 100 2.14 497229.656 10645.028 #DIV/0! 104.0 4% 14 2013OCT23_C_200_Stds Standard 200 2.14 934955.375 22515.732 #DIV/0! 195.6 -2% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -74% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.05 -1% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.0 -53% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.3 -40% 19 2013OCT23_C_MM_0 2.14 283.637 11.899 #DIV/0! 1.0 0% 20 2013OCT23_C_MM_1 2.14 4394.486 60.816 #DIV/0! 3.8 -24% 21 2013OCT23_C_MM_5 2.14 26709.699 366.905 #DIV/0! 7.7 -23% 22 2013OCT23_C_MM_10 2.14 59547.539 1366.26 #DIV/0! 19.9 -20% 23 2013OCT23_C_MM_25 2.14 130037.719 2730.486 #DIV/0! 37.0 -26% 24 2013OCT23_C_MM_50 2.14 236514.781 5029.979 #DIV/0! 66.3 -34% 25 2013OCT23_C_MM_100 2.14 506475.719 12546.581 #DIV/0! 119.5 -40% 26 2013OCT23_C_SolvA_5 2.14 2.696 1.228 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 2.17 35.688 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 2.13 415.925 66.457 #DIV/0! 0.87 0.83 168 29 2013OCT23_C_NOAA_2 2.14 399.654 4.22 #DIV/0! 0.84 0.80 30 2013OCT23_C_NOAA_3 2.14 552.331 4.928 #DIV/0! 1.16 1.10 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 #DIV/0! 0.00 0.00 34 2013OCT23_C_HornPt_2 2.14 61.627 9.399 #DIV/0! 0.13 0.12 35 2013OCT23_C_HornPt_3 2.12 35.464 11.819 #DIV/0! 0.07 0.07 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.14 286.78 16.704 #DIV/0! 0.60 0.57 39 2013OCT23_C_50Bridge1_2 2.14 194.278 34.997 #DIV/0! 0.41 0.39 40 2013OCT23_C_50Bridge1_3 2.14 420.74 13.526 #DIV/0! 0.88 0.84 41 2013OCT23_C_SolvA_11 0.096 #DIV/0! 42 2013OCT23_C_SolvA_12 2.15 23.854 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.14 147.427 10.056 #DIV/0! 0.31 0.29 44 2013OCT23_C_50Bridge2_2 2.14 181.597 14.393 #DIV/0! 0.38 0.36 45 2013OCT23_C_50Bridge2_3 2.14 118.305 12.222 #DIV/0! 0.25 0.24 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 2.14 129493.258 2423.49 #DIV/0! 270.89 258.41 49 2013OCT23_C_SolvA_15 2.14 55.252 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 2.12 61.126 4.112 #DIV/0! 0.13 0.12 52 2013OCT23_C_50BridgeFurtherPt_2 2.13 22.471 16.106 #DIV/0! 0.05 0.04 53 2013OCT23_C_50BridgeFurtherPt_3 2.15 42.501 14.769 #DIV/0! 0.09 0.08 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 23.172 #DIV/0! 0.00 0.00 57 2013OCT23_C_PrestonLn_2 2.15 249.064 26.584 #DIV/0! 0.52 0.50 58 2013OCT23_C_PrestonLn_3 #DIV/0! 0.00 0.00 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 16.363 #DIV/0! 0.00 0.00 62 2013OCT23_C_FrazierPt_2 2.16 142.457 20.35 #DIV/0! 0.30 0.28 63 2013OCT23_C_FrazierPt_3 2.16 168.473 14.827 #DIV/0! 0.35 0.34 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.14 55.443 16.66 #DIV/0! 0.12 0.11 67 2013OCT23_C_SwingBridge_2 2.14 97.359 22.988 #DIV/0! 0.20 0.19 68 2013OCT23_C_SwingBridge_3 2.14 213.881 19.08 #DIV/0! 0.45 0.43 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 #DIV/0! 0.00 0.00 72 2013OCT23_C_KingstonLn1_2 2.12 22.025 15.926 #DIV/0! 0.05 0.04 73 2013OCT23_C_KingstonLn1_3 2.13 105.92 14.353 #DIV/0! 0.22 0.21 169 74 2013OCT23_C_SolvA_25 2.18 1.397 0.12 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 2.14 89252.789 1531.216 #DIV/0! 186.71 178.11 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 2.13 38.959 14.053 #DIV/0! 0.08 0.08 80 2013OCT23_C_KingstonLn2_2 2.12 40.163 9.789 #DIV/0! 0.08 0.08 81 2013OCT23_C_KingstonLn2_3 2.14 42.825 20.25 #DIV/0! 0.09 0.09 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.13 96.994 9.98 #DIV/0! 0.20 0.19 85 2013OCT23_C_Cordova_2 2.14 74.406 9.549 #DIV/0! 0.16 0.15 86 2013OCT23_C_Cordova_3 2.14 89.787 14.366 #DIV/0! 0.19 0.18 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 2.14 11.597 10.548 #DIV/0! 0.02 0.02 90 2013OCT23_C_Tuckahoe1_2 2.13 13.856 9.438 #DIV/0! 0.03 0.03 91 2013OCT23_C_Tuckahoe1_3 2.12 23.157 12.171 #DIV/0! 0.05 0.05 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.13 14.363 12.125 #DIV/0! 0.03 0.03 95 2013OCT23_C_Tuckahoe2_2 2.13 10.273 9.584 #DIV/0! 0.02 0.02 96 2013OCT23_C_Tuckahoe2_3 2.12 53.381 4.324 #DIV/0! 0.11 0.11 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 2.12 20.496 6.3 #DIV/0! 0.04 0.04 100 2013OCT23_C_GermanBranch_2 2.13 7.81 6.759 #DIV/0! 0.02 0.02 101 2013OCT23_C_GermanBranch_3 2.13 19.51 4.355 #DIV/0! 0.04 0.04 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 2.14 110658.125 1711.942 #DIV/0! 231.49 220.82 105 2013OCT23_C_SolvA_39 2.437 #DIV/0! 106 2013OCT23_C_SolvA_40 0.954 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.15 177.663 4.21 #DIV/0! 0.37 0.35 108 2013OCT23_C_Greensboro1_2 2.15 120.324 18.403 #DIV/0! 0.25 0.24 109 2013OCT23_C_Greensboro1_3 2.13 76.817 18.087 #DIV/0! 0.16 0.15 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 2.14 18.978 0.313 #DIV/0! 112 2013OCT23_C_Greensboro2_1 2.13 7.757 12.446 #DIV/0! 0.02 0.02 113 2013OCT23_C_Greensboro2_2 2.13 20.105 9.664 #DIV/0! 0.04 0.04 114 2013OCT23_C_Greensboro2_3 2.12 12.82 11.448 #DIV/0! 0.03 0.03 115 2013OCT23_C_SolvA_43 2.14 0.717 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 2.14 3.845 7.929 #DIV/0! 0.01 0.01 118 2013OCT23_C_BeaverDam_2 2.14 31.817 3.541 #DIV/0! 0.07 0.06 170 119 2013OCT23_C_BeaverDam_3 2.13 9.311 6.851 #DIV/0! 0.02 0.02 120 2013OCT23_C_SolvA_45 2.13 2.045 #DIV/0! 121 2013OCT23_C_SolvA_46 0.634 #DIV/0! 122 2013OCT23_C_LongMarsh_1 2.13 69.369 6.332 #DIV/0! 0.15 0.14 123 2013OCT23_C_LongMarsh_2 9.054 #DIV/0! 0.00 0.00 124 2013OCT23_C_LongMarsh_3 2.15 54.172 #DIV/0! 0.11 0.11 125 2013OCT23_C_SolvA_47 2.12 0.772 0.194 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 2.14 12.653 0.751 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 2.15 236.791 0.213 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 2.15 225.689 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 2.14 1428.963 58.176 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 2.14 4766.719 38.207 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 2.14 18219.82 333.744 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 2.14 36833.039 704.451 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 2.14 95157.773 1582.906 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 2.14 176848.641 3936.216 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 2.14 317120.375 6890.588 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 2.14 571223.875 14942.125 #DIV/0! 138 2013OCT23_C_SolvA_49 0.949 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 0.521 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 18: saccharine yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0.004 3.024 0 2 2013OCT23_C_Lab Blk 11.905 0 3 2013OCT23_C_Travel Blk 0.037 36.946 0 4 2013OCT23_C_0-01_Std Standard 0.01 0.404 5.704 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0.087 7.93 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 12.405 0 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 2.77 142.206 0 0.0 -100% 8 2013OCT23_C_1_Std Standard 1 1.84 1167.243 153.108 1536.91 1 1.3 26% 9 2013OCT23_C_5_Std Standard 5 1.84 6588.181 999.433 7417.932 1 7.1 42% 10 2013OCT23_C_10_Std Standard 10 1.85 13662.14 1863.683 14904.244 1 14.8 48% 11 2013OCT23_C_25_Std Standard 25 1.84 33573.602 5332.937 36585.926 1 36.3 45% 12 2013OCT23_C_50_Std Standard 50 1.85 56652.434 8550.485 63286.816 1 61.2 22% 13 2013OCT23_C_100_Std Standard 100 1.84 98296.227 16272.578 110638.641 1 106.3 6% 14 2013OCT23_C_200_Stds Standard 200 1.84 175070.5 30090.076 200494.719 1 189.2 -5% 15 2013OCT23_C_SolvA_2 0.224 5.187 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 0.241 3.954 #DIV/0! 0.00 -100% 17 2013OCT23_C_SolvA_3 6.34 1.627 #DIV/0! 0.0 -100% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.6 25% 171 19 2013OCT23_C_MM_0 1.84 2736.99 214.609 2927.451 1 1.3 29% 20 2013OCT23_C_MM_1 1.84 3792.301 331.674 4243.981 1 6.4 28% 21 2013OCT23_C_MM_5 1.84 8353.405 1099.416 9531.494 1 13.3 33% 22 2013OCT23_C_MM_10 1.84 14909.925 2485.873 17448.137 1 34.4 38% 23 2013OCT23_C_MM_25 1.84 29062.129 4278.883 32720.021 1 60.4 21% 24 2013OCT23_C_MM_50 1.84 48946.449 7875.839 53253.016 1 107.3 7% 25 2013OCT23_C_MM_100 1.84 99080.664 14720.16 102713.516 1 195.5 -2% 26 2013OCT23_C_SolvA_5 0.236 7.795 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 7.446 9.906 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 21.641 201.182 #DIV/0! 0.00 0.00 29 2013OCT23_C_NOAA_2 0.857 62.162 #DIV/0! 0.00 0.00 30 2013OCT23_C_NOAA_3 16.154 223.337 #DIV/0! 0.00 0.00 31 2013OCT23_C_SolvA_7 0.569 2.895 #DIV/0! 32 2013OCT23_C_SolvA_8 0.251 7.091 #DIV/0! 33 2013OCT23_C_HornPt_1 1.84 1736.227 168.039 2016.712 1 18.77 18.04 34 2013OCT23_C_HornPt_2 1.84 1817.163 208.563 2124.457 1 19.64 18.88 35 2013OCT23_C_HornPt_3 1.84 1677.943 171.052 2290.09 1 18.14 17.43 36 2013OCT23_C_SolvA_9 0.108 7.89 #DIV/0! 37 2013OCT23_C_SolvA_10 0.712 13.648 #DIV/0! 38 2013OCT23_C_50Bridge1_1 1.84 1289.628 130.862 1834.253 1 13.94 13.40 39 2013OCT23_C_50Bridge1_2 1.84 1407.18 157.028 1543.435 1 15.21 14.62 40 2013OCT23_C_50Bridge1_3 1.84 1268.856 220.195 1449.84 1 13.72 13.18 41 2013OCT23_C_SolvA_11 1.9 0.453 0.406 2.78 0 42 2013OCT23_C_SolvA_12 1.84 0.2 0.446 0.749 0 43 2013OCT23_C_50Bridge2_1 1.84 2810.158 401.169 3599.787 1 30.38 29.20 44 2013OCT23_C_50Bridge2_2 1.84 3308.682 387.828 3735.37 1 35.76 34.38 45 2013OCT23_C_50Bridge2_3 1.84 3049.805 359.945 3537.248 1 32.97 31.69 46 2013OCT23_C_SolvA_13 0.187 0.511 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 1.84 30208.252 4715.613 31849.652 1 326.53 313.86 49 2013OCT23_C_SolvA_15 0.271 1.553 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 1.84 1779.943 128.109 1755.659 1 19.24 18.49 52 2013OCT23_C_50BridgeFurtherPt_2 1.84 1431.848 107.185 1701.718 1 15.48 14.88 53 2013OCT23_C_50BridgeFurtherPt_3 1.84 1473.044 155.174 1839.185 1 15.92 15.30 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 0.102 0.085 #DIV/0! 56 2013OCT23_C_PrestonLn_1 1.85 1840.792 193.742 1991.244 1 19.90 19.13 57 2013OCT23_C_PrestonLn_2 1.84 1529.923 65.613 1975.789 1 16.54 15.90 58 2013OCT23_C_PrestonLn_3 1.84 1740.317 176.967 1811.405 1 18.81 18.08 59 2013OCT23_C_SolvA_19 0.217 1.716 #DIV/0! 60 2013OCT23_C_SolvA_20 0.204 3.025 #DIV/0! 61 2013OCT23_C_FrazierPt_1 1.84 570.192 18.559 755.718 1 6.16 5.92 62 2013OCT23_C_FrazierPt_2 1.8 653.621 112.996 820.182 1 7.07 6.79 63 2013OCT23_C_FrazierPt_3 1.84 642.121 41.353 796.755 1 6.94 6.67 172 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 0.287 0.969 #DIV/0! 66 2013OCT23_C_SwingBridge_1 0.329 39.502 #DIV/0! 0.00 0.00 67 2013OCT23_C_SwingBridge_2 0.518 8.475 #DIV/0! 0.00 0.00 68 2013OCT23_C_SwingBridge_3 0.801 94.673 #DIV/0! 0.00 0.00 69 2013OCT23_C_SolvA_23 2.724 #DIV/0! 70 2013OCT23_C_SolvA_24 1.474 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 1.84 1433.922 176.293 1946.818 1 15.50 14.90 72 2013OCT23_C_KingstonLn1_2 1.85 1335.663 159.12 1651.201 1 14.44 13.88 73 2013OCT23_C_KingstonLn1_3 1.86 1303.07 140.393 1839.712 1 14.09 13.54 74 2013OCT23_C_SolvA_25 0.314 0.347 #DIV/0! 75 2013OCT23_C_SolvA_26 0.009 #DIV/0! 76 2013OCT23_C_QC_Std25_2 1.85 30717.287 4567.323 34749.457 1 332.03 319.15 77 2013OCT23_C_SolvA_27 0.242 0.364 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 1.84 2395.297 213.473 2762.358 1 25.89 24.89 80 2013OCT23_C_KingstonLn2_2 1.85 2000.248 309.701 2372.159 1 21.62 20.78 81 2013OCT23_C_KingstonLn2_3 1.84 2007.469 197.841 2564.731 1 21.70 20.86 82 2013OCT23_C_SolvA_29 0.361 0.655 #DIV/0! 83 2013OCT23_C_SolvA_30 0.319 8.909 #DIV/0! 84 2013OCT23_C_Cordova_1 1.82 371.458 4.448 708.713 1 4.02 3.86 85 2013OCT23_C_Cordova_2 1.83 313.978 38.874 636.126 1 3.39 3.26 86 2013OCT23_C_Cordova_3 1.85 322.757 4.739 602.876 1 3.49 3.35 87 2013OCT23_C_SolvA_31 5.602 #DIV/0! 88 2013OCT23_C_SolvA_32 0.218 6.843 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 1.85 1622.261 183.817 1894.901 1 17.54 16.85 90 2013OCT23_C_Tuckahoe1_2 1.87 1673.718 145.463 1694.348 1 18.09 17.39 91 2013OCT23_C_Tuckahoe1_3 1.85 1349.482 121.269 1525.88 1 14.59 14.02 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 0.234 5.251 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 0.226 74.338 #DIV/0! 0.00 0.00 95 2013OCT23_C_Tuckahoe2_2 2.36 108.417 #DIV/0! 0.00 0.00 96 2013OCT23_C_Tuckahoe2_3 0.805 43.858 #DIV/0! 0.00 0.00 97 2013OCT23_C_SolvA_35 0.333 6.665 #DIV/0! 98 2013OCT23_C_SolvA_36 1.533 2.429 #DIV/0! 99 2013OCT23_C_GermanBranch_1 0.343 #DIV/0! 0.00 0.00 100 2013OCT23_C_GermanBranch_2 2.481 98.206 #DIV/0! 0.00 0.00 101 2013OCT23_C_GermanBranch_3 #DIV/0! 0.00 0.00 102 2013OCT23_C_SolvA_37 0.319 0.049 #DIV/0! 103 2013OCT23_C_SolvA_38 0.449 0.74 #DIV/0! 104 2013OCT23_C_QC_Std25_3 1.85 30702.6 5459.699 34833.883 1 331.87 318.99 105 2013OCT23_C_SolvA_39 0.173 5.793 #DIV/0! 106 2013OCT23_C_SolvA_40 2.897 #DIV/0! 107 2013OCT23_C_Greensboro1_1 1.85 922.177 78.002 1344.02 1 9.97 9.58 108 2013OCT23_C_Greensboro1_2 1.86 838.664 57.677 1216.473 1 9.07 8.71 173 109 2013OCT23_C_Greensboro1_3 1.86 966.036 59.223 1251.24 1 10.44 10.04 110 2013OCT23_C_SolvA_41 0.675 1.942 #DIV/0! 111 2013OCT23_C_SolvA_42 0.87 6.878 #DIV/0! 112 2013OCT23_C_Greensboro2_1 1.85 686.557 33.025 885.928 1 7.42 7.13 113 2013OCT23_C_Greensboro2_2 1.85 691.89 115.835 841.825 1 7.48 7.19 114 2013OCT23_C_Greensboro2_3 1.85 756.165 33.32 793.123 1 8.17 7.86 115 2013OCT23_C_SolvA_43 0.177 7.092 #DIV/0! 116 2013OCT23_C_SolvA_44 0.079 0.719 #DIV/0! 117 2013OCT23_C_BeaverDam_1 1.85 12145.845 1753.175 13754.679 1 131.29 126.19 118 2013OCT23_C_BeaverDam_2 1.85 11790.259 1762.193 13654.122 1 127.44 122.50 119 2013OCT23_C_BeaverDam_3 1.85 11326.348 1692.614 13097.013 1 122.43 117.68 120 2013OCT23_C_SolvA_45 0.222 0.154 #DIV/0! 121 2013OCT23_C_SolvA_46 0.237 4.077 #DIV/0! 122 2013OCT23_C_LongMarsh_1 52.762 #DIV/0! 0.00 0.00 123 2013OCT23_C_LongMarsh_2 0.239 70.62 #DIV/0! 0.00 0.00 124 2013OCT23_C_LongMarsh_3 0.028 #DIV/0! 0.00 0.00 125 2013OCT23_C_SolvA_47 0.331 0.075 #DIV/0! 126 2013OCT23_C_SolvA_48 0.035 0.228 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 0.108 8.761 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 0.687 22.82 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 10.861 8.261 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 1.85 580.485 673.53 0 131 2013OCT23_C_1_Std_2 Standard 1 1.85 1195.232 125.529 1384.982 1 132 2013OCT23_C_5_Std_2 Standard 5 1.85 5933.538 697.008 7299.464 1 133 2013OCT23_C_10_Std_2 Standard 10 1.85 12300.422 1791.854 14044.234 1 134 2013OCT23_C_25_Std_2 Standard 25 1.85 31856.037 4992.529 35554.242 1 135 2013OCT23_C_50_Std_2 Standard 50 1.85 55901.242 8526.864 61794.953 1 136 2013OCT23_C_100_Std_2 Standard 100 1.85 99294.531 15762.505 111965.922 1 137 2013OCT23_C_200_Stds_2 Standard 200 1.85 180835.641 28046.289 199479.875 1 138 2013OCT23_C_SolvA_49 0.343 11.435 #DIV/0! 139 2013OCT23_C_Surrogate_2 0.273 5.904 #DIV/0! 140 2013OCT23_C_SolvA_50 0.384 2.04 #DIV/0! 141 2013OCT23_C_SolvA_51 0.762 2.54 #DIV/0! 142 2013OCT23_C_SolvA_52 0.169 0.042 #DIV/0! 143 2013OCT23_C_SolvA_53 0.366 0.009 #DIV/0! Compound 19: 2.4-D yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0.261 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0 4 2013OCT23_C_0-01_Std Standard 0.01 0.438 10.134 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 0.944 12.591 0 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 1.842 0 0.0 -100% 8 2013OCT23_C_1_Std Standard 1 6.17 2850.221 114.469 0 1.1 12% 174 9 2013OCT23_C_5_Std Standard 5 6.17 16400.371 1077.588 353.551 1 6.4 29% 10 2013OCT23_C_10_Std Standard 10 6.18 30676.197 2715.561 968.739 1 12.1 21% 11 2013OCT23_C_25_Std Standard 25 6.19 77317.219 6119.085 1535.486 1 30.4 22% 12 2013OCT23_C_50_Std Standard 50 6.19 139203.063 12230.813 2634.709 1 54.7 9% 13 2013OCT23_C_100_Std Standard 100 6.16 269535.375 24000.219 4933.44 1 106.0 6% 14 2013OCT23_C_200_Stds Standard 200 6.16 501326.094 47362.262 10491.839 1 197.1 -1% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.00 -100% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.2 109% 18 2013OCT23_C_SolvA_4 #DIV/0! 0.5 2% 19 2013OCT23_C_MM_0 6.16 8554.947 671.645 120.981 1 1.1 13% 20 2013OCT23_C_MM_1 6.18 10173.895 963.862 320.359 1 5.8 17% 21 2013OCT23_C_MM_5 6.19 24630.965 1771.687 581.61 1 11.7 17% 22 2013OCT23_C_MM_10 6.19 45943.742 3381.069 811.507 1 29.3 17% 23 2013OCT23_C_MM_25 6.17 87381.883 6859.21 1930.891 1 53.4 7% 24 2013OCT23_C_MM_50 6.16 144911.031 14076.053 2671.801 1 101.9 2% 25 2013OCT23_C_MM_100 6.17 337484.406 29992.559 5934.534 1 195.4 -2% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 5.563 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 6.18 5203.669 334.57 254.523 1 20.46 16.36 29 2013OCT23_C_NOAA_2 6.17 4671.946 344.52 122.949 1 18.37 14.69 30 2013OCT23_C_NOAA_3 6.18 4556.79 545.878 102.742 1 17.92 14.33 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 1.703 #DIV/0! 33 2013OCT23_C_HornPt_1 6.18 5315.703 324.38 0 20.90 16.72 34 2013OCT23_C_HornPt_2 6.16 5763.685 168.173 0 22.66 18.13 35 2013OCT23_C_HornPt_3 6.17 5854.961 342.881 0 23.02 18.41 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 6.15 4152.222 347.609 0 16.33 13.06 39 2013OCT23_C_50Bridge1_2 6.15 5345.377 273.066 185.636 1 21.02 16.81 40 2013OCT23_C_50Bridge1_3 6.17 6301.367 484.347 0 24.78 19.82 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 6.16 4018.055 231.783 0 15.80 12.64 44 2013OCT23_C_50Bridge2_2 6.15 4905.155 242.297 0 19.29 15.43 45 2013OCT23_C_50Bridge2_3 6.16 4676.052 281.554 0 18.39 14.70 46 2013OCT23_C_SolvA_13 3.228 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 6.15 78887.039 7144.692 1172.74 1 310.17 248.08 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 6.19 4073.82 188.562 0 16.02 12.81 52 2013OCT23_C_50BridgeFurtherPt_2 6.19 5075.379 254.272 0 19.96 15.96 53 2013OCT23_C_50BridgeFurtherPt_3 6.17 4614.959 187.035 4.422 1 18.15 14.51 54 2013OCT23_C_SolvA_17 0.261 0.85 #DIV/0! 175 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 6.17 5119.633 482.298 0 20.13 16.10 57 2013OCT23_C_PrestonLn_2 6.18 5330.842 415.216 0 20.96 16.76 58 2013OCT23_C_PrestonLn_3 6.18 5819.602 320.854 0 22.88 18.30 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 141.123 #DIV/0! 61 2013OCT23_C_FrazierPt_1 6.17 11789.386 778.739 0 46.35 37.07 62 2013OCT23_C_FrazierPt_2 6.19 10733.585 936.405 0 42.20 33.75 63 2013OCT23_C_FrazierPt_3 6.19 10148.072 597.533 424.819 1 39.90 31.91 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 6.18 27751.363 2030.856 666.136 1 109.11 87.27 67 2013OCT23_C_SwingBridge_2 6.19 26475.57 2266.714 0 104.10 83.26 68 2013OCT23_C_SwingBridge_3 6.19 25161.727 2593.214 601.453 1 98.93 79.13 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 6.19 43900.5 4409.39 768.062 1 172.61 138.05 72 2013OCT23_C_KingstonLn1_2 6.2 42534.941 3358.145 1009.905 1 167.24 133.76 73 2013OCT23_C_KingstonLn1_3 6.19 42545.105 3134.097 819.352 1 167.28 133.79 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 6.19 76086.992 6108.483 1515.417 1 299.16 239.27 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 6.19 50339.207 3603.917 1018.292 1 197.93 158.30 80 2013OCT23_C_KingstonLn2_2 6.18 48213.383 3689.942 948.412 1 189.57 151.62 81 2013OCT23_C_KingstonLn2_3 6.17 50275.363 4475.261 727.128 1 197.68 158.10 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 #DIV/0! 0.00 0.00 85 2013OCT23_C_Cordova_2 #DIV/0! 0.00 0.00 86 2013OCT23_C_Cordova_3 #DIV/0! 0.00 0.00 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 6.19 1661.279 125.21 78.744 1 6.53 5.22 90 2013OCT23_C_Tuckahoe1_2 6.19 2270.937 37.435 0 8.93 7.14 91 2013OCT23_C_Tuckahoe1_3 6.19 1401.54 53.694 30.186 1 5.51 4.41 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 0.011 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 6.17 2504.985 76.794 0 9.85 7.88 95 2013OCT23_C_Tuckahoe2_2 6.17 2114.009 25.497 0 8.31 6.65 96 2013OCT23_C_Tuckahoe2_3 6.18 1887.598 32.744 0 7.42 5.94 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 #DIV/0! 0.00 0.00 176 100 2013OCT23_C_GermanBranch_2 #DIV/0! 0.00 0.00 101 2013OCT23_C_GermanBranch_3 #DIV/0! 0.00 0.00 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 6.18 78570.352 7197.767 1287.171 1 308.93 247.08 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 #DIV/0! 0.00 0.00 108 2013OCT23_C_Greensboro1_2 #DIV/0! 0.00 0.00 109 2013OCT23_C_Greensboro1_3 #DIV/0! 0.00 0.00 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 0.07 #DIV/0! 0.00 0.00 113 2013OCT23_C_Greensboro2_2 0.321 121.376 #DIV/0! 0.00 0.00 114 2013OCT23_C_Greensboro2_3 #DIV/0! 0.00 0.00 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 #DIV/0! 0.00 0.00 118 2013OCT23_C_BeaverDam_2 #DIV/0! 0.00 0.00 119 2013OCT23_C_BeaverDam_3 0.614 7.808 #DIV/0! 0.00 0.00 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 30.67 #DIV/0! 0.00 0.00 123 2013OCT23_C_LongMarsh_2 6.16 600.898 4.824 0 2.36 1.89 124 2013OCT23_C_LongMarsh_3 6.14 571.877 14.339 7.45 1 2.25 1.80 125 2013OCT23_C_SolvA_47 0.666 37.654 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 6.19 531.035 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 6.16 1297.365 0.915 92.469 1 131 2013OCT23_C_1_Std_2 Standard 1 6.17 2861.547 258.509 302.361 1 132 2013OCT23_C_5_Std_2 Standard 5 6.18 14832.557 971.843 366.98 1 133 2013OCT23_C_10_Std_2 Standard 10 6.18 29861.078 2725.845 337.393 1 134 2013OCT23_C_25_Std_2 Standard 25 6.18 74522.57 6607.632 1413.707 1 135 2013OCT23_C_50_Std_2 Standard 50 6.19 135708.797 12055.506 2998.737 1 136 2013OCT23_C_100_Std_2 Standard 100 6.19 259269.828 22586.137 5542.936 1 137 2013OCT23_C_200_Stds_2 Standard 200 6.19 497079.031 42515.836 10913.315 1 138 2013OCT23_C_SolvA_49 0.021 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 20: 13C-2.4-D yes=1,no=0 Ident'd? 177 Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! 2 2013OCT23_C_Lab Blk 6.17 349069.125 #DIV/0! 354335 Avg 3 2013OCT23_C_Travel Blk 6.17 380430.219 #DIV/0! 6% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 6.16 350724.063 #DIV/0! 5 2013OCT23_C_0-05_Std Standard 0.05 6.18 354334.625 #DIV/0! 6 2013OCT23_C_0-1_Std Standard 0.1 6.18 390725.594 #DIV/0! 7 2013OCT23_C_0-5_Std Standard 0.5 6.17 366521.406 #DIV/0! 8 2013OCT23_C_1_Std Standard 1 6.16 377467.844 #DIV/0! 9 2013OCT23_C_5_Std Standard 5 6.17 378447.719 #DIV/0! 10 2013OCT23_C_10_Std Standard 10 6.18 367240.469 #DIV/0! 11 2013OCT23_C_25_Std Standard 25 6.18 363193.781 #DIV/0! 12 2013OCT23_C_50_Std Standard 50 6.18 357004.063 #DIV/0! 13 2013OCT23_C_100_Std Standard 100 6.16 322598.219 #DIV/0! 14 2013OCT23_C_200_Stds Standard 200 6.16 339849.125 #DIV/0! 15 2013OCT23_C_SolvA_2 #DIV/0! 16 2013OCT23_C_Surrogate_1 #DIV/0! 17 2013OCT23_C_SolvA_3 #DIV/0! 18 2013OCT23_C_SolvA_4 #DIV/0! 19 2013OCT23_C_MM_0 6.16 376389.25 #DIV/0! 20 2013OCT23_C_MM_1 6.18 339004.688 #DIV/0! 21 2013OCT23_C_MM_5 6.19 354051.719 #DIV/0! 22 2013OCT23_C_MM_10 6.19 403550.563 #DIV/0! 23 2013OCT23_C_MM_25 6.17 360904.188 #DIV/0! 24 2013OCT23_C_MM_50 6.16 365465.031 #DIV/0! 25 2013OCT23_C_MM_100 6.18 439823.563 #DIV/0! 26 2013OCT23_C_SolvA_5 #DIV/0! 27 2013OCT23_C_SolvA_6 #DIV/0! 28 2013OCT23_C_NOAA_1 6.18 360021.781 #DIV/0! 29 2013OCT23_C_NOAA_2 6.16 346425.406 #DIV/0! 30 2013OCT23_C_NOAA_3 6.18 354578.094 #DIV/0! 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 6.18 343166.844 #DIV/0! 34 2013OCT23_C_HornPt_2 6.15 328270.875 #DIV/0! 35 2013OCT23_C_HornPt_3 6.16 336221.656 #DIV/0! 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 6.16 397718 #DIV/0! 39 2013OCT23_C_50Bridge1_2 6.15 392782.719 #DIV/0! 40 2013OCT23_C_50Bridge1_3 6.16 388161.25 #DIV/0! 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 6.15 333218.344 #DIV/0! 44 2013OCT23_C_50Bridge2_2 6.15 329192.906 #DIV/0! 45 2013OCT23_C_50Bridge2_3 6.17 327883.625 #DIV/0! 178 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 6.15 370473.063 #DIV/0! 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 6.19 361093.781 #DIV/0! 52 2013OCT23_C_50BridgeFurtherPt_2 6.18 345095.844 #DIV/0! 53 2013OCT23_C_50BridgeFurtherPt_3 6.16 343127.938 #DIV/0! 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 6.18 351896.25 #DIV/0! 57 2013OCT23_C_PrestonLn_2 6.18 341684.125 #DIV/0! 58 2013OCT23_C_PrestonLn_3 6.16 344590.375 #DIV/0! 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 6.17 315109 #DIV/0! 62 2013OCT23_C_FrazierPt_2 6.18 315868.469 #DIV/0! 63 2013OCT23_C_FrazierPt_3 6.18 309758.688 #DIV/0! 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 6.18 353688.375 #DIV/0! 67 2013OCT23_C_SwingBridge_2 6.18 342513 #DIV/0! 68 2013OCT23_C_SwingBridge_3 6.19 331137.188 #DIV/0! 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 6.19 322962.406 #DIV/0! 72 2013OCT23_C_KingstonLn1_2 6.19 310797.813 #DIV/0! 73 2013OCT23_C_KingstonLn1_3 6.19 310392.531 #DIV/0! 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 6.19 353315.969 #DIV/0! 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 6.19 365024.906 #DIV/0! 80 2013OCT23_C_KingstonLn2_2 6.18 361314.469 #DIV/0! 81 2013OCT23_C_KingstonLn2_3 6.18 356123.906 #DIV/0! 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 6.19 328366.156 #DIV/0! 85 2013OCT23_C_Cordova_2 6.19 315661.031 #DIV/0! 86 2013OCT23_C_Cordova_3 6.18 309353.594 #DIV/0! 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 6.18 378863.594 #DIV/0! 90 2013OCT23_C_Tuckahoe1_2 6.18 364555.125 #DIV/0! 179 91 2013OCT23_C_Tuckahoe1_3 6.18 362309.438 #DIV/0! 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 6.17 352532.594 #DIV/0! 95 2013OCT23_C_Tuckahoe2_2 6.16 341376.594 #DIV/0! 96 2013OCT23_C_Tuckahoe2_3 6.16 342644.938 #DIV/0! 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 6.16 344275.656 #DIV/0! 100 2013OCT23_C_GermanBranch_2 6.16 326963.781 #DIV/0! 101 2013OCT23_C_GermanBranch_3 6.16 330990.406 #DIV/0! 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 6.18 362283.469 #DIV/0! 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 6.17 389972.781 #DIV/0! 108 2013OCT23_C_Greensboro1_2 6.17 375880.625 #DIV/0! 109 2013OCT23_C_Greensboro1_3 6.17 376785.469 #DIV/0! 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 6.18 337698.156 #DIV/0! 113 2013OCT23_C_Greensboro2_2 6.16 322775.656 #DIV/0! 114 2013OCT23_C_Greensboro2_3 6.18 330919.25 #DIV/0! 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 6.2 350278.469 #DIV/0! 118 2013OCT23_C_BeaverDam_2 6.2 328425.25 #DIV/0! 119 2013OCT23_C_BeaverDam_3 6.18 338167.594 #DIV/0! 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 6.16 339681.875 #DIV/0! 123 2013OCT23_C_LongMarsh_2 6.17 329104.094 #DIV/0! 124 2013OCT23_C_LongMarsh_3 6.17 321515.219 #DIV/0! 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 6.18 357191.5 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 6.19 328505.781 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 6.18 366646.469 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 6.16 343783.188 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 6.16 363371.969 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 6.18 362730.281 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 6.18 343994.344 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 6.18 342921.063 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 6.18 344697.781 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 6.19 310945.063 #DIV/0! 180 137 2013OCT23_C_200_Stds_2 Standard 200 6.19 323051.344 #DIV/0! 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! Compound 22: AlachlorESA yes=1,no=0 Conc. (ng/g) m/z 80 m/z 160 m/z 121 Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 0 3 2013OCT23_C_Travel Blk 0.289 0 4 2013OCT23_C_0-01_Std Standard 0.01 0 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 0 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 5.12 117.556 718.566 0 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 5.08 4609.065 387.99 2913.992 1 1.1 6% 8 2013OCT23_C_1_Std Standard 1 5.07 9587.429 967.55 6834.971 1 2.2 10% 9 2013OCT23_C_5_Std Standard 5 5.09 51041.543 4899.927 31658.396 1 11.7 17% 10 2013OCT23_C_10_Std Standard 10 5.1 89212.898 9219.54 60326.953 1 20.5 2% 11 2013OCT23_C_25_Std Standard 25 5.1 240251.234 24603.807 169479.547 1 55.1 10% 12 2013OCT23_C_50_Std Standard 50 5.1 438127.844 45842.707 324316.5 1 100.5 1% 13 2013OCT23_C_100_Std Standard 100 5.09 898865.875 94181.883 605796.938 1 206.3 3% 14 2013OCT23_C_200_Stds Standard 200 5.08 1678722.75 191287.719 1174133.375 1 385.2 -4% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.00 -100% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.3 -87% 18 2013OCT23_C_SolvA_4 2.33 #DIV/0! 1.2 20% 19 2013OCT23_C_MM_0 5.09 162789.359 18204.809 110589.766 1 2.4 19% 20 2013OCT23_C_MM_1 5.09 151486.313 17488.18 108179.086 1 11.8 18% 21 2013OCT23_C_MM_5 5.09 203076.234 23244.906 144819.141 1 22.5 12% 22 2013OCT23_C_MM_10 5.1 289308.281 31100.932 204647.125 1 56.8 14% 23 2013OCT23_C_MM_25 5.08 406352.438 43510.359 279445.531 1 104.4 4% 24 2013OCT23_C_MM_50 5.07 601126.813 70196.836 419526.156 1 205.6 3% 25 2013OCT23_C_MM_100 5.08 1093050 129682.508 786394.188 1 405.9 1% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 5.08 49095.578 5408.989 33352.219 1 112.66 106.23 29 2013OCT23_C_NOAA_2 5.08 45753.648 4889.403 31982.74 1 104.99 98.99 30 2013OCT23_C_NOAA_3 5.09 44271.148 5168.467 30735.832 1 101.59 95.79 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 27.284 52.226 0 33 2013OCT23_C_HornPt_1 5.09 60247.438 7232.138 41332.895 1 138.25 130.35 34 2013OCT23_C_HornPt_2 5.06 59220.484 6490.509 40080.051 1 135.89 128.13 35 2013OCT23_C_HornPt_3 5.09 56256.535 6590.95 38809.414 1 129.09 121.72 36 2013OCT23_C_SolvA_9 0.045 #DIV/0! 181 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 5.08 84773.773 8591.895 59018.16 1 194.53 183.42 39 2013OCT23_C_50Bridge1_2 5.07 87649.625 9376.106 59540.227 1 201.13 189.64 40 2013OCT23_C_50Bridge1_3 5.08 83786.078 8859.703 58328.289 1 192.26 181.28 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 5.07 73444.391 7407.675 50553.219 1 168.53 158.91 44 2013OCT23_C_50Bridge2_2 5.08 71893.195 7023.561 50704.324 1 164.97 155.55 45 2013OCT23_C_50Bridge2_3 5.09 71176.594 7339.754 49181.492 1 163.33 154.00 46 2013OCT23_C_SolvA_13 4.96 102.996 6.03 14.483 0 47 2013OCT23_C_SolvA_14 5.07 0.002 #DIV/0! 48 2013OCT23_C_QC_Std25_1 5.08 225343.031 24833.656 159098.281 1 517.09 487.56 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 5.06 30.576 9.247 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 5.1 80431.297 8735.832 54494.539 1 184.56 174.03 52 2013OCT23_C_50BridgeFurtherPt_2 5.09 74531.273 8391.967 49707.555 1 171.02 161.26 53 2013OCT23_C_50BridgeFurtherPt_3 5.08 74813.25 8752.622 51918.531 1 171.67 161.87 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 5.08 183758.719 19223.377 127111.57 1 421.66 397.59 57 2013OCT23_C_PrestonLn_2 5.09 170454.453 17886.65 122471.836 1 391.14 368.80 58 2013OCT23_C_PrestonLn_3 5.08 168181.047 19259.641 113214.969 1 385.92 363.89 59 2013OCT23_C_SolvA_19 9.857 11.568 0 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 5.09 104618.977 11335.918 71482.5 1 240.07 226.36 62 2013OCT23_C_FrazierPt_2 5.09 97364.234 10853.979 68284.945 1 223.42 210.66 63 2013OCT23_C_FrazierPt_3 5.09 101028.438 10996.79 66221.75 1 231.83 218.59 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 5.09 108470.664 10835.085 67043.773 1 248.90 234.69 67 2013OCT23_C_SwingBridge_2 5.09 102057.883 10575.681 68051.438 1 234.19 220.82 68 2013OCT23_C_SwingBridge_3 5.1 102831.75 10691.91 68609.109 1 235.96 222.49 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 15.724 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 5.1 96048.641 10293.86 63637.145 1 220.40 207.82 72 2013OCT23_C_KingstonLn1_2 5.1 95209.969 9209.655 61420.965 1 218.47 206.00 73 2013OCT23_C_KingstonLn1_3 5.1 89757.992 9860.28 61396.16 1 205.96 194.21 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 5.11 227398.391 24461.609 159335.281 1 521.80 492.01 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 5.11 114867.883 11673.763 74749.766 1 263.58 248.53 80 2013OCT23_C_KingstonLn2_2 5.09 105225.477 11013.405 72267.867 1 241.46 227.67 81 2013OCT23_C_KingstonLn2_3 5.1 106958.555 10558.438 73050.906 1 245.43 231.42 182 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 55.571 #DIV/0! 84 2013OCT23_C_Cordova_1 5.1 403649.156 31065.686 268144.719 1 926.24 873.36 85 2013OCT23_C_Cordova_2 5.12 370078 32091.297 259600.531 1 849.20 800.72 86 2013OCT23_C_Cordova_3 5.1 383266.875 30499.844 262793.594 1 879.47 829.26 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 22.41 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 5.1 252582.922 29344.707 170165.328 1 579.59 546.50 90 2013OCT23_C_Tuckahoe1_2 5.1 251170.328 28423.367 167101.297 1 576.35 543.45 91 2013OCT23_C_Tuckahoe1_3 5.11 252543.953 30122.342 163958.734 1 579.50 546.42 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 5.1 234530.953 26273.533 162546.641 1 538.17 507.44 95 2013OCT23_C_Tuckahoe2_2 5.09 237089.906 26593.197 158387.656 1 544.04 512.98 96 2013OCT23_C_Tuckahoe2_3 5.1 234917.141 26356.299 166396.922 1 539.06 508.28 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 5.1 232815.438 27672.75 165195.047 1 534.23 503.73 100 2013OCT23_C_GermanBranch_2 5.09 245878.391 27712.564 162248.891 1 564.21 532.00 101 2013OCT23_C_GermanBranch_3 5.09 247646.375 27508.662 162590.453 1 568.26 535.82 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 1.791 #DIV/0! 104 2013OCT23_C_QC_Std25_3 5.11 242320.625 26425.295 170826.766 1 556.04 524.30 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 53.306 #DIV/0! 107 2013OCT23_C_Greensboro1_1 5.1 174100.984 20695.861 118398.008 1 399.50 376.69 108 2013OCT23_C_Greensboro1_2 5.1 176107.344 19973.732 113066.945 1 404.11 381.04 109 2013OCT23_C_Greensboro1_3 5.09 175693.922 19591.166 118353.359 1 403.16 380.14 110 2013OCT23_C_SolvA_41 24.375 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 5.11 145064.156 17849.1 100913.156 1 332.87 313.87 113 2013OCT23_C_Greensboro2_2 5.1 144757.438 17313.232 100175.484 1 332.17 313.20 114 2013OCT23_C_Greensboro2_3 5.11 148981.656 17890.336 99239.398 1 341.86 322.34 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 23.224 17.855 0 117 2013OCT23_C_BeaverDam_1 5.12 281448.406 37003.211 188189.094 1 645.83 608.96 118 2013OCT23_C_BeaverDam_2 5.12 276016.469 36236.117 182151.516 1 633.36 597.20 119 2013OCT23_C_BeaverDam_3 5.11 281587.781 36685.648 203432.063 1 646.15 609.26 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 11.422 #DIV/0! 122 2013OCT23_C_LongMarsh_1 5.1 155445.125 21016.486 103608.375 1 356.69 336.33 123 2013OCT23_C_LongMarsh_2 5.1 155586.984 21293.318 103969.242 1 357.02 336.64 124 2013OCT23_C_LongMarsh_3 5.1 155002.141 21270.332 103292.742 1 355.68 335.37 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 1.634 #DIV/0! 183 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 9.039 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 1167.896 526.527 0 130 2013OCT23_C_0-5_Std_2 Standard 0.5 5.1 5231.982 563.734 3435.434 1 131 2013OCT23_C_1_Std_2 Standard 1 5.08 10349.129 1176.002 7026.393 1 132 2013OCT23_C_5_Std_2 Standard 5 5.11 51254.418 5012.7 35098.637 1 133 2013OCT23_C_10_Std_2 Standard 10 5.12 98013.234 10135.116 66579.508 1 134 2013OCT23_C_25_Std_2 Standard 25 5.11 247551.625 25008.25 170258.297 1 135 2013OCT23_C_50_Std_2 Standard 50 5.12 455121.438 46464.688 305670.813 1 136 2013OCT23_C_100_Std_2 Standard 100 5.12 896119.875 93316.82 610547.125 1 137 2013OCT23_C_200_Stds_2 Standard 200 5.12 1768873.25 188035.406 1248241.25 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 5.721 13.089 0 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 6.37 #DIV/0! Compound 24: Metolachlor ESA yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT23_SolvA_1 0 2 2013OCT23_C_Lab Blk 5.39 289.471 17.58 8.413 0 3 2013OCT23_C_Travel Blk 5.39 191.565 195.186 44.582 1 4 2013OCT23_C_0-01_Std Standard 0.01 5.38 105.39 163.513 0 0.02 98% 5 2013OCT23_C_0-05_Std Standard 0.05 5.4 209.426 168.39 0 0.04 -21% 6 2013OCT23_C_0-1_Std Standard 0.1 5.4 565.768 496.772 22.007 1 0.11 7% 7 2013OCT23_C_0-5_Std Standard 0.5 5.39 3325.528 1634.709 234.429 1 0.6 25% 8 2013OCT23_C_1_Std Standard 1 5.38 5823.056 4083.771 522.143 1 1.1 10% 9 2013OCT23_C_5_Std Standard 5 5.38 30094.078 21168.262 3022.734 1 5.7 13% 10 2013OCT23_C_10_Std Standard 10 5.39 57311.133 41115.07 6986.698 1 10.8 8% 11 2013OCT23_C_25_Std Standard 25 5.39 146963.719 103046.43 13774.608 1 27.7 11% 12 2013OCT23_C_50_Std Standard 50 5.39 276672.188 195630.344 27723.939 1 52.1 4% 13 2013OCT23_C_100_Std Standard 100 5.38 562603.188 388340 58650.465 1 106.0 6% 14 2013OCT23_C_200_Stds Standard 200 5.37 1110106.75 741047.875 118392.609 1 209.1 5% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 5.39 62.417 5.31 0.294 1 0.07 47% 17 2013OCT23_C_SolvA_3 #DIV/0! 0.1 -18% 18 2013OCT23_C_SolvA_4 5.4 37.953 4.966 0.487 1 0.6 14% 19 2013OCT23_C_MM_0 5.36 1703244.875 1104707.125 173847.844 1 1.0 4% 20 2013OCT23_C_MM_1 5.37 1487637.5 956426.25 150440.641 1 4.7 -7% 21 2013OCT23_C_MM_5 5.37 1607387.625 1056007.25 167430.109 1 9.7 -3% 22 2013OCT23_C_MM_10 5.38 1920058.5 1248823.375 204103.375 1 23.9 -4% 23 2013OCT23_C_MM_25 5.36 1784199.25 1141091 186792.25 1 43.2 -14% 24 2013OCT23_C_MM_50 5.36 1934610.625 1247028.75 202545.359 1 87.7 -12% 25 2013OCT23_C_MM_100 5.36 2408446.75 1628410 256248.375 1 179.2 -10% 26 2013OCT23_C_SolvA_5 #DIV/0! Forced (0,0) MM 184 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 5.38 353342.406 237876.5 36736.168 1 665.50 547.07 29 2013OCT23_C_NOAA_2 5.37 350392.531 240195.641 36081.727 1 659.94 542.50 30 2013OCT23_C_NOAA_3 5.38 337446.875 240498.969 34840.773 1 635.56 522.46 31 2013OCT23_C_SolvA_7 5.37 154.739 29.134 1.55 1 32 2013OCT23_C_SolvA_8 5.39 30.479 59.852 0 33 2013OCT23_C_HornPt_1 5.38 438674.125 297210 51030.773 1 826.21 679.19 34 2013OCT23_C_HornPt_2 5.36 442645.125 307231.531 46455.957 1 833.69 685.34 35 2013OCT23_C_HornPt_3 5.37 431348.875 295851.156 45338.328 1 812.42 667.85 36 2013OCT23_C_SolvA_9 5.39 30.477 51.473 6.873 1 37 2013OCT23_C_SolvA_10 5.38 9.978 33.906 12.194 0 38 2013OCT23_C_50Bridge1_1 5.36 641020.438 440763 66550.563 1 1207.32 992.48 39 2013OCT23_C_50Bridge1_2 5.36 630949.313 425592.625 67157.969 1 1188.35 976.88 40 2013OCT23_C_50Bridge1_3 5.37 630966.188 423949.75 68259.258 1 1188.38 976.91 41 2013OCT23_C_SolvA_11 5.34 71.573 4.994 0 42 2013OCT23_C_SolvA_12 5.39 204.905 26.916 0.973 1 43 2013OCT23_C_50Bridge2_1 5.37 543302.375 376041.5 54440.988 1 1023.27 841.18 44 2013OCT23_C_50Bridge2_2 5.36 538354.375 365990.656 56217.781 1 1013.95 833.52 45 2013OCT23_C_50Bridge2_3 5.37 543412.875 359425.438 53702.766 1 1023.48 841.35 46 2013OCT23_C_SolvA_13 5.42 1.639 25.269 0 47 2013OCT23_C_SolvA_14 5.31 39.917 3.631 0.231 1 48 2013OCT23_C_QC_Std25_1 5.38 153330.109 104498.086 14434.023 1 288.79 237.40 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 5.36 183.035 238.64 0.439 1 51 2013OCT23_C_50BridgeFurtherPt_1 5.39 583403.688 398645.344 62040.098 1 1098.80 903.27 52 2013OCT23_C_50BridgeFurtherPt_2 5.38 592852.625 409741.469 60106.035 1 1116.60 917.90 53 2013OCT23_C_50BridgeFurtherPt_3 5.37 605317.688 403436.813 65687.023 1 1140.07 937.20 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 5.37 1068558 688656 109603.461 1 2012.55 1654.42 57 2013OCT23_C_PrestonLn_2 5.37 1050359.625 688369.688 115126.805 1 1978.28 1626.25 58 2013OCT23_C_PrestonLn_3 5.36 1070228.5 697082.125 110593.609 1 2015.70 1657.01 59 2013OCT23_C_SolvA_19 5.45 85.892 32.171 0.341 1 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 5.37 888031.438 595942.625 93208.063 1 1672.54 1374.92 62 2013OCT23_C_FrazierPt_2 5.38 863777.563 572955.813 89184.117 1 1626.86 1337.37 63 2013OCT23_C_FrazierPt_3 5.38 866013.125 576612.813 89714.953 1 1631.07 1340.83 64 2013OCT23_C_SolvA_21 5.37 60.382 3.808 0.337 1 65 2013OCT23_C_SolvA_22 5.47 9.707 47.047 0 66 2013OCT23_C_SwingBridge_1 5.37 862403.25 572342.438 91864.898 1 1624.28 1335.24 67 2013OCT23_C_SwingBridge_2 5.38 857571.313 558502.75 86359.141 1 1615.17 1327.76 68 2013OCT23_C_SwingBridge_3 5.38 817860.25 548929.125 86569.516 1 1540.38 1266.27 69 2013OCT23_C_SolvA_23 5.38 229.509 0.951 #DIV/0! 70 2013OCT23_C_SolvA_24 5.38 42.873 120.351 0 71 2013OCT23_C_KingstonLn1_1 5.39 760410.5 515255.625 79803.008 1 1432.18 1177.32 185 72 2013OCT23_C_KingstonLn1_2 5.39 753094.625 509930.156 73646.836 1 1418.40 1166.00 73 2013OCT23_C_KingstonLn1_3 5.39 765980 509184.344 78019.984 1 1442.67 1185.95 74 2013OCT23_C_SolvA_25 5.4 16.771 30.74 9.162 0 75 2013OCT23_C_SolvA_26 5.4 8.176 3.85 #DIV/0! 76 2013OCT23_C_QC_Std25_2 5.4 127098.68 93553.219 11951.637 1 239.38 196.78 77 2013OCT23_C_SolvA_27 5.41 22.432 #DIV/0! 78 2013OCT23_C_SolvA_28 5.44 39.76 0.869 0.739 0 79 2013OCT23_C_KingstonLn2_1 5.39 912069.625 598721.688 93580.766 1 1717.82 1412.13 80 2013OCT23_C_KingstonLn2_2 5.38 897734.813 593684 89973.805 1 1690.82 1389.94 81 2013OCT23_C_KingstonLn2_3 5.38 902101.063 604020.438 91358.313 1 1699.04 1396.70 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 5.39 4.396 2.829 7.488 0 84 2013OCT23_C_Cordova_1 5.38 3105429.75 2078307 326389.625 1 5848.86 4808.06 85 2013OCT23_C_Cordova_2 5.39 2994766.75 2018976.25 317272.75 1 5640.43 4636.72 86 2013OCT23_C_Cordova_3 5.38 3071763 2056785.625 316518 1 5785.45 4755.93 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 5.39 130.608 8.781 3.348 0 89 2013OCT23_C_Tuckahoe1_1 5.38 2617491 1710035.875 268382.625 1 4929.86 4052.60 90 2013OCT23_C_Tuckahoe1_2 5.38 2536578 1699205.875 264522.313 1 4777.47 3927.32 91 2013OCT23_C_Tuckahoe1_3 5.38 2538942.75 1694223.875 261701.109 1 4781.92 3930.98 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 5.45 39.291 0.797 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 5.37 2484427.5 1635726.125 252296.906 1 4679.24 3846.58 95 2013OCT23_C_Tuckahoe2_2 5.37 2459050.25 1627290.5 252530.406 1 4631.45 3807.29 96 2013OCT23_C_Tuckahoe2_3 5.37 2424573 1620997.875 249271.438 1 4566.51 3753.91 97 2013OCT23_C_SolvA_35 5.42 33.652 2.333 #DIV/0! 98 2013OCT23_C_SolvA_36 5.36 118.716 0.626 #DIV/0! 99 2013OCT23_C_GermanBranch_1 5.37 2378315.5 1517050.375 241403.906 1 4479.39 3682.29 100 2013OCT23_C_GermanBranch_2 5.37 2306184.5 1552230.25 243451.578 1 4343.54 3570.61 101 2013OCT23_C_GermanBranch_3 5.37 2300141.5 1551623.625 237783.484 1 4332.15 3561.25 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 5.34 131.996 144.395 8.478 1 104 2013OCT23_C_QC_Std25_3 5.4 134761.891 99681.438 13351.635 1 253.81 208.65 105 2013OCT23_C_SolvA_39 5.42 3.466 105.515 0.384 1 106 2013OCT23_C_SolvA_40 5.4 58.716 98.628 1.257 1 107 2013OCT23_C_Greensboro1_1 5.38 1440251.875 935161.625 145038.188 1 2712.61 2229.91 108 2013OCT23_C_Greensboro1_2 5.38 1421438.5 927743.75 143640.75 1 2677.18 2200.78 109 2013OCT23_C_Greensboro1_3 5.38 1422949.125 942986.625 147631.734 1 2680.02 2203.12 110 2013OCT23_C_SolvA_41 5.4 137.173 2.307 1.14 0 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 5.39 1261168.375 810525.563 123608.906 1 2375.32 1952.64 113 2013OCT23_C_Greensboro2_2 5.37 1206492.25 799681.688 121939.961 1 2272.34 1867.98 114 2013OCT23_C_Greensboro2_3 5.39 1186626.25 782945.938 123809.023 1 2234.93 1837.22 115 2013OCT23_C_SolvA_43 5.34 158.536 177.006 1.413 1 116 2013OCT23_C_SolvA_44 #DIV/0! 186 117 2013OCT23_C_BeaverDam_1 5.4 3098158 2107996.25 322505.344 1 5835.16 4796.80 118 2013OCT23_C_BeaverDam_2 5.4 3056524 2115527.25 324149.25 1 5756.75 4732.34 119 2013OCT23_C_BeaverDam_3 5.38 3228033.25 2178374.5 335265.563 1 6079.77 4997.88 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 5.45 86.192 #DIV/0! 122 2013OCT23_C_LongMarsh_1 5.37 2632159 1762214 279396.25 1 4957.49 4075.31 123 2013OCT23_C_LongMarsh_2 5.37 2561736.25 1721430 263151.594 1 4824.85 3966.27 124 2013OCT23_C_LongMarsh_3 5.38 2539929.75 1714355.625 257055.969 1 4783.78 3932.51 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 5.4 299.304 0.257 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 5.41 391.278 282.654 30.617 1 129 2013OCT23_C_0-1_Std_2 Standard 0.1 5.41 434.987 428.249 0.003 1 130 2013OCT23_C_0-5_Std_2 Standard 0.5 5.4 3039.036 1497.961 248.747 1 131 2013OCT23_C_1_Std_2 Standard 1 5.4 5533.523 4218.774 794.678 1 132 2013OCT23_C_5_Std_2 Standard 5 5.4 24785.371 19148.51 2052.06 1 133 2013OCT23_C_10_Std_2 Standard 10 5.41 51281.688 37476.141 4600.724 1 134 2013OCT23_C_25_Std_2 Standard 25 5.41 127045.461 93384.617 12487.127 1 135 2013OCT23_C_50_Std_2 Standard 50 5.41 229380.406 168364.313 25383.617 1 136 2013OCT23_C_100_Std_2 Standard 100 5.41 465600.156 324420.344 47335.367 1 137 2013OCT23_C_200_Stds_2 Standard 200 5.41 951256.25 658245.938 97724.125 1 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 5.43 44.084 5.712 2.486 0 140 2013OCT23_C_SolvA_50 5.43 79.627 21.799 0.948 1 145 2013OCT25_C_500_Std Standard 500 5.4 2788866.75 1951647.25 308554.781 1 146 2013OCT25_C_SolvA_2 #DIV/0! 147 2013OCT25_C_800_Std Standard 800 5.4 4184800.25 3005405.25 465354.75 1 Compound 25: Sucralose yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! 2 2013OCT23_C_Lab Blk #DIV/0! 3 2013OCT23_C_Travel Blk 67.224 #DIV/0! 4 2013OCT23_C_0-01_Std Standard 0.01 #DIV/0! 0.00 -100% 5 2013OCT23_C_0-05_Std Standard 0.05 #DIV/0! 0.00 -100% 6 2013OCT23_C_0-1_Std Standard 0.1 #DIV/0! 0.00 -100% 7 2013OCT23_C_0-5_Std Standard 0.5 60.208 #DIV/0! 0.0 -100% 8 2013OCT23_C_1_Std Standard 1 #DIV/0! 0.0 -100% 9 2013OCT23_C_5_Std Standard 5 2.23 49.287 #DIV/0! 2.6 -49% 10 2013OCT23_C_10_Std Standard 10 2.24 114.912 #DIV/0! 6.0 -40% 11 2013OCT23_C_25_Std Standard 25 2.24 641.814 #DIV/0! 33.4 33% 12 2013OCT23_C_50_Std Standard 50 2.24 758.02 #DIV/0! 39.4 -21% 13 2013OCT23_C_100_Std Standard 100 2.24 1850.436 #DIV/0! 96.2 -4% 14 2013OCT23_C_200_Stds Standard 200 2.24 3920.628 #DIV/0! 203.8 2% 15 2013OCT23_C_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT23_C_Surrogate_1 #DIV/0! 0.00 -100% 187 17 2013OCT23_C_SolvA_3 #DIV/0! 0.0 -100% 18 2013OCT23_C_SolvA_4 0.731 #DIV/0! 0.0 -100% 19 2013OCT23_C_MM_0 2.24 382.205 #DIV/0! 0.0 -100% 20 2013OCT23_C_MM_1 2.26 234.417 0.083 #DIV/0! 0.0 -100% 21 2013OCT23_C_MM_5 2.23 376.382 #DIV/0! 3.5 -65% 22 2013OCT23_C_MM_10 2.24 448.153 #DIV/0! 13.7 -45% 23 2013OCT23_C_MM_25 2.24 815.937 #DIV/0! 29.9 -40% 24 2013OCT23_C_MM_50 2.24 1294.197 435.174 #DIV/0! 68.8 -31% 25 2013OCT23_C_MM_100 2.24 3108.449 572.595 #DIV/0! 127.0 -37% 26 2013OCT23_C_SolvA_5 2.26 10.318 1.27 #DIV/0! Forced (0,0) MM 27 2013OCT23_C_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT23_C_NOAA_1 2.25 770.634 312.552 #DIV/0! 400.55 309.09 29 2013OCT23_C_NOAA_2 2.24 976.554 340.701 #DIV/0! 507.59 391.69 30 2013OCT23_C_NOAA_3 2.25 865.844 406.351 #DIV/0! 450.04 347.28 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 2.24 761.497 504.208 #DIV/0! 395.81 305.43 34 2013OCT23_C_HornPt_2 2.24 1115.233 448.658 #DIV/0! 579.67 447.31 35 2013OCT23_C_HornPt_3 2.24 785.92 234.377 #DIV/0! 408.50 315.22 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.25 660.066 #DIV/0! 343.08 264.75 39 2013OCT23_C_50Bridge1_2 2.25 817.69 258.152 #DIV/0! 425.01 327.97 40 2013OCT23_C_50Bridge1_3 2.24 728.22 199.751 #DIV/0! 378.51 292.08 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.24 632.149 151.794 #DIV/0! 328.57 253.55 44 2013OCT23_C_50Bridge2_2 2.23 619.003 477.944 #DIV/0! 321.74 248.28 45 2013OCT23_C_50Bridge2_3 2.24 532.574 253.477 #DIV/0! 276.82 213.61 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 2.24 443.085 128.057 #DIV/0! 230.30 177.72 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 2.24 823.804 291.831 #DIV/0! 428.19 330.42 52 2013OCT23_C_50BridgeFurtherPt_2 2.24 520.007 #DIV/0! 270.29 208.57 53 2013OCT23_C_50BridgeFurtherPt_3 2.24 881.273 70.458 #DIV/0! 458.06 353.47 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 #DIV/0! 0.00 0.00 57 2013OCT23_C_PrestonLn_2 #DIV/0! 0.00 0.00 58 2013OCT23_C_PrestonLn_3 #DIV/0! 0.00 0.00 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 106.431 #DIV/0! 0.00 0.00 62 2013OCT23_C_FrazierPt_2 24.075 #DIV/0! 0.00 0.00 188 63 2013OCT23_C_FrazierPt_3 #DIV/0! 0.00 0.00 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.24 194.403 #DIV/0! 101.05 77.97 67 2013OCT23_C_SwingBridge_2 4.394 #DIV/0! 0.00 0.00 68 2013OCT23_C_SwingBridge_3 2.23 145.569 251.002 #DIV/0! 75.66 58.39 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 2.23 0.358 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 2.26 111.003 242.205 #DIV/0! 57.70 44.52 72 2013OCT23_C_KingstonLn1_2 2.2 274.007 549.316 #DIV/0! 142.42 109.90 73 2013OCT23_C_KingstonLn1_3 2.23 316.297 77.961 #DIV/0! 164.40 126.86 74 2013OCT23_C_SolvA_25 0.375 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 2.24 406.45 73.534 #DIV/0! 211.26 163.02 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 #DIV/0! 0.00 0.00 80 2013OCT23_C_KingstonLn2_2 #DIV/0! 0.00 0.00 81 2013OCT23_C_KingstonLn2_3 #DIV/0! 0.00 0.00 82 2013OCT23_C_SolvA_29 0.148 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.24 159.285 211.851 #DIV/0! 82.79 63.89 85 2013OCT23_C_Cordova_2 2.25 290.227 331.766 #DIV/0! 150.85 116.41 86 2013OCT23_C_Cordova_3 #DIV/0! 0.00 0.00 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 1.347 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 556.378 #DIV/0! 0.00 0.00 90 2013OCT23_C_Tuckahoe1_2 #DIV/0! 0.00 0.00 91 2013OCT23_C_Tuckahoe1_3 #DIV/0! 0.00 0.00 92 2013OCT23_C_SolvA_33 0.78 #DIV/0! 93 2013OCT23_C_SolvA_34 2.2 0.729 0.757 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.26 100.277 314.03 #DIV/0! 52.12 40.22 95 2013OCT23_C_Tuckahoe2_2 2.24 151.504 212.348 #DIV/0! 78.75 60.77 96 2013OCT23_C_Tuckahoe2_3 14.751 #DIV/0! 0.00 0.00 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 99 2013OCT23_C_GermanBranch_1 2.22 216.905 521.901 #DIV/0! 112.74 87.00 100 2013OCT23_C_GermanBranch_2 2.23 302.082 238.654 #DIV/0! 157.01 121.16 101 2013OCT23_C_GermanBranch_3 2.26 135.729 502.844 #DIV/0! 70.55 54.44 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 0.143 #DIV/0! 104 2013OCT23_C_QC_Std25_3 2.24 548.424 242.324 #DIV/0! 285.06 219.97 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.26 311.906 577.305 #DIV/0! 162.12 125.10 189 108 2013OCT23_C_Greensboro1_2 2.25 367.567 286.683 #DIV/0! 191.05 147.43 109 2013OCT23_C_Greensboro1_3 2.24 316.237 633.119 #DIV/0! 164.37 126.84 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 #DIV/0! 0.00 0.00 113 2013OCT23_C_Greensboro2_2 2.26 207.262 652.748 #DIV/0! 107.73 83.13 114 2013OCT23_C_Greensboro2_3 2.25 385.695 442.596 #DIV/0! 200.47 154.70 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 0.69 #DIV/0! 117 2013OCT23_C_BeaverDam_1 246.843 #DIV/0! 0.00 0.00 118 2013OCT23_C_BeaverDam_2 #DIV/0! 0.00 0.00 119 2013OCT23_C_BeaverDam_3 #DIV/0! 0.00 0.00 120 2013OCT23_C_SolvA_45 0.326 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 399.417 #DIV/0! 0.00 0.00 123 2013OCT23_C_LongMarsh_2 #DIV/0! 0.00 0.00 124 2013OCT23_C_LongMarsh_3 2.26 321.684 348.705 #DIV/0! 167.20 129.02 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 5.002 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 121.088 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 2.25 66.814 155.736 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 2.26 263.829 121.103 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 2.24 575.818 282.352 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 2.24 1324.225 163.781 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 2.24 2442.57 99.213 #DIV/0! 138 2013OCT23_C_SolvA_49 2.21 1.449 2 #DIV/0! 139 2013OCT23_C_Surrogate_2 2.29 1.571 153.868 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 1.101 #DIV/0! Compound 26: Sucralose-d6 yes=1,no=0 Ident'd? Name Type Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT23_SolvA_1 #DIV/0! 2 2013OCT23_C_Lab Blk 2.22 2181.447 #DIV/0! 1872 Avg 3 2013OCT23_C_Travel Blk 2.22 2002.782 #DIV/0! 19% RSD 4 2013OCT23_C_0-01_Std Standard 0.01 2.22 1545.789 #DIV/0! 5 2013OCT23_C_0-05_Std Standard 0.05 2.22 2284.596 #DIV/0! 6 2013OCT23_C_0-1_Std Standard 0.1 2.22 2057.668 #DIV/0! 7 2013OCT23_C_0-5_Std Standard 0.5 2.22 2465.018 #DIV/0! 190 8 2013OCT23_C_1_Std Standard 1 2.23 1646.005 #DIV/0! 9 2013OCT23_C_5_Std Standard 5 2.22 2317.749 #DIV/0! 10 2013OCT23_C_10_Std Standard 10 2.23 2202.523 #DIV/0! 11 2013OCT23_C_25_Std Standard 25 2.22 1745.842 #DIV/0! 12 2013OCT23_C_50_Std Standard 50 2.23 1808.487 #DIV/0! 13 2013OCT23_C_100_Std Standard 100 2.22 1801.932 #DIV/0! 14 2013OCT23_C_200_Stds Standard 200 2.23 1980.844 #DIV/0! 15 2013OCT23_C_SolvA_2 #DIV/0! 16 2013OCT23_C_Surrogate_1 #DIV/0! 17 2013OCT23_C_SolvA_3 #DIV/0! 18 2013OCT23_C_SolvA_4 #DIV/0! 19 2013OCT23_C_MM_0 2.23 1822.952 #DIV/0! 20 2013OCT23_C_MM_1 2.23 1858.047 #DIV/0! 21 2013OCT23_C_MM_5 2.23 2088.85 #DIV/0! 22 2013OCT23_C_MM_10 2.23 2253.091 #DIV/0! 23 2013OCT23_C_MM_25 2.22 1955.765 #DIV/0! 24 2013OCT23_C_MM_50 2.23 2519.396 #DIV/0! 25 2013OCT23_C_MM_100 2.24 2474.991 #DIV/0! 26 2013OCT23_C_SolvA_5 #DIV/0! 27 2013OCT23_C_SolvA_6 #DIV/0! 28 2013OCT23_C_NOAA_1 2.23 2027.966 #DIV/0! 29 2013OCT23_C_NOAA_2 2.22 2146.973 #DIV/0! 30 2013OCT23_C_NOAA_3 2.23 2049.976 #DIV/0! 31 2013OCT23_C_SolvA_7 #DIV/0! 32 2013OCT23_C_SolvA_8 #DIV/0! 33 2013OCT23_C_HornPt_1 2.22 1924.781 #DIV/0! 34 2013OCT23_C_HornPt_2 2.22 2201.919 #DIV/0! 35 2013OCT23_C_HornPt_3 2.22 2237.296 #DIV/0! 36 2013OCT23_C_SolvA_9 #DIV/0! 37 2013OCT23_C_SolvA_10 #DIV/0! 38 2013OCT23_C_50Bridge1_1 2.22 2332.97 #DIV/0! 39 2013OCT23_C_50Bridge1_2 2.22 2606.503 #DIV/0! 40 2013OCT23_C_50Bridge1_3 2.22 1961.233 #DIV/0! 41 2013OCT23_C_SolvA_11 #DIV/0! 42 2013OCT23_C_SolvA_12 #DIV/0! 43 2013OCT23_C_50Bridge2_1 2.22 3076.811 #DIV/0! 44 2013OCT23_C_50Bridge2_2 2.22 1999.02 #DIV/0! 45 2013OCT23_C_50Bridge2_3 2.22 2043.055 #DIV/0! 46 2013OCT23_C_SolvA_13 #DIV/0! 47 2013OCT23_C_SolvA_14 #DIV/0! 48 2013OCT23_C_QC_Std25_1 2.22 1964.058 #DIV/0! 49 2013OCT23_C_SolvA_15 #DIV/0! 50 2013OCT23_C_SolvA_16 #DIV/0! 51 2013OCT23_C_50BridgeFurtherPt_1 2.22 1963.169 #DIV/0! 52 2013OCT23_C_50BridgeFurtherPt_2 2.23 2343.483 #DIV/0! 53 2013OCT23_C_50BridgeFurtherPt_3 2.23 1949.822 #DIV/0! 191 54 2013OCT23_C_SolvA_17 #DIV/0! 55 2013OCT23_C_SolvA_18 #DIV/0! 56 2013OCT23_C_PrestonLn_1 2.23 1665.949 #DIV/0! 57 2013OCT23_C_PrestonLn_2 2.23 2377.733 #DIV/0! 58 2013OCT23_C_PrestonLn_3 2.22 2102.771 #DIV/0! 59 2013OCT23_C_SolvA_19 #DIV/0! 60 2013OCT23_C_SolvA_20 #DIV/0! 61 2013OCT23_C_FrazierPt_1 2.23 1540.802 #DIV/0! 62 2013OCT23_C_FrazierPt_2 2.24 1305.294 #DIV/0! 63 2013OCT23_C_FrazierPt_3 2.22 1748.636 #DIV/0! 64 2013OCT23_C_SolvA_21 #DIV/0! 65 2013OCT23_C_SolvA_22 #DIV/0! 66 2013OCT23_C_SwingBridge_1 2.23 1513.13 #DIV/0! 67 2013OCT23_C_SwingBridge_2 2.22 1950.081 #DIV/0! 68 2013OCT23_C_SwingBridge_3 2.23 1612.709 #DIV/0! 69 2013OCT23_C_SolvA_23 #DIV/0! 70 2013OCT23_C_SolvA_24 #DIV/0! 71 2013OCT23_C_KingstonLn1_1 2.23 1437.201 #DIV/0! 72 2013OCT23_C_KingstonLn1_2 2.23 1917.27 #DIV/0! 73 2013OCT23_C_KingstonLn1_3 2.23 1705.616 #DIV/0! 74 2013OCT23_C_SolvA_25 #DIV/0! 75 2013OCT23_C_SolvA_26 #DIV/0! 76 2013OCT23_C_QC_Std25_2 2.23 893.934 #DIV/0! 77 2013OCT23_C_SolvA_27 #DIV/0! 78 2013OCT23_C_SolvA_28 #DIV/0! 79 2013OCT23_C_KingstonLn2_1 2.24 1882.917 #DIV/0! 80 2013OCT23_C_KingstonLn2_2 2.23 1964.149 #DIV/0! 81 2013OCT23_C_KingstonLn2_3 2.23 1707.639 #DIV/0! 82 2013OCT23_C_SolvA_29 #DIV/0! 83 2013OCT23_C_SolvA_30 #DIV/0! 84 2013OCT23_C_Cordova_1 2.22 1832.602 #DIV/0! 85 2013OCT23_C_Cordova_2 2.23 2249.954 #DIV/0! 86 2013OCT23_C_Cordova_3 2.23 1917.937 #DIV/0! 87 2013OCT23_C_SolvA_31 #DIV/0! 88 2013OCT23_C_SolvA_32 #DIV/0! 89 2013OCT23_C_Tuckahoe1_1 2.24 1783.512 #DIV/0! 90 2013OCT23_C_Tuckahoe1_2 2.23 1820.924 #DIV/0! 91 2013OCT23_C_Tuckahoe1_3 2.23 1913.282 #DIV/0! 92 2013OCT23_C_SolvA_33 #DIV/0! 93 2013OCT23_C_SolvA_34 #DIV/0! 94 2013OCT23_C_Tuckahoe2_1 2.22 2097.962 #DIV/0! 95 2013OCT23_C_Tuckahoe2_2 2.22 2283.351 #DIV/0! 96 2013OCT23_C_Tuckahoe2_3 2.23 1691.377 #DIV/0! 97 2013OCT23_C_SolvA_35 #DIV/0! 98 2013OCT23_C_SolvA_36 #DIV/0! 192 99 2013OCT23_C_GermanBranch_1 2.23 2319.369 #DIV/0! 100 2013OCT23_C_GermanBranch_2 2.23 1599.296 #DIV/0! 101 2013OCT23_C_GermanBranch_3 2.23 1946.113 #DIV/0! 102 2013OCT23_C_SolvA_37 #DIV/0! 103 2013OCT23_C_SolvA_38 #DIV/0! 104 2013OCT23_C_QC_Std25_3 2.22 1817.952 #DIV/0! 105 2013OCT23_C_SolvA_39 #DIV/0! 106 2013OCT23_C_SolvA_40 #DIV/0! 107 2013OCT23_C_Greensboro1_1 2.23 2021.967 #DIV/0! 108 2013OCT23_C_Greensboro1_2 2.23 1811.929 #DIV/0! 109 2013OCT23_C_Greensboro1_3 2.24 2285.401 #DIV/0! 110 2013OCT23_C_SolvA_41 #DIV/0! 111 2013OCT23_C_SolvA_42 #DIV/0! 112 2013OCT23_C_Greensboro2_1 2.23 2314.482 #DIV/0! 113 2013OCT23_C_Greensboro2_2 2.23 1741.815 #DIV/0! 114 2013OCT23_C_Greensboro2_3 2.23 1317.127 #DIV/0! 115 2013OCT23_C_SolvA_43 #DIV/0! 116 2013OCT23_C_SolvA_44 #DIV/0! 117 2013OCT23_C_BeaverDam_1 2.23 1722.333 #DIV/0! 118 2013OCT23_C_BeaverDam_2 2.23 2053.967 #DIV/0! 119 2013OCT23_C_BeaverDam_3 2.23 1718.502 #DIV/0! 120 2013OCT23_C_SolvA_45 #DIV/0! 121 2013OCT23_C_SolvA_46 #DIV/0! 122 2013OCT23_C_LongMarsh_1 2.23 1665.454 #DIV/0! 123 2013OCT23_C_LongMarsh_2 2.23 1820.102 #DIV/0! 124 2013OCT23_C_LongMarsh_3 2.23 1436.835 #DIV/0! 125 2013OCT23_C_SolvA_47 #DIV/0! 126 2013OCT23_C_SolvA_48 #DIV/0! 127 2013OCT23_C_0-01_Std_2 Standard 0.01 2.23 1330.085 #DIV/0! 128 2013OCT23_C_0-05_Std_2 Standard 0.05 2.22 959.825 #DIV/0! 129 2013OCT23_C_0-1_Std_2 Standard 0.1 2.22 1807.835 #DIV/0! 130 2013OCT23_C_0-5_Std_2 Standard 0.5 2.22 1487.42 #DIV/0! 131 2013OCT23_C_1_Std_2 Standard 1 2.22 1960.239 #DIV/0! 132 2013OCT23_C_5_Std_2 Standard 5 2.22 1661.211 #DIV/0! 133 2013OCT23_C_10_Std_2 Standard 10 2.23 1672.934 #DIV/0! 134 2013OCT23_C_25_Std_2 Standard 25 2.23 1415.005 #DIV/0! 135 2013OCT23_C_50_Std_2 Standard 50 2.22 1394.082 #DIV/0! 136 2013OCT23_C_100_Std_2 Standard 100 2.23 1368.488 #DIV/0! 137 2013OCT23_C_200_Stds_2 Standard 200 2.23 1186.672 #DIV/0! 138 2013OCT23_C_SolvA_49 #DIV/0! 139 2013OCT23_C_Surrogate_2 #DIV/0! 140 2013OCT23_C_SolvA_50 #DIV/0! 141 2013OCT23_C_SolvA_51 #DIV/0! 142 2013OCT23_C_SolvA_52 #DIV/0! 143 2013OCT23_C_SolvA_53 #DIV/0! 193 D.2 Raw data for Anacostia River analysis - IS correction is not shown in this data sheet Quantify Compound Summary Report Printed Thu Oct 24 20:00:53 2013 Compound 1: CAAT yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0 2 2013OCT21_A_Lab Blk 0 3 2013OCT21_A_Travel Blk 0 4 2013OCT21_A_0-01_Std 0.01 0.036 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 0 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 2.8 308.914 0 0.2 51% 7 2013OCT21_A_0-5_Std 0.5 2.81 1134.391 1127.63 835.79 1 0.6 11% 8 2013OCT21_A_1_Std 1 2.81 2282.431 1713.648 852.082 1 1.1 11% 9 2013OCT21_A_5_Std 5 2.8 13551.553 11643.304 7312.964 1 6.6 32% 10 2013OCT21_A_10_Std 10 2.8 25435.396 20721.354 13806.282 1 12.4 24% 11 2013OCT21_A_25_Std 25 2.8 60965.055 50308.902 33758.477 1 29.8 19% 12 2013OCT21_A_50_Std 50 2.8 111100.133 93204.633 61161.004 1 54.2 8% 13 2013OCT21_A_100_Std 100 2.8 213671.828 182320.688 120296.656 1 104.3 4% 14 2013OCT21_A_200_Stds 200 2.8 392406.344 335860 203344.672 1 191.6 -4% 15 2013OCT21_A_SolvA_2 #DIV/0! 0.0 197% 16 2013OCT21_A_Surrogate_1 19.91 0 0.0 -29% 17 2013OCT21_A_SolvA_3 #DIV/0! 0.2 59% 18 2013OCT21_A_SolvA_4 0 0.6 26% 19 2013OCT21_A_MM_0 2.8 3696.233 3134.925 2156.529 1 1.0 3% 20 2013OCT21_A_MM_1 2.8 7056.191 5461.028 3921.634 1 6.7 33% 21 2013OCT21_A_MM_5 2.8 17612.869 14699.948 10228.54 1 12.4 24% 22 2013OCT21_A_MM_10 2.8 29086.516 23105.473 15275.459 1 30.4 21% 23 2013OCT21_A_MM_25 2.8 60116.34 48998.27 32792.371 1 55.2 10% 24 2013OCT21_A_MM_50 2.81 108634.914 87009.906 58478.953 1 104.9 5% 25 2013OCT21_A_MM_100 2.8 221913.016 185584.219 122842.453 1 199.9 0% 26 2013OCT21_A_SolvA_5 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 2.81 3559.884 2868.627 1591.958 1 17.38 16.38 29 2013OCT21_A_BerwynRd_2 2.8 3664.294 2558.382 1542.409 1 17.89 16.86 30 2013OCT21_A_BerwynRd_3 2.81 3501.175 3057.219 1985.045 1 17.09 16.11 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 2.8 4309.184 3578.602 2456.238 1 21.04 19.82 34 2013OCT21_A_UMD_2 2.8 4517.222 3176.5 2003.448 1 22.05 20.78 35 2013OCT21_A_UMD_3 2.8 4596.953 3418.398 2599.271 1 22.44 21.15 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 194 38 2013OCT21_A_Arboretum1_1 2.81 4204.888 2827.535 2227.049 1 20.53 19.34 39 2013OCT21_A_Arboretum1_2 2.81 4295.087 3463.62 2230.087 1 20.97 19.76 40 2013OCT21_A_Arboretum1_3 2.81 4337.297 3481.018 2408.508 1 21.17 19.95 41 2013OCT21_A_SolvA_11 19.017 #DIV/0! 42 2013OCT21_A_SolvA_12 0.744 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.8 4877.375 3531.15 2857.529 1 23.81 22.44 44 2013OCT21_A_Arboretum2_2 2.81 5076.842 2595.186 2110.371 1 24.78 23.35 45 2013OCT21_A_Arboretum2_3 2.81 4820.272 3895.326 2416.514 1 23.53 22.17 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 2.8 63258.148 51093.566 33095.879 1 308.81 290.99 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 2.8 5052.644 3959.49 2448.374 1 24.67 23.24 52 2013OCT21_A_NorthDr1_2 2.81 5592.044 3696.618 3304.756 1 27.30 25.72 53 2013OCT21_A_NorthDr1_3 2.8 5461.167 3945.245 3020.321 1 26.66 25.12 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 2.81 4694.319 4300.312 2446.489 1 22.92 21.59 57 2013OCT21_A_NorthDr2_2 2.8 4746.346 3694.977 3085.117 1 23.17 21.83 58 2013OCT21_A_NorthDr2_3 2.8 4885.666 3738.627 2612.862 1 23.85 22.47 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.8 4868.817 3378.624 2875.28 1 23.77 22.40 62 2013OCT21_A_AnacostiaPk_2 2.81 4974.495 3541.832 2608.618 1 24.28 22.88 63 2013OCT21_A_AnacostiaPk_3 2.8 4821.31 3329.337 2266.986 1 23.54 22.18 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.81 1587.171 1082.856 940.589 1 7.75 7.30 67 2013OCT21_A_GreenbeltPk_2 2.81 1799.016 1304.326 940.797 1 8.78 8.28 68 2013OCT21_A_GreenbeltPk_3 2.8 1587.796 1657.16 951.377 1 7.75 7.30 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.81 4924.31 4062.735 2593.98 1 24.04 22.65 72 2013OCT21_A_PowderMillRd_2 2.81 4835.218 3746.461 2842.11 1 23.60 22.24 73 2013OCT21_A_PowderMillRd_3 2.81 5168.017 3835.859 2708.367 1 25.23 23.77 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.8 62535.492 52226.176 35707.25 1 305.28 287.67 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 2.81 3565.304 3112.041 2313.301 1 17.40 16.40 80 2013OCT21_A_ResearchRd_2 2.81 3943.918 3587.532 2311.422 1 19.25 18.14 81 2013OCT21_A_ResearchRd_3 2.8 3788.143 2810.057 2156.582 1 18.49 17.43 82 2013OCT21_A_SolvA_29 #DIV/0! 195 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.8 4598.436 2866.549 2073.188 1 22.45 21.15 85 2013OCT21_A_Skateboard_2 2.81 4411.809 2750.494 2104.471 1 21.54 20.29 86 2013OCT21_A_Skateboard_3 2.8 3659.609 2740.599 2515.675 1 17.87 16.83 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 150.131 #DIV/0! 89 2013OCT21_A_SligoCreek_1 2.8 2461.231 1901.629 1394.98 1 12.01 11.32 90 2013OCT21_A_SligoCreek_2 2.8 2734.852 1750.651 1435.871 1 13.35 12.58 91 2013OCT21_A_SligoCreek_3 2.8 2425.933 1835.003 1190.91 1 11.84 11.16 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.8 6053.579 4369.966 3446.201 1 29.55 27.85 95 2013OCT21_A_RiverdaleRd_2 2.8 6094.268 5045.188 3144.552 1 29.75 28.03 96 2013OCT21_A_RiverdaleRd_3 2.81 6939.92 4668.266 4068.635 1 33.88 31.92 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 2.79 60.851 78.78 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 2.8 72.865 9.044 17.759 0 102 2013OCT21_A_0-1_Std_2 0.1 2.81 324.984 237.661 0 103 2013OCT21_A_0-5_Std_2 0.5 2.8 1286.783 1348.343 0 104 2013OCT21_A_1_Std_2 1 2.8 2106.015 1984.993 1319.002 1 105 2013OCT21_A_5_Std_2 5 2.8 13634.713 10742.219 7502.584 1 106 2013OCT21_A_10_Std_2 10 2.8 25409.914 21514.541 14402.192 1 107 2013OCT21_A_25_Std_2 25 2.81 62202.75 51962.117 34216.738 1 108 2013OCT21_A_50_Std_2 50 2.8 113010.672 97601.75 64209.707 1 109 2013OCT21_A_100_Std_2 100 2.8 214968.406 173288.156 126974.18 1 110 2013OCT21_A_200_Stds_2 200 2.81 409434.813 351806.063 236618.797 1 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 2: CEAT yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0 2 2013OCT21_A_Lab Blk 0 3 2013OCT21_A_Travel Blk 0 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 2.27 361.424 278.594 0 0.0 -5% 6 2013OCT21_A_0-1_Std 0.1 2.27 1042.319 693.464 0 0.1 37% 7 2013OCT21_A_0-5_Std 0.5 2.27 3577.796 4024.61 5234.51 1 0.5 -6% 8 2013OCT21_A_1_Std 1 2.27 7885.216 8156.392 11543.513 1 1.0 3% 9 2013OCT21_A_5_Std 5 2.27 40956.934 43910.586 52623.242 1 5.4 7% 196 10 2013OCT21_A_10_Std 10 2.27 78400.063 86323.109 102931.336 1 10.3 3% 11 2013OCT21_A_25_Std 25 2.27 195219.641 207255.172 247297.234 1 25.6 2% 12 2013OCT21_A_50_Std 50 2.27 379088.438 386288.188 474856.813 1 49.7 -1% 13 2013OCT21_A_100_Std 100 2.27 731487 781272.125 940761.188 1 95.8 -4% 14 2013OCT21_A_200_Stds 200 2.27 1404751.875 1481993.75 1812547.75 1 184.1 -8% 15 2013OCT21_A_SolvA_2 #DIV/0! 0.0 29% 16 2013OCT21_A_Surrogate_1 #DIV/0! 0.1 61% 17 2013OCT21_A_SolvA_3 #DIV/0! 0.2 51% 18 2013OCT21_A_SolvA_4 #DIV/0! 0.6 15% 19 2013OCT21_A_MM_0 2.27 8822.355 8914.719 10896.059 1 1.1 12% 20 2013OCT21_A_MM_1 2.27 17728.09 18777.992 23138.99 1 6.4 28% 21 2013OCT21_A_MM_5 2.27 56365.832 57505.633 69864.664 1 12.0 20% 22 2013OCT21_A_MM_10 2.27 88481.906 94878.18 114675.953 1 29.5 18% 23 2013OCT21_A_MM_25 2.27 184821 202481.516 244478.828 1 55.3 11% 24 2013OCT21_A_MM_50 2.27 350372.5 372410.188 444069.688 1 109.1 9% 25 2013OCT21_A_MM_100 2.27 748405.75 797230.438 959250.5 1 211.4 6% 26 2013OCT21_A_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 2.27 10435.189 11122.244 13570.162 1 13.67 14.33 29 2013OCT21_A_BerwynRd_2 2.27 10767.096 10855.727 13777.115 1 14.11 14.79 30 2013OCT21_A_BerwynRd_3 2.27 10135.005 12006.263 13452.787 1 13.28 13.92 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 2.27 9560.073 9293.247 10446.093 1 12.53 13.13 34 2013OCT21_A_UMD_2 2.27 9520.483 10471.779 12992.21 1 12.47 13.08 35 2013OCT21_A_UMD_3 2.27 9842.457 10348.212 10960.888 1 12.90 13.52 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 2.27 7533.813 8329.437 10258.46 1 9.87 10.35 39 2013OCT21_A_Arboretum1_2 2.27 8404.867 9003.815 9408.37 1 11.01 11.54 40 2013OCT21_A_Arboretum1_3 2.27 8249.977 9261.613 11133.458 1 10.81 11.33 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.27 8878.268 8860.572 10567.701 1 11.63 12.19 44 2013OCT21_A_Arboretum2_2 2.27 8727.384 9610.319 11856.523 1 11.44 11.99 45 2013OCT21_A_Arboretum2_3 2.27 8486.918 9105.131 11300.909 1 11.12 11.66 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 2.27 214716.906 223295.438 274265.875 1 281.34 294.90 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 2.27 15869.056 17148.031 20379.178 1 20.79 21.80 52 2013OCT21_A_NorthDr1_2 2.27 14718.539 16598.414 21071.365 1 19.29 20.22 53 2013OCT21_A_NorthDr1_3 2.27 15535.917 15583.973 19995.742 1 20.36 21.34 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 197 56 2013OCT21_A_NorthDr2_1 2.27 15190.952 15885.634 19085.752 1 19.90 20.86 57 2013OCT21_A_NorthDr2_2 2.27 14490.879 16245.345 21223.902 1 18.99 19.90 58 2013OCT21_A_NorthDr2_3 2.27 15878.239 15568.822 20239.932 1 20.81 21.81 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.27 9299.353 10959.285 11113.176 1 12.18 12.77 62 2013OCT21_A_AnacostiaPk_2 2.27 9317.083 11257.184 12398.323 1 12.21 12.80 63 2013OCT21_A_AnacostiaPk_3 2.27 10009.281 10712.394 12074.516 1 13.12 13.75 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.27 3483.46 4154.448 5131.362 1 4.56 4.78 67 2013OCT21_A_GreenbeltPk_2 2.27 3218.009 3371.941 4146.969 1 4.22 4.42 68 2013OCT21_A_GreenbeltPk_3 2.27 3671.676 3173.687 5261.331 1 4.81 5.04 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.27 8842.16 8639.277 10353.762 1 11.59 12.14 72 2013OCT21_A_PowderMillRd_2 2.27 7061.84 8417.748 10860.603 1 9.25 9.70 73 2013OCT21_A_PowderMillRd_3 2.27 8226.511 8553.978 10118.693 1 10.78 11.30 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.27 217116 228911.234 273051.938 1 284.49 298.20 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 2.27 15749.537 16340.565 19825.416 1 20.64 21.63 80 2013OCT21_A_ResearchRd_2 2.27 16355.639 17967.959 19933.732 1 21.43 22.46 81 2013OCT21_A_ResearchRd_3 2.27 17440.828 16077.889 20576.705 1 22.85 23.95 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.27 5497.958 6058.53 6969.838 1 7.20 7.55 85 2013OCT21_A_Skateboard_2 2.27 4930.771 4922.867 7032.834 1 6.46 6.77 86 2013OCT21_A_Skateboard_3 2.27 6101.84 6599.745 6507.48 1 8.00 8.38 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 #DIV/0! 89 2013OCT21_A_SligoCreek_1 2.27 4503.315 4841.385 5671.086 1 5.90 6.19 90 2013OCT21_A_SligoCreek_2 2.27 4841.328 5030.047 5869.199 1 6.34 6.65 91 2013OCT21_A_SligoCreek_3 2.27 5005.158 4539.318 6410.985 1 6.56 6.87 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.27 13985.52 15991.804 18140.406 1 18.33 19.21 95 2013OCT21_A_RiverdaleRd_2 2.27 14610.815 16070.472 20066.596 1 19.14 20.07 96 2013OCT21_A_RiverdaleRd_3 2.27 14129.913 15983.23 20059.646 1 18.51 19.41 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 2.26 98.609 27.488 #DIV/0! 198 101 2013OCT21_A_0-05_Std_2 0.05 2.29 614.356 322.394 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 2.27 1154.752 1250.256 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 2.27 4405.411 4386.381 6087.618 1 104 2013OCT21_A_1_Std_2 1 2.27 8569.365 8927.637 10809.769 1 105 2013OCT21_A_5_Std_2 5 2.27 48855.793 49389.332 57853.563 1 106 2013OCT21_A_10_Std_2 10 2.27 91875.766 100294.953 118401.367 1 107 2013OCT21_A_25_Std_2 25 2.27 225426.891 236501.031 276439.594 1 108 2013OCT21_A_50_Std_2 50 2.27 421832.156 440482.281 537468.375 1 109 2013OCT21_A_100_Std_2 100 2.27 832948.313 886638.875 1055743.875 1 110 2013OCT21_A_200_Stds_2 200 2.27 1613414.25 1699219.875 2017937.875 1 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 3: CIAT yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 #DIV/0! #DIV/0! 2 2013OCT21_A_Lab Blk 2.8 450.891 400.462 693.728 0 #DIV/0! 3 2013OCT21_A_Travel Blk #DIV/0! #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 2.8 244.803 151.889 1043.518 1 0.01 -1% 5 2013OCT21_A_0-05_Std 0.05 2.8 1023.859 1007.338 3933.092 1 0.04 -17% 6 2013OCT21_A_0-1_Std 0.1 2.81 3197.693 2835.502 12226.565 1 0.1 29% 7 2013OCT21_A_0-5_Std 0.5 2.81 14829.271 13712.326 56412.59 1 0.6 20% 8 2013OCT21_A_1_Std 1 2.81 27229.41 23045.871 97570.617 1 1.1 10% 9 2013OCT21_A_5_Std 5 2.81 162035.406 141584.969 576737.813 1 6.6 31% 10 2013OCT21_A_10_Std 10 2.81 299955.875 258808.875 1076854.5 1 12.1 21% 11 2013OCT21_A_25_Std 25 2.8 685592.375 618881.875 2600610.5 1 27.7 11% 12 2013OCT21_A_50_Std 50 2.8 1269030.75 1082116 4556643.5 1 51.4 3% 13 2013OCT21_A_100_Std 100 2.8 2460230 2203913.75 8002871 1 99.6 0% 14 2013OCT21_A_200_Stds 200 2.81 4550775.5 3907647.25 10687466 1 184.2 -8% 15 2013OCT21_A_SolvA_2 2.81 333.132 #DIV/0! 0.0 13% 16 2013OCT21_A_Surrogate_1 #DIV/0! 0.0 -12% 17 2013OCT21_A_SolvA_3 #DIV/0! 0.1 35% 18 2013OCT21_A_SolvA_4 #DIV/0! 0.6 27% 19 2013OCT21_A_MM_0 2.81 44209.113 37966.926 165263.328 1 1.2 16% 20 2013OCT21_A_MM_1 2.8 77493.891 70583.93 269533.25 1 7.1 42% 21 2013OCT21_A_MM_5 2.81 200448.172 181614.859 764161.188 1 13.4 34% 22 2013OCT21_A_MM_10 2.81 307239.906 282931.313 1173358.5 1 31.2 25% 23 2013OCT21_A_MM_25 2.81 664882.125 585636.813 2448672.75 1 59.2 18% 24 2013OCT21_A_MM_50 2.81 1179528.5 1012557.188 4275258 1 112.5 13% 25 2013OCT21_A_MM_100 2.81 2326066.75 2077419.625 7716813 1 205.6 3% 26 2013OCT21_A_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 199 28 2013OCT21_A_BerwynRd_1 2.81 38375.145 35667.16 144667.188 1 15.53 16.73 29 2013OCT21_A_BerwynRd_2 2.81 42174.961 32467.666 155106.031 1 17.07 18.39 30 2013OCT21_A_BerwynRd_3 2.81 41953.984 36929.414 148305.781 1 16.98 18.29 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 2.81 51116.672 44195.488 185198.531 1 20.69 22.29 34 2013OCT21_A_UMD_2 2.81 50994.863 44228.883 191239.047 1 20.64 22.23 35 2013OCT21_A_UMD_3 2.81 51212.906 46719.531 190590.266 1 20.73 22.33 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 2.81 46435.84 41540.727 173379.484 1 18.79 20.25 39 2013OCT21_A_Arboretum1_2 2.81 47703.551 41184.078 177175.016 1 19.31 20.80 40 2013OCT21_A_Arboretum1_3 2.81 49039.355 43536.043 179727.188 1 19.85 21.38 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.81 50245.777 44914.273 190352.266 1 20.34 21.91 44 2013OCT21_A_Arboretum2_2 2.81 52403.398 44296.73 189767.172 1 21.21 22.85 45 2013OCT21_A_Arboretum2_3 2.81 50191.059 49368.676 194581.969 1 20.31 21.88 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 2.81 714088 652743.625 2701291 1 289.01 311.35 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 2.81 56816.801 50038.039 210050.219 1 23.00 24.77 52 2013OCT21_A_NorthDr1_2 2.81 57005.176 47888.625 216182.844 1 23.07 24.85 53 2013OCT21_A_NorthDr1_3 2.81 56982.973 51467.52 213769.922 1 23.06 24.85 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 2.81 51204.555 47212.676 198472.656 1 20.72 22.33 57 2013OCT21_A_NorthDr2_2 2.81 56176.086 49429.734 196757.578 1 22.74 24.49 58 2013OCT21_A_NorthDr2_3 2.81 55505.066 48455.375 203906.328 1 22.46 24.20 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.81 51409.539 46871.727 197430.375 1 20.81 22.42 62 2013OCT21_A_AnacostiaPk_2 2.81 54207.793 44051.613 198688.25 1 21.94 23.64 63 2013OCT21_A_AnacostiaPk_3 2.81 48314.316 45866.84 191298.359 1 19.55 21.07 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.81 19077.111 17456.197 70616.969 1 7.72 8.32 67 2013OCT21_A_GreenbeltPk_2 2.81 20290.656 17139.496 68449.414 1 8.21 8.85 68 2013OCT21_A_GreenbeltPk_3 2.81 18792.955 18295.086 74766.281 1 7.61 8.19 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.81 55975.68 50649.246 204402.609 1 22.66 24.41 72 2013OCT21_A_PowderMillRd_2 2.81 57591.703 52271.895 211510.281 1 23.31 25.11 200 73 2013OCT21_A_PowderMillRd_3 2.81 58095.133 52457.035 210358.969 1 23.51 25.33 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.81 763931.5 670667.438 2719940 1 309.19 333.08 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 2.81 47102.625 43036.629 170095.938 1 19.06 20.54 80 2013OCT21_A_ResearchRd_2 2.81 47590.898 44120.438 180871.594 1 19.26 20.75 81 2013OCT21_A_ResearchRd_3 2.8 50288.133 42210.977 168225.828 1 20.35 21.93 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.8 47881.566 41589.395 169285.109 1 19.38 20.88 85 2013OCT21_A_Skateboard_2 2.8 48999.75 43708.836 163473.344 1 19.83 21.36 86 2013OCT21_A_Skateboard_3 2.8 47834.629 42713.539 178714.484 1 19.36 20.86 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 2.81 241.267 95.97 41.149 0 89 2013OCT21_A_SligoCreek_1 2.8 30971.717 27617.688 112226.805 1 12.54 13.50 90 2013OCT21_A_SligoCreek_2 2.8 29490.469 28242.32 107688.625 1 11.94 12.86 91 2013OCT21_A_SligoCreek_3 2.81 30286.328 28320.064 114599.055 1 12.26 13.21 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.8 69091.258 67484.805 254286.031 1 27.96 30.12 95 2013OCT21_A_RiverdaleRd_2 2.81 66964.844 68529.352 274317.875 1 27.10 29.20 96 2013OCT21_A_RiverdaleRd_3 2.81 73989.648 67705.523 249757.813 1 29.95 32.26 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 2.8 279.157 257.501 1405.279 1 101 2013OCT21_A_0-05_Std_2 0.05 2.81 1082.482 1268.319 4811.827 1 102 2013OCT21_A_0-1_Std_2 0.1 2.8 3335.443 3450.927 14340.876 1 103 2013OCT21_A_0-5_Std_2 0.5 2.8 15705.853 14301.647 52180.371 1 104 2013OCT21_A_1_Std_2 1 2.8 28773.66 27389.689 106412.469 1 105 2013OCT21_A_5_Std_2 5 2.8 175308.219 154911.547 618713.313 1 106 2013OCT21_A_10_Std_2 10 2.81 330998.875 292365.969 1197768.875 1 107 2013OCT21_A_25_Std_2 25 2.81 771365.125 718463.938 2876485 1 108 2013OCT21_A_50_Std_2 50 2.8 1462112 1322248.375 5153456 1 109 2013OCT21_A_100_Std_2 100 2.81 2779975 2536363.75 8828277 1 110 2013OCT21_A_200_Stds_2 200 2.81 5081034 4685666 11167619 1 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 4: OIET yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff 201 Name Std. Conc RT Area 1? Area 2? Area #VALUE! 1 2013OCT21_SolvA_1 2.13 312.975 944.806 1290.941 1 2 2013OCT21_A_Lab Blk 2.13 541.082 794.141 1411.241 1 3 2013OCT21_A_Travel Blk 2.14 1097.261 2455.411 3269.718 1 4 2013OCT21_A_0-01_Std 0.01 2.12 580.797 1481.063 2604.066 1 0.0 87% 5 2013OCT21_A_0-05_Std 0.05 2.13 1802.111 3477.823 5386.139 1 0.1 16% 6 2013OCT21_A_0-1_Std 0.1 2.13 4194.489 7462.787 11845.754 1 0.1 35% 7 2013OCT21_A_0-5_Std 0.5 2.13 19512.398 34124.855 51056.629 1 0.6 26% 8 2013OCT21_A_1_Std 1 2.13 38767.359 67816.813 100650.602 1 1.2 25% 9 2013OCT21_A_5_Std 5 2.13 111672.164 196361.672 291533.875 1 3.6 -28% 10 2013OCT21_A_10_Std 10 2.13 204213.359 368263.594 554663.188 1 6.6 -34% 11 2013OCT21_A_25_Std 25 2.13 555438.125 995733.938 1493792.5 1 17.9 -28% 12 2013OCT21_A_50_Std 50 2.13 1446770.5 2548183.25 3779779 1 46.6 -7% 13 2013OCT21_A_100_Std 100 2.13 3059717.75 5222373 6766549.5 1 98.5 -1% 14 2013OCT21_A_200_Stds 200 2.13 5922230 7775076 8825046 1 190.7 -5% 15 2013OCT21_A_SolvA_2 2.12 1568.544 2034.216 3132.181 1 0.0 264% 16 2013OCT21_A_Surrogate_1 2.13 446.95 1252.702 1514.58 0 0.1 58% 17 2013OCT21_A_SolvA_3 #DIV/0! 0.1 35% 18 2013OCT21_A_SolvA_4 2.16 682.3 1393.267 1583.154 0 0.7 38% 19 2013OCT21_A_MM_0 2.13 38516.344 63883.551 94258.508 1 1.4 36% 20 2013OCT21_A_MM_1 2.13 80581.602 143929.297 209283 1 4.0 -20% 21 2013OCT21_A_MM_5 2.13 250284.547 438751.813 656085.75 1 7.4 -26% 22 2013OCT21_A_MM_10 2.13 423365.938 746362.563 1102349.5 1 19.8 -21% 23 2013OCT21_A_MM_25 2.13 884667.75 1537688.375 2313318.5 1 51.4 3% 24 2013OCT21_A_MM_50 2.13 606412.563 1064600.625 1546698.5 1 112.5 12% 25 2013OCT21_A_MM_100 2.13 3909915.75 5887996.5 7345645.5 1 206.2 3% 26 2013OCT21_A_SolvA_5 1273.367 1503.922 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 2.13 652.726 871.85 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 2.14 62736.883 113966.156 170024.25 1 20.20 18.82 29 2013OCT21_A_BerwynRd_2 2.13 66276.609 116742.195 171449.313 1 21.34 19.89 30 2013OCT21_A_BerwynRd_3 2.13 65455.668 115616.281 171193.656 1 21.08 19.64 31 2013OCT21_A_SolvA_7 991.549 #DIV/0! 32 2013OCT21_A_SolvA_8 2.12 504.574 1066.622 2046.408 1 33 2013OCT21_A_UMD_1 2.13 34073.926 59006.113 86341.313 1 10.97 10.22 34 2013OCT21_A_UMD_2 2.13 35159.848 58615.758 86757.008 1 11.32 10.55 35 2013OCT21_A_UMD_3 2.13 35338.398 56051.207 89548.227 1 11.38 10.60 36 2013OCT21_A_SolvA_9 469.54 558.109 0 37 2013OCT21_A_SolvA_10 2.12 464.3 472.146 558.562 0 38 2013OCT21_A_Arboretum1_1 2.13 36941.379 61944.426 87208.008 1 11.90 11.08 39 2013OCT21_A_Arboretum1_2 2.13 37116.875 67178.656 98925.063 1 11.95 11.14 40 2013OCT21_A_Arboretum1_3 2.13 37461.563 67271.141 98040.109 1 12.06 11.24 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.13 40087.145 68920.109 94420.641 1 12.91 12.03 44 2013OCT21_A_Arboretum2_2 2.13 39668.285 69874.891 106015.375 1 12.77 11.90 45 2013OCT21_A_Arboretum2_3 2.13 39947.84 71221.727 103917.016 1 12.86 11.99 202 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 767.926 944.002 0 48 2013OCT21_A_QC_Std25_1 2.13 577384.5 1008917.313 1513998 1 185.93 173.24 49 2013OCT21_A_SolvA_15 2.12 265.755 861.883 1065.173 1 50 2013OCT21_A_SolvA_16 2.12 381.375 415.432 1489.563 0 51 2013OCT21_A_NorthDr1_1 2.13 30827.459 55970.293 80814.438 1 9.93 9.25 52 2013OCT21_A_NorthDr1_2 2.13 30770.268 56700.52 83849.063 1 9.91 9.23 53 2013OCT21_A_NorthDr1_3 2.13 32336.328 57049.551 81871.156 1 10.41 9.70 54 2013OCT21_A_SolvA_17 2.12 286.347 35.727 938.371 0 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 2.13 32084.271 51839.086 80504.297 1 10.33 9.63 57 2013OCT21_A_NorthDr2_2 2.13 32974.324 56942.637 82023.586 1 10.62 9.89 58 2013OCT21_A_NorthDr2_3 2.13 31233.988 56827.844 82296.063 1 10.06 9.37 59 2013OCT21_A_SolvA_19 316.294 449.169 0 60 2013OCT21_A_SolvA_20 1182.274 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.13 23864.773 44791.07 66563.164 1 7.68 7.16 62 2013OCT21_A_AnacostiaPk_2 2.13 25784.188 41408.094 66112.805 1 8.30 7.74 63 2013OCT21_A_AnacostiaPk_3 2.13 23685.416 43327.098 60015.438 1 7.63 7.11 64 2013OCT21_A_SolvA_21 2.14 1107.031 2220.556 2068.91 1 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.13 20402.385 36986.559 49828.633 1 6.57 6.12 67 2013OCT21_A_GreenbeltPk_2 2.13 21371.764 34177.891 54060.109 1 6.88 6.41 68 2013OCT21_A_GreenbeltPk_3 2.13 21655.51 38695.633 56407.156 1 6.97 6.50 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.13 23786.447 42701.816 63243.797 1 7.66 7.14 72 2013OCT21_A_PowderMillRd_2 2.13 25686.912 44540.164 66510.328 1 8.27 7.71 73 2013OCT21_A_PowderMillRd_3 2.13 25813.84 44418.77 62219.391 1 8.31 7.75 74 2013OCT21_A_SolvA_25 447.377 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.13 597223.813 1020855.563 1533892.875 1 192.32 179.19 77 2013OCT21_A_SolvA_27 2.13 371.491 1134.988 1079.955 0 78 2013OCT21_A_SolvA_28 2.14 343.764 1309.719 #DIV/0! 79 2013OCT21_A_ResearchRd_1 2.13 101554.188 177482.516 260080.734 1 32.70 30.47 80 2013OCT21_A_ResearchRd_2 2.13 105465.469 184118.594 268326.875 1 33.96 31.64 81 2013OCT21_A_ResearchRd_3 2.13 107474.344 183848.891 275958.031 1 34.61 32.25 82 2013OCT21_A_SolvA_29 2.12 562.1 577.038 #DIV/0! 83 2013OCT21_A_SolvA_30 2.12 436.822 532.155 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.13 21405.824 39314.363 56910.102 1 6.89 6.42 85 2013OCT21_A_Skateboard_2 2.13 23523.57 41121.02 58838.527 1 7.58 7.06 86 2013OCT21_A_Skateboard_3 2.13 22500.486 42304.895 56745.055 1 7.25 6.75 87 2013OCT21_A_SolvA_31 2.12 319.769 510.027 659.816 1 88 2013OCT21_A_SolvA_32 2.12 5053.669 10228.499 15285.631 1 89 2013OCT21_A_SligoCreek_1 2.13 22446.184 38179.523 60248.797 1 7.23 6.73 90 2013OCT21_A_SligoCreek_2 2.13 21475.133 38780.875 59481.328 1 6.92 6.44 203 91 2013OCT21_A_SligoCreek_3 2.13 25031.76 42306.688 61187.855 1 8.06 7.51 92 2013OCT21_A_SolvA_33 2.14 633.229 619.683 745.77 0 93 2013OCT21_A_SolvA_34 688.034 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.13 55576.016 90484.797 142193.359 1 17.90 16.68 95 2013OCT21_A_RiverdaleRd_2 2.13 59987.887 99208.875 147667.188 1 19.32 18.00 96 2013OCT21_A_RiverdaleRd_3 2.13 56606.777 100722.641 149650.078 1 18.23 16.98 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 620.306 #DIV/0! 99 2013OCT21_A_SolvA_37 1672.203 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 2.12 1129.033 1992.026 3130.406 1 101 2013OCT21_A_0-05_Std_2 0.05 2.12 2446.918 4147.655 5957.315 1 102 2013OCT21_A_0-1_Std_2 0.1 2.13 4179.644 8843.726 11311.616 1 103 2013OCT21_A_0-5_Std_2 0.5 2.13 21428.232 35568.676 56187.398 1 104 2013OCT21_A_1_Std_2 1 2.12 42251.664 75054.539 106413.492 1 105 2013OCT21_A_5_Std_2 5 2.12 124838.672 212329.609 304742.969 1 106 2013OCT21_A_10_Std_2 10 2.13 231143.719 401955.281 594720.938 1 107 2013OCT21_A_25_Std_2 25 2.13 615993.188 1042057.563 1540557.5 1 108 2013OCT21_A_50_Std_2 50 2.12 1596533.125 2771674.75 4142093.75 1 109 2013OCT21_A_100_Std_2 100 2.13 3492703 5593869 7005423.5 1 110 2013OCT21_A_200_Stds_2 200 2.13 6402839 8281439.5 9148247 0 111 2013OCT21_A_SolvA_38 2.13 4265.138 6368.419 9056.809 1 112 2013OCT21_A_Surrogate_2 2.12 1273.553 1679.081 2949.056 1 113 2013OCT21_A_SolvA_39 2.13 1214.255 1300.554 3145.234 0 114 2013OCT21_A_SolvA_40 2.13 2433.218 4640.607 8079.837 1 115 2013OCT21_A_SolvA_41 2.14 677.49 1703.375 #DIV/0! 116 2013OCT21_A_SolvA_42 2.14 506.597 1447.115 #DIV/0! Compound 5: Atrazine yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area #VALUE! 1 2013OCT21_SolvA_1 5.44 417.423 979.464 1869.91 1 2 2013OCT21_A_Lab Blk 5.42 3397.819 5490.835 16321.513 1 3 2013OCT21_A_Travel Blk 5.41 5271.725 6561.954 17545.588 1 4 2013OCT21_A_0-01_Std 0.01 5.42 1693.839 2001.853 5201.206 1 0.0 210% 5 2013OCT21_A_0-05_Std 0.05 5.41 4274.767 4787.533 14195.386 1 0.1 56% 6 2013OCT21_A_0-1_Std 0.1 5.41 7490.69 9027.336 27077.662 1 0.1 37% 7 2013OCT21_A_0-5_Std 0.5 5.41 31909.107 40620.68 114638.828 1 0.6 17% 8 2013OCT21_A_1_Std 1 5.42 64674.402 79159.117 215497.453 1 1.2 18% 9 2013OCT21_A_5_Std 5 5.41 321345.344 401998.938 1161227.625 1 5.9 17% 10 2013OCT21_A_10_Std 10 5.41 625706.563 781792 2200077.5 1 11.4 14% 11 2013OCT21_A_25_Std 25 5.41 1565248 1939772.25 5517760 1 28.6 14% 12 2013OCT21_A_50_Std 50 5.41 2967704.25 3626218.5 9912106 1 54.2 8% 13 2013OCT21_A_100_Std 100 5.41 5688427 6942977.5 14072538 1 104.0 4% 14 2013OCT21_A_200_Stds 200 5.42 10572069 11920034 16016493 0 193.2 -3% 15 2013OCT21_A_SolvA_2 5.42 1380.87 1850.547 3892.956 1 0.0 360% 16 2013OCT21_A_Surrogate_1 5.41 4697.487 4694.695 14430.813 0 0.1 83% 17 2013OCT21_A_SolvA_3 5.41 889.141 722.485 1938.097 0 0.2 56% 204 18 2013OCT21_A_SolvA_4 5.42 526.527 502.245 1986.435 0 0.6 16% 19 2013OCT21_A_MM_0 5.41 135838.266 171757.375 486267.188 1 1.2 24% 20 2013OCT21_A_MM_1 5.41 221098.5 258406.047 754974.938 1 6.2 24% 21 2013OCT21_A_MM_5 5.42 481379.5 593659.313 1701705.5 1 12.0 20% 22 2013OCT21_A_MM_10 5.42 740101.25 917896.5 2626082.5 1 30.4 21% 23 2013OCT21_A_MM_25 5.41 1423429 1770045 5098840.5 1 56.0 12% 24 2013OCT21_A_MM_50 5.41 2628607.5 3123730 9217575 1 102.6 3% 25 2013OCT21_A_MM_100 5.41 5766957.5 6960671.5 13588813 1 199.5 0% 26 2013OCT21_A_SolvA_5 2005.057 #DIV/0! Forced (0,0) MM 27 2013OCT21_A_SolvA_6 5.44 288.716 606.701 1724.398 1 (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 5.42 122328.477 150863.922 425805.031 1 22.36 22.27 29 2013OCT21_A_BerwynRd_2 5.42 123737.469 152978.406 446493.063 1 22.62 22.53 30 2013OCT21_A_BerwynRd_3 5.42 124067.734 154849.953 441318.5 1 22.68 22.59 31 2013OCT21_A_SolvA_7 1065.448 #DIV/0! 32 2013OCT21_A_SolvA_8 288.135 546.679 0 33 2013OCT21_A_UMD_1 5.42 144149.203 174201.703 500259.781 1 26.35 26.25 34 2013OCT21_A_UMD_2 5.41 141219.734 169811.719 512826.125 1 25.81 25.71 35 2013OCT21_A_UMD_3 5.41 141454.844 176991.594 505150.344 1 25.86 25.75 36 2013OCT21_A_SolvA_9 828.738 #DIV/0! 37 2013OCT21_A_SolvA_10 5.4 357.62 351.26 965.746 1 38 2013OCT21_A_Arboretum1_1 5.41 130735.531 162891.531 465128.25 1 23.90 23.80 39 2013OCT21_A_Arboretum1_2 5.42 134015.266 161418.266 482447.469 1 24.50 24.40 40 2013OCT21_A_Arboretum1_3 5.41 133267.047 163507.078 469991.094 1 24.36 24.26 41 2013OCT21_A_SolvA_11 744.485 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 5.41 150569.891 181355.313 535844.688 1 27.52 27.41 44 2013OCT21_A_Arboretum2_2 5.41 152705.813 183978.766 521921.438 1 27.91 27.80 45 2013OCT21_A_Arboretum2_3 5.41 152293.297 185202.625 526623.563 1 27.84 27.73 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 817.475 #DIV/0! 48 2013OCT21_A_QC_Std25_1 5.41 1581056.625 1969864.25 5374051.5 1 289.00 287.86 49 2013OCT21_A_SolvA_15 623.186 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 5.41 174806.484 216435.781 636830.125 1 31.95 31.83 52 2013OCT21_A_NorthDr1_2 5.41 182622.516 225150.219 644538.438 1 33.38 33.25 53 2013OCT21_A_NorthDr1_3 5.41 181499.188 225087.25 634991.5 1 33.18 33.05 54 2013OCT21_A_SolvA_17 534.289 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 5.41 180816.859 220280.953 640008.438 1 33.05 32.92 57 2013OCT21_A_NorthDr2_2 5.41 176799.203 226549.281 643439.313 1 32.32 32.19 58 2013OCT21_A_NorthDr2_3 5.41 182187.734 228874.406 650383.563 1 33.30 33.17 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 5.41 211550.219 254445.234 734054.938 1 38.67 38.52 62 2013OCT21_A_AnacostiaPk_2 5.41 218566.359 258383.922 766503.875 1 39.95 39.79 205 63 2013OCT21_A_AnacostiaPk_3 5.41 213299.25 256974.781 757044.063 1 38.99 38.84 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 5.42 73253.5 88621.422 254383.5 1 13.39 13.34 67 2013OCT21_A_GreenbeltPk_2 5.41 73145.945 87698.336 261552.063 1 13.37 13.32 68 2013OCT21_A_GreenbeltPk_3 5.42 72515.602 89549.695 258067.406 1 13.26 13.20 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 5.42 162168.328 200803.375 567108.75 1 29.64 29.53 72 2013OCT21_A_PowderMillRd_2 5.42 161488.719 204621.813 576776.938 1 29.52 29.40 73 2013OCT21_A_PowderMillRd_3 5.42 162008.203 200951.375 565914.375 1 29.61 29.50 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 5.42 1602732.625 2014133.75 5408109 1 292.96 291.81 77 2013OCT21_A_SolvA_27 853.679 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 5.42 97667.555 126409.07 349362.125 1 17.85 17.78 80 2013OCT21_A_ResearchRd_2 5.42 100633.477 125484.508 356696.75 1 18.39 18.32 81 2013OCT21_A_ResearchRd_3 5.41 97589.891 124289.414 352091.188 1 17.84 17.77 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 363.085 #DIV/0! 84 2013OCT21_A_Skateboard_1 5.41 74906.094 89690.766 271247.656 1 13.69 13.64 85 2013OCT21_A_Skateboard_2 5.41 76387.086 98001.844 247447.094 1 13.96 13.91 86 2013OCT21_A_Skateboard_3 5.41 79010.945 101493.266 281899.25 1 14.44 14.39 87 2013OCT21_A_SolvA_31 298.962 #DIV/0! 88 2013OCT21_A_SolvA_32 350.855 #DIV/0! 89 2013OCT21_A_SligoCreek_1 5.41 76841.414 93559.023 273029.406 1 14.05 13.99 90 2013OCT21_A_SligoCreek_2 5.41 78483.891 98995.523 251382.359 1 14.35 14.29 91 2013OCT21_A_SligoCreek_3 5.42 80646.672 97586.383 276887.563 1 14.74 14.68 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 5.41 223517.969 270291.438 749830.063 1 40.86 40.70 95 2013OCT21_A_RiverdaleRd_2 5.42 230867.625 284499.688 807502.813 1 42.20 42.03 96 2013OCT21_A_RiverdaleRd_3 5.41 231396.547 284103.344 797791.5 1 42.30 42.13 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 5.46 190.613 186.614 315.481 1 100 2013OCT21_A_0-01_Std_2 0.01 5.42 2515.352 2097.357 5740.375 1 101 2013OCT21_A_0-05_Std_2 0.05 5.42 4995.196 5719.824 12708.467 1 102 2013OCT21_A_0-1_Std_2 0.1 5.42 8528.118 10334.804 27253.393 1 103 2013OCT21_A_0-5_Std_2 0.5 5.41 31639.422 42809.398 115020.797 1 104 2013OCT21_A_1_Std_2 1 5.42 68057.305 85549.914 222250.578 1 105 2013OCT21_A_5_Std_2 5 5.41 339347.188 440126.625 1160029.375 1 106 2013OCT21_A_10_Std_2 10 5.42 658856.625 856011.688 2248512 1 107 2013OCT21_A_25_Std_2 25 5.42 1661196.625 2102077.75 5422608.5 1 108 2013OCT21_A_50_Std_2 50 5.42 3064306 3880825.5 10285664 1 206 109 2013OCT21_A_100_Std_2 100 5.42 5613715.5 7258197 14315309 1 110 2013OCT21_A_200_Stds_2 200 5.42 10916357 12395697 16274816 0 111 2013OCT21_A_SolvA_38 5.42 862.49 1008.381 2711.543 1 112 2013OCT21_A_Surrogate_2 5.43 3915.042 5468.088 14843.536 1 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 5.43 467.488 750.513 #DIV/0! 115 2013OCT21_A_SolvA_41 5.47 889.424 241.776 #DIV/0! 116 2013OCT21_A_SolvA_42 5.41 382.675 201.858 1130.707 #VALUE! Compound 6: Atrazine-d5 yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 5.35 2004.663 #DIV/0! 2 2013OCT21_A_Lab Blk 5.36 14075238 7273547.5 4609407 1 13929421 Avg 3 2013OCT21_A_Travel Blk 5.35 14039521 7321757 4676833.5 1 2% RSD 4 2013OCT21_A_0-01_Std 0.01 5.35 14117988 7177742.5 4585351.5 1 5 2013OCT21_A_0-05_Std 0.05 5.34 14136143 7378416.5 4681689.5 1 6 2013OCT21_A_0-1_Std 0.1 5.34 14473721 7977883.5 5066404 1 7 2013OCT21_A_0-5_Std 0.5 5.36 14260557 7464709 4727933.5 1 8 2013OCT21_A_1_Std 1 5.36 14440857 7538144 4881647 1 9 2013OCT21_A_5_Std 5 5.35 14297127 7598988.5 4879968 1 10 2013OCT21_A_10_Std 10 5.35 14533373 7401070.5 4768509.5 1 11 2013OCT21_A_25_Std 25 5.35 14344426 7461565 4791853 1 12 2013OCT21_A_50_Std 50 5.35 14537136 7521989 4807948.5 1 13 2013OCT21_A_100_Std 100 5.35 14353577 6861177.5 4490569.5 1 14 2013OCT21_A_200_Stds 200 5.36 14405652 7139064.5 4524167 1 15 2013OCT21_A_SolvA_2 5.35 2410.012 #DIV/0! 16 2013OCT21_A_Surrogate_1 5.35 2024.4 413.372 0 17 2013OCT21_A_SolvA_3 5.34 1465.207 #DIV/0! 18 2013OCT21_A_SolvA_4 5.33 709.656 0 19 2013OCT21_A_MM_0 5.35 14186214 6757210.5 4283387.5 1 20 2013OCT21_A_MM_1 5.34 14356299 7483306.5 4850473.5 1 21 2013OCT21_A_MM_5 5.35 14380394 7607803 4840681 1 22 2013OCT21_A_MM_10 5.36 14160291 6950178.5 4411139 1 23 2013OCT21_A_MM_25 5.35 13381280 6157545.5 3968484 1 24 2013OCT21_A_MM_50 5.35 13538918 6406274 4023505.5 1 25 2013OCT21_A_MM_100 5.35 14924145 7595225 4861708.5 1 26 2013OCT21_A_SolvA_5 5.35 2759.982 607.751 0 27 2013OCT21_A_SolvA_6 5.35 1837.182 #DIV/0! 28 2013OCT21_A_BerwynRd_1 5.36 14219781 6941952 4482451 1 29 2013OCT21_A_BerwynRd_2 5.36 14230854 7062302.5 4545507 1 30 2013OCT21_A_BerwynRd_3 5.36 14272455 7143338.5 4591472.5 1 31 2013OCT21_A_SolvA_7 5.35 3353.199 837.487 #DIV/0! 32 2013OCT21_A_SolvA_8 5.36 1144.435 1184.829 #DIV/0! 33 2013OCT21_A_UMD_1 5.36 13923450 6903063.5 4424485 1 34 2013OCT21_A_UMD_2 5.35 13887372 6926354 4394442 1 35 2013OCT21_A_UMD_3 5.36 13953992 6912360.5 4377028 1 207 36 2013OCT21_A_SolvA_9 5.35 3593.195 #DIV/0! 37 2013OCT21_A_SolvA_10 5.35 2495.167 #DIV/0! 38 2013OCT21_A_Arboretum1_1 5.36 13554300 6101185 3861477.75 1 39 2013OCT21_A_Arboretum1_2 5.35 13543496 6039521.5 3923241.75 1 40 2013OCT21_A_Arboretum1_3 5.35 13474219 6175414 3914022 1 41 2013OCT21_A_SolvA_11 5.34 2015.495 984.224 0 42 2013OCT21_A_SolvA_12 5.37 1733.022 #DIV/0! 43 2013OCT21_A_Arboretum2_1 5.35 13884635 6716271 4354292 1 44 2013OCT21_A_Arboretum2_2 5.35 13888651 6793288 4337651.5 1 45 2013OCT21_A_Arboretum2_3 5.35 13926538 6839075.5 4358937.5 1 46 2013OCT21_A_SolvA_13 5.35 3123.791 478.976 #DIV/0! 47 2013OCT21_A_SolvA_14 5.34 1515.218 1094.991 0 48 2013OCT21_A_QC_Std25_1 5.35 14182088 7444947 4814668 1 49 2013OCT21_A_SolvA_15 5.35 1813.854 #DIV/0! 50 2013OCT21_A_SolvA_16 5.35 905.994 #DIV/0! 51 2013OCT21_A_NorthDr1_1 5.35 13780104 6744717 4354959.5 1 52 2013OCT21_A_NorthDr1_2 5.35 13814799 6861179.5 4329462.5 1 53 2013OCT21_A_NorthDr1_3 5.35 13915854 7010863 4395889.5 1 54 2013OCT21_A_SolvA_17 5.35 1738.964 #DIV/0! 55 2013OCT21_A_SolvA_18 5.34 1364.401 #DIV/0! 56 2013OCT21_A_NorthDr2_1 5.35 13787451 6766248.5 4306567 1 57 2013OCT21_A_NorthDr2_2 5.35 13879863 6756401 4326294.5 1 58 2013OCT21_A_NorthDr2_3 5.35 13823032 6754570 4365511.5 1 59 2013OCT21_A_SolvA_19 5.34 2320.753 1032.213 69.894 0 60 2013OCT21_A_SolvA_20 5.35 1998.835 672.471 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 5.35 13448161 5899899 3773902 1 62 2013OCT21_A_AnacostiaPk_2 5.35 13302580 5884293 3774469.75 1 63 2013OCT21_A_AnacostiaPk_3 5.35 13266647 6019120 3835872.5 1 64 2013OCT21_A_SolvA_21 5.35 2789.657 1539.903 894.026 1 65 2013OCT21_A_SolvA_22 5.35 2374.788 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 5.35 13458886 6261348.5 3999166.75 1 67 2013OCT21_A_GreenbeltPk_2 5.36 13503110 6208178.5 3970038.75 1 68 2013OCT21_A_GreenbeltPk_3 5.36 13645113 6180442.5 3893736.5 1 69 2013OCT21_A_SolvA_23 5.35 2512.085 129.742 #DIV/0! 70 2013OCT21_A_SolvA_24 5.38 501.015 2.051 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 5.36 13343666 6148723.5 3937124.75 1 72 2013OCT21_A_PowderMillRd_2 5.36 13535962 6271051.5 4080081.75 1 73 2013OCT21_A_PowderMillRd_3 5.36 13485807 6233701.5 4076421 1 74 2013OCT21_A_SolvA_25 5.35 1983.399 #DIV/0! 75 2013OCT21_A_SolvA_26 5.35 1611.493 #DIV/0! 76 2013OCT21_A_QC_Std25_2 5.36 13992905 7333018.5 4628573 1 77 2013OCT21_A_SolvA_27 5.37 907.978 #DIV/0! 78 2013OCT21_A_SolvA_28 5.37 564.815 1101.785 13.322 0 79 2013OCT21_A_ResearchRd_1 5.36 13852475 6863017.5 4356190.5 1 80 2013OCT21_A_ResearchRd_2 5.35 13822173 6764686 4315517.5 1 208 81 2013OCT21_A_ResearchRd_3 5.35 14209553 7026699 4436236 1 82 2013OCT21_A_SolvA_29 5.35 2323.436 1334.27 575.067 1 83 2013OCT21_A_SolvA_30 5.34 1567.643 #DIV/0! 84 2013OCT21_A_Skateboard_1 5.35 13429757 6472960 4104865.25 1 85 2013OCT21_A_Skateboard_2 5.35 13502713 6544524.5 4182578.25 1 86 2013OCT21_A_Skateboard_3 5.35 13590453 6683068.5 4104899 1 87 2013OCT21_A_SolvA_31 5.34 3214.839 #DIV/0! 88 2013OCT21_A_SolvA_32 5.34 2368.215 #DIV/0! 89 2013OCT21_A_SligoCreek_1 5.35 13647788 6788002 4364379 1 90 2013OCT21_A_SligoCreek_2 5.35 13753756 6942424 4437402 1 91 2013OCT21_A_SligoCreek_3 5.35 13732918 6933182 4388214 1 92 2013OCT21_A_SolvA_33 5.33 3581.733 1698.758 0 93 2013OCT21_A_SolvA_34 5.33 1938.115 529.16 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 5.35 14011278 7074791.5 4445424 1 95 2013OCT21_A_RiverdaleRd_2 5.36 14155911 7220608.5 4651953 1 96 2013OCT21_A_RiverdaleRd_3 5.36 14047692 7181109.5 4527613 1 97 2013OCT21_A_SolvA_35 5.35 3217.339 #DIV/0! 98 2013OCT21_A_SolvA_36 5.36 1328.589 506.899 #DIV/0! 99 2013OCT21_A_SolvA_37 5.34 886.556 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 5.35 13962516 7188666 4625785.5 1 101 2013OCT21_A_0-05_Std_2 0.05 5.36 13891159 7228161 4560281 1 102 2013OCT21_A_0-1_Std_2 0.1 5.35 14107463 8064385.5 5012513 1 103 2013OCT21_A_0-5_Std_2 0.5 5.35 14215882 7588053.5 4877861.5 1 104 2013OCT21_A_1_Std_2 1 5.36 14196969 7665830.5 4944172.5 1 105 2013OCT21_A_5_Std_2 5 5.35 13920663 7752861 4828510.5 1 106 2013OCT21_A_10_Std_2 10 5.35 14317347 7520562.5 4727332 1 107 2013OCT21_A_25_Std_2 25 5.36 14014271 7476866.5 4690551.5 1 108 2013OCT21_A_50_Std_2 50 5.36 14220180 7563298 4828478.5 1 109 2013OCT21_A_100_Std_2 100 5.36 13801496 6870064 4287314.5 1 110 2013OCT21_A_200_Stds_2 200 5.37 14066888 6892796.5 4279682.5 1 111 2013OCT21_A_SolvA_38 5.38 3265.136 #DIV/0! 112 2013OCT21_A_Surrogate_2 5.36 1553.005 10.311 0 113 2013OCT21_A_SolvA_39 5.36 1881.296 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 5.35 2075.444 #VALUE! Compound 7: Terbuthylazine yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area #VALUE! 1 2013OCT21_SolvA_1 251.809 #DIV/0! Samples 2 2013OCT21_A_Lab Blk 8.05 5464103 4370759.5 #DIV/0! 5274829 Overall Avg 3 2013OCT21_A_Travel Blk 8.04 5375939.5 4302423 #DIV/0! 11% RSD 4 2013OCT21_A_0-01_Std 0.01 #DIV/0! 93% % Rec 5 2013OCT21_A_0-05_Std 0.05 #DIV/0! Standard surrogate 6 2013OCT21_A_0-1_Std 0.1 #DIV/0! 5677138.5 Avg 7 2013OCT21_A_0-5_Std 0.5 #DIV/0! 4% RSD 209 8 2013OCT21_A_1_Std 1 #DIV/0! 9 2013OCT21_A_5_Std 5 #DIV/0! 10 2013OCT21_A_10_Std 10 #DIV/0! 11 2013OCT21_A_25_Std 25 #DIV/0! 12 2013OCT21_A_50_Std 50 #DIV/0! 13 2013OCT21_A_100_Std 100 #DIV/0! 14 2013OCT21_A_200_Stds 200 #DIV/0! 15 2013OCT21_A_SolvA_2 #DIV/0! 16 2013OCT21_A_Surrogate_1 8.04 5517075 4402204.5 #DIV/0! 17 2013OCT21_A_SolvA_3 #DIV/0! 18 2013OCT21_A_SolvA_4 #DIV/0! 19 2013OCT21_A_MM_0 8.03 5341357 4344647.5 #DIV/0! 20 2013OCT21_A_MM_1 8.03 6100802 4857215 #DIV/0! 21 2013OCT21_A_MM_5 8.05 6218709.5 4961911.5 #DIV/0! 22 2013OCT21_A_MM_10 8.05 5698231 4522960.5 #DIV/0! 23 2013OCT21_A_MM_25 8.04 5123209 4069541.25 #DIV/0! 24 2013OCT21_A_MM_50 8.04 4920097.5 3912610 #DIV/0! 25 2013OCT21_A_MM_100 8.04 6324871.5 5056123 #DIV/0! 26 2013OCT21_A_SolvA_5 #DIV/0! 27 2013OCT21_A_SolvA_6 #DIV/0! Avg Rec 28 2013OCT21_A_BerwynRd_1 8.05 5543072.5 4381378.5 #DIV/0! 5569270 98% 29 2013OCT21_A_BerwynRd_2 8.05 5566948 4443067.5 #DIV/0! 30 2013OCT21_A_BerwynRd_3 8.05 5597789 4488632.5 #DIV/0! 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! Avg Rec 33 2013OCT21_A_UMD_1 8.05 5561580 4434400 #DIV/0! 5572996 98% 34 2013OCT21_A_UMD_2 8.05 5575063.5 4445162 #DIV/0! 35 2013OCT21_A_UMD_3 8.05 5582345 4463611 #DIV/0! 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! Avg Rec 38 2013OCT21_A_Arboretum1_1 8.05 3878743.75 3068465.25 #DIV/0! 3895450 69% 39 2013OCT21_A_Arboretum1_2 8.05 3893504 3112110.25 #DIV/0! 40 2013OCT21_A_Arboretum1_3 8.04 3914102.75 3073217.5 #DIV/0! 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! Avg Rec 43 2013OCT21_A_Arboretum2_1 8.04 5428338.5 4300967.5 #DIV/0! 5441227 96% 44 2013OCT21_A_Arboretum2_2 8.04 5438284 4336686.5 #DIV/0! 45 2013OCT21_A_Arboretum2_3 8.04 5457057 4362898 #DIV/0! 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 #DIV/0! 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! Avg Rec 51 2013OCT21_A_NorthDr1_1 8.04 5356466 4258412 #DIV/0! 5380992 95% 52 2013OCT21_A_NorthDr1_2 8.04 5402210 4304622.5 #DIV/0! 53 2013OCT21_A_NorthDr1_3 8.04 5384300.5 4288385 #DIV/0! 210 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! Avg Rec 56 2013OCT21_A_NorthDr2_1 8.04 5524943 4395427 #DIV/0! 5577523 98% 57 2013OCT21_A_NorthDr2_2 8.04 5580157.5 4494056.5 #DIV/0! 58 2013OCT21_A_NorthDr2_3 8.04 5627468 4474777 #DIV/0! 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! Avg Rec 61 2013OCT21_A_AnacostiaPk_1 8.04 4150161.75 3303170.75 #DIV/0! 4162016 73% 62 2013OCT21_A_AnacostiaPk_2 8.04 4169853.75 3323744 #DIV/0! 63 2013OCT21_A_AnacostiaPk_3 8.04 4166032.25 3322091.75 #DIV/0! 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! Avg Rec 66 2013OCT21_A_GreenbeltPk_1 8.04 5460354 4335028.5 #DIV/0! 5445142 96% 67 2013OCT21_A_GreenbeltPk_2 8.05 5467218.5 4364470.5 #DIV/0! 68 2013OCT21_A_GreenbeltPk_3 8.05 5407852 4328195 #DIV/0! 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! Avg Rec 71 2013OCT21_A_PowderMillRd_1 8.07 5048984 4011158.5 #DIV/0! 5072490 89% 72 2013OCT21_A_PowderMillRd_2 8.06 5072442 4002962.75 #DIV/0! 73 2013OCT21_A_PowderMillRd_3 8.05 5096044 4052478.25 #DIV/0! 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 #DIV/0! 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! Avg Rec 79 2013OCT21_A_ResearchRd_1 8.05 5860556.5 4649338.5 #DIV/0! 5890993 104% 80 2013OCT21_A_ResearchRd_2 8.05 5895893.5 4668773.5 #DIV/0! 81 2013OCT21_A_ResearchRd_3 8.05 5916527.5 4661542.5 #DIV/0! 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! Avg Rec 84 2013OCT21_A_Skateboard_1 8.05 5018630 3965514.25 #DIV/0! 5065730 89% 85 2013OCT21_A_Skateboard_2 8.05 5085594 3988062.75 #DIV/0! 86 2013OCT21_A_Skateboard_3 8.04 5092965.5 4014136 #DIV/0! 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 #DIV/0! Avg Rec 89 2013OCT21_A_SligoCreek_1 8.05 5628502.5 4463879 #DIV/0! 5691008 100% 90 2013OCT21_A_SligoCreek_2 8.04 5692197 4513188.5 #DIV/0! 91 2013OCT21_A_SligoCreek_3 8.05 5752324.5 4579278.5 #DIV/0! 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! Avg Rec 94 2013OCT21_A_RiverdaleRd_1 8.04 5616049.5 4396854.5 #DIV/0! 5711144 101% 95 2013OCT21_A_RiverdaleRd_2 8.05 5771745 4562024 #DIV/0! 96 2013OCT21_A_RiverdaleRd_3 8.05 5745636.5 4539150 #DIV/0! 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 211 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 #DIV/0! 104 2013OCT21_A_1_Std_2 1 26.356 99.556 #DIV/0! 105 2013OCT21_A_5_Std_2 5 1909.344 #DIV/0! 106 2013OCT21_A_10_Std_2 10 80.793 #DIV/0! 107 2013OCT21_A_25_Std_2 25 991.371 #DIV/0! 108 2013OCT21_A_50_Std_2 50 45.703 #DIV/0! 109 2013OCT21_A_100_Std_2 100 95.744 901.178 #DIV/0! 110 2013OCT21_A_200_Stds_2 200 199.986 1227.51 #DIV/0! 111 2013OCT21_A_SolvA_38 5.899 168.453 #DIV/0! 112 2013OCT21_A_Surrogate_2 8.08 5837202 4602407 #DIV/0! 113 2013OCT21_A_SolvA_39 987.454 #DIV/0! 114 2013OCT21_A_SolvA_40 52.012 802.503 #DIV/0! 115 2013OCT21_A_SolvA_41 297.059 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 8: Metolachlor OH yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area #VALUE! 1 2013OCT21_SolvA_1 18.215 #DIV/0! 2 2013OCT21_A_Lab Blk #DIV/0! 3 2013OCT21_A_Travel Blk #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 0 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 7.26 3993.32 3023.557 31614.438 1 0.1 -21% 7 2013OCT21_A_0-5_Std 0.5 7.28 22239.229 14709.119 162013.875 1 0.4 -12% 8 2013OCT21_A_1_Std 1 7.27 48081.281 29905.766 347017.344 1 0.9 -5% 9 2013OCT21_A_5_Std 5 7.28 239230.453 169404.922 1718704.625 1 4.7 -5% 10 2013OCT21_A_10_Std 10 7.27 495652.406 323088.656 3321788.75 1 9.8 -2% 11 2013OCT21_A_25_Std 25 7.27 1250430.875 814977.313 8001591 1 24.7 -1% 12 2013OCT21_A_50_Std 50 7.27 2559695 1667849.625 13707923 1 50.6 1% 13 2013OCT21_A_100_Std 100 7.28 4411741 2886635.25 0 87.1 -13% 14 2013OCT21_A_200_Stds 200 7.28 10445131 6808627.5 0 206.3 3% 15 2013OCT21_A_SolvA_2 101.881 #DIV/0! 0.0 -100% 16 2013OCT21_A_Surrogate_1 136.116 97.501 0 0.1 6% 17 2013OCT21_A_SolvA_3 16.146 678.027 0 0.1 -6% 18 2013OCT21_A_SolvA_4 #DIV/0! 0.4 -11% 19 2013OCT21_A_MM_0 7.3 1084.861 1910.321 15449.635 1 1.0 -3% 20 2013OCT21_A_MM_1 7.26 50228 34298.402 320388.75 1 5.0 0% 21 2013OCT21_A_MM_5 7.27 236658.797 154467.719 1621064 1 9.5 -5% 22 2013OCT21_A_MM_10 7.28 468315.75 300968.906 2985351.75 1 24.5 -2% 23 2013OCT21_A_MM_25 7.28 1021312.625 663164.813 6435876.5 1 49.4 -1% 24 2013OCT21_A_MM_50 7.28 2007854.125 1297813.625 11475832 1 85.9 -14% 25 2013OCT21_A_MM_100 7.27 4982504 3238196.25 0 207.3 4% 212 26 2013OCT21_A_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT21_A_SolvA_6 38.606 1110.133 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 7.29 8950.002 6731.282 75639.039 1 1.77 1.88 29 2013OCT21_A_BerwynRd_2 7.26 9055.284 7023.362 70638.078 1 1.79 1.90 30 2013OCT21_A_BerwynRd_3 7.29 10182.21 6829.305 73038.547 1 2.01 2.14 31 2013OCT21_A_SolvA_7 61.232 #DIV/0! 32 2013OCT21_A_SolvA_8 34.645 #DIV/0! 33 2013OCT21_A_UMD_1 7.28 5077.91 3696.448 43669.309 1 1.00 1.07 34 2013OCT21_A_UMD_2 7.28 5655.69 3706.275 42347.512 1 1.12 1.19 35 2013OCT21_A_UMD_3 7.28 5831.278 3651.742 45693.676 1 1.15 1.23 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 483.48 #DIV/0! 38 2013OCT21_A_Arboretum1_1 7.27 6786.315 5006.77 47725.27 1 1.34 1.43 39 2013OCT21_A_Arboretum1_2 7.28 5847.773 4499.974 48688.695 1 1.16 1.23 40 2013OCT21_A_Arboretum1_3 7.26 6431.846 5418.619 47638.094 1 1.27 1.35 41 2013OCT21_A_SolvA_11 0.745 #DIV/0! 42 2013OCT21_A_SolvA_12 719.771 #DIV/0! 43 2013OCT21_A_Arboretum2_1 7.28 7496.967 4848.629 45385.516 1 1.48 1.58 44 2013OCT21_A_Arboretum2_2 7.27 7331.011 5418.903 45923.695 1 1.45 1.54 45 2013OCT21_A_Arboretum2_3 7.26 7768.634 5425.45 48054.402 1 1.53 1.63 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 7.27 1195197.375 781418.563 7916897.5 1 236.07 251.44 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 155.294 0.49 #DIV/0! 51 2013OCT21_A_NorthDr1_1 7.26 3993.8 2343.419 27811.633 1 0.79 0.84 52 2013OCT21_A_NorthDr1_2 7.28 4378.838 1772.981 29489.236 1 0.86 0.92 53 2013OCT21_A_NorthDr1_3 7.27 3182.99 2421.447 27393.547 1 0.63 0.67 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 7.22 294.101 42.422 185.452 0 56 2013OCT21_A_NorthDr2_1 7.26 3453.148 2187.398 31918.398 1 0.68 0.73 57 2013OCT21_A_NorthDr2_2 7.28 3729.058 2440.721 26967.783 1 0.74 0.78 58 2013OCT21_A_NorthDr2_3 7.27 3410.732 2660.648 31320.314 1 0.67 0.72 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 5.925 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 7.26 5475.658 3728.437 29997.666 1 1.08 1.15 62 2013OCT21_A_AnacostiaPk_2 7.27 5132.217 3340.553 33737.902 1 1.01 1.08 63 2013OCT21_A_AnacostiaPk_3 7.26 4675.965 3332.843 29049.674 1 0.92 0.98 64 2013OCT21_A_SolvA_21 52.515 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 7.28 3121.557 1623.715 21546.205 1 0.62 0.66 67 2013OCT21_A_GreenbeltPk_2 7.28 2453.985 2404.771 30874.969 1 0.48 0.52 68 2013OCT21_A_GreenbeltPk_3 7.29 2414.012 1625.514 26063.295 1 0.48 0.51 69 2013OCT21_A_SolvA_23 77.095 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 213 71 2013OCT21_A_PowderMillRd_1 7.29 4161.04 2859.408 26567.26 1 0.82 0.88 72 2013OCT21_A_PowderMillRd_2 7.28 3131.44 2204.347 41667.934 1 0.62 0.66 73 2013OCT21_A_PowderMillRd_3 7.28 3681.298 2341.993 39453.566 1 0.73 0.77 74 2013OCT21_A_SolvA_25 227.265 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 7.29 1210150.5 777984.25 8387415.5 1 239.03 254.58 77 2013OCT21_A_SolvA_27 85.216 0.795 #DIV/0! 78 2013OCT21_A_SolvA_28 57.21 9.763 #DIV/0! 79 2013OCT21_A_ResearchRd_1 7.28 11560.346 8108.987 87850.492 1 2.28 2.43 80 2013OCT21_A_ResearchRd_2 7.28 11872.289 7336.686 83960.43 1 2.34 2.50 81 2013OCT21_A_ResearchRd_3 7.27 10427.433 7517.821 78727.32 1 2.06 2.19 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 124.718 136.527 #DIV/0! 84 2013OCT21_A_Skateboard_1 7.29 2977.963 2206.299 20296.594 1 0.59 0.63 85 2013OCT21_A_Skateboard_2 7.27 2217.893 1165.37 9067.192 1 0.44 0.47 86 2013OCT21_A_Skateboard_3 7.28 1945.522 1675.399 19239.088 1 0.38 0.41 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 36.397 3728.879 #DIV/0! 89 2013OCT21_A_SligoCreek_1 7.29 2302.466 124.87 28750.318 1 0.45 0.48 90 2013OCT21_A_SligoCreek_2 7.26 3378.701 2228.559 26012.783 1 0.67 0.71 91 2013OCT21_A_SligoCreek_3 7.27 2816.994 68.12 28918.977 1 0.56 0.59 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 7.28 10220.753 6744.503 81493.805 1 2.02 2.15 95 2013OCT21_A_RiverdaleRd_2 7.28 10509.825 6997.643 84274.391 1 2.08 2.21 96 2013OCT21_A_RiverdaleRd_3 7.28 9799.29 6838.5 81246.883 1 1.94 2.06 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 130.127 407.033 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 4192.285 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 7.25 2678.708 1316.117 21160.391 1 102 2013OCT21_A_0-1_Std_2 0.1 7.28 4768.078 2773.577 41699.602 1 103 2013OCT21_A_0-5_Std_2 0.5 7.28 22551.33 15313.521 182038.406 1 104 2013OCT21_A_1_Std_2 1 7.28 49299.191 30158.129 396486.375 1 105 2013OCT21_A_5_Std_2 5 7.28 252337.438 164013.109 2017697.625 1 106 2013OCT21_A_10_Std_2 10 7.28 482025.125 312302.25 3788248.75 1 107 2013OCT21_A_25_Std_2 25 7.29 1240643.125 794840.25 8970866 1 108 2013OCT21_A_50_Std_2 50 7.28 2501057.5 1599994.375 15066285 1 109 2013OCT21_A_100_Std_2 100 7.29 4347511.5 2794005.25 #DIV/0! 110 2013OCT21_A_200_Stds_2 200 7.3 10497197 6724114 #DIV/0! 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 41.285 61.359 #DIV/0! 116 2013OCT21_A_SolvA_42 9.224 #DIV/0! 214 Compound 9: Alachlor yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area #VALUE! 1 2013OCT21_SolvA_1 #DIV/0! 2 2013OCT21_A_Lab Blk #DIV/0! 3 2013OCT21_A_Travel Blk #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 0 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 2121.573 0 0.0 -100% 7 2013OCT21_A_0-5_Std 0.5 9.23 14271.123 4418.521 1 1.5 207% 8 2013OCT21_A_1_Std 1 9.23 16320.879 7462.073 1 1.8 75% 9 2013OCT21_A_5_Std 5 9.24 103787.477 44925.199 1 11.1 123% 10 2013OCT21_A_10_Std 10 9.24 171365.5 78414.711 1 18.4 84% 11 2013OCT21_A_25_Std 25 9.24 393069.344 174139.75 1 42.2 69% 12 2013OCT21_A_50_Std 50 9.24 648949.5 284998.75 1 69.7 39% 13 2013OCT21_A_100_Std 100 9.24 1013263.5 441715.906 1 108.8 9% 14 2013OCT21_A_200_Stds 200 9.24 1632650.125 717157.563 1 175.3 -12% 15 2013OCT21_A_SolvA_2 2418.435 #DIV/0! 0.0 -100% 16 2013OCT21_A_Surrogate_1 0 0.0 -100% 17 2013OCT21_A_SolvA_3 0 0.0 -100% 18 2013OCT21_A_SolvA_4 0 1.1 117% 19 2013OCT21_A_MM_0 1835.225 #DIV/0! 1.8 84% 20 2013OCT21_A_MM_1 9.23 6336.536 6468.819 0 10.7 115% 21 2013OCT21_A_MM_5 9.24 63326.02 28054.232 1 20.0 100% 22 2013OCT21_A_MM_10 9.24 116159.891 49987.668 1 44.5 78% 23 2013OCT21_A_MM_25 9.24 252549.813 111915.523 1 75.4 51% 24 2013OCT21_A_MM_50 9.24 419838.938 197198.625 1 126.0 26% 25 2013OCT21_A_MM_100 9.24 759341.5 341776.656 1 190.2 -5% 26 2013OCT21_A_SolvA_5 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 #DIV/0! 0.00 0.00 29 2013OCT21_A_BerwynRd_2 #DIV/0! 0.00 0.00 30 2013OCT21_A_BerwynRd_3 #DIV/0! 0.00 0.00 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 103.573 #DIV/0! 33 2013OCT21_A_UMD_1 #DIV/0! 0.00 0.00 34 2013OCT21_A_UMD_2 2362.683 #DIV/0! 0.00 0.00 35 2013OCT21_A_UMD_3 #DIV/0! 0.00 0.00 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 1223.906 #DIV/0! 0.00 0.00 39 2013OCT21_A_Arboretum1_2 #DIV/0! 0.00 0.00 40 2013OCT21_A_Arboretum1_3 #DIV/0! 0.00 0.00 41 2013OCT21_A_SolvA_11 217.078 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 641.206 #DIV/0! 0.00 0.00 215 44 2013OCT21_A_Arboretum2_2 #DIV/0! 0.00 0.00 45 2013OCT21_A_Arboretum2_3 #DIV/0! 0.00 0.00 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 9.24 378652.094 174861.984 1 406.62 479.12 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 4.753 #DIV/0! 0.00 0.00 52 2013OCT21_A_NorthDr1_2 #DIV/0! 0.00 0.00 53 2013OCT21_A_NorthDr1_3 76.783 #DIV/0! 0.00 0.00 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 #DIV/0! 0.00 0.00 57 2013OCT21_A_NorthDr2_2 73.87 #DIV/0! 0.00 0.00 58 2013OCT21_A_NorthDr2_3 177.964 #DIV/0! 0.00 0.00 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 #DIV/0! 0.00 0.00 62 2013OCT21_A_AnacostiaPk_2 #DIV/0! 0.00 0.00 63 2013OCT21_A_AnacostiaPk_3 #DIV/0! 0.00 0.00 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 #DIV/0! 0.00 0.00 67 2013OCT21_A_GreenbeltPk_2 #DIV/0! 0.00 0.00 68 2013OCT21_A_GreenbeltPk_3 #DIV/0! 0.00 0.00 69 2013OCT21_A_SolvA_23 163.992 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 #DIV/0! 0.00 0.00 72 2013OCT21_A_PowderMillRd_2 #DIV/0! 0.00 0.00 73 2013OCT21_A_PowderMillRd_3 267.831 #DIV/0! 0.00 0.00 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 9.24 403957.344 182694.891 1 433.79 511.14 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 43.967 #DIV/0! 79 2013OCT21_A_ResearchRd_1 #DIV/0! 0.00 0.00 80 2013OCT21_A_ResearchRd_2 #DIV/0! 0.00 0.00 81 2013OCT21_A_ResearchRd_3 10.057 #DIV/0! 0.00 0.00 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 #DIV/0! 0.00 0.00 85 2013OCT21_A_Skateboard_2 #DIV/0! 0.00 0.00 86 2013OCT21_A_Skateboard_3 #DIV/0! 0.00 0.00 87 2013OCT21_A_SolvA_31 376.137 #DIV/0! 88 2013OCT21_A_SolvA_32 #DIV/0! 216 89 2013OCT21_A_SligoCreek_1 346.684 #DIV/0! 0.00 0.00 90 2013OCT21_A_SligoCreek_2 #DIV/0! 0.00 0.00 91 2013OCT21_A_SligoCreek_3 #DIV/0! 0.00 0.00 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 852.554 #DIV/0! 0.00 0.00 95 2013OCT21_A_RiverdaleRd_2 #DIV/0! 0.00 0.00 96 2013OCT21_A_RiverdaleRd_3 257.088 #DIV/0! 0.00 0.00 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 9.23 10099.708 5541.45 1 104 2013OCT21_A_1_Std_2 1 9.24 17152.039 7338.054 1 105 2013OCT21_A_5_Std_2 5 9.24 99957.023 48874.863 1 106 2013OCT21_A_10_Std_2 10 9.24 186421.5 85572.297 1 107 2013OCT21_A_25_Std_2 25 9.24 414386.031 185652.672 1 108 2013OCT21_A_50_Std_2 50 9.24 701899.625 309449.406 1 109 2013OCT21_A_100_Std_2 100 9.24 1173355.125 521543.563 1 110 2013OCT21_A_200_Stds_2 200 9.24 1771086.875 793005.313 1 111 2013OCT21_A_SolvA_38 316.264 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 1479.469 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 10: Acetochlor yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 #DIV/0! #DIV/0! 2 2013OCT21_A_Lab Blk #DIV/0! #DIV/0! 3 2013OCT21_A_Travel Blk 1145.637 #DIV/0! #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 9.22 1938.003 732.441 0 0.0 174% 5 2013OCT21_A_0-05_Std 0.05 9.22 5459.345 3305.548 1939.967 1 0.1 54% 6 2013OCT21_A_0-1_Std 0.1 9.23 18676.184 10693.58 2442.528 1 0.3 164% 7 2013OCT21_A_0-5_Std 0.5 9.23 82480.695 39606.652 14741.24 1 1.2 133% 8 2013OCT21_A_1_Std 1 9.23 140877.719 65079.414 21287.139 1 2.0 99% 9 2013OCT21_A_5_Std 5 9.23 862282.563 422699.094 135482.547 1 12.2 144% 10 2013OCT21_A_10_Std 10 9.23 1516811 788052.563 254902.922 1 21.4 114% 11 2013OCT21_A_25_Std 25 9.23 3477622.5 1731745.75 586385.563 1 49.2 97% 12 2013OCT21_A_50_Std 50 9.23 5646129.5 2866501 949497.625 1 79.8 60% 13 2013OCT21_A_100_Std 100 9.23 8718172 4639678 1470266.875 1 123.3 23% 14 2013OCT21_A_200_Stds 200 9.23 11713331 7301560.5 2459591.25 1 165.6 -17% 15 2013OCT21_A_SolvA_2 9.23 19823.416 9389.305 3013.693 1 0.0 63% 217 16 2013OCT21_A_Surrogate_1 9.23 2577.276 1496.188 956.85 0 0.1 58% 17 2013OCT21_A_SolvA_3 9.23 4682.438 #DIV/0! 0.3 166% 18 2013OCT21_A_SolvA_4 9.23 4762.76 1546.043 0 1.1 113% 19 2013OCT21_A_MM_0 718.073 1465.42 #DIV/0! 2.0 104% 20 2013OCT21_A_MM_1 9.23 91525.266 49269.301 16705.018 1 12.3 146% 21 2013OCT21_A_MM_5 9.23 509792.906 258124.125 89434.461 1 22.6 126% 22 2013OCT21_A_MM_10 9.23 914778.438 457419.438 156830.422 1 51.2 105% 23 2013OCT21_A_MM_25 9.23 2026091.125 1061980.75 369932.469 1 85.7 71% 24 2013OCT21_A_MM_50 9.23 3771692.75 1875157.5 651414.063 1 138.4 38% 25 2013OCT21_A_MM_100 9.23 6624227.5 3388457 1183465 1 179.3 -10% 26 2013OCT21_A_SolvA_5 9.23 9792.908 4047.252 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 #DIV/0! 0.00 0.00 29 2013OCT21_A_BerwynRd_2 #DIV/0! 0.00 0.00 30 2013OCT21_A_BerwynRd_3 #DIV/0! 0.00 0.00 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 9.24 3122.686 1189.972 0 33 2013OCT21_A_UMD_1 112.549 304.321 #DIV/0! 0.00 0.00 34 2013OCT21_A_UMD_2 #DIV/0! 0.00 0.00 35 2013OCT21_A_UMD_3 #DIV/0! 0.00 0.00 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 316.738 #DIV/0! 0.00 0.00 39 2013OCT21_A_Arboretum1_2 447.362 #DIV/0! 0.00 0.00 40 2013OCT21_A_Arboretum1_3 0.222 98.731 #DIV/0! 0.00 0.00 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 #DIV/0! 0.00 0.00 44 2013OCT21_A_Arboretum2_2 1349.271 71.886 #DIV/0! 0.00 0.00 45 2013OCT21_A_Arboretum2_3 #DIV/0! 0.00 0.00 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 9.23 3463476.75 1740808.625 573508.75 1 489.69 502.43 49 2013OCT21_A_SolvA_15 9.23 2768.596 #DIV/0! 50 2013OCT21_A_SolvA_16 9.21 1991.19 #DIV/0! 51 2013OCT21_A_NorthDr1_1 #DIV/0! 0.00 0.00 52 2013OCT21_A_NorthDr1_2 164.397 #DIV/0! 0.00 0.00 53 2013OCT21_A_NorthDr1_3 #DIV/0! 0.00 0.00 54 2013OCT21_A_SolvA_17 138.841 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 #DIV/0! 0.00 0.00 57 2013OCT21_A_NorthDr2_2 #DIV/0! 0.00 0.00 58 2013OCT21_A_NorthDr2_3 #DIV/0! 0.00 0.00 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 9.28 1262.886 1306.821 1946.235 0 0.18 0.18 218 62 2013OCT21_A_AnacostiaPk_2 #DIV/0! 0.00 0.00 63 2013OCT21_A_AnacostiaPk_3 457.418 #DIV/0! 0.00 0.00 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 #DIV/0! 0.00 0.00 67 2013OCT21_A_GreenbeltPk_2 2.241 #DIV/0! 0.00 0.00 68 2013OCT21_A_GreenbeltPk_3 #DIV/0! 0.00 0.00 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 81.242 #DIV/0! 0.00 0.00 72 2013OCT21_A_PowderMillRd_2 34.876 #DIV/0! 0.00 0.00 73 2013OCT21_A_PowderMillRd_3 #DIV/0! 0.00 0.00 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 9.23 3557257 1766142.875 603098.688 1 502.95 516.04 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 #DIV/0! 0.00 0.00 80 2013OCT21_A_ResearchRd_2 #DIV/0! 0.00 0.00 81 2013OCT21_A_ResearchRd_3 #DIV/0! 0.00 0.00 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 9.25 543.577 947.472 #DIV/0! 0.08 0.08 85 2013OCT21_A_Skateboard_2 #DIV/0! 0.00 0.00 86 2013OCT21_A_Skateboard_3 #DIV/0! 0.00 0.00 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 9.24 2193.867 768.497 0 89 2013OCT21_A_SligoCreek_1 1835.741 #DIV/0! 0.00 0.00 90 2013OCT21_A_SligoCreek_2 #DIV/0! 0.00 0.00 91 2013OCT21_A_SligoCreek_3 #DIV/0! 0.00 0.00 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 905.041 #DIV/0! 0.00 0.00 95 2013OCT21_A_RiverdaleRd_2 #DIV/0! 0.00 0.00 96 2013OCT21_A_RiverdaleRd_3 #DIV/0! 0.00 0.00 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 9.21 1155.524 804.936 403.547 1 101 2013OCT21_A_0-05_Std_2 0.05 9.23 5598.087 2803.475 729.432 1 102 2013OCT21_A_0-1_Std_2 0.1 9.23 18789.332 7524.274 2958.848 1 103 2013OCT21_A_0-5_Std_2 0.5 9.23 75202.195 36302.57 11464.431 1 104 2013OCT21_A_1_Std_2 1 9.23 144361.766 70345.477 23575.285 1 105 2013OCT21_A_5_Std_2 5 9.23 871215.938 413838 147577.313 1 106 2013OCT21_A_10_Std_2 10 9.23 1600967.375 777876.938 264446.75 1 107 2013OCT21_A_25_Std_2 25 9.23 3623884.5 1715329.875 618588.813 1 219 108 2013OCT21_A_50_Std_2 50 9.23 6062495.5 3054136.5 1039495.875 1 109 2013OCT21_A_100_Std_2 100 9.23 9786985 5207425 1801845 1 110 2013OCT21_A_200_Stds_2 200 9.23 12681367 8044805 2737876.75 1 111 2013OCT21_A_SolvA_38 9.23 22418.76 11865.14 4270.614 1 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 9.25 1931.776 1478.5 0 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 11: Alachlor-d13 yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT21_SolvA_1 #DIV/0! Samples 2 2013OCT21_A_Lab Blk 9.22 56442.852 #DIV/0! 33807 Overall Avg 3 2013OCT21_A_Travel Blk 9.21 46921.891 #DIV/0! 19% RSD 4 2013OCT21_A_0-01_Std 0.01 #DIV/0! 69% % Rec 5 2013OCT21_A_0-05_Std 0.05 #DIV/0! Standard surrogate 6 2013OCT21_A_0-1_Std 0.1 #DIV/0! 49318.41 Avg 7 2013OCT21_A_0-5_Std 0.5 #DIV/0! 5% RSD 8 2013OCT21_A_1_Std 1 #DIV/0! 9 2013OCT21_A_5_Std 5 #DIV/0! 10 2013OCT21_A_10_Std 10 #DIV/0! 11 2013OCT21_A_25_Std 25 #DIV/0! 12 2013OCT21_A_50_Std 50 #DIV/0! 13 2013OCT21_A_100_Std 100 #DIV/0! 14 2013OCT21_A_200_Stds 200 0.967 #DIV/0! 15 2013OCT21_A_SolvA_2 #DIV/0! 16 2013OCT21_A_Surrogate_1 9.21 47701.656 #DIV/0! 17 2013OCT21_A_SolvA_3 #DIV/0! 18 2013OCT21_A_SolvA_4 #DIV/0! 19 2013OCT21_A_MM_0 9.21 35043.43 #DIV/0! 20 2013OCT21_A_MM_1 9.21 38508.219 #DIV/0! 21 2013OCT21_A_MM_5 9.21 37247.711 #DIV/0! 22 2013OCT21_A_MM_10 9.21 36998.199 229.056 #DIV/0! 23 2013OCT21_A_MM_25 9.21 32120.535 39.794 #DIV/0! 24 2013OCT21_A_MM_50 9.21 25872.199 #DIV/0! 25 2013OCT21_A_MM_100 9.21 25617.328 #DIV/0! 26 2013OCT21_A_SolvA_5 #DIV/0! 27 2013OCT21_A_SolvA_6 #DIV/0! Avg Rec 28 2013OCT21_A_BerwynRd_1 9.21 31649.359 139.881 #DIV/0! 30726 62% 29 2013OCT21_A_BerwynRd_2 9.22 28922.582 10.158 #DIV/0! 5% 30 2013OCT21_A_BerwynRd_3 9.21 31607.543 #DIV/0! 31 2013OCT21_A_SolvA_7 51.885 #DIV/0! 32 2013OCT21_A_SolvA_8 11.518 63.036 #DIV/0! Avg Rec 33 2013OCT21_A_UMD_1 9.21 34251.375 #DIV/0! 36050 73% 34 2013OCT21_A_UMD_2 9.21 37313.754 245.638 1104.512 #DIV/0! 4% 220 35 2013OCT21_A_UMD_3 9.21 36585.555 #DIV/0! 36 2013OCT21_A_SolvA_9 186.461 #DIV/0! 37 2013OCT21_A_SolvA_10 11.467 #DIV/0! Avg Rec 38 2013OCT21_A_Arboretum1_1 9.21 23828.77 100.152 #DIV/0! 25424 52% 39 2013OCT21_A_Arboretum1_2 9.21 25371.391 #DIV/0! 6% 40 2013OCT21_A_Arboretum1_3 9.21 27072.529 1181.047 #DIV/0! 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! Avg Rec 43 2013OCT21_A_Arboretum2_1 9.21 27392.719 98.422 #DIV/0! 31373 64% 44 2013OCT21_A_Arboretum2_2 9.21 34864.59 883.379 #DIV/0! 12% 45 2013OCT21_A_Arboretum2_3 9.21 31861.803 787.701 #DIV/0! 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 #DIV/0! 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 126.36 #DIV/0! Avg Rec 51 2013OCT21_A_NorthDr1_1 9.21 38376.035 #DIV/0! 38286 78% 52 2013OCT21_A_NorthDr1_2 9.21 40190.445 #DIV/0! 5% 53 2013OCT21_A_NorthDr1_3 9.21 36291.445 #DIV/0! 54 2013OCT21_A_SolvA_17 18.016 #DIV/0! 55 2013OCT21_A_SolvA_18 506.475 #DIV/0! Avg Rec 56 2013OCT21_A_NorthDr2_1 9.21 37041.625 #DIV/0! 37245 76% 57 2013OCT21_A_NorthDr2_2 9.21 35367.375 77.325 #DIV/0! 5% 58 2013OCT21_A_NorthDr2_3 9.21 39326.867 284.974 #DIV/0! 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! Avg Rec 61 2013OCT21_A_AnacostiaPk_1 9.21 21036.449 209.629 #DIV/0! 22620 46% 62 2013OCT21_A_AnacostiaPk_2 9.21 26194.41 #DIV/0! 14% 63 2013OCT21_A_AnacostiaPk_3 9.22 20628.627 #DIV/0! 64 2013OCT21_A_SolvA_21 55.099 #DIV/0! 65 2013OCT21_A_SolvA_22 26.438 #DIV/0! Avg Rec 66 2013OCT21_A_GreenbeltPk_1 9.21 28806.643 1261.405 788.506 #DIV/0! 32422 66% 67 2013OCT21_A_GreenbeltPk_2 9.22 31973.207 365.529 #DIV/0! 12% 68 2013OCT21_A_GreenbeltPk_3 9.22 36486.848 #DIV/0! 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! Avg Rec 71 2013OCT21_A_PowderMillRd_1 9.22 30137.766 #DIV/0! 29976 61% 72 2013OCT21_A_PowderMillRd_2 9.21 30758.201 150.002 #DIV/0! 3% 73 2013OCT21_A_PowderMillRd_3 9.22 29030.65 575.894 #DIV/0! 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 #DIV/0! 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! Avg Rec 79 2013OCT21_A_ResearchRd_1 9.22 36894.398 #DIV/0! 37420 76% 221 80 2013OCT21_A_ResearchRd_2 9.21 39355.117 58.527 #DIV/0! 5% 81 2013OCT21_A_ResearchRd_3 9.21 36011.703 #DIV/0! 82 2013OCT21_A_SolvA_29 137.813 540.196 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! Avg Rec 84 2013OCT21_A_Skateboard_1 9.22 33115.004 165.986 588.923 #DIV/0! 33868 69% 85 2013OCT21_A_Skateboard_2 9.21 33909.551 37.243 582.898 #DIV/0! 2% 86 2013OCT21_A_Skateboard_3 9.21 34578.078 52.004 1530.705 #DIV/0! 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 #DIV/0! Avg Rec 89 2013OCT21_A_SligoCreek_1 9.21 35776.211 9.212 #DIV/0! 38307 78% 90 2013OCT21_A_SligoCreek_2 9.21 38684.977 2325.771 #DIV/0! 6% 91 2013OCT21_A_SligoCreek_3 9.21 40460.195 3716.51 #DIV/0! 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 38.797 #DIV/0! Avg Rec 94 2013OCT21_A_RiverdaleRd_1 9.21 34948.957 106.252 #DIV/0! 33861 69% 95 2013OCT21_A_RiverdaleRd_2 9.22 30576.305 1423.578 772.527 #DIV/0! 9% 96 2013OCT21_A_RiverdaleRd_3 9.21 36057.688 1153.957 #DIV/0! 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 8.681 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 #DIV/0! 104 2013OCT21_A_1_Std_2 1 #DIV/0! 105 2013OCT21_A_5_Std_2 5 #DIV/0! 106 2013OCT21_A_10_Std_2 10 #DIV/0! 107 2013OCT21_A_25_Std_2 25 #DIV/0! 108 2013OCT21_A_50_Std_2 50 #DIV/0! 109 2013OCT21_A_100_Std_2 100 #DIV/0! 110 2013OCT21_A_200_Stds_2 200 #DIV/0! 111 2013OCT21_A_SolvA_38 103.101 108.934 #DIV/0! 112 2013OCT21_A_Surrogate_2 9.22 50935.164 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 1.752 #DIV/0! 116 2013OCT21_A_SolvA_42 19.2 #DIV/0! Compound 12: Metolachlor yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 3675.009 #DIV/0! 2 2013OCT21_A_Lab Blk 9.21 364702.406 106041.641 0 3 2013OCT21_A_Travel Blk 9.21 326135.75 92270.172 0 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 13.218 0 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 9.29 6377.198 1387.298 609.526 1 0.3 181% 222 7 2013OCT21_A_0-5_Std 0.5 9.29 14442.484 4363.103 736.269 1 0.6 27% 8 2013OCT21_A_1_Std 1 9.29 21788.514 8204.61 1125.438 1 1.0 -4% 9 2013OCT21_A_5_Std 5 9.29 150317.141 45096.043 3171.859 1 6.6 32% 10 2013OCT21_A_10_Std 10 9.29 278632.469 82169.5 7134.352 1 12.3 23% 11 2013OCT21_A_25_Std 25 9.28 657931 201597.484 15464.028 1 29.0 16% 12 2013OCT21_A_50_Std 50 9.28 1133540.625 360481.719 28216.711 1 49.9 0% 13 2013OCT21_A_100_Std 100 9.29 2020106.875 660437.938 49168.043 1 89.0 -11% 14 2013OCT21_A_200_Stds 200 9.29 4454945 1253139.75 92614.859 1 196.2 -2% 15 2013OCT21_A_SolvA_2 9.3 72497.289 17205.631 2545.752 1 0.0 -100% 16 2013OCT21_A_Surrogate_1 9.21 329307.219 93797.758 0 0.1 113% 17 2013OCT21_A_SolvA_3 9.31 43464.32 9289.182 1157.159 0 0.2 92% 18 2013OCT21_A_SolvA_4 9.33 33184.855 6982.071 0 0.6 17% 19 2013OCT21_A_MM_0 9.23 337910.594 103022.539 4453.306 1 1.1 11% 20 2013OCT21_A_MM_1 9.27 371519.094 112268.695 4322.255 1 6.4 28% 21 2013OCT21_A_MM_5 9.27 461248 139170.438 5592.764 1 12.0 20% 22 2013OCT21_A_MM_10 9.28 502389.406 159662.734 8705.738 1 28.2 13% 23 2013OCT21_A_MM_25 9.28 651573.188 212709.578 12288.311 1 50.5 1% 24 2013OCT21_A_MM_50 9.28 940190.063 312372.594 20431.895 1 99.5 0% 25 2013OCT21_A_MM_100 9.29 1688215.625 559634.688 41782.148 1 208.3 4% 26 2013OCT21_A_SolvA_5 5065.537 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 9.21 262432.938 84913.023 2463.368 1 115.57 198.40 29 2013OCT21_A_BerwynRd_2 9.21 282631.688 80110.867 2022.555 1 124.47 213.67 30 2013OCT21_A_BerwynRd_3 9.21 272005.281 82403.625 1959.661 1 119.79 205.63 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 9.33 17872.174 2618.263 866.17 1 33 2013OCT21_A_UMD_1 9.28 845047 251857.25 14188.039 1 372.15 638.84 34 2013OCT21_A_UMD_2 9.28 826474.75 258674.141 14405.325 1 363.97 624.80 35 2013OCT21_A_UMD_3 9.28 826301.5 250576.813 13168.556 1 363.90 624.67 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 9.27 261696.344 86503.367 5023.703 1 115.25 197.84 39 2013OCT21_A_Arboretum1_2 9.27 267733.938 82104.953 4115.625 1 117.91 202.40 40 2013OCT21_A_Arboretum1_3 9.27 269794.719 84361.813 3963.866 1 118.82 203.96 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 9.27 347898 106515.18 6175.958 1 153.21 263.01 44 2013OCT21_A_Arboretum2_2 9.27 346957.406 104268.844 4345.533 1 152.80 262.29 45 2013OCT21_A_Arboretum2_3 9.27 341429.063 106626.797 5326.867 1 150.36 258.12 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 9.29 618052 183617.219 13907.041 1 272.19 467.24 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 9.24 472529.563 136774.938 3907.052 1 208.10 357.23 52 2013OCT21_A_NorthDr1_2 9.24 475837.406 140450.859 5134.98 1 209.55 359.73 223 53 2013OCT21_A_NorthDr1_3 9.24 476557.375 135582.906 6331.079 1 209.87 360.27 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 9.23 421800.813 129922.938 6408.828 1 185.76 318.88 57 2013OCT21_A_NorthDr2_2 9.27 444383.406 133348.672 4192.967 1 195.70 335.95 58 2013OCT21_A_NorthDr2_3 9.24 443299.219 126990.023 4765.184 1 195.23 335.13 59 2013OCT21_A_SolvA_19 0.678 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 9.23 167993.922 54844.887 2397.459 1 73.98 127.00 62 2013OCT21_A_AnacostiaPk_2 9.23 178868.734 55636.918 3498.319 1 78.77 135.22 63 2013OCT21_A_AnacostiaPk_3 9.23 168983.359 48912.961 2517.554 1 74.42 127.75 64 2013OCT21_A_SolvA_21 426.24 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 9.21 207126.984 64893.688 1862.902 1 91.22 156.59 67 2013OCT21_A_GreenbeltPk_2 9.21 207541.156 64746.199 2954.292 1 91.40 156.90 68 2013OCT21_A_GreenbeltPk_3 9.21 209813.344 64028.797 3526.392 1 92.40 158.62 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 219.06 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 9.22 270855.906 83093.148 3173.398 1 119.28 204.76 72 2013OCT21_A_PowderMillRd_2 9.22 293075.375 87825.211 2731.35 1 129.07 221.56 73 2013OCT21_A_PowderMillRd_3 9.22 284317.344 90889 2100.383 1 125.21 214.94 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 9.29 632403.188 191750.359 14064.681 1 278.51 478.09 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 862.005 #DIV/0! 79 2013OCT21_A_ResearchRd_1 9.21 271026.563 83336.781 2475.398 1 119.36 204.89 80 2013OCT21_A_ResearchRd_2 9.21 275624.594 85534.852 1924.896 1 121.38 208.37 81 2013OCT21_A_ResearchRd_3 9.21 279440.813 84639.867 1651.471 1 123.06 211.25 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 9.21 195636.922 60262.359 1304.283 1 86.16 147.90 85 2013OCT21_A_Skateboard_2 9.21 197478.141 62373.027 951.978 1 86.97 149.29 86 2013OCT21_A_Skateboard_3 9.21 195389.234 63326.496 2022.242 1 86.05 147.71 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 2.524 27.513 #DIV/0! 89 2013OCT21_A_SligoCreek_1 9.21 223650.984 67018.938 2307.448 1 98.49 169.08 90 2013OCT21_A_SligoCreek_2 9.21 227603 67345.734 2672.668 1 100.23 172.06 91 2013OCT21_A_SligoCreek_3 9.21 224130.406 71518.695 1958.134 1 98.71 169.44 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 9.28 572053.563 186057.938 10263.556 1 251.93 432.46 95 2013OCT21_A_RiverdaleRd_2 9.28 567959.375 180686.516 9452.528 1 250.12 429.37 96 2013OCT21_A_RiverdaleRd_3 9.28 568007.438 176534.281 9284.246 1 250.15 429.41 97 2013OCT21_A_SolvA_35 #DIV/0! 224 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 643.416 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 9.28 2423.118 939.842 0 102 2013OCT21_A_0-1_Std_2 0.1 9.29 4361.39 1706.275 0 103 2013OCT21_A_0-5_Std_2 0.5 9.29 13297.483 5465.062 729.252 1 104 2013OCT21_A_1_Std_2 1 9.29 25189.594 8008.782 0 105 2013OCT21_A_5_Std_2 5 9.29 144929.328 45397.074 4146.459 1 106 2013OCT21_A_10_Std_2 10 9.29 273035.781 90583.297 6248.162 1 107 2013OCT21_A_25_Std_2 25 9.29 640717.938 197749.281 14195.837 1 108 2013OCT21_A_50_Std_2 50 9.28 1147528.375 374502.75 29220.512 1 109 2013OCT21_A_100_Std_2 100 9.29 2259941.75 728849.125 54274.141 1 110 2013OCT21_A_200_Stds_2 200 9.29 4728944.5 1374815.5 101035.109 1 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 9.21 334687.281 101191.75 0 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 342.691 #DIV/0! Compound 13: Metolachlor-d6 yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 #DIV/0! 2 2013OCT21_A_Lab Blk 9.28 8250585 5477685.5 1281901.75 1 7184384 Avg 3 2013OCT21_A_Travel Blk 9.28 7794437.5 4987675.5 1146521.125 1 9% RSD 4 2013OCT21_A_0-01_Std 0.01 9.28 7195267 4473107.5 980988.625 1 5 2013OCT21_A_0-05_Std 0.05 9.28 7494817 4771128.5 1267269.625 1 6 2013OCT21_A_0-1_Std 0.1 9.28 8323604.5 5649263 1370602 1 7 2013OCT21_A_0-5_Std 0.5 9.28 7836098 5085065.5 1156243.125 1 8 2013OCT21_A_1_Std 1 9.28 7598929.5 4810184.5 1076384.875 1 9 2013OCT21_A_5_Std 5 9.28 8155342.5 5356228.5 1239020.25 1 10 2013OCT21_A_10_Std 10 9.28 7957873.5 5131886 1178130.375 1 11 2013OCT21_A_25_Std 25 9.28 7781991 4977285 1139606.625 1 12 2013OCT21_A_50_Std 50 9.28 7626637 4865851.5 1095759.75 1 13 2013OCT21_A_100_Std 100 9.28 7317863 4283207 925501.563 1 14 2013OCT21_A_200_Stds 200 9.28 7600978 3576872.5 873597.938 1 15 2013OCT21_A_SolvA_2 9.28 18027.301 4237.423 18205.725 0 16 2013OCT21_A_Surrogate_1 9086.122 0 17 2013OCT21_A_SolvA_3 9.28 6204.392 1602.096 60.77 0 18 2013OCT21_A_SolvA_4 9.29 5756.349 927.875 7308.408 0 19 2013OCT21_A_MM_0 9.28 6647391.5 3869165.75 792234.188 1 20 2013OCT21_A_MM_1 9.28 6873682.5 4183710 1055339.75 1 21 2013OCT21_A_MM_5 9.28 6994933 4151952.25 869988.625 1 22 2013OCT21_A_MM_10 9.28 6767759 3948892 798273.063 1 23 2013OCT21_A_MM_25 9.28 6609224.5 3083108 765953.313 1 24 2013OCT21_A_MM_50 9.28 6631787.5 3040242.5 727727.938 1 225 25 2013OCT21_A_MM_100 9.28 6905015.5 3347274.75 830323.938 1 26 2013OCT21_A_SolvA_5 9.27 13257.126 5373.829 5331.922 0 27 2013OCT21_A_SolvA_6 9.28 5378.55 1499.262 4365.739 0 28 2013OCT21_A_BerwynRd_1 9.28 7337404 4180276.5 877496 1 29 2013OCT21_A_BerwynRd_2 9.28 7100298.5 4241250 897032.75 1 30 2013OCT21_A_BerwynRd_3 9.28 7144680.5 4198380.5 894662.188 1 31 2013OCT21_A_SolvA_7 9.27 18459.842 5567.095 3685.669 0 32 2013OCT21_A_SolvA_8 9.28 5761.599 1673.863 4140.345 0 33 2013OCT21_A_UMD_1 9.28 7269099.5 4287353.5 901752.438 1 34 2013OCT21_A_UMD_2 9.28 7239293 4297690 909867.438 1 35 2013OCT21_A_UMD_3 9.28 7213100.5 4309882.5 891466.313 1 36 2013OCT21_A_SolvA_9 9.28 18558.887 4087.483 5213.258 0 37 2013OCT21_A_SolvA_10 9.27 7259.134 2567.228 1.775 0 38 2013OCT21_A_Arboretum1_1 9.27 6019675 2381715.25 570682 1 39 2013OCT21_A_Arboretum1_2 9.27 6063927.5 2330737.75 569907.438 1 40 2013OCT21_A_Arboretum1_3 9.27 5987042.5 2410718.5 588265.5 1 41 2013OCT21_A_SolvA_11 9.27 13710.19 3992.792 5550.948 0 42 2013OCT21_A_SolvA_12 9.27 6957.333 1264.622 4325.414 0 43 2013OCT21_A_Arboretum2_1 9.28 6531207 3030040.75 745290.25 1 44 2013OCT21_A_Arboretum2_2 9.28 6564019.5 2993650.25 727573.313 1 45 2013OCT21_A_Arboretum2_3 9.28 6527284 3077521.25 747743.938 1 46 2013OCT21_A_SolvA_13 9.27 16212.617 4711.249 5964.432 0 47 2013OCT21_A_SolvA_14 9.27 9159.185 1906.534 6023.146 0 48 2013OCT21_A_QC_Std25_1 9.28 7853360.5 4798965 1063262.125 1 49 2013OCT21_A_SolvA_15 9.27 16364.319 3596.422 3555.586 0 50 2013OCT21_A_SolvA_16 9.28 6523.091 1010.225 4624.946 0 51 2013OCT21_A_NorthDr1_1 9.28 7354470.5 4492157 961017.688 1 52 2013OCT21_A_NorthDr1_2 9.28 7352904 4494656.5 967123.375 1 53 2013OCT21_A_NorthDr1_3 9.28 7354849 4573850.5 995798.75 1 54 2013OCT21_A_SolvA_17 9.27 22478.787 6243.418 5419.585 0 55 2013OCT21_A_SolvA_18 9.27 5934.818 3.378 #DIV/0! 56 2013OCT21_A_NorthDr2_1 9.28 7287212 4309738.5 932996 1 57 2013OCT21_A_NorthDr2_2 9.28 7198228 4377863.5 947251.813 1 58 2013OCT21_A_NorthDr2_3 9.28 7311094 4403109 926822.688 1 59 2013OCT21_A_SolvA_19 9.27 18617.762 5806.039 #DIV/0! 60 2013OCT21_A_SolvA_20 9.26 7237.174 1150.017 2296.375 0 61 2013OCT21_A_AnacostiaPk_1 9.27 5646479 2144842.75 514026.938 1 62 2013OCT21_A_AnacostiaPk_2 9.27 5696779.5 2199723.5 524274.563 1 63 2013OCT21_A_AnacostiaPk_3 9.27 5726322.5 2109782.25 512282.563 1 64 2013OCT21_A_SolvA_21 9.27 17477.201 5165.082 5276.491 0 65 2013OCT21_A_SolvA_22 9.27 8729.706 5198.63 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 9.28 6557629 2970686.5 745297.688 1 67 2013OCT21_A_GreenbeltPk_2 9.28 6562540 2967136.25 732767.125 1 68 2013OCT21_A_GreenbeltPk_3 9.28 6551676 2899779.25 704992.563 1 69 2013OCT21_A_SolvA_23 9.28 20483.221 3754.266 4096.455 0 226 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 9.28 7000636.5 3220086.25 774216 1 72 2013OCT21_A_PowderMillRd_2 9.28 6833801 3294389.25 785834.875 1 73 2013OCT21_A_PowderMillRd_3 9.28 6791323 3339809 806803 1 74 2013OCT21_A_SolvA_25 9.28 19999.676 6044.845 4581.51 0 75 2013OCT21_A_SolvA_26 9.28 12171.94 2555.066 5.924 0 76 2013OCT21_A_QC_Std25_2 9.28 7724027.5 4968709.5 1141055.25 1 77 2013OCT21_A_SolvA_27 9.27 18128.139 4791.054 4696.136 0 78 2013OCT21_A_SolvA_28 9.28 10453.287 1825.319 2287.51 0 79 2013OCT21_A_ResearchRd_1 9.28 7401486 4370327 912623.625 1 80 2013OCT21_A_ResearchRd_2 9.28 7220221 4449461.5 944930.688 1 81 2013OCT21_A_ResearchRd_3 9.28 7174258.5 4492598.5 945117.438 1 82 2013OCT21_A_SolvA_29 9.28 18138.068 5336.318 3392.397 0 83 2013OCT21_A_SolvA_30 9.27 3654.465 1565.133 #DIV/0! 84 2013OCT21_A_Skateboard_1 9.28 6518519.5 3099456.75 745322.5 1 85 2013OCT21_A_Skateboard_2 9.28 6566066.5 3068563 754261.188 1 86 2013OCT21_A_Skateboard_3 9.27 6457942 3782201.25 780116.875 1 87 2013OCT21_A_SolvA_31 9.27 17773.418 5476.061 5025.465 0 88 2013OCT21_A_SolvA_32 9.27 9828.34 2997.428 4612.898 0 89 2013OCT21_A_SligoCreek_1 9.28 6797336.5 4101908.5 846662.625 1 90 2013OCT21_A_SligoCreek_2 9.28 6830927.5 4111942.75 832392.125 1 91 2013OCT21_A_SligoCreek_3 9.28 6822275.5 4155174.25 864127 1 92 2013OCT21_A_SolvA_33 9.27 17872.826 6073.452 1637.841 1 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 9.28 7106372.5 4383991.5 919551.438 1 95 2013OCT21_A_RiverdaleRd_2 9.28 7111571.5 4429270 945680.75 1 96 2013OCT21_A_RiverdaleRd_3 9.28 7126479 4313211.5 917554.813 1 97 2013OCT21_A_SolvA_35 9.27 18674.674 6272.189 3289 0 98 2013OCT21_A_SolvA_36 9.27 5915.947 1324.601 2213.893 0 99 2013OCT21_A_SolvA_37 9.27 5800.855 1282.177 3.417 0 100 2013OCT21_A_0-01_Std_2 0.01 9.28 7190946.5 4476990 973887.75 1 101 2013OCT21_A_0-05_Std_2 0.05 9.28 7395306.5 4708665 1040545.063 1 102 2013OCT21_A_0-1_Std_2 0.1 9.28 8126522 5575877.5 1322244.5 1 103 2013OCT21_A_0-5_Std_2 0.5 9.28 7659781 5096049.5 1183400.75 1 104 2013OCT21_A_1_Std_2 1 9.28 7610211 4863709.5 1076127.5 1 105 2013OCT21_A_5_Std_2 5 9.28 8004441.5 5475279.5 1313388.5 1 106 2013OCT21_A_10_Std_2 10 9.28 8008801.5 5283627 1219610.5 1 107 2013OCT21_A_25_Std_2 25 9.28 7820097.5 5100421.5 1144917.25 1 108 2013OCT21_A_50_Std_2 50 9.28 7749059 5100621.5 1154987.25 1 109 2013OCT21_A_100_Std_2 100 9.28 7615840 4825081.5 1034017.063 1 110 2013OCT21_A_200_Stds_2 200 9.28 7935707.5 4589780 987111.625 1 111 2013OCT21_A_SolvA_38 9.27 22101.746 4724.717 4486.186 0 112 2013OCT21_A_Surrogate_2 9.27 2846.091 425.839 1393.782 0 113 2013OCT21_A_SolvA_39 9.28 8220.537 1121.339 2731.554 0 114 2013OCT21_A_SolvA_40 9.27 4654.405 1483.961 1810.469 0 115 2013OCT21_A_SolvA_41 #DIV/0! 227 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 15: Acesulfame yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 1.48 0.438 0.625 0 #DIV/0! 2 2013OCT21_A_Lab Blk 0 #DIV/0! 3 2013OCT21_A_Travel Blk 1.33 0.406 0.414 0 #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 0.152 0 0.00 -100% 5 2013OCT21_A_0-05_Std 0.05 0.469 0 0.00 -100% 6 2013OCT21_A_0-1_Std 0.1 2.562 0 0.00 -100% 7 2013OCT21_A_0-5_Std 0.5 35.043 0 0.00 -100% 8 2013OCT21_A_1_Std 1 1.45 3456.352 435.317 1 1.1 5% 9 2013OCT21_A_5_Std 5 1.45 18255.584 2395.691 1 5.6 11% 10 2013OCT21_A_10_Std 10 1.45 37506.648 4831.041 1 11.4 14% 11 2013OCT21_A_25_Std 25 1.45 95517.055 11218.758 1 29.1 16% 12 2013OCT21_A_50_Std 50 1.45 177499.047 21061.492 1 54.0 8% 13 2013OCT21_A_100_Std 100 1.45 328822.25 45343.793 1 100.0 0% 14 2013OCT21_A_200_Stds 200 1.45 624657.188 82268.336 1 190.0 -5% 15 2013OCT21_A_SolvA_2 #DIV/0! 0.00 -100% 16 2013OCT21_A_Surrogate_1 0.406 0 0.00 -100% 17 2013OCT21_A_SolvA_3 0.22 0 0.00 -100% 18 2013OCT21_A_SolvA_4 0.649 0 0.5 -3% 19 2013OCT21_A_MM_0 5.726 #DIV/0! 1.1 8% 20 2013OCT21_A_MM_1 1.46 5219.369 418.447 1 5.8 15% 21 2013OCT21_A_MM_5 1.45 23289.35 2814.522 1 11.5 15% 22 2013OCT21_A_MM_10 1.45 44725.473 5122.188 1 28.5 14% 23 2013OCT21_A_MM_25 1.45 90109.414 10622.322 1 58.4 17% 24 2013OCT21_A_MM_50 1.45 167288.953 20964.67 1 112.4 12% 25 2013OCT21_A_MM_100 1.45 373915.531 47325.508 1 199.5 0% 26 2013OCT21_A_SolvA_5 0.401 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 1.45 797.167 58.095 1 2.42 2.17 29 2013OCT21_A_BerwynRd_2 1.45 806.739 28.329 1 2.45 2.20 30 2013OCT21_A_BerwynRd_3 1.42 756.861 5.182 0 2.30 2.06 31 2013OCT21_A_SolvA_7 0.342 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 1.44 668.99 62.05 1 2.03 1.82 34 2013OCT21_A_UMD_2 1.45 528.882 7.104 0 1.61 1.44 35 2013OCT21_A_UMD_3 1.46 436.084 15.921 1 1.33 1.19 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 1.18 #DIV/0! 38 2013OCT21_A_Arboretum1_1 1.45 1308.569 44.674 1 3.98 3.57 39 2013OCT21_A_Arboretum1_2 1.45 1598.068 142.418 1 4.86 4.36 40 2013OCT21_A_Arboretum1_3 1.45 1336.176 130.357 1 4.06 3.64 41 2013OCT21_A_SolvA_11 0.442 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 228 43 2013OCT21_A_Arboretum2_1 1.46 1375.099 54.933 1 4.18 3.75 44 2013OCT21_A_Arboretum2_2 1.44 1652.024 49.483 1 5.03 4.51 45 2013OCT21_A_Arboretum2_3 1.44 1567.529 66.39 1 4.77 4.28 46 2013OCT21_A_SolvA_13 0.468 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 1.45 102748.031 12381.767 1 312.55 280.28 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 1.46 483.776 2.184 0 1.47 1.32 52 2013OCT21_A_NorthDr1_2 1.46 481.264 2.114 0 1.46 1.31 53 2013OCT21_A_NorthDr1_3 1.44 419.786 18.245 1 1.28 1.15 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 1.45 532.348 39.237 1 1.62 1.45 57 2013OCT21_A_NorthDr2_2 1.45 639.794 16.397 0 1.95 1.75 58 2013OCT21_A_NorthDr2_3 1.46 388.047 27.417 1 1.18 1.06 59 2013OCT21_A_SolvA_19 1.41 2.54 1.071 0 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 1.43 1714.611 88.735 1 5.22 4.68 62 2013OCT21_A_AnacostiaPk_2 1.44 2007.863 94.493 1 6.11 5.48 63 2013OCT21_A_AnacostiaPk_3 1.43 1624.987 179.687 1 4.94 4.43 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 1.46 828.212 50.33 1 2.52 2.26 67 2013OCT21_A_GreenbeltPk_2 1.46 1474.67 83.529 1 4.49 4.02 68 2013OCT21_A_GreenbeltPk_3 1.48 1141.067 71.74 1 3.47 3.11 69 2013OCT21_A_SolvA_23 0.532 #DIV/0! 70 2013OCT21_A_SolvA_24 0.782 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 1.45 769.519 1.171 0 2.34 2.10 72 2013OCT21_A_PowderMillRd_2 1.46 643.39 8.541 0 1.96 1.76 73 2013OCT21_A_PowderMillRd_3 1.45 490.494 36.724 1 1.49 1.34 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 1.45 98804.492 13841.4 1 300.55 269.52 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 0.851 #DIV/0! 0.00 0.00 80 2013OCT21_A_ResearchRd_2 1.025 #DIV/0! 0.00 0.00 81 2013OCT21_A_ResearchRd_3 0.598 #DIV/0! 0.00 0.00 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 1.44 1667.539 90.71 1 5.07 4.55 85 2013OCT21_A_Skateboard_2 1.43 2247.318 71.305 1 6.84 6.13 86 2013OCT21_A_Skateboard_3 1.43 1808.606 38.37 0 5.50 4.93 87 2013OCT21_A_SolvA_31 #DIV/0! 229 88 2013OCT21_A_SolvA_32 0.156 #DIV/0! 89 2013OCT21_A_SligoCreek_1 1.45 2152.347 177.348 1 6.55 5.87 90 2013OCT21_A_SligoCreek_2 1.46 2250.63 76.872 1 6.85 6.14 91 2013OCT21_A_SligoCreek_3 1.46 2210.959 288.038 1 6.73 6.03 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 0.393 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 1.46 1021.915 27.958 1 3.11 2.79 95 2013OCT21_A_RiverdaleRd_2 1.44 903.295 37.128 1 2.75 2.46 96 2013OCT21_A_RiverdaleRd_3 1.46 782.094 51.328 1 2.38 2.13 97 2013OCT21_A_SolvA_35 0.659 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 0.438 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 0.301 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 1.46 1591.487 71.017 1 104 2013OCT21_A_1_Std_2 1 1.45 3564.885 262.935 1 105 2013OCT21_A_5_Std_2 5 1.45 18961.479 2590.356 1 106 2013OCT21_A_10_Std_2 10 1.45 37649.023 4052.945 1 107 2013OCT21_A_25_Std_2 25 1.45 93573.969 10559.774 1 108 2013OCT21_A_50_Std_2 50 1.46 192082.672 21855.158 1 109 2013OCT21_A_100_Std_2 100 1.46 369621 46068.848 1 110 2013OCT21_A_200_Stds_2 200 1.46 655960.375 84487.367 1 111 2013OCT21_A_SolvA_38 1.42 0.446 0.406 0 112 2013OCT21_A_Surrogate_2 1.33 0.692 0 113 2013OCT21_A_SolvA_39 1.41 0.524 0.875 0 114 2013OCT21_A_SolvA_40 1.36 0.449 0.43 0 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 1.37 1.008 0.434 0 Compound 16: Acesulfame-d4 yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0 2 2013OCT21_A_Lab Blk 1.44 227345.656 40437.5 0 255339 Avg 3 2013OCT21_A_Travel Blk 1.44 223496.453 40089.109 0 6% RSD 4 2013OCT21_A_0-01_Std 0.01 1.44 232556.75 40253.73 0 5 2013OCT21_A_0-05_Std 0.05 1.44 240519.344 42139.547 0 6 2013OCT21_A_0-1_Std 0.1 1.44 271795.063 45503.402 0 7 2013OCT21_A_0-5_Std 0.5 1.44 265336.031 47067.563 1 8 2013OCT21_A_1_Std 1 1.44 263602.781 47187.012 1 9 2013OCT21_A_5_Std 5 1.44 236442.047 40091.031 1 10 2013OCT21_A_10_Std 10 1.44 227264.391 39865.801 1 11 2013OCT21_A_25_Std 25 1.44 238082.469 39726.852 1 12 2013OCT21_A_50_Std 50 1.44 225780.547 42289.363 1 13 2013OCT21_A_100_Std 100 1.44 212700.844 37971.875 1 14 2013OCT21_A_200_Stds 200 1.44 208540.016 35625.184 1 230 15 2013OCT21_A_SolvA_2 0.473 #DIV/0! 16 2013OCT21_A_Surrogate_1 1.3 0.195 0 17 2013OCT21_A_SolvA_3 1.31 1.594 0.68 0 18 2013OCT21_A_SolvA_4 1.31 0.317 0 19 2013OCT21_A_MM_0 1.44 244625.656 41263.203 1 20 2013OCT21_A_MM_1 1.44 300776.375 54036.902 1 21 2013OCT21_A_MM_5 1.44 295950.344 52540.32 1 22 2013OCT21_A_MM_10 1.44 289872.875 50060.82 1 23 2013OCT21_A_MM_25 1.44 233310.188 38747.832 1 24 2013OCT21_A_MM_50 1.44 233887.563 41447.152 1 25 2013OCT21_A_MM_100 1.44 275117.875 49872.043 1 26 2013OCT21_A_SolvA_5 1.37 13.018 0.57 0 27 2013OCT21_A_SolvA_6 1.43 0.528 0.414 0 28 2013OCT21_A_BerwynRd_1 1.44 279202.438 49547.496 1 29 2013OCT21_A_BerwynRd_2 1.44 288060.094 47136.418 1 30 2013OCT21_A_BerwynRd_3 1.44 267260.531 48177.539 1 31 2013OCT21_A_SolvA_7 0.882 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 1.44 267956.75 47979.535 1 34 2013OCT21_A_UMD_2 1.44 261410.188 46375.031 1 35 2013OCT21_A_UMD_3 1.44 269099.063 44752.188 1 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 0.352 #DIV/0! 38 2013OCT21_A_Arboretum1_1 1.44 270184.188 45883.309 1 39 2013OCT21_A_Arboretum1_2 1.44 254929.984 44807.629 1 40 2013OCT21_A_Arboretum1_3 1.43 267170.031 46493.648 1 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 0.211 #DIV/0! 43 2013OCT21_A_Arboretum2_1 1.44 269409.75 48443.922 1 44 2013OCT21_A_Arboretum2_2 1.44 272580.406 48036.398 1 45 2013OCT21_A_Arboretum2_3 1.44 266467.594 49642.133 1 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 1.44 251078.047 41302.547 1 49 2013OCT21_A_SolvA_15 1.36 0.43 0.328 0 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 1.44 248911.781 44863.734 1 52 2013OCT21_A_NorthDr1_2 1.44 259643.063 44878.223 1 53 2013OCT21_A_NorthDr1_3 1.44 265628.563 43311.281 1 54 2013OCT21_A_SolvA_17 1.3 1.657 1.348 0 55 2013OCT21_A_SolvA_18 1.43 0.969 0.491 0 56 2013OCT21_A_NorthDr2_1 1.44 261197.047 47908.707 1 57 2013OCT21_A_NorthDr2_2 1.44 267377.875 46065.402 1 58 2013OCT21_A_NorthDr2_3 1.44 266545.938 45220.234 1 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 1.28 0.316 0.371 0 231 61 2013OCT21_A_AnacostiaPk_1 1.44 266773.125 45684.984 1 62 2013OCT21_A_AnacostiaPk_2 1.43 263976.563 46401.348 1 63 2013OCT21_A_AnacostiaPk_3 1.44 258325.594 44875.461 1 64 2013OCT21_A_SolvA_21 1.27 0.864 0.235 1 65 2013OCT21_A_SolvA_22 1.33 0.738 0.687 0 66 2013OCT21_A_GreenbeltPk_1 1.44 246000.031 44931.758 1 67 2013OCT21_A_GreenbeltPk_2 1.44 245967.672 43575.387 1 68 2013OCT21_A_GreenbeltPk_3 1.44 253506.484 43346.078 1 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 0.446 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 1.44 256698.297 43537.16 1 72 2013OCT21_A_PowderMillRd_2 1.44 255450.453 45905.359 1 73 2013OCT21_A_PowderMillRd_3 1.44 251595.172 44713.609 1 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 1.34 0.434 0.438 0 76 2013OCT21_A_QC_Std25_2 1.44 256457.406 43336.891 1 77 2013OCT21_A_SolvA_27 1.46 0.156 0.086 0 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 1.44 270705.156 48437.535 1 80 2013OCT21_A_ResearchRd_2 1.44 273733.906 47172.285 1 81 2013OCT21_A_ResearchRd_3 1.44 273884.563 46100.594 1 82 2013OCT21_A_SolvA_29 1.38 1.102 0.544 0 83 2013OCT21_A_SolvA_30 1.37 0.301 27.27 0 84 2013OCT21_A_Skateboard_1 1.44 255551.656 45275.184 1 85 2013OCT21_A_Skateboard_2 1.44 255607.547 42911.703 1 86 2013OCT21_A_Skateboard_3 1.44 244147.953 41881.145 1 87 2013OCT21_A_SolvA_31 1.36 0.176 0.305 0 88 2013OCT21_A_SolvA_32 1.44 1.079 0.365 1 89 2013OCT21_A_SligoCreek_1 1.44 258710.734 46498.02 1 90 2013OCT21_A_SligoCreek_2 1.44 252477.969 44331.215 1 91 2013OCT21_A_SligoCreek_3 1.44 253387.547 43212.617 1 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 1.41 0.328 0.653 0 94 2013OCT21_A_RiverdaleRd_1 1.44 283121.938 45031.828 1 95 2013OCT21_A_RiverdaleRd_2 1.44 262617.938 45304.855 1 96 2013OCT21_A_RiverdaleRd_3 1.44 270786.781 47664.586 1 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 1.36 0.01 0.515 0 99 2013OCT21_A_SolvA_37 0.61 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 1.44 265671.656 47440.73 1 101 2013OCT21_A_0-05_Std_2 0.05 1.44 250578.266 44940.234 1 102 2013OCT21_A_0-1_Std_2 0.1 1.44 256986.453 44722.082 1 103 2013OCT21_A_0-5_Std_2 0.5 1.44 252928.547 43343.125 1 104 2013OCT21_A_1_Std_2 1 1.44 252386.641 43802.91 1 105 2013OCT21_A_5_Std_2 5 1.44 252875.375 44144.969 1 106 2013OCT21_A_10_Std_2 10 1.44 252122.188 43953.109 1 232 107 2013OCT21_A_25_Std_2 25 1.44 245615.609 39711.484 1 108 2013OCT21_A_50_Std_2 50 1.44 265304.719 44587.523 1 109 2013OCT21_A_100_Std_2 100 1.44 240745.844 40956.445 1 110 2013OCT21_A_200_Stds_2 200 1.44 224727.594 38586.625 1 111 2013OCT21_A_SolvA_38 1.32 0.008 0.287 0 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 17: Cyclamate yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0 #DIV/0! 2 2013OCT21_A_Lab Blk 0 #DIV/0! 3 2013OCT21_A_Travel Blk 0 #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 0.076 0 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 2.14 630.969 0 0.1 -2% 7 2013OCT21_A_0-5_Std 0.5 2.14 4807.046 41.099 1 0.7 49% 8 2013OCT21_A_1_Std 1 2.14 9318.563 94.727 1 1.4 45% 9 2013OCT21_A_5_Std 5 2.14 41366.371 798.79 1 6.4 29% 10 2013OCT21_A_10_Std 10 2.14 82485.07 1379.411 1 12.8 28% 11 2013OCT21_A_25_Std 25 2.14 212273.594 4275.825 1 33.0 32% 12 2013OCT21_A_50_Std 50 2.14 379028.188 7272.556 1 58.9 18% 13 2013OCT21_A_100_Std 100 2.14 690086.25 13900.981 1 107.3 7% 14 2013OCT21_A_200_Stds 200 2.14 1241596 25162.693 1 193.0 -4% 15 2013OCT21_A_SolvA_2 0.03 #DIV/0! 0.0 -100% 16 2013OCT21_A_Surrogate_1 0 0.0 -11% 17 2013OCT21_A_SolvA_3 0 0.1 -15% 18 2013OCT21_A_SolvA_4 0 0.4 -15% 19 2013OCT21_A_MM_0 2.14 665.568 0 0.9 -7% 20 2013OCT21_A_MM_1 2.14 8169.074 0 4.5 -10% 21 2013OCT21_A_MM_5 2.14 42067.059 766.324 1 8.7 -13% 22 2013OCT21_A_MM_10 2.14 75820.656 1419.856 1 21.6 -14% 23 2013OCT21_A_MM_25 2.14 150481.5 2667.708 1 43.7 -13% 24 2013OCT21_A_MM_50 2.14 280932.75 4820.501 1 75.8 -24% 25 2013OCT21_A_MM_100 2.14 662939.063 13036.046 1 128.5 -36% 26 2013OCT21_A_SolvA_5 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 2.14 410.934 0.281 1 0.64 0.64 29 2013OCT21_A_BerwynRd_2 2.13 304.739 0 0.47 0.48 30 2013OCT21_A_BerwynRd_3 2.14 508.747 1.826 1 0.79 0.79 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 2.14 237.65 0 0.37 0.37 233 34 2013OCT21_A_UMD_2 2.16 186.053 5.546 1 0.29 0.29 35 2013OCT21_A_UMD_3 2.14 91.261 0 0.14 0.14 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 2.14 1444.267 0 2.24 2.25 39 2013OCT21_A_Arboretum1_2 2.14 1462.851 11.319 1 2.27 2.28 40 2013OCT21_A_Arboretum1_3 2.14 1837.435 1.402 1 2.86 2.87 41 2013OCT21_A_SolvA_11 #DIV/0! 42 2013OCT21_A_SolvA_12 0.112 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.13 835.298 4.76 1 1.30 1.30 44 2013OCT21_A_Arboretum2_2 2.14 823.99 0 1.28 1.29 45 2013OCT21_A_Arboretum2_3 2.14 725.69 0 1.13 1.13 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 2.13 0.246 0.284 0 48 2013OCT21_A_QC_Std25_1 2.14 210919.484 3200.945 1 327.81 329.00 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 2.14 268.115 0 0.42 0.42 52 2013OCT21_A_NorthDr1_2 0.362 #DIV/0! 0.00 0.00 53 2013OCT21_A_NorthDr1_3 0.768 #DIV/0! 0.00 0.00 54 2013OCT21_A_SolvA_17 0.29 #DIV/0! 55 2013OCT21_A_SolvA_18 0.311 #DIV/0! 56 2013OCT21_A_NorthDr2_1 2.12 370.383 15.2 1 0.58 0.58 57 2013OCT21_A_NorthDr2_2 2.16 294.838 0.214 1 0.46 0.46 58 2013OCT21_A_NorthDr2_3 2.15 217.978 0.884 1 0.34 0.34 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 0.537 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.14 2411.697 8.714 1 3.75 3.76 62 2013OCT21_A_AnacostiaPk_2 2.14 2177.276 17.635 1 3.38 3.40 63 2013OCT21_A_AnacostiaPk_3 2.14 2220.281 0.174 1 3.45 3.46 64 2013OCT21_A_SolvA_21 2.14 22.522 0.111 1 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.14 690.669 0.622 1 1.07 1.08 67 2013OCT21_A_GreenbeltPk_2 2.14 630.217 0.697 1 0.98 0.98 68 2013OCT21_A_GreenbeltPk_3 2.14 563.764 1.153 1 0.88 0.88 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.14 262.95 0.661 1 0.41 0.41 72 2013OCT21_A_PowderMillRd_2 2.14 240.065 0 0.37 0.37 73 2013OCT21_A_PowderMillRd_3 #DIV/0! 0.00 0.00 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.14 172861.047 3509.965 1 268.66 269.63 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 2.15 4.523 0 234 79 2013OCT21_A_ResearchRd_1 #DIV/0! 0.00 0.00 80 2013OCT21_A_ResearchRd_2 2.13 99.451 1.395 1 0.15 0.16 81 2013OCT21_A_ResearchRd_3 2.14 195.474 0.124 1 0.30 0.30 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.13 527.723 0.751 1 0.82 0.82 85 2013OCT21_A_Skateboard_2 2.14 777.648 1.721 1 1.21 1.21 86 2013OCT21_A_Skateboard_3 2.14 917.774 0.758 1 1.43 1.43 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 0.433 #DIV/0! 89 2013OCT21_A_SligoCreek_1 2.13 664.152 0 1.03 1.04 90 2013OCT21_A_SligoCreek_2 2.14 659.477 0 1.02 1.03 91 2013OCT21_A_SligoCreek_3 2.14 752.014 0.217 1 1.17 1.17 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.14 145.278 2.592 1 0.23 0.23 95 2013OCT21_A_RiverdaleRd_2 2.14 226.343 0 0.35 0.35 96 2013OCT21_A_RiverdaleRd_3 2.14 352.461 0 0.55 0.55 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 2.15 33.061 0 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 2.14 284.76 0 102 2013OCT21_A_0-1_Std_2 0.1 2.14 548.895 0.345 1 103 2013OCT21_A_0-5_Std_2 0.5 2.14 2739.771 73.35 1 104 2013OCT21_A_1_Std_2 1 2.14 5970.582 19.87 1 105 2013OCT21_A_5_Std_2 5 2.14 28887.996 317.583 1 106 2013OCT21_A_10_Std_2 10 2.14 55796.219 918.83 1 107 2013OCT21_A_25_Std_2 25 2.14 138782.328 2045.014 1 108 2013OCT21_A_50_Std_2 50 2.14 281488.656 5607.925 1 109 2013OCT21_A_100_Std_2 100 2.14 487806.906 10885.487 1 110 2013OCT21_A_200_Stds_2 200 2.14 826661.313 18912.873 1 111 2013OCT21_A_SolvA_38 2.04 24.915 0 112 2013OCT21_A_Surrogate_2 2.05 0.025 0 113 2013OCT21_A_SolvA_39 2.12 4.092 1.212 0 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 2.14 2.446 0.523 0 116 2013OCT21_A_SolvA_42 2.14 57.908 0 Compound 18: saccharine yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0.079 2.396 #DIV/0! #DIV/0! 2 2013OCT21_A_Lab Blk 0.232 #DIV/0! #DIV/0! 3 2013OCT21_A_Travel Blk 10.792 70.214 #DIV/0! #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 7.008 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 0.352 22.649 0 0.0 -100% 235 6 2013OCT21_A_0-1_Std 0.1 3.216 0 0.0 -100% 7 2013OCT21_A_0-5_Std 0.5 10.012 47.515 0 0.0 -100% 8 2013OCT21_A_1_Std 1 0.118 120.38 0 0.0 -100% 9 2013OCT21_A_5_Std 5 1.84 4939.854 691.64 5593.675 1 5.9 18% 10 2013OCT21_A_10_Std 10 1.84 10501.483 1468.962 11037.345 1 12.6 26% 11 2013OCT21_A_25_Std 25 1.84 26325.223 4073.019 27980.854 1 31.5 26% 12 2013OCT21_A_50_Std 50 1.84 45952.977 7074.208 49130.398 1 55.0 10% 13 2013OCT21_A_100_Std 100 1.84 84519.898 13952.235 88063.273 1 101.2 1% 14 2013OCT21_A_200_Stds 200 1.84 156217.484 23976.918 165575.031 1 187.1 -6% 15 2013OCT21_A_SolvA_2 1.78 1.021 0.701 4.958 0 0.0 -93% 16 2013OCT21_A_Surrogate_1 1.91 0.82 0.007 0.152 0 0.0 -2% 17 2013OCT21_A_SolvA_3 1.82 0.055 0.891 18.182 0 0.0 -89% 18 2013OCT21_A_SolvA_4 1.87 0.659 0.082 2.534 0 0.8 58% 19 2013OCT21_A_MM_0 1.83 924.289 41.641 1363.462 1 1.6 60% 20 2013OCT21_A_MM_1 1.84 2107.819 281.578 2875.705 1 7.3 47% 21 2013OCT21_A_MM_5 1.84 7274.659 1134.407 7816.946 1 13.7 37% 22 2013OCT21_A_MM_10 1.84 12758.624 2042.454 13078.803 1 33.0 32% 23 2013OCT21_A_MM_25 1.84 23419.465 3232.371 24193.338 1 62.9 26% 24 2013OCT21_A_MM_50 1.84 41130.906 6141.629 43753.984 1 114.3 14% 25 2013OCT21_A_MM_100 1.84 90919.656 13276.226 93082.578 1 198.4 -1% 26 2013OCT21_A_SolvA_5 1.83 11.586 0.516 1.146 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 1.89 24.625 0.648 4.684 1 (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 1.84 1514.607 118.567 1624.237 1 18.14 17.12 29 2013OCT21_A_BerwynRd_2 1.85 1376.357 124.318 1590.248 1 16.49 15.56 30 2013OCT21_A_BerwynRd_3 1.82 1310.663 259.516 1525.022 1 15.70 14.81 31 2013OCT21_A_SolvA_7 1.84 2.499 0.784 0.02 0 32 2013OCT21_A_SolvA_8 1.85 0.214 0.079 0 33 2013OCT21_A_UMD_1 1.84 3366.909 613.166 3802.248 1 40.33 38.06 34 2013OCT21_A_UMD_2 1.84 3086.098 625.246 3955.061 1 36.96 34.88 35 2013OCT21_A_UMD_3 1.83 3393.47 467.141 3710.457 1 40.65 38.36 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 1.77 0.176 0.097 0.548 0 38 2013OCT21_A_Arboretum1_1 1.83 1010.35 60.502 1109.895 1 12.10 11.42 39 2013OCT21_A_Arboretum1_2 1.83 1053.469 134.653 991.722 1 12.62 11.91 40 2013OCT21_A_Arboretum1_3 1.84 759.347 41.532 1088.56 1 9.10 8.58 41 2013OCT21_A_SolvA_11 1.81 0.21 0.428 1.422 0 42 2013OCT21_A_SolvA_12 1.83 0.158 0.198 2.022 0 43 2013OCT21_A_Arboretum2_1 1.81 811.283 34.635 826.428 1 9.72 9.17 44 2013OCT21_A_Arboretum2_2 1.84 935.948 57.55 988.621 1 11.21 10.58 45 2013OCT21_A_Arboretum2_3 1.84 850.741 36.093 657.67 1 10.19 9.62 46 2013OCT21_A_SolvA_13 1.82 1.936 0.276 4.254 1 47 2013OCT21_A_SolvA_14 1.82 0.239 0.929 0.048 0 48 2013OCT21_A_QC_Std25_1 1.84 27350.768 4175.815 29100.213 1 327.60 309.14 49 2013OCT21_A_SolvA_15 1.89 1.188 0.513 3.292 0 50 2013OCT21_A_SolvA_16 1.82 0.079 5.106 28.738 0 51 2013OCT21_A_NorthDr1_1 1.83 375.08 10.997 388.177 1 4.49 4.24 236 52 2013OCT21_A_NorthDr1_2 1.81 213.237 22.671 359.244 1 2.55 2.41 53 2013OCT21_A_NorthDr1_3 1.83 330.824 0.591 442.166 1 3.96 3.74 54 2013OCT21_A_SolvA_17 1.8 0.648 0.469 3.986 0 55 2013OCT21_A_SolvA_18 1.84 9.504 11.771 3.012 0 56 2013OCT21_A_NorthDr2_1 #DIV/0! 0.00 0.00 57 2013OCT21_A_NorthDr2_2 #DIV/0! 0.00 0.00 58 2013OCT21_A_NorthDr2_3 #DIV/0! 0.00 0.00 59 2013OCT21_A_SolvA_19 1.86 0.452 0.621 5.187 0 60 2013OCT21_A_SolvA_20 1.89 8.29 0.622 16.766 1 61 2013OCT21_A_AnacostiaPk_1 1.84 2151.462 131.58 2246.731 1 25.77 24.32 62 2013OCT21_A_AnacostiaPk_2 1.85 1915.651 258.421 2356.055 1 22.95 21.65 63 2013OCT21_A_AnacostiaPk_3 1.83 2053.649 252.255 2014.673 1 24.60 23.21 64 2013OCT21_A_SolvA_21 1.74 5.858 0.225 13.009 1 65 2013OCT21_A_SolvA_22 1.87 2.02 0.251 2.321 1 66 2013OCT21_A_GreenbeltPk_1 1.84 518.437 6.216 53.132 0 6.21 5.86 67 2013OCT21_A_GreenbeltPk_2 1.84 468.223 11.724 0 5.61 5.29 68 2013OCT21_A_GreenbeltPk_3 1.82 433.455 336.855 0 5.19 4.90 69 2013OCT21_A_SolvA_23 1.87 7.42 0.552 3.074 1 70 2013OCT21_A_SolvA_24 1.84 0.265 0.319 1.287 0 71 2013OCT21_A_PowderMillRd_1 1.83 1311.854 309.664 1746.616 1 15.71 14.83 72 2013OCT21_A_PowderMillRd_2 1.84 1707.467 103.49 1708.403 1 20.45 19.30 73 2013OCT21_A_PowderMillRd_3 1.84 1581.246 178.553 1831.884 1 18.94 17.87 74 2013OCT21_A_SolvA_25 1.85 1.845 0.519 0.725 0 75 2013OCT21_A_SolvA_26 1.84 2.97 0.081 0.88 1 76 2013OCT21_A_QC_Std25_2 1.84 27673.57 4433.617 32316.789 1 331.47 312.79 77 2013OCT21_A_SolvA_27 1.73 0.156 0.121 0.121 0 78 2013OCT21_A_SolvA_28 1.83 0.846 0.424 2.547 0 79 2013OCT21_A_ResearchRd_1 1.85 1214.611 101.769 1531.559 1 14.55 13.73 80 2013OCT21_A_ResearchRd_2 1.85 1294.7 248.663 1418.056 1 15.51 14.63 81 2013OCT21_A_ResearchRd_3 1.84 1531.075 156.766 1416.907 1 18.34 17.31 82 2013OCT21_A_SolvA_29 1.83 7.927 0.17 3.23 1 83 2013OCT21_A_SolvA_30 1.84 1.251 0.099 1.365 1 84 2013OCT21_A_Skateboard_1 1.84 879.276 40.715 995.56 1 10.53 9.94 85 2013OCT21_A_Skateboard_2 1.84 919.94 0.829 931.002 1 11.02 10.40 86 2013OCT21_A_Skateboard_3 1.84 960.704 0.032 1069.441 1 11.51 10.86 87 2013OCT21_A_SolvA_31 1.86 0.408 0.439 0.151 0 88 2013OCT21_A_SolvA_32 1.83 2.686 0.212 2.102 1 89 2013OCT21_A_SligoCreek_1 1.84 928.605 12.553 960.032 1 11.12 10.50 90 2013OCT21_A_SligoCreek_2 1.85 842.27 36.615 1024.613 1 10.09 9.52 91 2013OCT21_A_SligoCreek_3 1.84 900.523 12.559 1065.602 1 10.79 10.18 92 2013OCT21_A_SolvA_33 1.82 0.397 0.273 #DIV/0! 93 2013OCT21_A_SolvA_34 1.9 2.429 4.997 22.536 0 94 2013OCT21_A_RiverdaleRd_1 1.83 920.435 860.916 0 11.02 10.40 95 2013OCT21_A_RiverdaleRd_2 1.84 805.382 22.027 956.795 1 9.65 9.10 96 2013OCT21_A_RiverdaleRd_3 1.84 852.588 0.071 826.116 1 10.21 9.64 237 97 2013OCT21_A_SolvA_35 1.87 0.204 0.468 9.389 0 98 2013OCT21_A_SolvA_36 1.85 21.132 0.164 6.695 1 99 2013OCT21_A_SolvA_37 1.83 0.081 0.079 7.857 0 100 2013OCT21_A_0-01_Std_2 0.01 1.86 0.558 0.079 13.286 1 101 2013OCT21_A_0-05_Std_2 0.05 1.8 40.71 0.317 12.583 1 102 2013OCT21_A_0-1_Std_2 0.1 1.83 8.769 0.769 49.392 1 103 2013OCT21_A_0-5_Std_2 0.5 1.85 658.561 627.411 0 104 2013OCT21_A_1_Std_2 1 1.85 1338.73 36.784 1251.727 1 105 2013OCT21_A_5_Std_2 5 1.84 6118.883 683.925 6422.284 1 106 2013OCT21_A_10_Std_2 10 1.84 11434.652 1634.684 12749.787 1 107 2013OCT21_A_25_Std_2 25 1.84 27509.838 4099.674 29641.443 1 108 2013OCT21_A_50_Std_2 50 1.84 52492.852 8187.052 56889 1 109 2013OCT21_A_100_Std_2 100 1.85 95441.758 15225.647 105697.852 1 110 2013OCT21_A_200_Stds_2 200 1.85 165659.172 27017.125 179503.578 1 111 2013OCT21_A_SolvA_38 1.82 0.107 0.214 0.753 0 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 1.86 12.656 0.234 0.511 0 114 2013OCT21_A_SolvA_40 1.82 0.236 0.352 4.932 0 115 2013OCT21_A_SolvA_41 1.85 0.337 0.348 0.079 0 116 2013OCT21_A_SolvA_42 1.86 1.837 0.005 6.661 #VALUE! Compound 19: 2.4-D yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0.395 0 #DIV/0! 2 2013OCT21_A_Lab Blk 0 #DIV/0! 3 2013OCT21_A_Travel Blk 0 #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 0 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 0 0.0 -100% 7 2013OCT21_A_0-5_Std 0.5 93.892 0 0.0 -100% 8 2013OCT21_A_1_Std 1 6.17 3253.502 138.55 18.617 0 1.3 32% 9 2013OCT21_A_5_Std 5 6.15 14296.175 1179.956 0 5.8 16% 10 2013OCT21_A_10_Std 10 6.15 29411.203 2660.789 268.032 1 11.9 19% 11 2013OCT21_A_25_Std 25 6.15 75474.281 6571.927 1552.262 1 30.6 22% 12 2013OCT21_A_50_Std 50 6.14 135882.328 11248.182 2650.082 1 55.0 10% 13 2013OCT21_A_100_Std 100 6.15 263989.625 24003.086 5545.547 1 106.9 7% 14 2013OCT21_A_200_Stds 200 6.16 473897.594 42221.18 9497.976 1 191.9 -4% 15 2013OCT21_A_SolvA_2 #DIV/0! 0.0 -100% 16 2013OCT21_A_Surrogate_1 7.975 0 0.0 -100% 17 2013OCT21_A_SolvA_3 6.19 260.879 2.753 0 0.0 -100% 18 2013OCT21_A_SolvA_4 0 0.8 58% 19 2013OCT21_A_MM_0 6.15 43817.676 3541.24 868.902 1 1.4 45% 20 2013OCT21_A_MM_1 6.14 55001.75 3962.114 563.595 1 6.2 23% 21 2013OCT21_A_MM_5 6.16 65638.711 6229.565 1396.208 1 11.7 17% 22 2013OCT21_A_MM_10 6.16 78564.594 6795.677 1141.472 1 30.5 22% 23 2013OCT21_A_MM_25 6.15 103472.602 8380.604 1795.902 1 57.4 15% 238 24 2013OCT21_A_MM_50 6.15 161150.469 12710.11 2756.98 1 105.7 6% 25 2013OCT21_A_MM_100 6.15 324212.531 27009.475 6175.449 1 197.1 -1% 26 2013OCT21_A_SolvA_5 16.15 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 0.236 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 6.16 7601.922 791.439 68.498 1 30.78 28.09 29 2013OCT21_A_BerwynRd_2 6.15 6819.355 352.62 55.977 1 27.61 25.20 30 2013OCT21_A_BerwynRd_3 6.15 7684.723 666.776 17.095 1 31.12 28.39 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 6.17 5425.34 270.538 0 21.97 20.04 34 2013OCT21_A_UMD_2 6.15 4648.798 362.219 0 18.83 17.18 35 2013OCT21_A_UMD_3 6.15 5750.264 477.611 168.315 1 23.29 21.25 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 6.15 177492.109 14761.985 3500.327 1 718.75 655.77 39 2013OCT21_A_Arboretum1_2 6.15 174121.016 14935.038 3137.495 1 705.10 643.32 40 2013OCT21_A_Arboretum1_3 6.15 172704.125 14655.689 3371.425 1 699.36 638.08 41 2013OCT21_A_SolvA_11 1.151 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 6.14 177398.109 14619.271 3372.948 1 718.37 655.43 44 2013OCT21_A_Arboretum2_2 6.15 173378.563 13842.564 3114.131 1 702.09 640.58 45 2013OCT21_A_Arboretum2_3 6.14 175147.469 14690.09 3293.505 1 709.25 647.11 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 6.15 77882.414 6843.69 1354.657 1 315.38 287.75 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 0.011 25.306 #DIV/0! 51 2013OCT21_A_NorthDr1_1 6.15 1530.256 46.861 0 6.20 5.65 52 2013OCT21_A_NorthDr1_2 6.15 1262.442 26.881 66.216 1 5.11 4.66 53 2013OCT21_A_NorthDr1_3 6.14 1680.395 166.588 136.296 1 6.80 6.21 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 6.14 1853.222 123.001 12.976 1 7.50 6.85 57 2013OCT21_A_NorthDr2_2 6.13 2186.024 147.86 0 8.85 8.08 58 2013OCT21_A_NorthDr2_3 6.15 1886.192 77.418 0 7.64 6.97 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 27.735 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 6.15 111130.141 9232.975 1573.201 1 450.02 410.59 62 2013OCT21_A_AnacostiaPk_2 6.15 104373.398 9119.897 2231.113 1 422.66 385.62 63 2013OCT21_A_AnacostiaPk_3 6.14 106496.953 8684.026 2660.04 1 431.26 393.47 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 6.16 87821.102 7244.079 1122.787 1 355.63 324.47 67 2013OCT21_A_GreenbeltPk_2 6.16 85958.906 6892.089 1454.692 1 348.09 317.59 68 2013OCT21_A_GreenbeltPk_3 6.17 86983.969 7734.839 1617.165 1 352.24 321.38 239 69 2013OCT21_A_SolvA_23 0.015 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 6.18 13721.16 1092.472 2.716 1 55.56 50.70 72 2013OCT21_A_PowderMillRd_2 6.17 13196.448 1103.89 269.736 1 53.44 48.76 73 2013OCT21_A_PowderMillRd_3 6.17 14553.685 866.272 0 58.93 53.77 74 2013OCT21_A_SolvA_25 0.824 #DIV/0! 75 2013OCT21_A_SolvA_26 0.242 49.304 #DIV/0! 76 2013OCT21_A_QC_Std25_2 6.17 76527.789 6963.28 1262.203 1 309.90 282.74 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 6.17 28392.713 2024.617 460.778 1 114.98 104.90 80 2013OCT21_A_ResearchRd_2 6.16 28208.953 2457.065 390.218 1 114.23 104.22 81 2013OCT21_A_ResearchRd_3 6.15 28040.559 2144.949 287.054 1 113.55 103.60 82 2013OCT21_A_SolvA_29 5.095 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 6.16 44807.988 3947.847 781.783 1 181.45 165.55 85 2013OCT21_A_Skateboard_2 6.15 44585.051 4239 1095.852 1 180.55 164.73 86 2013OCT21_A_Skateboard_3 6.15 41968.23 3566.041 50.432 1 169.95 155.06 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 #DIV/0! 89 2013OCT21_A_SligoCreek_1 6.16 6368.31 226.077 0 25.79 23.53 90 2013OCT21_A_SligoCreek_2 6.16 5309.688 372.65 30.19 1 21.50 19.62 91 2013OCT21_A_SligoCreek_3 6.16 5285.29 321.844 0 21.40 19.53 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 0.466 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 6.15 14868.549 1223.894 0 60.21 54.93 95 2013OCT21_A_RiverdaleRd_2 6.16 12425.471 736.481 0 50.32 45.91 96 2013OCT21_A_RiverdaleRd_3 6.17 12489.717 939.497 223.692 1 50.58 46.15 97 2013OCT21_A_SolvA_35 0.63 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 64.076 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 0.638 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 2.528 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 6.16 1953.588 74.196 0 104 2013OCT21_A_1_Std_2 1 6.17 3580.597 #DIV/0! 105 2013OCT21_A_5_Std_2 5 6.16 15224.285 918.311 161.188 1 106 2013OCT21_A_10_Std_2 10 6.16 28807.563 2619.322 476.923 1 107 2013OCT21_A_25_Std_2 25 6.17 75373.93 5917.396 1348.376 1 108 2013OCT21_A_50_Std_2 50 6.17 141685.438 12764.992 2388.157 1 109 2013OCT21_A_100_Std_2 100 6.19 260922 24542.576 4941.317 1 110 2013OCT21_A_200_Stds_2 200 6.19 486729.188 42914.016 10050.792 1 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 6.17 71.277 2.813 #DIV/0! 113 2013OCT21_A_SolvA_39 6.07 0.745 3.581 34.743 0 114 2013OCT21_A_SolvA_40 #DIV/0! 240 115 2013OCT21_A_SolvA_41 6.12 192.163 0.565 74.807 0 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 20: 13C-2.4-D yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT21_SolvA_1 #DIV/0! 2 2013OCT21_A_Lab Blk 6.16 382715.313 #DIV/0! 360838 Avg 3 2013OCT21_A_Travel Blk 6.15 370849.781 #DIV/0! 7% RSD 4 2013OCT21_A_0-01_Std 0.01 6.14 354726.781 #DIV/0! 5 2013OCT21_A_0-05_Std 0.05 6.13 371578.031 #DIV/0! 6 2013OCT21_A_0-1_Std 0.1 6.14 408098.875 #DIV/0! 7 2013OCT21_A_0-5_Std 0.5 6.16 382689.406 #DIV/0! 8 2013OCT21_A_1_Std 1 6.16 398757.563 #DIV/0! 9 2013OCT21_A_5_Std 5 6.15 383754.5 #DIV/0! 10 2013OCT21_A_10_Std 10 6.14 363551.188 #DIV/0! 11 2013OCT21_A_25_Std 25 6.14 368100.125 #DIV/0! 12 2013OCT21_A_50_Std 50 6.14 377152.813 #DIV/0! 13 2013OCT21_A_100_Std 100 6.15 339059.781 #DIV/0! 14 2013OCT21_A_200_Stds 200 6.16 337193.563 #DIV/0! 15 2013OCT21_A_SolvA_2 #DIV/0! 16 2013OCT21_A_Surrogate_1 #DIV/0! 17 2013OCT21_A_SolvA_3 #DIV/0! 18 2013OCT21_A_SolvA_4 #DIV/0! 19 2013OCT21_A_MM_0 6.14 356945.969 #DIV/0! 20 2013OCT21_A_MM_1 6.14 398611.594 #DIV/0! 21 2013OCT21_A_MM_5 6.16 400209.313 #DIV/0! 22 2013OCT21_A_MM_10 6.16 374275.344 #DIV/0! 23 2013OCT21_A_MM_25 6.16 319852.469 #DIV/0! 24 2013OCT21_A_MM_50 6.15 323199 #DIV/0! 25 2013OCT21_A_MM_100 6.14 397141.156 #DIV/0! 26 2013OCT21_A_SolvA_5 #DIV/0! 27 2013OCT21_A_SolvA_6 #DIV/0! 28 2013OCT21_A_BerwynRd_1 6.16 390083.563 #DIV/0! 29 2013OCT21_A_BerwynRd_2 6.15 379924.406 #DIV/0! 30 2013OCT21_A_BerwynRd_3 6.15 383410.531 #DIV/0! 31 2013OCT21_A_SolvA_7 #DIV/0! 32 2013OCT21_A_SolvA_8 #DIV/0! 33 2013OCT21_A_UMD_1 6.15 366313.313 #DIV/0! 34 2013OCT21_A_UMD_2 6.15 363592.656 #DIV/0! 35 2013OCT21_A_UMD_3 6.15 363453.938 #DIV/0! 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 6.15 361398.938 #DIV/0! 39 2013OCT21_A_Arboretum1_2 6.15 361720.688 #DIV/0! 40 2013OCT21_A_Arboretum1_3 6.14 357376.344 #DIV/0! 41 2013OCT21_A_SolvA_11 #DIV/0! 241 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 6.14 368202.438 #DIV/0! 44 2013OCT21_A_Arboretum2_2 6.14 357343.031 #DIV/0! 45 2013OCT21_A_Arboretum2_3 6.14 364070.063 #DIV/0! 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 #DIV/0! 48 2013OCT21_A_QC_Std25_1 6.15 387903.406 #DIV/0! 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 #DIV/0! 51 2013OCT21_A_NorthDr1_1 6.14 378250.625 #DIV/0! 52 2013OCT21_A_NorthDr1_2 6.15 360904.063 #DIV/0! 53 2013OCT21_A_NorthDr1_3 6.14 367232.656 #DIV/0! 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 #DIV/0! 56 2013OCT21_A_NorthDr2_1 6.15 360497.469 #DIV/0! 57 2013OCT21_A_NorthDr2_2 6.15 368130.25 #DIV/0! 58 2013OCT21_A_NorthDr2_3 6.15 356447.344 #DIV/0! 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 6.14 342995.375 #DIV/0! 62 2013OCT21_A_AnacostiaPk_2 6.14 330414.25 #DIV/0! 63 2013OCT21_A_AnacostiaPk_3 6.14 315018.875 #DIV/0! 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 6.15 326458.094 #DIV/0! 67 2013OCT21_A_GreenbeltPk_2 6.16 318395.344 #DIV/0! 68 2013OCT21_A_GreenbeltPk_3 6.16 316920.344 #DIV/0! 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 6.18 337198.844 #DIV/0! 72 2013OCT21_A_PowderMillRd_2 6.17 323516.75 #DIV/0! 73 2013OCT21_A_PowderMillRd_3 6.17 324221.813 #DIV/0! 74 2013OCT21_A_SolvA_25 #DIV/0! 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 6.17 382661.281 #DIV/0! 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 6.17 383461.438 #DIV/0! 80 2013OCT21_A_ResearchRd_2 6.16 376073.031 #DIV/0! 81 2013OCT21_A_ResearchRd_3 6.16 366148.344 #DIV/0! 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 6.16 348735.375 #DIV/0! 85 2013OCT21_A_Skateboard_2 6.16 335907.781 #DIV/0! 86 2013OCT21_A_Skateboard_3 6.16 333995.219 #DIV/0! 242 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 #DIV/0! 89 2013OCT21_A_SligoCreek_1 6.16 363456.375 #DIV/0! 90 2013OCT21_A_SligoCreek_2 6.15 348261.375 #DIV/0! 91 2013OCT21_A_SligoCreek_3 6.16 351999.563 #DIV/0! 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 6.15 443826.688 #DIV/0! 95 2013OCT21_A_RiverdaleRd_2 6.16 374579.125 #DIV/0! 96 2013OCT21_A_RiverdaleRd_3 6.16 372451.656 #DIV/0! 97 2013OCT21_A_SolvA_35 #DIV/0! 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 6.16 364059.375 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 6.16 345307.625 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 6.16 383629.719 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 6.16 367007.875 #DIV/0! 104 2013OCT21_A_1_Std_2 1 6.16 367254.344 #DIV/0! 105 2013OCT21_A_5_Std_2 5 6.16 363593.031 #DIV/0! 106 2013OCT21_A_10_Std_2 10 6.16 354663.031 #DIV/0! 107 2013OCT21_A_25_Std_2 25 6.17 350223.906 #DIV/0! 108 2013OCT21_A_50_Std_2 50 6.17 361617.875 #DIV/0! 109 2013OCT21_A_100_Std_2 100 6.18 322960.813 #DIV/0! 110 2013OCT21_A_200_Stds_2 200 6.19 322970.406 #DIV/0! 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 22: AlachlorESA yes=1,no=0 Conc. (ng/g) m/z 80 m/z 160 m/z 121 Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0 #DIV/0! 2 2013OCT21_A_Lab Blk 32.855 33.365 0 #DIV/0! 3 2013OCT21_A_Travel Blk 0 #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 606.406 389.991 0 0.2 -85% 6 2013OCT21_A_0-1_Std 0.1 5.04 861.211 90.59 734.292 1 0.2 -89% 7 2013OCT21_A_0-5_Std 0.5 5.03 4498.74 528.657 3153.459 1 1.1 12% 8 2013OCT21_A_1_Std 1 5.01 9241.874 781.171 6313.713 1 2.3 15% 9 2013OCT21_A_5_Std 5 5.02 45790.844 4575.625 33375.082 1 11.4 14% 10 2013OCT21_A_10_Std 10 5.03 91897.82 9226.567 63404.02 1 22.9 15% 11 2013OCT21_A_25_Std 25 5.02 229839.266 24640.066 160121.953 1 57.3 15% 12 2013OCT21_A_50_Std 50 5.01 425136.313 45610.77 302919.281 1 106.0 6% 13 2013OCT21_A_100_Std 100 5.02 841220.625 90463.219 590574.438 1 209.7 5% 243 14 2013OCT21_A_200_Stds 200 5.03 1622888.625 177486.609 1157711.375 1 404.6 1% 15 2013OCT21_A_SolvA_2 #DIV/0! 0.0 -100% 16 2013OCT21_A_Surrogate_1 4.99 29.235 20.884 #DIV/0! 0.0 -96% 17 2013OCT21_A_SolvA_3 4.98 12.924 0.295 #DIV/0! 0.0 -100% 18 2013OCT21_A_SolvA_4 4.96 5.1 1.327 #DIV/0! 1.2 22% 19 2013OCT21_A_MM_0 5.01 34997.957 4403.819 23583.91 1 2.2 9% 20 2013OCT21_A_MM_1 5.01 48914.18 6320.543 33603.559 1 11.8 18% 21 2013OCT21_A_MM_5 5.02 90485.422 10833.327 62535.535 1 22.6 13% 22 2013OCT21_A_MM_10 5.03 133512.359 14871.476 89490.484 1 56.7 13% 23 2013OCT21_A_MM_25 5.02 243330.641 26845.494 169615.266 1 106.1 6% 24 2013OCT21_A_MM_50 5.02 428502.594 46549.023 299918.344 1 203.0 1% 25 2013OCT21_A_MM_100 5.02 950094.125 105548.047 664578.25 1 383.9 -4% 26 2013OCT21_A_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT21_A_SolvA_6 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 5.03 60125.414 8251.422 39540.152 1 149.91 135.42 29 2013OCT21_A_BerwynRd_2 5.03 58807.84 8517.948 40309.512 1 146.63 132.45 30 2013OCT21_A_BerwynRd_3 5.03 58869.25 8129.633 39731.574 1 146.78 132.59 31 2013OCT21_A_SolvA_7 4.95 8.839 0.196 24.166 1 32 2013OCT21_A_SolvA_8 4.97 0.356 21.625 #DIV/0! 33 2013OCT21_A_UMD_1 5.03 25427.695 3465.324 16975.199 1 63.40 57.27 34 2013OCT21_A_UMD_2 5.02 26061.207 3752.357 17653.395 1 64.98 58.70 35 2013OCT21_A_UMD_3 5.04 25554.535 3709.785 17401.029 1 63.72 57.55 36 2013OCT21_A_SolvA_9 5.02 6.262 #DIV/0! 37 2013OCT21_A_SolvA_10 4.96 13.374 7.414 #DIV/0! 38 2013OCT21_A_Arboretum1_1 5.03 22185.438 3044.818 15150.078 1 55.32 49.97 39 2013OCT21_A_Arboretum1_2 5.03 22874.76 2991.101 14472.168 1 57.04 51.52 40 2013OCT21_A_Arboretum1_3 5.02 22443.668 2910.394 15248.77 1 55.96 50.55 41 2013OCT21_A_SolvA_11 5.03 43.461 1.525 #DIV/0! 42 2013OCT21_A_SolvA_12 #DIV/0! 43 2013OCT21_A_Arboretum2_1 5.01 22487.689 3018.52 15486.753 1 56.07 50.65 44 2013OCT21_A_Arboretum2_2 5.03 22346.164 2865.602 15572.642 1 55.72 50.33 45 2013OCT21_A_Arboretum2_3 5.02 21932.854 2905.839 15321.29 1 54.69 49.40 46 2013OCT21_A_SolvA_13 4.99 12.453 0.423 #DIV/0! 47 2013OCT21_A_SolvA_14 5.04 38.582 0.586 #DIV/0! 48 2013OCT21_A_QC_Std25_1 5.03 234791.656 24798.967 164319.734 1 585.42 528.81 49 2013OCT21_A_SolvA_15 4.97 0.356 12.342 #DIV/0! 50 2013OCT21_A_SolvA_16 5.02 42.453 5.956 28.314 1 51 2013OCT21_A_NorthDr1_1 5.02 49088.949 6541.271 33614.426 1 122.40 110.56 52 2013OCT21_A_NorthDr1_2 5.03 49984.063 6655.724 32810.313 1 124.63 112.58 53 2013OCT21_A_NorthDr1_3 5.03 49020.836 7112.074 33572.719 1 122.23 110.41 54 2013OCT21_A_SolvA_17 5.09 14.68 16.732 33.821 0 55 2013OCT21_A_SolvA_18 5.06 8.522 9.94 #DIV/0! 56 2013OCT21_A_NorthDr2_1 5.03 49527.266 6875.637 33554.648 1 123.49 111.55 57 2013OCT21_A_NorthDr2_2 5.03 50679.02 6724.444 33166.926 1 126.36 114.14 58 2013OCT21_A_NorthDr2_3 5.02 50885.68 6495.115 33072.504 1 126.88 114.61 59 2013OCT21_A_SolvA_19 4.99 9.734 0.015 #DIV/0! 244 60 2013OCT21_A_SolvA_20 5.03 0.005 20.319 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 5.01 20621.117 2674.59 13686.908 1 51.42 46.44 62 2013OCT21_A_AnacostiaPk_2 5.01 20177.916 2939.62 13923.216 1 50.31 45.45 63 2013OCT21_A_AnacostiaPk_3 5.02 20431.947 3044.718 13193.445 1 50.94 46.02 64 2013OCT21_A_SolvA_21 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 5.05 6873.174 1065.166 4863.652 1 17.14 15.48 67 2013OCT21_A_GreenbeltPk_2 5.05 6980.878 1021.76 4547.331 1 17.41 15.72 68 2013OCT21_A_GreenbeltPk_3 5.05 6821.861 1032.974 4652.19 1 17.01 15.36 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 4.98 8.57 1.004 3.86 1 71 2013OCT21_A_PowderMillRd_1 5.05 71782.617 9928.019 47645.566 1 178.98 161.67 72 2013OCT21_A_PowderMillRd_2 5.05 72254.508 10369.083 47275.18 1 180.16 162.73 73 2013OCT21_A_PowderMillRd_3 5.05 71817.828 10324.527 48729.281 1 179.07 161.75 74 2013OCT21_A_SolvA_25 5 0.368 5.451 #DIV/0! 75 2013OCT21_A_SolvA_26 5.04 11.748 14.213 #DIV/0! 76 2013OCT21_A_QC_Std25_2 5.05 231156.688 24165.734 160441.031 1 576.36 520.62 77 2013OCT21_A_SolvA_27 #DIV/0! 78 2013OCT21_A_SolvA_28 #DIV/0! 79 2013OCT21_A_ResearchRd_1 5.05 53552.492 6865.009 36451.137 1 133.53 120.61 80 2013OCT21_A_ResearchRd_2 5.05 54113.301 6848.076 36153.969 1 134.92 121.88 81 2013OCT21_A_ResearchRd_3 5.03 53570.848 6459.331 36963.699 1 133.57 120.65 82 2013OCT21_A_SolvA_29 4.92 27.028 0.379 24.421 1 83 2013OCT21_A_SolvA_30 4.94 14.81 3.555 15.734 1 84 2013OCT21_A_Skateboard_1 5.04 14678.15 2244.802 10474.064 1 36.60 33.06 85 2013OCT21_A_Skateboard_2 5.03 15605.485 2259.206 10198.002 1 38.91 35.15 86 2013OCT21_A_Skateboard_3 5.03 15400.594 2203.426 10383.521 1 38.40 34.69 87 2013OCT21_A_SolvA_31 5.04 24.351 9.303 11.927 0 88 2013OCT21_A_SolvA_32 5.07 18.949 16.89 #DIV/0! 89 2013OCT21_A_SligoCreek_1 5.05 5918.142 705.983 3686.567 1 14.76 13.33 90 2013OCT21_A_SligoCreek_2 5.03 5584.608 798.586 3891.45 1 13.92 12.58 91 2013OCT21_A_SligoCreek_3 5.03 5509.838 870.817 3983.4 1 13.74 12.41 92 2013OCT21_A_SolvA_33 4.95 4.545 22.229 #DIV/0! 93 2013OCT21_A_SolvA_34 5.02 28.584 0.904 5.433 1 94 2013OCT21_A_RiverdaleRd_1 5.03 42670.797 6394.938 29451.287 1 106.39 96.10 95 2013OCT21_A_RiverdaleRd_2 5.05 42048.777 5635.708 28067.092 1 104.84 94.70 96 2013OCT21_A_RiverdaleRd_3 5.05 41741 5729.88 27219.998 1 104.08 94.01 97 2013OCT21_A_SolvA_35 5.05 1.844 #DIV/0! 98 2013OCT21_A_SolvA_36 4.94 8.47 0.618 #DIV/0! 99 2013OCT21_A_SolvA_37 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 159.466 366.131 0 102 2013OCT21_A_0-1_Std_2 0.1 5.09 897.999 193.122 747.653 1 103 2013OCT21_A_0-5_Std_2 0.5 4908.102 2804.437 0 104 2013OCT21_A_1_Std_2 1 5.07 8747.435 1136.925 6401.111 1 105 2013OCT21_A_5_Std_2 5 5.06 47202.641 4688.594 31948.66 1 245 106 2013OCT21_A_10_Std_2 10 5.06 90540.742 9188.837 62707.703 1 107 2013OCT21_A_25_Std_2 25 5.07 227450.609 23858.674 157440.516 1 108 2013OCT21_A_50_Std_2 50 5.07 425392.75 44113.418 299931.594 1 109 2013OCT21_A_100_Std_2 100 5.07 814123.438 87590.836 576720.938 1 110 2013OCT21_A_200_Stds_2 200 5.07 1539615.375 168095.906 1092467.125 1 111 2013OCT21_A_SolvA_38 5.02 33.317 61.343 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 5.03 26.012 9.573 #DIV/0! 114 2013OCT21_A_SolvA_40 4.97 28.883 1.36 #DIV/0! 115 2013OCT21_A_SolvA_41 4.92 27.106 0.001 #DIV/0! 116 2013OCT21_A_SolvA_42 4.99 32.764 2.554 #VALUE! Compound 24: Metolachlor ESA yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area 0 1 2013OCT21_SolvA_1 0 #DIV/0! 2 2013OCT21_A_Lab Blk 5.29 221.634 0 #DIV/0! 3 2013OCT21_A_Travel Blk 111.086 2.164 0 #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 104.886 19.504 0 0.0 -100% 5 2013OCT21_A_0-05_Std 0.05 5.29 524.254 181.108 0 0.1 95% 6 2013OCT21_A_0-1_Std 0.1 5.29 491.987 390.165 114.933 1 0.1 -8% 7 2013OCT21_A_0-5_Std 0.5 5.32 2507.533 2184.624 145.975 1 0.5 -7% 8 2013OCT21_A_1_Std 1 5.31 6347.45 3804.438 760.118 1 1.2 18% 9 2013OCT21_A_5_Std 5 5.31 30936.357 19495.93 2592.682 1 5.8 15% 10 2013OCT21_A_10_Std 10 5.3 64759.605 42920.832 6236.498 1 12.0 20% 11 2013OCT21_A_25_Std 25 5.3 146828.547 101620.063 16044.433 1 27.3 9% 12 2013OCT21_A_50_Std 50 5.3 294278.719 189540.313 33784.277 1 54.8 10% 13 2013OCT21_A_100_Std 100 5.3 578197.688 377627.594 60131.164 1 107.6 8% 14 2013OCT21_A_200_Stds 200 5.31 1145698.625 715551.125 120315.266 1 213.2 7% 15 2013OCT21_A_SolvA_2 2.881 #DIV/0! 0.0 42% 16 2013OCT21_A_Surrogate_1 0 0.1 64% 17 2013OCT21_A_SolvA_3 1.421 #DIV/0! 0.1 40% 18 2013OCT21_A_SolvA_4 5.29 63.966 9.413 0 0.6 27% 19 2013OCT21_A_MM_0 5.3 158479.906 104635.289 17166.953 1 0.9 -14% 20 2013OCT21_A_MM_1 5.29 188883.469 125383.953 20317.928 1 5.1 2% 21 2013OCT21_A_MM_5 5.3 217584.422 142021.031 23116.691 1 10.2 2% 22 2013OCT21_A_MM_10 5.3 229735.344 155914.25 22348.729 1 25.5 2% 23 2013OCT21_A_MM_25 5.3 293189.625 189825.063 27913.965 1 49.6 -1% 24 2013OCT21_A_MM_50 5.3 437599.219 275868.094 43487.086 1 93.5 -6% 25 2013OCT21_A_MM_100 5.29 838012.625 543428.313 88765.719 1 184.7 -8% 26 2013OCT21_A_SolvA_5 5.34 30.069 6.202 0.079 0 Forced (0,0) MM 27 2013OCT21_A_SolvA_6 5.23 68.578 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 5.3 291795.406 186762.438 28941.803 1 542.92 447.96 29 2013OCT21_A_BerwynRd_2 5.3 285345.594 186003.703 31741.631 1 530.92 438.06 30 2013OCT21_A_BerwynRd_3 5.3 282066.781 185463.094 30654.799 1 524.82 433.02 31 2013OCT21_A_SolvA_7 5.32 49.123 19.48 11.602 0 32 2013OCT21_A_SolvA_8 5.27 84.772 24.908 0 246 33 2013OCT21_A_UMD_1 5.31 112213.531 73458.305 10445.797 1 208.79 172.27 34 2013OCT21_A_UMD_2 5.31 115791.742 75934.195 13208.129 1 215.44 177.76 35 2013OCT21_A_UMD_3 5.31 117129.664 74934.492 11981.318 1 217.93 179.82 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 5.3 87273.289 53879.75 9099.18 1 162.38 133.98 39 2013OCT21_A_Arboretum1_2 5.3 84375.656 53675.629 8857.227 1 156.99 129.53 40 2013OCT21_A_Arboretum1_3 5.3 84758.227 58705.625 9413.541 1 157.70 130.12 41 2013OCT21_A_SolvA_11 5.27 54.919 60.737 0.782 1 42 2013OCT21_A_SolvA_12 5.26 10.035 2.127 #DIV/0! 43 2013OCT21_A_Arboretum2_1 5.3 86505.227 54322.637 8484.381 1 160.95 132.80 44 2013OCT21_A_Arboretum2_2 5.3 85708.484 51871.57 9687.895 1 159.47 131.58 45 2013OCT21_A_Arboretum2_3 5.3 84132.43 60099.203 8279.54 1 156.54 129.16 46 2013OCT21_A_SolvA_13 5.29 38.081 12.881 0 47 2013OCT21_A_SolvA_14 5.3 36.397 1.369 4.794 0 48 2013OCT21_A_QC_Std25_1 5.31 159442.109 105953.555 15104.621 1 296.66 244.77 49 2013OCT21_A_SolvA_15 5.26 1.09 1.033 0 50 2013OCT21_A_SolvA_16 5.29 26.08 2.955 0 51 2013OCT21_A_NorthDr1_1 5.31 164182.219 108175.063 19389.576 1 305.48 252.05 52 2013OCT21_A_NorthDr1_2 5.31 162893.641 110212.398 16613.234 1 303.08 250.07 53 2013OCT21_A_NorthDr1_3 5.31 162754.719 106205.547 17596.777 1 302.82 249.86 54 2013OCT21_A_SolvA_17 5.31 5.604 20.809 3.302 0 55 2013OCT21_A_SolvA_18 5.19 15.159 0.226 1.088 0 56 2013OCT21_A_NorthDr2_1 5.31 162303.109 108874.063 16875.051 1 301.98 249.16 57 2013OCT21_A_NorthDr2_2 5.31 167142.156 109741.883 18038.727 1 310.99 256.59 58 2013OCT21_A_NorthDr2_3 5.31 159364.297 108803.203 17907.496 1 296.51 244.65 59 2013OCT21_A_SolvA_19 5.29 25.836 26.823 0.682 1 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 5.3 63506.031 39857.84 6399.558 1 118.16 97.49 62 2013OCT21_A_AnacostiaPk_2 5.3 60808.48 35432.734 6492.863 1 113.14 93.35 63 2013OCT21_A_AnacostiaPk_3 5.3 58339.523 38747.816 6545.181 1 108.55 89.56 64 2013OCT21_A_SolvA_21 5.31 59.603 0.674 0 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 5.31 19019.229 14272.813 2306.141 1 35.39 29.20 67 2013OCT21_A_GreenbeltPk_2 5.32 22076.408 11834.313 2019.308 1 41.08 33.89 68 2013OCT21_A_GreenbeltPk_3 5.32 19389.963 12379.188 2017.657 1 36.08 29.77 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 5.28 0.229 1.149 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 5.33 118355.914 78668 13117.253 1 220.21 181.70 72 2013OCT21_A_PowderMillRd_2 5.33 110639.438 79043.18 11461.432 1 205.86 169.85 73 2013OCT21_A_PowderMillRd_3 5.33 114623.578 73760.055 11742.698 1 213.27 175.97 74 2013OCT21_A_SolvA_25 5.32 131.369 0.227 1.128 0 75 2013OCT21_A_SolvA_26 #DIV/0! 76 2013OCT21_A_QC_Std25_2 5.34 143985.531 98922.406 16580.457 1 267.90 221.04 77 2013OCT21_A_SolvA_27 5.26 8.659 3.643 #DIV/0! 247 78 2013OCT21_A_SolvA_28 5.22 46.796 4.16 17.797 0 79 2013OCT21_A_ResearchRd_1 5.33 645726.688 410908.844 68077.031 1 1201.45 991.31 80 2013OCT21_A_ResearchRd_2 5.32 633871.25 415234.469 65886.578 1 1179.39 973.11 81 2013OCT21_A_ResearchRd_3 5.32 636556.125 434257.969 70472.414 1 1184.38 977.23 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 5.32 48075.367 30633.402 5024.492 1 89.45 73.80 85 2013OCT21_A_Skateboard_2 5.32 46815.328 29241.559 5091.922 1 87.11 71.87 86 2013OCT21_A_Skateboard_3 5.32 42400.742 33487.094 4490.286 1 78.89 65.09 87 2013OCT21_A_SolvA_31 5.31 83.673 #DIV/0! 88 2013OCT21_A_SolvA_32 5.28 22.036 2.645 0 89 2013OCT21_A_SligoCreek_1 5.32 37852.719 27852.703 3282.973 1 70.43 58.11 90 2013OCT21_A_SligoCreek_2 5.32 41185.867 27138.549 4584.904 1 76.63 63.23 91 2013OCT21_A_SligoCreek_3 5.32 39467.785 26341.238 4547.979 1 73.43 60.59 92 2013OCT21_A_SolvA_33 5.23 14.199 15.955 0.043 1 93 2013OCT21_A_SolvA_34 5.19 2.141 0.804 1.087 0 94 2013OCT21_A_RiverdaleRd_1 5.32 187669.531 134335.5 18156.773 1 349.18 288.11 95 2013OCT21_A_RiverdaleRd_2 5.33 182930.938 123831.141 17782.074 1 340.36 280.83 96 2013OCT21_A_RiverdaleRd_3 5.33 179481.016 118237.125 19579.1 1 333.94 275.54 97 2013OCT21_A_SolvA_35 5.25 87.004 8.953 18.422 0 98 2013OCT21_A_SolvA_36 #DIV/0! 99 2013OCT21_A_SolvA_37 5.18 0.748 1.159 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 5.34 76.29 13.331 11.976 0 101 2013OCT21_A_0-05_Std_2 0.05 5.36 440.516 367.746 26.417 1 102 2013OCT21_A_0-1_Std_2 0.1 5.34 753.522 21.895 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 5.34 3409.227 1765.279 112.75 1 104 2013OCT21_A_1_Std_2 1 5.36 4618.839 4686.167 502.314 1 105 2013OCT21_A_5_Std_2 5 5.34 27541.877 21053.164 3279.418 1 106 2013OCT21_A_10_Std_2 10 5.34 54649.02 41319.813 6449.487 1 107 2013OCT21_A_25_Std_2 25 5.36 136924.781 97696.094 16202.482 1 108 2013OCT21_A_50_Std_2 50 5.34 266460.438 178540.75 28708.863 1 109 2013OCT21_A_100_Std_2 100 5.36 502777.813 332879.719 54976.484 1 110 2013OCT21_A_200_Stds_2 200 5.37 992688.313 659593.188 103200.539 1 111 2013OCT21_A_SolvA_38 5.36 20.462 44.283 0 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 5.29 0.446 0.673 0.44 0 114 2013OCT21_A_SolvA_40 5.31 2.924 1.128 13.947 0 115 2013OCT21_A_SolvA_41 5.23 8.311 2.099 0 116 2013OCT21_A_SolvA_42 #DIV/0! Compound 25: Sucralose yes=1,no=0 Conc. (ng/g) Ident'd? Calc'd %diff Name Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT21_SolvA_1 #DIV/0! #DIV/0! 2 2013OCT21_A_Lab Blk #DIV/0! #DIV/0! 3 2013OCT21_A_Travel Blk 2.19 0.274 #DIV/0! #DIV/0! 4 2013OCT21_A_0-01_Std 0.01 #DIV/0! 0.0 -100% 248 5 2013OCT21_A_0-05_Std 0.05 #DIV/0! 0.0 -100% 6 2013OCT21_A_0-1_Std 0.1 #DIV/0! 0.0 -100% 7 2013OCT21_A_0-5_Std 0.5 2.22 15.95 422.772 #DIV/0! 0.6 10% 8 2013OCT21_A_1_Std 1 2.21 11.226 201.481 #DIV/0! 0.4 -61% 9 2013OCT21_A_5_Std 5 2.24 94.771 328.033 #DIV/0! 3.3 -35% 10 2013OCT21_A_10_Std 10 2.23 366.102 #DIV/0! 12.6 26% 11 2013OCT21_A_25_Std 25 2.24 519.818 283.939 #DIV/0! 17.9 -28% 12 2013OCT21_A_50_Std 50 2.24 1272.53 139.509 #DIV/0! 43.9 -12% 13 2013OCT21_A_100_Std 100 2.24 3671.12 315.258 #DIV/0! 126.6 27% 14 2013OCT21_A_200_Stds 200 2.24 5479.765 597.563 #DIV/0! 189.0 -5% 15 2013OCT21_A_SolvA_2 2.27 5.879 #DIV/0! 0.0 280% 16 2013OCT21_A_Surrogate_1 #DIV/0! 0.0 -100% 17 2013OCT21_A_SolvA_3 2.29 20.079 0.095 #DIV/0! 0.0 -100% 18 2013OCT21_A_SolvA_4 2.32 2.351 0.416 #DIV/0! 0.0 -100% 19 2013OCT21_A_MM_0 2.24 390.859 678.423 #DIV/0! 0.0 -100% 20 2013OCT21_A_MM_1 2.24 784.011 1076.443 #DIV/0! 0.8 -85% 21 2013OCT21_A_MM_5 2.24 805.815 #DIV/0! 2.5 -75% 22 2013OCT21_A_MM_10 2.24 557.371 #DIV/0! 8.1 -67% 23 2013OCT21_A_MM_25 2.24 1005.389 583.248 #DIV/0! 37.4 -25% 24 2013OCT21_A_MM_50 2.24 1598.956 367.037 #DIV/0! 64.8 -35% 25 2013OCT21_A_MM_100 2.24 3721.924 448.408 #DIV/0! 125.3 -37% 26 2013OCT21_A_SolvA_5 #DIV/0! Forced (0,0) MM 27 2013OCT21_A_SolvA_6 2.33 0.548 0.814 #DIV/0! (ng/L in sample) 28 2013OCT21_A_BerwynRd_1 2.24 566.021 452.594 #DIV/0! 195.24 181.60 29 2013OCT21_A_BerwynRd_2 2.24 1049.348 334.853 #DIV/0! 361.95 336.67 30 2013OCT21_A_BerwynRd_3 2.24 758.957 #DIV/0! 261.78 243.50 31 2013OCT21_A_SolvA_7 2.17 26.602 1.245 #DIV/0! 32 2013OCT21_A_SolvA_8 2.26 4.781 #DIV/0! 33 2013OCT21_A_UMD_1 2.24 505.874 359.187 #DIV/0! 174.49 162.31 34 2013OCT21_A_UMD_2 2.24 248.882 360.611 #DIV/0! 85.85 79.85 35 2013OCT21_A_UMD_3 2.24 314.027 176.124 #DIV/0! 108.32 100.75 36 2013OCT21_A_SolvA_9 2.29 12.288 0.949 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 2.24 734.16 403.289 #DIV/0! 253.23 235.55 39 2013OCT21_A_Arboretum1_2 2.23 645.705 188.927 #DIV/0! 222.72 207.17 40 2013OCT21_A_Arboretum1_3 2.26 580.13 316.12 #DIV/0! 200.10 186.13 41 2013OCT21_A_SolvA_11 2.26 48.311 0.743 #DIV/0! 42 2013OCT21_A_SolvA_12 2.26 0.037 0.279 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.23 597.774 194.398 #DIV/0! 206.19 191.79 44 2013OCT21_A_Arboretum2_2 2.24 986.506 252.941 #DIV/0! 340.27 316.51 45 2013OCT21_A_Arboretum2_3 2.24 565.338 218.425 #DIV/0! 195.00 181.38 46 2013OCT21_A_SolvA_13 2.24 63.118 0.786 #DIV/0! 47 2013OCT21_A_SolvA_14 2.31 13.503 #DIV/0! 48 2013OCT21_A_QC_Std25_1 2.25 442.625 150.308 #DIV/0! 152.67 142.01 49 2013OCT21_A_SolvA_15 2.22 29.822 0.968 #DIV/0! 50 2013OCT21_A_SolvA_16 2.23 3.099 0.135 #DIV/0! 249 51 2013OCT21_A_NorthDr1_1 2.24 91.596 212.148 #DIV/0! 31.59 29.39 52 2013OCT21_A_NorthDr1_2 2.24 145.54 287.949 #DIV/0! 50.20 46.70 53 2013OCT21_A_NorthDr1_3 2.24 53.824 167.427 #DIV/0! 18.57 17.27 54 2013OCT21_A_SolvA_17 2.29 89.622 0.408 #DIV/0! 55 2013OCT21_A_SolvA_18 2.16 10.083 #DIV/0! 56 2013OCT21_A_NorthDr2_1 2.22 146.879 #DIV/0! 50.66 47.12 57 2013OCT21_A_NorthDr2_2 2.23 594.214 #DIV/0! 204.96 190.65 58 2013OCT21_A_NorthDr2_3 2.24 489.963 163.742 #DIV/0! 169.00 157.20 59 2013OCT21_A_SolvA_19 2.33 5.022 #DIV/0! 60 2013OCT21_A_SolvA_20 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.23 446.461 285.396 #DIV/0! 154.00 143.24 62 2013OCT21_A_AnacostiaPk_2 2.24 970.46 573.056 #DIV/0! 334.74 311.36 63 2013OCT21_A_AnacostiaPk_3 2.22 610.108 355.963 #DIV/0! 210.44 195.75 64 2013OCT21_A_SolvA_21 2.2 0.704 0.295 #DIV/0! 65 2013OCT21_A_SolvA_22 2.27 0.828 0.425 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.24 355.336 403.892 #DIV/0! 122.56 114.01 67 2013OCT21_A_GreenbeltPk_2 2.24 282.897 77.15 #DIV/0! 97.58 90.77 68 2013OCT21_A_GreenbeltPk_3 2.24 447.412 335.651 #DIV/0! 154.32 143.55 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 2.32 13.179 0.64 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.25 729.661 278.838 #DIV/0! 251.68 234.11 72 2013OCT21_A_PowderMillRd_2 2.24 292.874 484.595 #DIV/0! 101.02 93.97 73 2013OCT21_A_PowderMillRd_3 2.24 376.289 209.18 #DIV/0! 129.79 120.73 74 2013OCT21_A_SolvA_25 2.25 27.925 0.73 #DIV/0! 75 2013OCT21_A_SolvA_26 2.26 2.157 0.579 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.24 427.124 263.478 #DIV/0! 147.33 137.04 77 2013OCT21_A_SolvA_27 2.19 1.222 #DIV/0! 78 2013OCT21_A_SolvA_28 2.29 0.922 #DIV/0! 79 2013OCT21_A_ResearchRd_1 178.689 #DIV/0! 0.00 0.00 80 2013OCT21_A_ResearchRd_2 2.23 98.914 483.661 #DIV/0! 34.12 31.74 81 2013OCT21_A_ResearchRd_3 2.21 73.68 346.495 #DIV/0! 25.41 23.64 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.24 764.754 339.46 #DIV/0! 263.78 245.36 85 2013OCT21_A_Skateboard_2 2.24 663.673 400.386 #DIV/0! 228.92 212.93 86 2013OCT21_A_Skateboard_3 2.24 748.607 146.796 #DIV/0! 258.21 240.18 87 2013OCT21_A_SolvA_31 2.26 9.305 0.442 #DIV/0! 88 2013OCT21_A_SolvA_32 2.19 0.968 0.293 #DIV/0! 89 2013OCT21_A_SligoCreek_1 2.23 1093.953 223.282 #DIV/0! 377.33 350.99 90 2013OCT21_A_SligoCreek_2 2.24 1327.533 333.444 #DIV/0! 457.90 425.93 91 2013OCT21_A_SligoCreek_3 2.24 1163.763 90.077 #DIV/0! 401.41 373.38 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 2.27 2.375 1.215 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.24 597.876 #DIV/0! 206.22 191.82 95 2013OCT21_A_RiverdaleRd_2 2.24 452.243 25.569 #DIV/0! 155.99 145.10 250 96 2013OCT21_A_RiverdaleRd_3 2.24 394.609 420.904 #DIV/0! 136.11 126.61 97 2013OCT21_A_SolvA_35 2.22 0.842 #DIV/0! 98 2013OCT21_A_SolvA_36 2.32 1.178 0.493 #DIV/0! 99 2013OCT21_A_SolvA_37 2.21 18.902 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 2.21 1.101 325.418 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 81.56 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 #DIV/0! 104 2013OCT21_A_1_Std_2 1 #DIV/0! 105 2013OCT21_A_5_Std_2 5 2.23 22.206 64.761 #DIV/0! 106 2013OCT21_A_10_Std_2 10 2.23 72.543 275.265 #DIV/0! 107 2013OCT21_A_25_Std_2 25 2.23 236.023 177.545 #DIV/0! 108 2013OCT21_A_50_Std_2 50 2.24 1084.593 #DIV/0! 109 2013OCT21_A_100_Std_2 100 2.24 1880.1 351.59 #DIV/0! 110 2013OCT21_A_200_Stds_2 200 2.24 3633.302 294.725 #DIV/0! 111 2013OCT21_A_SolvA_38 2.17 43.45 0.715 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 2.3 7.189 0.627 #DIV/0! 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 2.23 0.019 #DIV/0! 116 2013OCT21_A_SolvA_42 2.29 42.666 0.401 #VALUE! Compound 26: Sucralose-d6 yes=1,no=0 Ident'd? Name Std. Conc RT Area 1? Area 2? Area #DIV/0! 1 2013OCT21_SolvA_1 2.19 2.377 #DIV/0! 2 2013OCT21_A_Lab Blk 2.23 2329.274 #DIV/0! 2353 Avg 3 2013OCT21_A_Travel Blk 2.22 2649.739 #DIV/0! 18% RSD 4 2013OCT21_A_0-01_Std 0.01 2.22 2683.007 #DIV/0! 5 2013OCT21_A_0-05_Std 0.05 2.22 2846.648 #DIV/0! 6 2013OCT21_A_0-1_Std 0.1 2.23 2754.531 #DIV/0! 7 2013OCT21_A_0-5_Std 0.5 2.23 3184.546 #DIV/0! 8 2013OCT21_A_1_Std 1 2.23 2264.291 #DIV/0! 9 2013OCT21_A_5_Std 5 2.22 3021.443 #DIV/0! 10 2013OCT21_A_10_Std 10 2.22 2674.575 #DIV/0! 11 2013OCT21_A_25_Std 25 2.22 2792.942 #DIV/0! 12 2013OCT21_A_50_Std 50 2.22 2840.874 #DIV/0! 13 2013OCT21_A_100_Std 100 2.22 3333.843 #DIV/0! 14 2013OCT21_A_200_Stds 200 2.22 2014.448 #DIV/0! 15 2013OCT21_A_SolvA_2 #DIV/0! 16 2013OCT21_A_Surrogate_1 2.32 0.295 #DIV/0! 17 2013OCT21_A_SolvA_3 #DIV/0! 18 2013OCT21_A_SolvA_4 #DIV/0! 19 2013OCT21_A_MM_0 2.22 2109.155 #DIV/0! 20 2013OCT21_A_MM_1 2.22 3231.193 #DIV/0! 21 2013OCT21_A_MM_5 2.23 3251.303 #DIV/0! 22 2013OCT21_A_MM_10 2.23 2399.296 #DIV/0! 251 23 2013OCT21_A_MM_25 2.22 2407.652 #DIV/0! 24 2013OCT21_A_MM_50 2.23 1797.519 #DIV/0! 25 2013OCT21_A_MM_100 2.23 2749.147 #DIV/0! 26 2013OCT21_A_SolvA_5 2.27 0.744 #DIV/0! 27 2013OCT21_A_SolvA_6 2.24 0.226 #DIV/0! 28 2013OCT21_A_BerwynRd_1 2.24 2174.993 #DIV/0! 29 2013OCT21_A_BerwynRd_2 2.22 2251.781 #DIV/0! 30 2013OCT21_A_BerwynRd_3 2.22 2333.839 #DIV/0! 31 2013OCT21_A_SolvA_7 2.29 1.136 #DIV/0! 32 2013OCT21_A_SolvA_8 2.17 7.816 #DIV/0! 33 2013OCT21_A_UMD_1 2.22 2024.318 #DIV/0! 34 2013OCT21_A_UMD_2 2.23 2744.286 #DIV/0! 35 2013OCT21_A_UMD_3 2.22 2634.369 #DIV/0! 36 2013OCT21_A_SolvA_9 #DIV/0! 37 2013OCT21_A_SolvA_10 #DIV/0! 38 2013OCT21_A_Arboretum1_1 2.22 2623.378 #DIV/0! 39 2013OCT21_A_Arboretum1_2 2.23 2398.812 #DIV/0! 40 2013OCT21_A_Arboretum1_3 2.22 2041.251 #DIV/0! 41 2013OCT21_A_SolvA_11 2.24 0.744 #DIV/0! 42 2013OCT21_A_SolvA_12 2.31 0.445 #DIV/0! 43 2013OCT21_A_Arboretum2_1 2.23 1984.819 #DIV/0! 44 2013OCT21_A_Arboretum2_2 2.23 2822.95 #DIV/0! 45 2013OCT21_A_Arboretum2_3 2.23 2179.32 #DIV/0! 46 2013OCT21_A_SolvA_13 #DIV/0! 47 2013OCT21_A_SolvA_14 2.32 0.304 #DIV/0! 48 2013OCT21_A_QC_Std25_1 2.22 2741 #DIV/0! 49 2013OCT21_A_SolvA_15 #DIV/0! 50 2013OCT21_A_SolvA_16 2.15 0.185 #DIV/0! 51 2013OCT21_A_NorthDr1_1 2.22 2479.567 #DIV/0! 52 2013OCT21_A_NorthDr1_2 2.22 2612.102 #DIV/0! 53 2013OCT21_A_NorthDr1_3 2.22 2825.502 #DIV/0! 54 2013OCT21_A_SolvA_17 #DIV/0! 55 2013OCT21_A_SolvA_18 2.3 49.219 #DIV/0! 56 2013OCT21_A_NorthDr2_1 2.23 2689.003 #DIV/0! 57 2013OCT21_A_NorthDr2_2 2.22 2514.505 #DIV/0! 58 2013OCT21_A_NorthDr2_3 2.22 2899.536 #DIV/0! 59 2013OCT21_A_SolvA_19 #DIV/0! 60 2013OCT21_A_SolvA_20 2.13 0.072 #DIV/0! 61 2013OCT21_A_AnacostiaPk_1 2.22 2073.153 #DIV/0! 62 2013OCT21_A_AnacostiaPk_2 2.22 1995.176 #DIV/0! 63 2013OCT21_A_AnacostiaPk_3 2.23 2543.218 #DIV/0! 64 2013OCT21_A_SolvA_21 2.24 2.378 #DIV/0! 65 2013OCT21_A_SolvA_22 #DIV/0! 66 2013OCT21_A_GreenbeltPk_1 2.23 2662.719 #DIV/0! 67 2013OCT21_A_GreenbeltPk_2 2.24 1981.668 #DIV/0! 252 68 2013OCT21_A_GreenbeltPk_3 2.22 2332.865 #DIV/0! 69 2013OCT21_A_SolvA_23 #DIV/0! 70 2013OCT21_A_SolvA_24 2.33 0.87 #DIV/0! 71 2013OCT21_A_PowderMillRd_1 2.23 2520.19 #DIV/0! 72 2013OCT21_A_PowderMillRd_2 2.23 2298.277 #DIV/0! 73 2013OCT21_A_PowderMillRd_3 2.22 2296.444 #DIV/0! 74 2013OCT21_A_SolvA_25 2.27 0.274 #DIV/0! 75 2013OCT21_A_SolvA_26 2.18 0.715 #DIV/0! 76 2013OCT21_A_QC_Std25_2 2.23 2289.259 #DIV/0! 77 2013OCT21_A_SolvA_27 2.29 0.61 #DIV/0! 78 2013OCT21_A_SolvA_28 2.3 0.464 #DIV/0! 79 2013OCT21_A_ResearchRd_1 2.23 2826.839 #DIV/0! 80 2013OCT21_A_ResearchRd_2 2.23 2418.483 #DIV/0! 81 2013OCT21_A_ResearchRd_3 2.23 2307.798 #DIV/0! 82 2013OCT21_A_SolvA_29 #DIV/0! 83 2013OCT21_A_SolvA_30 2.22 0.736 #DIV/0! 84 2013OCT21_A_Skateboard_1 2.22 1796.001 #DIV/0! 85 2013OCT21_A_Skateboard_2 2.22 2101.094 #DIV/0! 86 2013OCT21_A_Skateboard_3 2.23 2054.97 #DIV/0! 87 2013OCT21_A_SolvA_31 #DIV/0! 88 2013OCT21_A_SolvA_32 2.28 17.066 #DIV/0! 89 2013OCT21_A_SligoCreek_1 2.23 2064.381 #DIV/0! 90 2013OCT21_A_SligoCreek_2 2.23 1979.129 #DIV/0! 91 2013OCT21_A_SligoCreek_3 2.22 1559.837 #DIV/0! 92 2013OCT21_A_SolvA_33 #DIV/0! 93 2013OCT21_A_SolvA_34 #DIV/0! 94 2013OCT21_A_RiverdaleRd_1 2.22 3314.723 #DIV/0! 95 2013OCT21_A_RiverdaleRd_2 2.22 2449.115 #DIV/0! 96 2013OCT21_A_RiverdaleRd_3 2.22 1576.127 #DIV/0! 97 2013OCT21_A_SolvA_35 2.25 17.377 #DIV/0! 98 2013OCT21_A_SolvA_36 2.25 2.578 #DIV/0! 99 2013OCT21_A_SolvA_37 2.24 1.99 #DIV/0! 100 2013OCT21_A_0-01_Std_2 0.01 2.22 1857.189 #DIV/0! 101 2013OCT21_A_0-05_Std_2 0.05 2.22 2156.077 #DIV/0! 102 2013OCT21_A_0-1_Std_2 0.1 2.22 1587.181 #DIV/0! 103 2013OCT21_A_0-5_Std_2 0.5 2.22 1855.626 #DIV/0! 104 2013OCT21_A_1_Std_2 1 2.22 1980.704 #DIV/0! 105 2013OCT21_A_5_Std_2 5 2.22 1979.156 #DIV/0! 106 2013OCT21_A_10_Std_2 10 2.22 2174.564 #DIV/0! 107 2013OCT21_A_25_Std_2 25 2.22 2017.925 #DIV/0! 108 2013OCT21_A_50_Std_2 50 2.22 1968.658 #DIV/0! 109 2013OCT21_A_100_Std_2 100 2.23 1666.181 #DIV/0! 110 2013OCT21_A_200_Stds_2 200 2.23 1882.096 #DIV/0! 111 2013OCT21_A_SolvA_38 #DIV/0! 112 2013OCT21_A_Surrogate_2 #DIV/0! 113 2013OCT21_A_SolvA_39 2.17 0.799 #DIV/0! 253 114 2013OCT21_A_SolvA_40 #DIV/0! 115 2013OCT21_A_SolvA_41 #DIV/0! 116 2013OCT21_A_SolvA_42 2.27 0.335 #VALUE! 254 References Aga, D., Thurman, E., Yockel, M., Zimmerman, L., & Williams, T. 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